Fundamentals and applications of 3D and 4D printing of polymers: Challenges in polymer processing and prospects of future research

Author(s):  
Kalim Deshmukh ◽  
Aqib Muzaffar ◽  
Tomáš Kovářík ◽  
Tomáš Křenek ◽  
M. Basheer Ahamed ◽  
...  
2000 ◽  
Vol 123 (2) ◽  
pp. 173-210 ◽  
Author(s):  
Yogesh Jaluria

There has been an explosive growth in the development of new materials and processing techniques in recent years to meet the challenges posed by new applications arising in electronics, telecommunications, aerospace, transportation, and other new and traditional areas. Semiconductor and optical materials, composites, ceramics, biomaterials, advanced polymers, and specialized alloys are some of the materials that have seen intense interest and research activity over the last two decades. New approaches have been developed to improve product quality, reduce cost, and achieve essentially custom-made material properties. Current trends indicate continued research effort in materials processing as demand for specialized materials continues to increase. Fluid flow that arises in many materials processing applications is critical in the determination of the quality and characteristics of the final product and in the control, operation, and optimization of the system. This review is focused on the fluid flow phenomena underlying a wide variety of materials processing operations such as optical fiber manufacture, crystal growth for semiconductor fabrication, casting, thin film manufacture, and polymer processing. The review outlines the main aspects that must be considered in materials processing, the basic considerations that are common across fluid flow phenomena involved in different areas, the present state of the art in analytical, experimental and numerical techniques that may be employed to study the flow, and the effect of fluid flow on the process and the product. The main issues that distinguish flow in materials processing from that in other fields, as well as the similar aspects, are outlined. The complexities that are inherent in materials processing, such as large material property changes, complicated domains, multiple regions, combined mechanisms, and complex boundary conditions are discussed. The governing equations and boundary conditions for typical processes, along with important parameters, common simplifications and specialized methods employed to study these processes are outlined. The field is vast and it is not possible to consider all the different techniques employed for materials processing. Among the processes discussed in some detail are polymer extrusion, optical fiber drawing, casting, continuous processing, and chemical vapor deposition for the fabrication of thin films. Besides indicating the effect of fluid flow on the final product, these results illustrate the nature of the basic problems, solution strategies, and issues involved in the area. The review also discusses present trends in materials processing and suggests future research needs. Of particular importance are well-controlled and well-designed experiments that would provide inputs for model validation and for increased understanding of the underlying fluid flow mechanisms. Also, accurate material property data are very much needed to obtain accurate and repeatable results that can form the basis for design and optimization. There is need for the development of innovative numerical and experimental approaches to study the complex flows that commonly arise in materials processing. Materials processing techniques that are in particular need of further detailed work are listed. Finally, it is stessed that it is critical to understand the basic mechanisms that determine changes in the material, in addition to the fluid flow aspects, in order to impact on the overall field of materials processing.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4209
Author(s):  
Yifei Ding ◽  
Mohammed H. Hassan ◽  
Otto Bakker ◽  
Srichand Hinduja ◽  
Paulo Bártolo

Microcellular injection moulding (MuCell®) is a polymer processing technology that uses a supercritical fluid inert gas, CO2 or N2, to produce light-weight products. Due to environmental pressures and the requirement of light-weight parts with good mechanical properties, this technology recently gained significant attention. However, poor surface appearance and limited mechanical properties still prevent the wide applications of this technique. This paper reviews the microcellular injection moulding process, main characteristics of the process, bubble nucleation and growth, and major recent developments in the field. Strategies to improve both the surface quality and mechanical properties are discussed in detail as well as the relationships between processing parameters, morphology, and surface and mechanical properties. Modelling approaches to simulate microcellular injection moulding and the mathematical models behind Moldex 3D and Moldflow, the two most commonly used software tools by industry and academia, are reviewed, and the main limitations are highlighted. Finally, future research perspectives to further develop this technology are also discussed.


2019 ◽  
Vol 10 (1) ◽  
pp. 9 ◽  
Author(s):  
Ana P. Piedade

3D printing of polymers can now be considered as a common processing technology for the development of biomaterials. These can be constituted out of polymeric abiotic material alone or can be co-printed with living cells. However, the adaptive and shape-morphing characteristics cannot be developed with the rigid, pre-determined structures obtained by 3D printing. In order to produce functional engineered biomaterials, the dynamic properties/characteristics of the living cells must be attained. 4D printing can be envisaged as a route to achieve these goals. This paper intends to give a brief review of the pioneer 4D printing research that has been developed and to present an insight into future research in this field.


Actuators ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 31
Author(s):  
Hannah Carlotta Koch ◽  
David Schmelzeisen ◽  
Thomas Gries

Four-dimensional textiles are textiles that can change shape or function over time by the influence of a stimulus, mainly force and heat. In this review, the focus is on 4D textiles made by additive manufacturing which is built on the concept of 4D printing. A literature survey in Web of Science and Scopus was carried out, which resulted in 29 contributions on additive manufacturing on pre-stressed textiles. In this paper, an overview of materials, production technologies and testing methods is given. The concepts of form giving and shape change transferred to 4D textiles are classified. The influencing factors on the properties of the material structure are presented. The main focus of the literature lies in defining process and material properties for improving the adhesion. Only limited research has been conducted on simulating the material behavior. Ideas for applications exist but no research has been conducted on real applications. Therefore, the challenges are identified, and future research directions are derived.


Author(s):  
Wendy Putnam ◽  
Christopher Viney

Liquid crystalline polymers (solutions or melts) can be spun into fibers and films that have a higher axial strength and stiffness than conventionally processed polymers. These superior properties are due to the spontaneous molecular extension and alignment that is characteristic of liquid crystalline phases. Much of the effort in processing conventional polymers goes into extending and aligning the chains, while, in liquid crystalline polymer processing, the primary microstructural rearrangement involves converting local molecular alignment into global molecular alignment. Unfortunately, the global alignment introduced by processing relaxes quickly upon cessation of shear, and the molecular orientation develops a periodic misalignment relative to the shear direction. The axial strength and stiffness are reduced by this relaxation.Clearly there is a need to solidify the liquid crystalline state (i.e. remove heat or solvent) before significant relaxation occurs. Several researchers have observed this relaxation, mainly in solutions of hydroxypropyl cellulose (HPC) because they are lyotropic under ambient conditions.


2019 ◽  
Vol 4 (1) ◽  
pp. 59-76 ◽  
Author(s):  
Alison E. Fowler ◽  
Rebecca E. Irwin ◽  
Lynn S. Adler

Parasites are linked to the decline of some bee populations; thus, understanding defense mechanisms has important implications for bee health. Recent advances have improved our understanding of factors mediating bee health ranging from molecular to landscape scales, but often as disparate literatures. Here, we bring together these fields and summarize our current understanding of bee defense mechanisms including immunity, immunization, and transgenerational immune priming in social and solitary species. Additionally, the characterization of microbial diversity and function in some bee taxa has shed light on the importance of microbes for bee health, but we lack information that links microbial communities to parasite infection in most bee species. Studies are beginning to identify how bee defense mechanisms are affected by stressors such as poor-quality diets and pesticides, but further research on this topic is needed. We discuss how integrating research on host traits, microbial partners, and nutrition, as well as improving our knowledge base on wild and semi-social bees, will help inform future research, conservation efforts, and management.


2020 ◽  
Vol 64 (1) ◽  
pp. 97-110
Author(s):  
Christian Sibbersen ◽  
Mogens Johannsen

Abstract In living systems, nucleophilic amino acid residues are prone to non-enzymatic post-translational modification by electrophiles. α-Dicarbonyl compounds are a special type of electrophiles that can react irreversibly with lysine, arginine, and cysteine residues via complex mechanisms to form post-translational modifications known as advanced glycation end-products (AGEs). Glyoxal, methylglyoxal, and 3-deoxyglucosone are the major endogenous dicarbonyls, with methylglyoxal being the most well-studied. There are several routes that lead to the formation of dicarbonyl compounds, most originating from glucose and glucose metabolism, such as the non-enzymatic decomposition of glycolytic intermediates and fructosyl amines. Although dicarbonyls are removed continuously mainly via the glyoxalase system, several conditions lead to an increase in dicarbonyl concentration and thereby AGE formation. AGEs have been implicated in diabetes and aging-related diseases, and for this reason the elucidation of their structure as well as protein targets is of great interest. Though the dicarbonyls and reactive protein side chains are of relatively simple nature, the structures of the adducts as well as their mechanism of formation are not that trivial. Furthermore, detection of sites of modification can be demanding and current best practices rely on either direct mass spectrometry or various methods of enrichment based on antibodies or click chemistry followed by mass spectrometry. Future research into the structure of these adducts and protein targets of dicarbonyl compounds may improve the understanding of how the mechanisms of diabetes and aging-related physiological damage occur.


1985 ◽  
Vol 16 (1) ◽  
pp. 25-28 ◽  
Author(s):  
Nicholas J. DeGregorio ◽  
Nancy Gross Polow

The present study was designed to investigate the effect of teacher training sessions on listener perception of voice disorders. Three ASHA certified speech-language pathologists provided the criteria mean. Thirty randomly selected teachers from a Bergen County school system, randomly placed into two groups, served as subjects. The experimental group received three training sessions on consecutive weeks. Three weeks after the end of training, both groups were given a posttest. Listener perception scores were significantly higher for the experimental group. The implications of these results for in-service workshops, teacher/speech-language pathologist interaction and future research are discussed.


2019 ◽  
Vol 50 (4) ◽  
pp. 693-702 ◽  
Author(s):  
Christine Holyfield ◽  
Sydney Brooks ◽  
Allison Schluterman

Purpose Augmentative and alternative communication (AAC) is an intervention approach that can promote communication and language in children with multiple disabilities who are beginning communicators. While a wide range of AAC technologies are available, little is known about the comparative effects of specific technology options. Given that engagement can be low for beginning communicators with multiple disabilities, the current study provides initial information about the comparative effects of 2 AAC technology options—high-tech visual scene displays (VSDs) and low-tech isolated picture symbols—on engagement. Method Three elementary-age beginning communicators with multiple disabilities participated. The study used a single-subject, alternating treatment design with each technology serving as a condition. Participants interacted with their school speech-language pathologists using each of the 2 technologies across 5 sessions in a block randomized order. Results According to visual analysis and nonoverlap of all pairs calculations, all 3 participants demonstrated more engagement with the high-tech VSDs than the low-tech isolated picture symbols as measured by their seconds of gaze toward each technology option. Despite the difference in engagement observed, there was no clear difference across the 2 conditions in engagement toward the communication partner or use of the AAC. Conclusions Clinicians can consider measuring engagement when evaluating AAC technology options for children with multiple disabilities and should consider evaluating high-tech VSDs as 1 technology option for them. Future research must explore the extent to which differences in engagement to particular AAC technologies result in differences in communication and language learning over time as might be expected.


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