Studies on graft polymerization onto glass fibers. II. Graft copolymerization of glass fiber having pendent mercaptan groups and its application

1982 ◽  
Vol 27 (12) ◽  
pp. 4849-4860 ◽  
Author(s):  
Takao Fujisawa ◽  
Masahiro Kobayashi ◽  
Koshiro Hashimoto ◽  
Ryutoku Yosomiya
Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2455
Author(s):  
Jiayuan He ◽  
Weizhen Chen ◽  
Boshan Zhang ◽  
Jiangjiang Yu ◽  
Hang Liu

Due to the sharp and corrosion-prone features of steel fibers, there is a demand for ultra-high-performance concrete (UHPC) reinforced with nonmetallic fibers. In this paper, glass fiber (GF) and the high-performance polypropylene (HPP) fiber were selected to prepare UHPC, and the effects of different fibers on the compressive, tensile and bending properties of UHPC were investigated, experimentally and numerically. Then, the damage evolution of UHPC was further studied numerically, adopting the concrete damaged plasticity (CDP) model. The difference between the simulation values and experimental values was within 5.0%, verifying the reliability of the numerical model. The results indicate that 2.0% fiber content in UHPC provides better mechanical properties. In addition, the glass fiber was more significant in strengthening the effect. Compared with HPP-UHPC, the compressive, tensile and flexural strength of GF-UHPC increased by about 20%, 30% and 40%, respectively. However, the flexural toughness indexes I5, I10 and I20 of HPP-UHPC were about 1.2, 2.0 and 3.8 times those of GF-UHPC, respectively, showing that the toughening effect of the HPP fiber is better.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2250
Author(s):  
Mohammad Amjadi ◽  
Ali Fatemi

Short glass fiber-reinforced (SGFR) thermoplastics are used in many industries manufactured by injection molding which is the most common technique for polymeric parts production. Glass fibers are commonly used as the reinforced material with thermoplastics and injection molding. In this paper, a critical plane-based fatigue damage model is proposed for tension–tension or tension–compression fatigue life prediction of SGFR thermoplastics considering fiber orientation and mean stress effects. Temperature and frequency effects were also included by applying the proposed damage model into a general fatigue model. Model predictions are presented and discussed by comparing with the experimental data from the literature.


Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2552 ◽  
Author(s):  
Uwe Gohs ◽  
Michael Mueller ◽  
Carsten Zschech ◽  
Serge Zhandarov

Continuous glass fiber-reinforced polypropylene composites produced by using hybrid yarns show reduced fiber-to-matrix adhesion in comparison to their thermosetting counterparts. Their consolidation involves no curing, and the chemical reactions are limited to the glass fiber surface, the silane coupling agent, and the maleic anhydride-grafted polypropylene. This paper investigates the impact of electron beam crosslinkable toughened polypropylene, alkylene-functionalized single glass fibers, and electron-induced grafting and crosslinking on the local interfacial shear strength and critical energy release rate in single glass fiber polypropylene model microcomposites. A systematic comparison of non-, amino-, alkyl-, and alkylene-functionalized single fibers in virgin, crosslinkable toughened and electron beam crosslinked toughened polypropylene was done in order to study their influence on the local interfacial strength parameters. In comparison to amino-functionalized single glass fibers in polypropylene/maleic anhydride-grafted polypropylene, an enhanced local interfacial shear strength (+20%) and critical energy release rate (+80%) were observed for alkylene-functionalized single glass fibers in electron beam crosslinked toughened polypropylene.


1997 ◽  
Vol 12 (4) ◽  
pp. 1091-1101 ◽  
Author(s):  
Seunggu Kang ◽  
Hongy Lin ◽  
Delbert E. Day ◽  
James O. Stoffer

The dependence of the optical and mechanical properties of optically transparent polymethyl methacrylate (PMMA) composites on the annealing temperature of BK10 glass fibers was investigated. Annealing was used to modify the refractive index (R.I.) of the glass fiber so that it would more closely match that of PMMA. Annealing increased the refractive index of the fibers and narrowed the distribution of refractive index of the fibers, but lowered their mechanical strength so the mechanical properties of composites reinforced with annealed fibers were not as good as for composites containing as-pulled (chilled) glass fibers. The refractive index of as-pulled 17.1 μm diameter fibers (R.I. = 1.4907) increased to 1.4918 and 1.4948 after annealing at 350 °C to 500 °C for 1 h or 0.5 h, respectively. The refractive index of glass fibers annealed at 400 °C/1 h best matched that of PMMA at 589.3 nm and 25 °C, so the composite reinforced with those fibers had the highest optical transmission. Because annealed glass fibers had a more uniform refractive index than unannealed fibers, the composites made with annealed fibers had a higher optical transmission. The mechanical strength of annealed fiber/PMMA composites decreased as the fiber annealing temperature increased. A composite containing fibers annealed at 450 °C/1 h had a tensile strength 26% lower than that of a composite made with as-pulled fibers, but 73% higher than that for unreinforced PMMA. This decrease was avoided by treating annealed fibers with HF. Composites made with annealed and HF (10 vol. %)-treated (for 30 s) glass fibers had a tensile strength (∼200 MPa) equivalent to that of the composites made with as-pulled fibers. However, as the treatment time in HF increased, the tensile strength of the composites decreased because of a significant reduction in diameter of the glass fiber which reduced the volume percent fiber in the composite.


Author(s):  
A. B. Baranov ◽  
T. I. Andreeva ◽  
I. D. Simonov-Emelʼyanov ◽  
O. E. Peksimov

In the course of this study, compositions and designed structures for the polysulfone (PSF) and short glass fibers systems were calculated. Additionally, disperse-filled polymer composite materials (DFPCM) based on PSF-190 were classified in accordance with their respective structures, and the optimal amount of glass fiber (13.5–18.5 vol %) was determined. This article describes the production of DFPCM using PSF and a short glass fiber with a twin-screw extruder (Labtech Engineering Company LTD, model Scientific FIC 20-40). Furthermore, optimal mixing parameters for the creation of composites wherein the glass fiber length exceeds the critical length (lcr) were established. The critical length was calculated, and the curves for fiber size distribution of polysulfone composites were depicted, and a difference in fiber concentration between the dispenser and the extrusion head (up to ~10–15%) was found when the fiber content was at 18–25 vol %. For the first time, optimal parameters (which pertain to medium-filled dispersions) for the structure of DFPCM based on PSF and short glass fiber are able to be demonstrated. 


2014 ◽  
Vol 11 (2) ◽  
pp. 540-546
Author(s):  
Baghdad Science Journal

In this research a study of the effect of quality, sequential and directional layers for three types of fibers are:(Kevlar fibers-49 woven roving and E- glass fiber woven roving and random) on the fatigue property using epoxy as matrix. The test specimens were prepared by hand lay-up method the epoxy resin used as a matrix type (Quick mast 105) in prepared material composit . Sinusoidal wave which is formed of variable stress amplitudes at 15 Hz cycles was employed in the fatigue test ( 10 mm )and (15mm) value 0f deflection arrival to numbers of cycle failure limit, by rotary bending method by ( S-N) curves this curves has been determined ( life , limit and fatigue strength) of composite . The results show us the reinforcement has important act to increased resistance to the fatigue compared with specimens have non reinforcement this side the specimens reinforcement of glass fiber have resistance to fatigue and fatigue life better than the specimens reinforcement of Kevlar fiber . According to hybrid composite sample fatigue test results showed that the sample which reinforced (Kevlar - regular glass – Kevlar) has a best results which showed stress carrying the most powerful and longer fatigue life with more than (1.3 ×10 6) cycle from other hybrids , while the sample with the sample with three Kevlar reinforced layers have less resistant to fatigue


2019 ◽  
Vol 24 ◽  
pp. 1-7
Author(s):  
Md. Naimul Islam ◽  
Harun Ar-Rashid ◽  
Farhana Islam ◽  
Nanda Karmaker ◽  
Farjana A. Koly ◽  
...  

E-glass fiber mat reinforced Unsaturated Polyester Resin (UPR)-based composites were fabricated by conventional hand lay-up technique. The fiber content was varied from 5 to 50% by weight. Mechanical properties (tensile and bending) of the fabricated composites were investigated. The tensile strength (TS) of the 5% and 50% fiber reinforced composites was 32 MPa and 72 MPa, respectively. Similarly, tensile modulus, bending strength and bending modulus of the composites were increased by the increase of fiber loading. Interfacial properties of the composites were investigated by scanning electron microscopy (SEM) and the results revealed that the interfacial bond between fiber and matrix was excellent. Keywords: Unsaturated Polyester Resin, Mechanical Properties, E-glass Fibers, Composites, Polymer.


Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2064 ◽  
Author(s):  
Stanisław Kuciel ◽  
Patrycja Bazan ◽  
Aneta Liber-Kneć ◽  
Aneta Gądek-Moszczak

The paper evaluated the possibility of potential reinforcing of poly(oxymethylene) (POM) by glass fiber and the influence of fiberglass addition on mechanical properties under dynamic load. Four types of composites with glass fiber and another four with carbon fiber were produced. The fiber content ranged from 5% to 40% by weight. In the experimental part, the basic mechanical and fatigue properties of POM-based composites were determined. The impact of water absorption was also investigated. The influence of fiber geometry on the mechanical behavior of fiber-reinforced composites of various diameters was determined. To refer to the effects of reinforcement and determine the features of the structure scanning electron microscopy images were taken. The results showed that the addition of up to 10 wt %. fiberglass increases the tensile properties and impact strength more than twice, the ability to absorb energy also increases in relation to neat poly(oxymethylene). Fiber geometry also has a significant impact on the mechanical properties. The study of the mechanical properties at dynamic loads over time suggests that composites filled with a smaller fiber diameter have better fatigue properties.


Blood ◽  
1981 ◽  
Vol 57 (6) ◽  
pp. 1119-1124 ◽  
Author(s):  
F Kodama ◽  
A Maruta ◽  
S Motomura ◽  
K Fukushima ◽  
M Umeda

Abstract A new method for hemopoietic colony formation that allows the preparation of permanent slides and medium changes during the incubation period was developed in vitro. Bone marrow cells from mice were spread over glass-fiber filters, which were placed on agar medium and cultivated for 7 days. Hemopoietic colonies appeared on the glass- fibers filters. The glass-fiber filters with colonies were stained by a peroxidase and nonspecific esterase double-staining method and mounted as permanent slides. Each colony could be clearly identified and easily counted after the staining. The dose-response relationship between the number of seeded cells and the colony counts was a linear one, with the line very nearly passing through the origin on extrapolation. The colonies were classified into three types by the staining results: granuloid type, monocyte-macrophage type, and mixed type, the last containing both granuloid and monocyte-macrophage cells. Medium change during the incubation period was attempted in the experiment for phagocytic activity of the cultured cells and proved to be useful. This system appears to be useful and convenient in the study of hemopoietic colony formation.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3929 ◽  
Author(s):  
Amirmohammad Rahimizadeh ◽  
Jordan Kalman ◽  
Rodolphe Henri ◽  
Kazem Fayazbakhsh ◽  
Larry Lessard

This research validates the viability of a recycling and reusing process for end-of-life glass fiber reinforced wind turbine blades. Short glass fibers from scrap turbine blades are reclaimed and mixed with polylactic acid (PLA) through a double extrusion process to produce composite feedstock with recycled glass fibers for fused filament fabrication (FFF) 3D printing. Reinforced filaments with different fiber contents, as high as 25% by weight, are extruded and used to 3D print tensile specimens per ASTM D638-14. For 25 wt% reinforcement, the samples showed up to 74% increase in specific stiffness compared to pure PLA samples, while there was a reduction of 42% and 65% in specific tensile strength and failure strain, respectively. To capture the level of impregnation of the non-pyrolyzed recycled fibers and PLA, samples made from reinforced filaments with virgin and recycled fibers are fabricated and assessed in terms of mechanical properties and interface. For the composite specimens out of reinforced PLA with recycled glass fibers, it was found that the specific modulus and tensile strength are respectively 18% and 19% higher than those of samples reinforced with virgin glass fibers. The cause for this observation is mainly attributed to the fact that the surface of recycled fibers is partially covered with epoxy particles, a phenomenon that allows for favorable interactions between the molecules of PLA and epoxy, thus improving the interface bonding between the fibers and PLA.


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