Effect of crystallite size, Raman surface modes and surface basicity on the gas sensing behavior of terbium-doped SnO2 nanoparticles

2016 ◽  
Vol 42 (3) ◽  
pp. 4323-4332 ◽  
Author(s):  
Gurpreet Singh ◽  
Rengasamy Thangaraj ◽  
Ravi Chand Singh
Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2123
Author(s):  
Ming Liu ◽  
Caochuang Wang ◽  
Pengcheng Li ◽  
Liang Cheng ◽  
Yongming Hu ◽  
...  

Many low-dimensional nanostructured metal oxides (MOXs) with impressive room-temperature gas-sensing characteristics have been synthesized, yet transforming them into relatively robust bulk materials has been quite neglected. Pt-decorated SnO2 nanoparticles with 0.25–2.5 wt% Pt were prepared, and highly attractive room-temperature hydrogen-sensing characteristics were observed for them all through pressing them into pellets. Some pressed pellets were further sintered over a wide temperature range of 600–1200 °C. Though the room-temperature hydrogen-sensing characteristics were greatly degraded in many samples after sintering, those samples with 0.25 wt% Pt and sintered at 800 °C exhibited impressive room-temperature hydrogen-sensing characteristics comparable to those of their counterparts of as-pressed pellets. The variation of room-temperature hydrogen-sensing characteristics among the samples was explained by the facts that the connectivity between SnO2 grains increases with increasing sintering temperature, and Pt promotes oxidation of SnO2 at high temperatures. These results clearly demonstrate that some low-dimensional MOX nanocrystals can be successfully transformed into bulk MOXs with improved robustness and comparable room-temperature gas-sensing characteristics.


2021 ◽  
Vol 93 (3) ◽  
pp. 30401
Author(s):  
Jiaxing Wang ◽  
Hai Yu ◽  
Yong Zhang

SnO2 nanoparticle architectures were successfully synthesized using a sol-gel method and developed for acetone gas detection. The morphology and structure of the particles were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The SnO2 nanoparticle architectures were configured as high-performance sensors to detect acetone and showed a very fast response time (<1 s), a short recovery time (10 s), good repeatability and high selectivity at a relatively low working temperature. Thus, SnO2 nanoparticles should be promising candidates for designing and fabricating acetone gas sensors with good gas sensing performance. The possible gas sensing mechanism is also presented.


Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 351 ◽  
Author(s):  
Dongping Xue ◽  
Junjun Wang ◽  
Yan Wang ◽  
Guang Sun ◽  
Jianliang Cao ◽  
...  

Methane detection is extremely difficult, especially at low temperatures, due to its high chemical stability. Here, WO3 nanosheets loaded with SnO2 nanoparticles with a particle size of about 2 nm were prepared by simple impregnation and subsequent calcination using SnO2 and WO3·H2O as precursors. The response of SnO2-loaded WO3 nanosheet composites to methane is about 1.4 times higher than that of pure WO3 at the low optimum operating temperature (90 °C). Satisfying repeatability and long-term stability are ensured. The dominant exposed (200) crystal plane of WO3 nanosheets has a good balance between easy oxygen chemisorption and high reactivity at the dangling bonds of W atoms, beneficial for gas-sensing properties. Moreover, the formation of a n–n type heterojunction at the SnO2-WO3 interface and additionally the increase of specific surface area and defect density via SnO2 loading enhance the response further. Therefore, the SnO2-WO3 composite is promising for the development of sensor devices to methane.


Sensors ◽  
2016 ◽  
Vol 16 (8) ◽  
pp. 1283 ◽  
Author(s):  
Tangirala Karthik ◽  
María Olvera ◽  
Arturo Maldonado ◽  
Heberto Gómez Pozos

2007 ◽  
Vol 126 (2) ◽  
pp. 478-484 ◽  
Author(s):  
Jaswinder Kaur ◽  
Rajesh Kumar ◽  
M.C. Bhatnagar

2001 ◽  
Vol 707 ◽  
Author(s):  
R.C. Ghan ◽  
Y. Lvov ◽  
R.S. Besser

ABSTRACTIn order to refine further the material technology for tin-oxide based gas sensing we are exploring the use of precision nanoparticle deposition for the sensing layer. Layers of SnO2 nanoparticles were grown on Quartz Crystal Microbalance (QCM) resonators using the layer-by-layer self-assembly technique. Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and Electron Diffraction Pattern (EDP) analyses were performed on the self-assembled layers of SnO2 nanoparticles. The results showed that SnO2 nanoparticle films are deposited uniformly across the substrate. The size of the nanoparticles is estimated to be about 3-5 nm. Electrical characterization was done using standard current-voltage measurement technique, which revealed that SnO2 nanoparticle films exhibit ohmic behavior. Calcination experiments have also been carried out by baking the substrate (with self-assembled nanoparticles) in air at 350°C. Results show that 50%-70% of the polymer layers (which are deposited as precursor layers and also alternately in-between SnO2 nanoparticle monolayers) are eliminated during the process.


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