Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions

Indoxacarb is a broad-spectrum insecticide and widely used in agriculture. The dissipations and residues of indoxacarb were researched at three different field sites in Beijing, Hunan, and Zhejiang provinces in China. Analytical methods for determining the residue of indoxacarb in paddy water, paddy soil, rice straw, rice hull, and brown rice were described. Indoxacarb residues were extracted from samples, cleaned up by solid phase extraction, and determined by high-performance liquid chromatography coupled with tandem mass spectrometry in the selected ion monitoring mode. The recoveries in paddy water, paddy soil, rice straw, rice hull, and brown rice matrices at three spiking levels ranged from 79.7% to 98.3%, respectively. The field and environmental conditions would affect the dissipations and residues of indoxacarb. The time to dissipate 50% of indoxacarb in paddy water, paddy soil, and rice straw was less than 9 days. The terminal residues obtained from Beijing at preharvest interval of 14 and 21 days were higher than the maximum limit of European Union. Therefore, a dosage of 24 g a. i. ha−1 at 28 days preharvest interval with 3 spraying times was recommended. Such accumulation of measured data is necessary to provide guidance for the proper and safe use of this pesticide.

Uptake and Dissipation of Carbofuran and Its Metabolite in Chinese Kale and Brinjal Cultivated Under Humid Tropic Climate

Carbofuran is an insecticide with a broad spectrum of activity and is relatively cheap. It is banned in many countries in the world; however, it remains widely used in Asia, Australia, and South America. Carbofuran is commonly used in vegetable farming in Malaysia and it is a legally registered pesticide. This study reports the uptake and dissipation of carbofuran and 3-ketocarbofuran in Chinese kale and brinjal under humid tropic field conditions. The residue profile in plants demonstrated an increase to a maximum, followed by a consistent reduction to a level below the limit of determination (<0.01 mg/kg) over the experimental period. The maximum residue concentration was attained on Day 3 for kale (1.16 mg/kg fresh weight) and Day 7 for brinjal (0.06 mg/kg fresh weight) after carbofuran application. In order to comply with the maximum residue level (MRL) of 0.01 mg/kg, the preharvest interval for kale and brinjal were suggested at 23 and 28 days, respectively. The preharvest interval indicates that carbofuran is not recommended for Chinese kale but it is acceptable for brinjal. The average half-life of carbofuran in soil is 1.24 days, shorter than the literature values reported based on temperate condition, indicating accelerated dissipation under tropical climate. The estimated half-life of carbofuran in leaves was shorter than that in fruits with kale leaves reported at 2.54 days whilst brinjal leaves and fruits recorded at 3.22 and 10.33 days, respectively.

Residual behaviour of imidacloprid in the country bean growing soil

The assessment of residual behavior of imidacloprid (Admire 20SL) in the soil of country bean agroecosystem and its risk assessment for consumption was studied. QuEChERS method was used for the extraction and clean-up of samples and the residues of imidacloprid was estimated using Gas Chromatography. The dissipation studies in the soil system were carried out by application of imidacloprid at five different dosages i.e. 100, 200, 300, 400, and 500 g a.i. ha-1. Average initial deposits of imidacloprid were found to be 0.99, 1.33, 1.62, 1.83 and 2.20 mg.kg-1. The residues reached below determination limit (BDL) of 0.01 mg kg-1 in 9 days for recommended dose and 12 days for remaining higher dosages. Half-life (T1/2)) of imidacloprid in the soil was observed to be 1.88, 1.74, 1.73, 1.56 and 1.52 days for 100, 200, 300, 400, and 500 g a.i. ha-1, respectively. The chemodynamics study of imidacloprid spray indicated that only 27.20 -28.40% sprays were deposited to the target site (plant canopy) and 71.60-72.80% were lost to non-target site such as soil and air. The drift of imidacloprid to soil (39.47-40.20%) was higher than the air (32.13-32.60%). Based on degradation pattern and maximum, the recommended preharvest interval (PHI) might be eight 9 days and a waiting period of two days might be suggested for reapplication of the imidacloprid in country bean agroecosystem. Bangladesh J. Agril. Res. 44(1): 89-101, March 2019

Determination of Residues of Diazinon and Chlorpyrifos in Lavender and Rosemary Leaves by Gas Chromatography

A sensitive gas chromatographic (GC) GC method has been developed for the determination of diazinon and chlorpyrifos residues in lavender and rosemary leaves. The developed method consists of blending weighed samples of chopped leaves with sodium sulfate as the dehydrating agent, extraction with ethyl acetate, filtration, evaporation with a rotary evaporator, and, finally, capillary GC determination of the pesticides. The recoveries of the method were greater than 90%, and the LOQ was less than 0.1 µg/mL. The method was applied to determine the rate of disappearance of diazinon and chlorpyrifos from lavender and rosemary leaves pretreated with the studied pesticides. The half-life values (t1/2) of diazinon were found to be 5.93 and 6.35 days for lavender and rosemary leaves, respectively, whereas the t1/2 values of chlorpyrifos were calculated to be 7.86 and 9.52 days for lavender and rosemary leaves, respectively. The safe harvest interval (preharvest interval; PHI) was suggested to be after 21 and 24 days for diazinon and chlorpyrifos, respectively. The PHI refers to the amount of time that must lapse (in days) after a pesticide application before a crop can be cut.

Reduced Metribuzin Preharvest Interval on Potato Yield and Tuber Quality

Metribuzin has a 60-d preharvest interval (PHI) in potato, which limits utility of metribuzin POST in potato. In certain years, the potato may not fully cover the area between the potato rows. This allows for late-season weed emergence and subsequent yield reduction through direct competition or harvest interference. Field experiments were conducted in 2011 at Castle Hayne, NC; Freeville, NY; Hasting, FL; and Plymouth, NC to determine the effect of a 30-d PHI on potato crop tolerance. The cultivars planted were ‘Superior' and ‘Yukon Gold' in Castle Hayne and Plymouth, ‘Castille' and Yukon Gold in Freeville, and ‘Atlantic' in Hastings. Treatments included metribuzin at 278 g ai ha−1PRE, 30, and 60 d before harvest (DBH), and metribuzin at 556 g ha−1at 30 and 60 DBH. Split application treatments included metribuzin at 556 g ha−1at PRE followed by metribuzin at 556 g ha−130 or 60 DBH and metribuzin at 842 g ha−1PRE followed by metribuzin at 278 g ha−1at 30 or 60 DBH. Potato injury was ≤ 8% at all locations, and injury was transient. There were no differences observed between metribuzin rate or application date for individual potato grades or total yield. Reducing the PHI in potato to 30 d would have no effect on yield and would provide a longer period for controlling broadleaf weeds.

Dissipation and Residues of Mandipropamid in Grape Using QuEChERS Methodology and HPLC-DAD

The HPLC method for determination of mandipropamid residues and its dissipation in grape was investigated. The mean recoveries of the analytical method were 98–102%. The samples were collected within 2 weeks after pesticide application, and the pesticide residues were extracted by an optimized QuEChERS method. Mandipropamid dissipated rapidly with half-life 2.20 days in grape. According to maximum residue limit (MRL) the preharvest interval (PHI) of mandipropamid on grape was 4 days, after the last treatment.

Peanut (Arachis hypogaea L.) Response to Lactofen at Various Postemergence Timings1

Field experiments were conducted at nine locations in Texas and Georgia in 2005 and 2006 to evaluate peanut tolerance to lactofen. Lactofen at 220 g ai/ha plus crop oil concentrate was applied to peanut at 6 leaf (lf), 6 lf followed by (fb) 15 days after the initial treatment (DAIT), 15 DAIT alone, 6 lf fb 30 DAIT, 30 DAIT alone, 6 lf fb 45 DAIT, 45 DAIT alone, 6 lf fb 60 DAIT, and 60 DAIT alone in weed-free plots. Lactofen caused visible leaf bronzing at all locations. Yield loss was observed when applications were made 45 DAIT, a timing that would correspond to plants in the R5 (beginning seed) to R6 (full seed) stage of growth. At all locations except the Texas High Plains, this application timing was within the 90 d preharvest interval. Growers who apply lactofen early in the peanut growing season to small weeds should have confidence that yields will not be negatively impacted despite dramatic above-ground injury symptoms; however, applications made later in the season, during seed fill, may adversely affect yield.

Reduced Midseason Pesticide Program for Control of Scab and Plum Curculio in Peach

Risks to peach production from scab (caused by Cladosporium carpophilum) and plum curculio (Conotrachelus nenuphar), two key pests in the southeastern United States, are high until 2 months past petal fall and then decreases during midseason. This suggests that reduced-input pesticide strategies may effectively control both pests during the latter period. In this study, we evaluated midseason pesticide applications according to an alternate-row middle (ARM) spray program in which sprays were applied only to every other tree row while reducing tractor speed and keeping application intervals unchanged relative to conventional spraying of both sides of the trees. In a 2-year trial in a research orchard, conventional sprays of fungicide (primarily sulfur) and insecticide (primarily phosmet) were applied at 10- to 14-day intervals until first cover, followed by continued conventional sprays of fungicide and insecticide (standard), conventional sprays of one pesticide together with ARM sprays of the other pesticide, or combined ARM sprays of both pesticides. Schedules with midseason ARM sprays of both pesticides also were evaluated in two commercial orchards in 2 years. In all experiments, plots receiving combined ARM sprays were equivalent to the standard in fruit quality and control of scab and plum curculio. Combined ARM spraying resulted in lower environmental nontarget effects (as estimated by the Environmental Impact Quotient) and reduced application time by 25 to 33% for each midseason spray and 12.5 to 18.5% for the entire period from petal fall to the preharvest interval.