scholarly journals Lateral variations in the Unit 7–8 boundary zone of the Rum Eastern Layered Intrusion, NW Scotland: implications for the origin and timing of Cr-spinel seam formation

2020 ◽  
Vol 175 (9) ◽  
Author(s):  
Felix E. D. Kaufmann ◽  
Brian O’Driscoll ◽  
Lutz Hecht
Keyword(s):  
Structural Characteristics ◽  
Layered Intrusion ◽  
Boundary Zone ◽  
Crystal Mush ◽  
Multi Stage ◽  
Close Proximity ◽  
Melt Infiltration ◽  
Lateral Variations ◽  
Magma Replenishment

Abstract The Rum Layered Suite, NW Scotland, hosts Cr-spinel seams at the bases of peridotite–troctolite macro-rhythmic units in the eastern portion of the intrusion. Here, we present detailed field observations together with microstructural and mineral chemical analyses for the Unit 7–8 Cr-spinel seam and associated cumulates in the Eastern Layered Intrusion. Detailed mapping and sampling reveal significant lateral variations in the structural characteristics and mineral compositions of the Unit 7–8 boundary zone rocks. Although the Cr-spinel seam is laterally continuous over ~ 3 km, it is absent towards the centre and the margins of the intrusion. The compositional characteristics of Cr-spinel and plagioclase vary systematically along strike, exhibiting a chemical evolution towards more differentiated compositions with increasing distance from the main feeder conduit of the Rum intrusion; the Long Loch Fault. On the basis of our combined datasets, we propose that the upper part of the troctolite, the anorthosite layer underlying the Cr-spinel seam and the seam itself formed during a multi-stage magma replenishment event. The stages can be summarised as follows: (1) peridotite schlieren and anorthosite autoliths formed following melt infiltration and cumulate assimilation in the crystal mush of the Unit 7 troctolite. (2) The anorthosite layer then formed from the Unit 7 troctolite crystal mush by thermal erosion and dissolution due to infiltrating magma. (3) Subsequent dissolution of the anorthosite layer by new replenishing magma led to peritectic in situ crystallisation of the Unit 7–8 Cr-spinel seam, with (4) continued magma input eventually producing the overlying Unit 8 peridotite. In the central part of the Rum Layered Suite, the aforementioned assimilation of the troctolitic footwall formed the anorthosite layer. However, the absence of anorthosite in close proximity to the Long Loch Fault can be explained by enhanced thermochemical erosion close to the feeder zone, and its absence close to the margins of the intrusion, at maximum distance from the Long Loch Fault, may be due to cooling of the magma and loss of erosion potential. In line with other recent studies on PGE-bearing chromitites in layered intrusions, we highlight the importance of multi-stage intrusive magma replenishment to the formation of spatially coupled anorthosite and Cr-spinel seams, as well as the lateral mineral chemical variations observed in the Unit 7–8 boundary zone cumulates.

scholarly journals Linking In Situ Crystallization and Magma Replenishment via Sill Intrusion in the Rum Western Layered Intrusion, NW Scotland

2018 ◽  
Vol 59 (8) ◽  
pp. 1605-1642 ◽  
Author(s):  
Luke N Hepworth ◽  
Brian O’Driscoll ◽  
Ralf Gertisser ◽  
J Stephen Daly ◽  
C Henry Emeleus
Keyword(s):  
Layered Intrusion ◽  
In Situ Crystallization ◽  
Sill Intrusion ◽  
Magma Replenishment

scholarly journals Formation of Bushveld anorthosite by reactive porous flow

2020 ◽  
Vol 176 (1) ◽  
Author(s):  
W. D. Maier ◽  
S.-J. Barnes ◽  
D. Muir ◽  
D. Savard ◽  
Y. Lahaye ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Compositional Data ◽  
Crystal Mush ◽  
Porous Flow ◽  
Scanning Electron

AbstractBushveld anorthosites commonly contain the so-called “mottles” comprising irregular, typically centimetric domains of oikocrystic pyroxene or olivine enclosing small, embayed plagioclase grains. The mottles were traditionally interpreted to result from solidification of trapped intercumulus liquid or via in situ crystallisation at the top of the crystal mush. Here, we present microtextural and compositional data of a mottle to place further constraints on the formation of anorthosite layers. Element maps generated by scanning electron microscopy reveal that plagioclase within and around the mottle has markedly elevated An contents (up to An95) relative to the host anorthosite and is strongly reversely zoned. Other unusual features, some of which were reported previously, include a halo of sub-vertically oriented, acicular phlogopite around the mottle, elevated contents of disseminated sulfides, and relatively evolved yet Ni-rich olivine (Fo71–75, 3000 ppm Ni). These features are interpreted to result from reactive porous flow of hot, acidic fluid enriched in nickel and sulfur through proto norite. The fluids dissolved mafic minerals and leached alkalis from the outer rims of plagioclase grains. Reconnaissance studies suggest that reversed zoning of plagioclase is a common feature in Bushveld norite and anorthosite. This implies that reactive porous flow could have been far more pervasive than currently realised and that Bushveld anorthosite layers formed through recrystallisation of norites.

Vertical igneous layering in the Ewarara layered intrusion, central Australia

1977 ◽  
Vol 114 (5) ◽  
pp. 365-374 ◽  
Author(s):  
A. D. T. Goode
Keyword(s):  
Layered Intrusion ◽  
Multiple Injection ◽  
Crystal Mush ◽  
Flow Differentiation ◽  
Central Australia ◽  
Ultramafic Cumulates ◽  
Inhomogeneous Crystal ◽  
Feeder Zone ◽  
Igneous Layering ◽  
Layered Sequence

SummaryThe Ewarara Intrusion of central Australia contains two vertical fine-banded horizons within a sequence of sub-horizontal ultramafic cumulates. The horizons are arranged in an en échelon pattern adjacent to a steep intrusional contact, and consist of an alternation of two layer types which correspond to the two major lithologies present in the horizontal sequence. The horizons are up to 5 m thick. A number of possible origins, including folding of originally horizontal cumulates, flow differentiation and multiple injection, do not satisfactorily explain the formation of the layering. The most likely origin appears to involve differential viscous flow along the steep contact of an inhomogeneous crystal mush derived from the horizontal layered sequence. This mobilization is related to fresh injections along a feeder zone trending 060µ, the only such zone recognized in the Giles Complex.

A study on the kinetics and thermal properties of polystyrene/diatomite nanocomposites prepared via in situ ATRP

2018 ◽  
Vol 33 (2) ◽  
pp. 180-197 ◽  
Author(s):  
Khezrollah Khezri ◽  
Yousef Fazli
Keyword(s):  
Molecular Weight ◽  
In Situ Polymerization ◽  
Structural Characteristics ◽  
Nitrogen Adsorption ◽  
Linear Increase ◽  
Size Exclusion ◽  
Scanning Calorimetry ◽  
Morphological Studies ◽  
Exclusion Chromatography

Pristine mesoporous diatomite was employed to prepare polystyrene/diatomite composites. Diatomite platelets were used for in situ polymerization of styrene by atom transfer radical polymerization to synthesize tailor-made polystyrene nanocomposites. X-Ray fluorescence spectrometer analysis and thermogravimetric analysis (TGA) were employed for evaluating some inherent properties of pristine diatomite platelets. Nitrogen adsorption/desorption isotherm is applied to examine surface area and structural characteristics of the diatomite platelets. Evaluation of pore size distribution and morphological studies were also performed by scanning and transmission electron microscopy. Conversion and molecular weight determinations were carried out using gas and size exclusion chromatography, respectively. Linear increase of ln ( M0/M) with time for all the samples shows that polymerization proceeds in a living manner. Addition of 3 wt% pristine mesoporous diatomite leads to an increase of conversion from 72% to 89%. Molecular weight of polystyrene chains increases from 11,326 g mol−1 to 14134 g mol−1 with the addition of 3 wt% pristine mesoporous diatomite; however, polydispersity index values increases from 1.13 to 1.38. Increasing thermal stability of the nanocomposites is demonstrated by TGA. Differential scanning calorimetry shows an increase in glass transition temperature from 81.9°C to 87.1°C by adding 3 wt% of mesoporous diatomite platelets.

In-situ preparation of nano MoSi 2 SiC composite by melt infiltration of silicon method

2017 ◽  
Vol 200 ◽  
pp. 287-294 ◽  
Author(s):  
Xiao Li Zhang ◽  
Jian Xu ◽  
Shi Xian Li ◽  
Ji Wei Fan ◽  
Zhi Qiang Jiang ◽  
...  
Keyword(s):  
In Situ Preparation ◽  
Melt Infiltration

scholarly journals Mass and Heat Transfer at Different Heat Exchange Surfaces and Their Suitability for Use in Thermal Desalination Plants

2016 ◽  
Vol 10 (1) ◽  
pp. 74-86 ◽  
Author(s):  
T. Schwarzer ◽  
H.J. Bart
Keyword(s):  
Heat Transfer ◽  
Salt Water ◽  
Structural Characteristics ◽  
Small Scale ◽  
User Friendliness ◽  
Multi Stage ◽  
Water Side ◽  
Thermal Desalination ◽  
Actual Use ◽  
Desalination Plants

A new concept for small scale multi-stage distillation (MSD) desalination plants is presented allowing an installation in remote rural areal due to low maintenance, operating and investment costs. It is based on extensive studies on heat and mass transfer using 6 different condensation / heat transfer surfaces or material combinations. Basically all 6 condensation surfaces except glass are of a sheet metal or an expanded metal (to the evaporation side) in combination to an acid- and heat-resistant foil (on the salt water side). The basic experiments were performed in a "lab scale" unit to determine their thermodynamic and structural characteristics and user-friendliness. After validation in a prototype novel oxidic condensation surfaces (AF) and material combinations are in actual use in the new MSD systems, following the requirements, including a good wetting and condensation behavior and a good heat transfer.

scholarly journals VERIFICAÇÃO DO DESEMPENHO DAS ESTACAS INJETADAS AUTOPERFURANTES EXECUTADAS EM SOLOS ARENOSOS PARA CONSTRUÇÃO DE USINA EÓLICA

2017 ◽  
Vol 13 (2) ◽  
Author(s):  
Rodrigo Cerqueira Rogerio
Keyword(s):  
Structural Characteristics ◽  
Load Capacity ◽  
The Self ◽  
Executive Processes ◽  
Empirical Methods ◽  
Deep Drilling ◽  
Load Tests ◽  
Different Diameters ◽  
Semi Empirical

RESUMO: Apresenta-se neste trabalho a solução adotada para execução das fundações do Parque de Usina Eólica localizado no Ceará, com a utilização das estacas injetadas autoperfurantes, executadas em presença de solos arenosos. No qual consiste em perfurar o solo com altíssima velocidade por rotação e “pull down”, através da injeção simultânea de nata de cimento com medias pressões. Ocasionando na estaca um diâmetro final que pode obter o dobro do bit de perfuração, de acordo com o tipo de solo, gerado pelo efeito do jato da nata de cimento. Detalhando os processos executivos, verificando os aspectos técnicos e operacionais, para melhor compreender as características estruturais deste elemento. De forma a verificar “in situ” o desempenho deste novo tipo de fundação profunda, foram realizadas provas de carga, em estacas com diferentes diâmetros e comprimentos, realizadas em perfis estratigráficos de solos arenosos, para melhor avaliação de sua capacidade de carga. Analisando-se os ensaios das provas de carga interpretados a base da extrapolação da curva carga versus recalque e das previsões da capacidade de carga, obtidas por meio dos métodos semi-empíricos de correlação com ensaios de penetração (SPT), avaliando os padrões de execução desta tipologia de estaca injetada para comunidade geotécnica. ABSTRACT: This paper aims to establish the selected solution to except the foundations of the Wind Energy Park in Ceará (Brazil), with an executive methodology of the self-drilling injection piles framed in loco in Sandy soil. In which the soil drilling is done with the highest speed by rotation and pull down, through the simultaneous injection of grouting with medium pressures. This kind of drilling causes in the pile a final diameter that can get the double bore bit, according to the type of soil, done by the grouting blast. The executive processes are detailed as a whole, and also presenting the pile materials composition, in order to understand the structural characteristics of this element. To verify the performance of this new kind of deep drilling, instrumentations were done: settlement control and load tests in constructions with different structural characteristics, in self-drilling injected piles with different diameters and length, done in stratigraphical sandy, for a better evaluation of its load capacity. Analyzing the essays of load tests interpreted in the basis of curve extrapolation load versus settlement and the previsions of the load capacity, obtained by semi-empirical methods correlating with the penetrations methods (SPT), offering information to the geotechnical community.

scholarly journals Graphene Oxide-Embedded Extracellular Matrix- Derived Hydrogel as a Multiresponsive Platform for 3D Bioprinting Applications

2021 ◽  
Vol 7 (3) ◽  
Author(s):  
Laura Rueda-Gensini ◽  
Julian A Serna ◽  
Javier Cifuentes ◽  
Juan C Cruz ◽  
Carolina Muñoz-Camargo
Keyword(s):  
Graphene Oxide ◽  
Mechanical Stability ◽  
Light Exposure ◽  
Structural Characteristics ◽  
Elastic Response ◽  
Cellular Interaction ◽  
3D Bioprinting ◽  
In Situ Reduction ◽  
Crosslinking Degree

Decellularized extracellular matrices (dECMs) have shown enormous potential for the biofabrication of tissues due to their biomimetic properties that promote enhanced cellular interaction and tissue regeneration. However, biofabrication schemes requiring electrostimulation pose an additional constraint due to the insulating properties of natural materials. Here, we propose a methacryloyl-modified decellularized small intestine submucosa (SISMA) hydrogel, embedded with graphene oxide (GO) nanosheets, for extrusion-based 3D bioprinting applications that require electrostimulation. Methacryloyl biochemicalmodification is performed to enhance the mechanical stability of dECM constructs by mediating photo-crosslinking reactions, and a multistep fabrication scheme is proposed to harness the bioactive and hydrophilic properties of GO and electroconductive properties of reduced GO. For this, GO was initially dispersed in SISMA hydrogels by exploiting its hydrophilicity and protein adsorption capabilities, and in situ reduction was subsequently performed to confer electroconductive abilities. SISMA-GO composite hydrogels were successfully prepared with enhanced structural characteristics, as shown by the higher crosslinking degree and increased elastic response upon blue-light exposure. Moreover, GO was homogeneously dispersed without affecting photocrosslinking reactions and hydrogel shear-thinning properties. Human adipose-derived mesenchymal stem cells were successfully bioprinted in SISMA-GO with high cell viability after 1 week and in situ reduction of GO during this period enhanced the electrical conductivity of these nanostructures. This work demonstrates the potential of SISMA-GO bioinks as bioactive and electroconductive scaffolds for electrostimulation applications in tissue engineering and regenerative medicine.

scholarly journals Multi-Stage Redox Systems Based on Dicationic P-Containing Polycyclic Aromatic Hydrocarbons

2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Organic Radical ◽  
Electrochemical Studies ◽  
Redox Systems ◽  
Redox States ◽  
Multi Stage ◽  
Polycyclic Aromatic ◽  
The Impact

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.

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