scholarly journals Temperature- and degree of cure-dependent viscoelastic properties of photopolymer resins used in digital light processing

Author(s):  
T. Rehbein ◽  
M. Johlitz ◽  
A. Lion ◽  
K. Sekmen ◽  
A. Constantinescu

AbstractIn the present paper, the degree of cure-dependent viscoelastic properties of a commercial photopolymer resin (Loctite$$^{\textregistered }$$ ® 3D 3830) used in digital light processing (DLP) 3D printing are investigated experimentally and described by suitable model equations. To do this, tests are carried out both on the liquid resin and printed specimens under various conditions. The experimental methods include photo-DSC, UV rheometry, and dynamic mechanical analysis. A commercial digital light processing (DLP) printer (Loctite$$^{\textregistered }$$ ® EQ PR10.1) is used for the printing of the samples. Model equations are proposed to describe the behavior of the material during and after the printing process. For the representation of the degree of cure depending on temperature and light intensity, the one-dimensional differential equation proposed in a previous paper is extended to capture a temperature-dependent threshold value. The change of the viscoelastic properties during crosslinking is captured macroscopically by time-temperature and time-cure superposition principles. The parameters of the model equations are identified using nonlinear optimization algorithms. A good representation of the experimental data is achieved by the proposed model equations. The findings of this paper help users in additive manufacturing of photopolymers to predict the material properties depending on the degree of cure and temperature of printed components.

2014 ◽  
Vol 6 (1) ◽  
pp. 1032-1035 ◽  
Author(s):  
Ramzi Suleiman

The research on quasi-luminal neutrinos has sparked several experimental studies for testing the "speed of light limit" hypothesis. Until today, the overall evidence favors the "null" hypothesis, stating that there is no significant difference between the observed velocities of light and neutrinos. Despite numerous theoretical models proposed to explain the neutrinos behavior, no attempt has been undertaken to predict the experimentally produced results. This paper presents a simple novel extension of Newton's mechanics to the domain of relativistic velocities. For a typical neutrino-velocity experiment, the proposed model is utilized to derive a general expression for . Comparison of the model's prediction with results of six neutrino-velocity experiments, conducted by five collaborations, reveals that the model predicts all the reported results with striking accuracy. Because in the proposed model, the direction of the neutrino flight matters, the model's impressive success in accounting for all the tested data, indicates a complete collapse of the Lorentz symmetry principle in situation involving quasi-luminal particles, moving in two opposite directions. This conclusion is support by previous findings, showing that an identical Sagnac effect to the one documented for radial motion, occurs also in linear motion.


2020 ◽  
Vol 23 (4) ◽  
pp. 274-284 ◽  
Author(s):  
Jingang Che ◽  
Lei Chen ◽  
Zi-Han Guo ◽  
Shuaiqun Wang ◽  
Aorigele

Background: Identification of drug-target interaction is essential in drug discovery. It is beneficial to predict unexpected therapeutic or adverse side effects of drugs. To date, several computational methods have been proposed to predict drug-target interactions because they are prompt and low-cost compared with traditional wet experiments. Methods: In this study, we investigated this problem in a different way. According to KEGG, drugs were classified into several groups based on their target proteins. A multi-label classification model was presented to assign drugs into correct target groups. To make full use of the known drug properties, five networks were constructed, each of which represented drug associations in one property. A powerful network embedding method, Mashup, was adopted to extract drug features from above-mentioned networks, based on which several machine learning algorithms, including RAndom k-labELsets (RAKEL) algorithm, Label Powerset (LP) algorithm and Support Vector Machine (SVM), were used to build the classification model. Results and Conclusion: Tenfold cross-validation yielded the accuracy of 0.839, exact match of 0.816 and hamming loss of 0.037, indicating good performance of the model. The contribution of each network was also analyzed. Furthermore, the network model with multiple networks was found to be superior to the one with a single network and classic model, indicating the superiority of the proposed model.


1985 ◽  
Vol 50 (11) ◽  
pp. 2396-2410
Author(s):  
Miloslav Hošťálek ◽  
Ivan Fořt

The study describes a method of modelling axial-radial circulation in a tank with an axial impeller and radial baffles. The proposed model is based on the analytical solution of the equation for vortex transport in the mean flow of turbulent liquid. The obtained vortex flow model is tested by the results of experiments carried out in a tank of diameter 1 m and with the bottom in the shape of truncated cone as well as by the data published for the vessel of diameter 0.29 m with flat bottom. Though the model equations are expressed in a simple form, good qualitative and even quantitative agreement of the model with reality is stated. Apart from its simplicity, the model has other advantages: minimum number of experimental data necessary for the completion of boundary conditions and integral nature of these data.


Author(s):  
Zihang Wei ◽  
Yunlong Zhang ◽  
Xiaoyu Guo ◽  
Xin Zhang

Through movement capacity is an essential factor used to reflect intersection performance, especially for signalized intersections, where a large proportion of vehicle demand is making through movements. Generally, left-turn spillback is considered a key contributor to affect through movement capacity, and blockage to the left-turn bay is known to decrease left-turn capacity. Previous studies have focused primarily on estimating the through movement capacity under a lagging protected only left-turn (lagging POLT) signal setting, as a left-turn spillback is more likely to happen under such a condition. However, previous studies contained assumptions (e.g., omit spillback), or were dedicated to one specific signal setting. Therefore, in this study, through movement capacity models based on probabilistic modeling of spillback and blockage scenarios are established under four different signal settings (i.e., leading protected only left-turn [leading POLT], lagging left-turn, protected plus permitted left-turn, and permitted plus protected left-turn). Through microscopic simulations, the proposed models are validated, and compared with existing capacity models and the one in the Highway Capacity Manual (HCM). The results of the comparisons demonstrate that the proposed models achieved significant advantages over all the other models and obtained high accuracies in all signal settings. Each proposed model for a given signal setting maintains consistent accuracy across various left-turn bay lengths. The proposed models of this study have the potential to serve as useful tools, for practicing transportation engineers, when determining the appropriate length of a left-turn bay with the consideration of spillback and blockage, and the adequate cycle length with a given bay length.


Mathematics ◽  
2021 ◽  
Vol 9 (15) ◽  
pp. 1815
Author(s):  
Diego I. Gallardo ◽  
Mário de Castro ◽  
Héctor W. Gómez

A cure rate model under the competing risks setup is proposed. For the number of competing causes related to the occurrence of the event of interest, we posit the one-parameter Bell distribution, which accommodates overdispersed counts. The model is parameterized in the cure rate, which is linked to covariates. Parameter estimation is based on the maximum likelihood method. Estimates are computed via the EM algorithm. In order to compare different models, a selection criterion for non-nested models is implemented. Results from simulation studies indicate that the estimation method and the model selection criterion have a good performance. A dataset on melanoma is analyzed using the proposed model as well as some models from the literature.


2003 ◽  
Author(s):  
Lijun Xu ◽  
Jamil A. Khan

A comprehensive axisymmetric model of the coupled thermal-electrical-mechanical analysis predicting weld nugget development and residual stresses for the resistance spot welding process of Al-alloys is developed. The model estimates the heat generation at the faying surface, the workpiece-electrode interface, and the Joule heating of the workpiece and electrode. The phase change due to melting in the weld pool is considered. The contact area and its pressure distribution at both the faying surface and the electrode-workpiece interface are determined from a coupled thermal-mechanical model using a finite element method. The knowledge of the interface pressure provides accurate prediction of the interfacial heat generation. For the numerical model, temperature dependent thermal, electrical and mechanical properties are used. The proposed model can successfidly calculate the nugget diameter and thickness, and predict the residual stresses and the elastic-plastic deformation history. The calculated nugget shape and the deformation of sheets based on the model are compared with the experimental data. The computed residual stresses approach the distribution of experimental measurement of the residual stress.


2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
Fabiola Navarro-Pardo ◽  
Ana L. Martínez-Hernández ◽  
Victor M. Castaño ◽  
José L. Rivera-Armenta ◽  
Francisco J. Medellín-Rodríguez ◽  
...  

Carbon nanotubes (CNTs) and graphene were used as reinforcing fillers in nylon 6,6 in order to obtain nanocomposites by using an injection moulding process. The two differently structured nanofillers were used in their pristine or reduced form, after oxidation treatment and after amino functionalisation. Three low nanofiller contents were employed. Crystallisation behaviour and perfection of nylon 6,6 crystals were determined by differential scanning calorimetry and wide angle X-ray diffraction, respectively. Crystallinity was slightly enhanced in most samples as the content of the nanofillers was increased. The dimensionality of the materials was found to provide different interfaces and therefore different features in the nylon 6,6 crystal growth resulting in improved crystal perfection. Dynamical, mechanical analysis showed the maximum increases provided by the two nanostructures correspond to the addition of 0.1 wt.% amino functionalised CNTs, enhancing in 30% the storage modulus and the incorporation of 0.5 wt.% of graphene oxide caused an increase of 44% in this property. The latter also provided better thermal stability when compared to pure nylon 6,6 under inert conditions. The superior properties of graphene nanocomposites were attributed to the larger surface area of the two-dimensional graphene compared to the one-dimensional CNTs.


2021 ◽  
Vol 7 ◽  
pp. e505
Author(s):  
Noha Ahmed Bayomy ◽  
Ayman E. Khedr ◽  
Laila A. Abd-Elmegid

The one constant in the world is change. The changing dynamics of business environment enforces the organizations to re-design or reengineer their business processes. The main objective of such reengineering processes is to provide services or produce products with the possible lowest cost, shortest time, and best quality. Accordingly, Business Process Re-engineering (BPR) provides a roadmap of how to efficiently achieve the operational goals in terms of enhanced flexibility and productivity, reduced cost, and improved quality of service or product. In this article, we propose an efficient model for BPR. The model specifies where the breakdowns occur in BPR implementation, justifies why such breakdowns occur, and proposes techniques to prevent their occurrence again. The proposed model has been built based on two main sections. The first section focuses on integrating Critical Success Factors (CSFs) and the performance of business processes during the reengineering processes. Additionally, it implements the association rule mining technique to investigate the relationship between CSFs and different business processes. The second section aims to measure the performance of business processes (intended success of BPR) by process time, cycle time, quality and cost before and after reengineering processes. A case study of the Egyptian Tax Authority (ETA) is used to test the efficiency of the proposed model.


Holzforschung ◽  
2011 ◽  
Vol 65 (2) ◽  
Author(s):  
Rahime Bag ◽  
Johnny Beaugrand ◽  
Patrice Dole ◽  
Bernard Kurek

Abstract The aim of this study was to determine the effect of removing extractives from the woody core of hemp (chènevotte) on the chain mobility of hemicelluloses and lignins, which can react during technological transformation such as de-fibering and/or composite materials production. Extractives are molecules with low molecular weight, which are present in the cell wall matrix and can be readily removed by solvents. In the present paper, the nature and amounts of extractives, removed under different conditions and with solvents of different polarities, were determined. The mobility and structural relaxations of lignins and hemicelluloses were stu-died in situ by dynamic mechanical analysis and dielectric analysis under controlled moisture content. Extractions at low temperature led to rigidification of lignins and plasticizing of hemicelluloses, probably due to local changes by the selective removal of molecules interacting with the polymers. Probably, the accessibility of hemicelluloses to plasticizing water was increased at controlled humidity. In contrast, hot extractions including water induced rigidification of the hemi-celluloses and plasticizing of lignins. This could be related to a combination of molecule extractions and chemical modi-fications of both polymers. This interpretation is supported by the variation of activation energy for relaxation of hemi-celluloses. It can be concluded that each type of extraction has a clear specific effect on the relaxation properties of the amorphous cell wall polymers.


2018 ◽  
Vol 53 (2) ◽  
pp. 155-171 ◽  
Author(s):  
Alice Courtois ◽  
Martin Hirsekorn ◽  
Maria Benavente ◽  
Agathe Jaillon ◽  
Lionel Marcin ◽  
...  

This paper presents a viscoelastic temperature- and degree-of-cure-dependent constitutive model for an epoxy resin. Multi-temperature relaxation tests on fully and partially cured rectangular epoxy specimens were conducted in a dynamic mechanical analysis apparatus with a three-point bending clamp. Master curves were constructed from the relaxation test results based on the time–temperature superposition hypothesis. The influence of the degree of cure was included through the cure-dependent glass transition temperature which was used as reference temperature for the shift factors. The model parameters were optimized by minimization of the differences between the model predictions and the experimental data. The model predictions were successfully validated against an independent creep-like strain history over which the temperature varied.


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