Changes in higher heating value and ash content of seaweed during ensiling

This research aimed to determine the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using Fourier transform near infrared spectroscopy as an alternative to bomb calorimetry and thermogravimetry. Bamboo culms used in this study had circumferences ranging from 16 to 40 cm. Model development was performed using partial least squares regression. The higher heating value, volatile matter, fixed carbon and ash content were predicted with coefficients of determination (r2) of 0.92, 0.82, 0.85 and 0.51; root mean square error of prediction (RMSEP) of 122 J g−1, 1.15%, 1.00% and 0.77%; ratio of the standard deviation to standard error of validation (RPD) of 3.66, 2.55, 2.62 and 1.44; and bias of 14.4 J g−1, −0.43%, 0.03% and −0.11%, respectively. This report shows that near infrared spectroscopy is quite successful in predicting the higher heating value, and is usable with screening for the determination of fixed carbon and volatile matter. For ash content, the method is not recommended. The models should be able to predict the properties of bamboo samples which are suitable for achieving higher efficiency for the biomass conversion process.

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Characterization of Refuse Derived Fuel Production from Municipal Solid Waste: The Case Studies in Latvia and Lithuania

Environmental and Climate Technologies ◽

10.2478/rtuect-2020-0090 ◽

2020 ◽

Vol 24 (3) ◽

pp. 112-118

Author(s):

Dace Âriņa ◽

Rūta Bendere ◽

Gintaras Denafas ◽

Jānis Kalnačs ◽

Mait Kriipsalu

Keyword(s):

Municipal Solid Waste ◽

Solid Waste ◽

Calorific Value ◽

Ash Content ◽

Fuel Production ◽

Heating Value ◽

Refuse Derived Fuel ◽

Morphological Composition ◽

The Mean

AbstractThe authors determined the morphological composition of refuse derived fuel (RDF) produced in Latvia and Lithuania by manually sorting. The parameters of RDF (moisture, net calorific value, ash content, carbon, nitrogen, hydrogen, sulphur, chlorine, metals) was determined using the EN standards. Comparing obtained results with data from literature, authors have found that the content of plastic is higher but paper and cardboard is lower than typical values. Results also show that the mean parameters for RDF can be classified with the class codes: Net heating value (3); chlorine (3); mercury (1), and responds to limits stated for 3rd class of solid recovered fuel. It is recommended to separate biological waste at source to lower moisture and ash content and increase heating value for potential fuel production from waste.

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CARACTERIZAÇÃO DE BIOMASSAS PARA A BRIQUETAGEM

FLORESTA ◽

10.5380/rf.v45i4.39700 ◽

2015 ◽

Vol 45 (4) ◽

pp. 713 ◽

Cited By ~ 12

Author(s):

Diego Aleixo Silva ◽

Gabriela Tami Nakashima ◽

João Lúcio Barros ◽

Alessandra Luzia Da Roz ◽

Fabio Minoru Yamaji

Keyword(s):

Particle Size ◽

Moisture Content ◽

Sugarcane Bagasse ◽

Saccharum Officinarum ◽

Ash Content ◽

Heating Value ◽

Pine Sawdust ◽

High Heating Value ◽

Sugarcane Straw ◽

High Heating

O objetivo deste trabalho foi caracterizar a produção de briquetes feita a partir de quatro diferentes biomassas residuais. Foram utilizados os resíduos de serragem de Eucalyptus sp, serragem de Pinus sp, bagaço de cana-de-açúcar (Saccharum officinarum L.) e palha de cana-de-açúcar. Os resíduos foram tratados para que obtivessem 12% de umidade e uma granulometria inferior a 1,70 mm. Foram produzidos 15 briquetes para cada um dos quatro tratamentos. A pressão utilizada foi de 1250 kgf.cm-2 durante 30 segundos. Os briquetes obtiveram densidades que oscilaram 0,88 a 1,11 g.cm-3. Isto representou uma faixa de 5 a 14 vezes a menos de ocupação de volume para uma mesma quantidade de massa. O poder calorifico foi de 19.180 J.kg-1 e 20.315 J.kg-1 para as serragens de eucalipto e pinus respectivamente. Para o bagaço e palha de cana os valores foram de 18.541 J.kg-1 e 15.628 J.kg-1. A palha da cana-de-açúcar apresentou um teor de cinzas de 12%. As expansões dos tratamentos oscilaram 4 a 9% e as resistências mecânicas variaram de 1,215 MPa à 0,270 MPa. Todos os briquetes se mostraram resistentes para um empilhamento superior a 10 m de altura. O procedimento adotado pode ajudar a diminuir o espaço de estocagem e de transporte. AbstractThis research aims to characterize the production of briquettes from four different biomasses. We used residues such as Eucalyptus sp sawdust, Pinus sp sawdust , sugarcane bagasse (Saccharum officinarum L.) and sugarcane straw. The residues were treated to obtain 12% moisture content and particle size less than 1.70 mm. We produced 15 briquettes for each treatment. The pressure used was 1250 kgf.cm-2 for 30 seconds. The briquettes obtained densities ranged from 0.88 to 1.11 g.cm-3. This represented a range of 5 to 14 times less volume occupancy for the same amount of mass. The high heating value (HHV) was 19,180 J.kg-1 and 20,315 J.kg-1 for eucalyptus and pine sawdust respectively. The HHV for the bagasse was 18,541 J.kg-1 and for straw was 15,628 J.kg-1. The straw presented an ash content of 12%. The expansions of the treatments ranged 4 to 9% and mechanical resistances ranging from 1,215 MPa to 0,270 MPa. All briquettes were resistant to a higher stacking to 10 m high. The methods can help to decrease the space of storage and transport.Keywords: Waste; biofuel; energy; compression; stacking.

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Potential for Developing Biocarbon Briquettes for Foundry Industry

Applied Sciences ◽

10.3390/app9245288 ◽

2019 ◽

Vol 9 (24) ◽

pp. 5288 ◽

Cited By ~ 1

Author(s):

Elsayed Mousa ◽

Mania Kazemi ◽

Mikael Larsson ◽

Gert Karlsson ◽

Erik Persson

Keyword(s):

Tensile Strength ◽

Energy Density ◽

Mechanical Strength ◽

Compaction Pressure ◽

Hydrated Lime ◽

Hydraulic Press ◽

Ash Content ◽

Heating Value ◽

Cupola Furnace ◽

Foundry Industry

The foundry industry is currently facing challenges to reduce the environmental impacts from application of fossil fuels. Replacing foundry coke with alternative renewable carbon sources can lead to significant decrease in fossil fuel consumption and fossil CO2 emission. The low bulk density, low energy density, low mechanical strength and the high reactivity of biocarbon materials are the main factors limiting their efficient implementation in a cupola furnace. The current study aimed at designing, optimizing and developing briquettes containing biocarbon, namely, biocarbon briquettes for an efficient use in cupola furnace. Laboratory hydraulic press with compaction pressure of about 160 MPa and stainless-steel moulds (Ø = 40 mm and 70 mm) were used for compaction. The density, heating value, energy density, mechanical strength and reactivity of biocarbon briquettes were measured and evaluated. The compressive strength and splitting tensile strength of biocarbon briquettes were measured by a compression device. The reactivity of biocarbon briquettes was measured under controlled conditions of temperature and gas atmosphere using the thermogravimetric analysis technique (TGA). Different types of binders were tested for the compaction of commercial charcoal fines with/without contribution of coke breeze. The effect of charcoal ratio, particle size, binder type, binder ratio, moisture content and compaction pressure on the quality of the biocarbon briquettes was investigated. Molasses with hydrated lime and cement were superior in enhancing the biocarbon briquettes strength and energy density among other tested binders and additives. The briquettes’ strength decreased as the biocarbon content increased. The optimum recipes consisted of 62% charcoal fines, 20% molasses, 10% hydrated lime and 8% cement. Cement is necessary to develop the tensile strength and hot mechanical strength of the briquettes. The charcoal with high ash content showed higher strength of briquettes but lower heating value compared to that with low ash content. Dispersion of silica suspension on charcoal particles during the mixing process was able to reduce the reactivity of biochar in the developed biocarbon briquettes. The biocarbon briquettes density and strength were increased by increasing the compaction pressure. Commercial powder hydrated lime was more effective in enhancing the briquettes’ strength compared to slaked burnt lime. Upscaling of biocarbon briquettes (Ø = 70 mm) and testing of hot mechanical strength under load indicated development of cracks which significantly reduced the strength of briquettes. Further development of biocarbon briquettes is needed to fulfil the requirements of a cupola furnace.

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PENGARUH SUHU DAN KONSENTRASI PEREKAT TERHADAP KARAKTERISTIK BRIKET BIOARANG BERBAHAN BAKU TANDAN KOSONG KELAPA SAWIT DENGAN PROSES PIROLISIS

Konversi ◽

10.20527/k.v4i2.266 ◽

2015 ◽

Vol 4 (2) ◽

pp. 16

Author(s):

Yuli Ristianingsih ◽

Ayuning Ulfa ◽

Rachmi Syafitri K.S

Keyword(s):

Solid Waste ◽

Palm Oil ◽

Calorific Value ◽

Volatile Matter ◽

Ash Content ◽

Crude Palm Oil ◽

Fixed Carbon ◽

Heating Value ◽

Empty Fruit Bunches ◽

Rate Of Combustion

Abstrak-Tandan Kosong Kelapa Sawit merupakan limbah padat hasil produksi Crude Palm Oil (CPO). Setiap 1(satu) ton tandan buah segar dihasilkan 23% limbah padat. Limbah padat ini dapat di konversi menjadi bahan bakar pengganti minyak yaitu briket. Briket bioarang adalah bahan bakar padat yang dapat digunakan sebagai bahan bakar alternatif pengganti bahan bakar yang berasal dari fosil seperti minyak dan gas. Penelitian ini bertujuan untuk mengetahui pengaruh suhu pirolisis terhadap yield bioarang yang dihasilkan dan mengetahui pengaruh konsentrasi perekat kanji (5% w/w, 10% w/w, 15% w/w) terhadap karakteristik briket hasil penelitian (kadar air, volatile matter, kadar abu, fixed carbon, nilai kalor dan laju pembakaran). Penelitian dilakukan dengan metode pirolisis yaitu proses pembakaran bahan baku dalam reaktor pirolisis dengan menggunakan suhu yang tinggi dan tanpa atau dengan sedikit oksigen. Pirolisis dilakukan selama 2,5 jam dengan variasi suhu yaitu 350°C, 400°C, 450°C dan 500°C. Arang yang dihasilkan dicampur dengan perekat sesuai variasi dan dicetak menjadi briket. Briket kemudian dianalisa kadar air, kadar abu, kadar karbon, kadar zat terbang, nilai kalor dan laju pembakaran. Briket dengan yield tertinggi terdapat pada suhu 350°C sebesar 51,53% dan yield terendah pada suhu 500°C sebesar 26,03%. Briket hasil penelitian ini telah memenuhi standar mutu briket sebagai bahan bakar dilihat dari nilai kalor. Komposisi optimal antara perekat kanji dan arang TKKS hasil pirolisis yaitu pada 5%:95% yang menghasilkan nilai kalor terbesar yaitu 6748,15kal/g. Kata kunci : Briket Bioarang, Pirolisis, Tandan Kosong Kelapa Sawit Abstract-Palm Oil Empty Fruit Bunches are solid waste from Crude Palm Oil (CPO industry). For 1 ton of fresh fruit bunches produced 23% of solid waste. This solid waste can be converted into alternative energy that called briquettes. Briquettes are solid fuel that can be used as an alternative fuel replacement for fossil fuels such as oil and gas. This study aims to determine the effect of temperature on the yield generated briquettes and the effect of stach adhesive concentration (5, 10 and 15% wt) to briquettes characteristics (moisture content, volatile matter, ash content, fixed carbon, calorific value and the rate of combustion). In this reseacrh, two kilograms of palm oil empty fruit bunches was burned using pyrolisis reactor at different temperatur (350, 400, 450 and 5000C) for 2.5 hour. Charcoal produced was mixed with an adhesive in accordance variations and molded into briquettes. Briquettes then analyzed the water content, ash content, carbon content, volatile matter content, heating value and rate of combustion. The maximum yield of briquettes which was obtained in this research is 51.53% at temperature 3500C and the lowest yield at temperature of 500 ° C by 26.03%. Briquettes results of this study have met the quality standards of fuel briquettes as seen from the heating value. Optimal adhesive composition between starch and charcoal TKKS is 5%: 95% that generates highest calorific value about 6748.15kal/ g. Keywords: Briquette Bioarang, Pyrolysis, oil palm empty bunches

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Biochar produced from poultry litter waste

Research Society and Development ◽

10.33448/rsd-v10i11.19704 ◽

2021 ◽

Vol 10 (11) ◽

pp. e351101119704

Author(s):

Moisés Edevaldo Pereira ◽

Luciano Donizeti Varanda ◽

Natália Rodrigues de Carvalho ◽

Carlos Roberto Sette Jr ◽

Franciane Andrade de Padua ◽

...

Keyword(s):

Electron Microscopy ◽

Scanning Electron Microscopy ◽

Residence Time ◽

Broiler Chickens ◽

Poultry Litter ◽

Proximate Analysis ◽

Ash Content ◽

Residence Times ◽

Heating Value ◽

Scanning Electron

Brazil generates substantial quantity of poultry litter waste because of its worldwide prominence in the production of broiler chickens. The volume of the poultry litter biomass generates considerable environmental impact. The objective was to characterize the biochar produced from poultry litter residue under different conditions with the aim of determining the best residence time and temperature. Poultry litter was collected after two batches of chicken breeding. Five treatments for biochar production were carried out at a temperature of 450 °C (defined by thermogravimetric analysis - TGA) and residence times of 0.5, 1, 2, 4, and 6h. The biochar produced was assessed using proximate analysis, moisture content, gravimetric yield, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and HHV (higher heating value). The results revealed that the best conditions for biochar production was 450 °C (pyrolysis) and residence time of 0.5h, with 37.21% gravimetric yield. We concluded that the biochar produced in this study is recommended for soil application but was not suitable for energy purposes because of its high ash content (up to 33.66%) and low HHV (18,907 J g-1).

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Investigation of Quantity, Quality and Energy Content of Indigenous Sugarcane Trash in Naoshehro Feroze District, Sindh

Engineering, Technology & Applied Science Research ◽

10.48084/etasr.2411 ◽

2018 ◽

Vol 8 (6) ◽

pp. 3609-3613

Author(s):

S. H. Solangi ◽

A. Q. Jakhrani ◽

K. C. Mukwana ◽

A. R. Jatoi ◽

M. R. Luhur

Keyword(s):

Energy Content ◽

Ash Content ◽

Fixed Carbon ◽

Heating Value ◽

Weight Percentage ◽

Sugarcane Varieties ◽

Green Leaves ◽

Sugarcane Crop

Quantity, characteristics, and energy content in sugarcane trash of six different indigenous sugarcane varieties were computed for their possible utilization. Results revealed that the total sugarcane trash weight percentage was 24.0% of the total sugarcane crop. Among all examined varieties, variety 240 produced the highest and the variety HS12 the lowest percentage of sugarcane trash with 28% and 18.6% respectively. Moisture and ash content were found less in brown leaves and more in the tops of sugarcane trash parts. The fixed carbon values in brown leaves, green leaves, and tops of the variety Thatta10 were the highest found, with 18.4%, 15.5%, and 17.3% respectively. Carbon element’s percentage in brown leaves of variety HS12 was the highest with 50.0% and in Thatta10 was the lowest with 43.4%. Highest heating value was found in Thatta10 with 16.0MJ/kg, which is close to the literature reported values.

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An alternative supply system for stump biomass – coarse grinding combined with sieving of the produced hog fuel

International Journal of Forest Engineering ◽

10.1080/14942119.2016.1166917 ◽

2016 ◽

Vol 27 (2) ◽

pp. 109-114

Author(s):

Anerud ◽

von Hofsten ◽

Eliasson

Keyword(s):

Lower Cost ◽

Ash Content ◽

Supply System ◽

Fuel Quality ◽

Transport Costs ◽

Heating Value ◽

Transport Distance ◽

System A ◽

Grinding System ◽

Heating Plant

Transport costs are one of the major costs in the supply chain of stumps for fuel. Stump parts are bulky and it is impossible to achieve full tonnages on trucks and trailers even though the load space is completely full. The transport economy for stumps is also negatively affected by the large amount of contaminants in the loads. Grinding the stumps at the landing and sieving of the produced hog fuel has the potential to increase load weights and reduce both the amount of contaminants and the transport costs. To evaluate such a system a series of studies were made. Results show that coarse grinding and sieving reduced both moisture and ash content in the produced fuel, thus increasing the heating value per ton delivered fuel and transforming a soil contaminated material to an acceptable fuel. Transport payloads increased substantially compared to transports of stump parts, but a transport distance of 110 km was needed before the coarse grinding system provided lower cost than the standard system with transports of stump parts and grinding at the heating plant. Further studies are needed to evaluate the total energy efficiency in the two systems. Coarse grinding and sieving is a feasible way to increase fuel quality and improve transport economy. However, total costs will in most cases be higher than for the loose stump system which renders the method preferable only in cases where the sieving process converts a non-acceptable material into an acceptable fuel.

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Effect of starch binder on charcoal briquette properties

International Agrophysics ◽

10.1515/intag-2016-0077 ◽

2017 ◽

Vol 31 (4) ◽

pp. 571-574 ◽

Cited By ~ 8

Author(s):

Gabriel Borowski ◽

Witold Stępniewski ◽

Katarzyna Wójcik-Oliveira

Keyword(s):

Ash Content ◽

Wheat Starch ◽

Maximum Temperature ◽

Burning Time ◽

Fixed Carbon ◽

Heating Value ◽

High Maximum ◽

Mixed Material ◽

Fixed Carbon Content ◽

Press Unit

Abstract The paper shows the results of a study on the effect of starch binder on the mechanical, physical and burning properties of charcoal briquettes. Two types of binders were repeatedly used to make briquettes of native wheat starch and modified wheat starch, at 8% of the whole. Briquetting was performed in a roller press unit, and pillow-shaped briquettes were made. The moisture of the mixed material ranged from 28 to 32%. The product, whether the former or the latter, was characterized by very good mechanical properties and satisfactory physical properties. Moreover, the type of starch binder had no effect on toughness, calorific heating value, volatiles, fixed carbon content and ash content. However, the combustion test showed quite different burning properties. As briquettes should have short firing up time and lower smokiness, as well as high maximum temperature and long burning time, we have concluded that briquettes with native wheat starch as a binder are more appropriate for burning in the grill.

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Fuel pellets from fine paper mill sludge supplemented by sawdust and by refined recovered lubricating oil

BioResources ◽

10.15376/biores.16.1.1144-1160 ◽

2020 ◽

Vol 16 (1) ◽

pp. 1144-1160

Author(s):

Ishaq Ahmad ◽

Min-Seok Lee ◽

Ho-Kyung Goo ◽

Chang-Yeong Lee ◽

Jeong-Heon Ryu ◽

...

Keyword(s):

Energy Demand ◽

Ignition Time ◽

Paper Mill ◽

Ash Content ◽

National Standards ◽

Lubricating Oil ◽

Paper Mill Sludge ◽

Heating Value ◽

Refined Oil ◽

Fuel Pellets

Fine paper mill sludge (FPMS) disposal has emerged as a problem since the dumping of FPMS was banned. This study investigated the effects of adding a refined recovered lubricating oil (ion-refined oil) to FPMS pellets to increase its heating value and combustion time and decrease ash content and ignition time. Fuel pellets were prepared in three conditions, C-1, C-2, and C-3. In C-1, ion-refined oil was added to FPMS to examine its burning capability. In C-2, two types of pellets were produced mixing sawdust and FPMS ratios of 25:75 and 50:50. A ratio of 50:50 was selected for C-3, to which the ion-refined oil was added in different ratios. The quality of the energy fuel pellets was determined using proximate and ultimate analyses, except for chlorine content, which was determined through liquid ion chromatography. The properties of fuel pellets were determined and compared with national standards. It was confirmed that the results for pellets at a ratio of 50:50 with 10% and 15% ion-refined oil were acceptable, because these results were comparatively similar to the standards. Finally, it was concluded that ion-refined oil was an effective additive to FPMS to increase the heating value for energy demand and lower the ash content.

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