XXXVII.—On a Sensitive State induced in Magnetic Materials by Thermal Treatment.

1908 ◽  
Vol 28 ◽  
pp. 615-626
Author(s):  
James G. Gray ◽  
Alexander D. Ross

SUMMARY1. Nickel and the Heusler alloy give “sensitive states” of nearly 2 and about 5 per cent. respectively for a magnetising field of 8 C.G.S. units.2. Steel wire specimens dropped vertically on a stone slab from a height of 1 metre showed a reduction of 37 per cent, in the “sensitive state” for a single fall, 49 per cent, for three falls, 62 per cent, for ten falls, and 73 per cent, for fifty falls.3. After the “sensitive state” has been removed from a specimen by the process of demagnetising by reversals, it cannot be completely restored by reannealing. That is, the specimens exhibit a fatigue effect.4. In the case of one variety of steel, the “sensitive state” had been reduced to less than one-half its original value after seven annealings, and to one-fifth after seventeen.5. No recovery from the fatigue condition was observed in specimens which had been laid aside for fifty-four days.6. Repeated annealings without intermediate magnetic testing showed neither an augmentation of the “sensitive state” nor a fatigue effect.7. Specimens demagnetised at −190° C., heated to room temperature, and cooled again to −190° C., showed a small “sensitive state” at that temperature.8. Larger effects were induced by heating from −190° C. to 15° C., or by cooling from 15° C. to −190° C.9. A “sensitive state” could be induced by any variation of temperature, but not by exposure to a steady temperature, either high or low. The effect is associated solely with change of temperature.10. The amount of “sensitive state” induced by equal temperature alterations varies with the position of the range on the temperature scale and with the material.11. The change from the “sensitive” to the normal condition is unaccompanied by any appreciable change in the specific electrical resistance or elastic constants of the material.

Nanoscale ◽  
2021 ◽  
Author(s):  
Lorenzo Branzi ◽  
Giacomo Lucchini ◽  
Elti Cattaruzza ◽  
Nicola Pinna ◽  
Alvise Benedetti ◽  
...  

We report on a Cu(II) catalyzed process for the production of cysteine based chiral carbon dots, the process does not require any thermal treatment and the carbon dots formation is...


2000 ◽  
Vol 622 ◽  
Author(s):  
Liang-Yu Chen ◽  
Gary W. Hunter ◽  
Philip G. Neudeck

ABSTRACTSingle crystal silicon carbide (SiC) has such excellent physical, chemical, and electronic properties that SiC based semiconductor electronics can operate at temperatures in excess of 600°C well beyond the high temperature limit for Si based semiconductor devices. SiC semiconductor devices have been demonstrated to be operable at temperatures as high as 600°C, but only in a probe-station environment partially because suitable packaging technology for high temperature (500°C and beyond) devices is still in development. One of the core technologies necessary for high temperature electronic packaging is semiconductor die-attach with low and stable electrical resistance. This paper discusses a low resistance die-attach method and the results of testing carried out at both room temperature and 500°C in air. A 1 mm2 SiC Schottky diode die was attached to aluminum nitride (AlN) and 96% pure alumina ceramic substrates using precious metal based thick-film material. The attached test die using this scheme survived both electronically and mechanically performance and stability tests at 500°C in oxidizing environment of air for 550 hours. The upper limit of electrical resistance of the die-attach interface estimated by forward I-V curves of an attached diode before and during heat treatment indicated stable and low attach-resistance at both room-temperature and 500°C over the entire 550 hours test period. The future durability tests are also discussed.


2015 ◽  
Vol 1117 ◽  
pp. 52-55
Author(s):  
Artis Linarts ◽  
Maris Knite

Polymer conductive filler composites are believed to be promising materials for flexible force sensor manufacture. Polyisoprene various carbon allotrope hybrid composites were made and their piezoresistive properties depending on the two type’s filler concentration and their ratio have been determined. Electrical resistance relaxations of hybrid composites at constant pressure in room temperature were determined as well. Experimental data of resistance relaxation was analyzed and fitted similarly to stress relaxation of polymers at constant pressure.


Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 893 ◽  
Author(s):  
Massimo Dell’Edera ◽  
Francesca Petronella ◽  
Alessandra Truppi ◽  
Leonarda Francesca Liotta ◽  
Nunzio Gallì ◽  
...  

We report the synthesis of mesoporous TiO2 nanostructures based on the decomposition of TiOSO4 in aqueous alkaline solution at room temperature, followed by mild thermal treatment (110 °C) in an oven and suitable to yield up to 40 g of product per batch. The duration of the thermal treatment was found to be crucial to control crystalline phase composition, specific surface area, surface chemistry and, accordingly, the photocatalytic properties of the obtained TiO2 nanocrystals. The thorough investigation of the prepared samples allowed us to explain the relationship between the structure of the obtained nanoparticles and their photocatalytic behavior, that was tested in a model reaction. In addition, the advantage of the mild treatment against a harsher calcination at 450 °C was illustrated. The proposed approach represents a facile and sustainable route to promptly access an effective photocatalyst, thus holding a significant promise for the development of solutions suitable to real technological application in environmental depollution.


Author(s):  
Cristina de la Calle ◽  
José Antonio Alonso ◽  
Ainara Aguadero ◽  
Maria Teresa Fernández-Díaz ◽  
Florence Porcher

AbstractThe preparation and characterization of two polymorphs of the title composition are described. One hexagonal perovskite, labeled as “H”, was synthesized by thermal treatment of reactive citrate precursor at 900 °C in high oxygen pressure (20 MPa) followed by slow cooling (10 °C/min) to room temperature. This 1D-structure displays aThe evolution of the crystal structure of the 3C phase has been explored


2018 ◽  
Vol 11 (10) ◽  
pp. 106501 ◽  
Author(s):  
Yoshiaki Ajima ◽  
Yuki Nakamura ◽  
Kenta Murakami ◽  
Hideo Teramoto ◽  
Ryota Jomen ◽  
...  

2017 ◽  
Vol 265 ◽  
pp. 456-462 ◽  
Author(s):  
P.L. Reznik ◽  
Mikhail Lobanov

Studies have been conducted as to the effect of Cu, Mn, Fe concentration changes in Al-Cu-Mn-Fe-Ti alloy, the conditions of thermal and deformational treatment of ingots and extruded rods 40 mm in diameter on the microstructure, phase composition and mechanical properties. It has been determined that changing Al-6.3Cu-0.3Mn-0.17Fe-0.15Ti alloy to Al-6.5Cu-0.7Mn-0.11Fe-0.15Ti causes an increase in the strength characteristics of extruded rods at the room temperature both after molding and in tempered and aged conditions, irrespective of the conditions of thermal treatment of the initial ingot (low-temperature annealing 420 °С for 2 h, or high-temperature annealing at 530 °С for 12 h). Increasing the extruding temperature from 330 to 480 °С, along with increasing Cu, Mn and decreasing Fe in the alloy Al-Cu-Mn-Ti, is accompanied by the increased level of ultimate strength in a quenched condition by 25% to 410 MPa, irrespective of the annealing conditions of the original ingot. An opportunity to apply the Al-6.3Cu-0.3Mn-0.17Fe-0.15Ti alloy with low-temperature annealing at 420 °С for 2 h and the molding temperature of 330 °С has been found to produce rods where, in the condition of full thermal treatment (tempering at 535 °С + aging at 200 °С for 8 hours), a structure is formed that ensures satisfactory characteristics of high temperature strength by resisting to fracture for more than 100 hours at 300 °С and 70 MPa.


2017 ◽  
Vol 373 ◽  
pp. 179-182 ◽  
Author(s):  
Francisco Guzman ◽  
Judy Tran ◽  
Kimberley Cousins ◽  
Paul K. Dixon ◽  
Douglas Smith ◽  
...  

Croconic acid is the first single molecular organic ferroelectric material exhibiting very high spontaneous polarization (~ 20 μC/cm2) at room temperature. Maximizing polarization depends on minimizing void defects in croconic acid crystals. In this experiment, the change in void defects upon the thermal treatment is characterized using positron annihilation lifetime spectroscopy. Both defect void size and intensity are measured, and their dependence upon the thermal treatment duration is studied. In addition, the relation between the void defect and ferroelectric hysteresis of croconic acid is established.


2007 ◽  
Vol 1042 ◽  
Author(s):  
Pen-Cheng Wang ◽  
Yaping Dan ◽  
Luke A. Somers ◽  
Alan G. MacDiarmid ◽  
A.T. Charlie Johnson

AbstractWe present the effect of thermal treatments on the transduction behaviors of HCl-doped polyaniline (PANI) nanofibers integrated in conductometric devices upon exposure to 1% H2 (carried by N2). After drying in N2 at 25ºC for 12 hours, devices showed a ∼10% decrease in electrical resistance upon exposure to 1% H2. However, devices subject to 12-hour drying in N2 at 25ºC followed by further thermal treatments in N2 at 100ºC, 164ºC or 200ºC for 30 minutes showed different transduction behaviors. Specifically, devices subject to thermal treatments at 100ºC and 164ºC showed a decrease in electrical resistance by ∼7% and <0.5%, respectively. More interestingly, the device subject to thermal treatment at 200ºC showed a transduction behavior with opposite polarity, i.e. a ∼5% increase in electrical resistance upon exposure to 1% H2. SEM, FTIR and TGA were employed to investigate the effect of thermal treatments on the morphology and chemical characteristics of HCl-doped polyaniline nanofibers. The results indicated that the change in the devices' interesting transduction behaviors might be related to the thermal treatment effects on the HCl-doped PANI nanofibers in (i) removal of adsorbed water, and (ii) crosslinking and/or degradation of polymer backbones.


2009 ◽  
Vol 1204 ◽  
Author(s):  
Letian Lin ◽  
Lu-Chang Qin ◽  
Sean Washburn ◽  
Scott Paulson

AbstractThe properties of a carbon nanotube (CNT), in particular a single-wall carbon nanotube (SWNT), are highly sensitive to the atomic structure of the nanotube described by its chirality (chiral indices). We have grown isolated SWNTs on a silicon substrate using chemical vapor deposition (CVD) and patterned sub-micron probes using electron beam lithography. The SWNT was exposed by etching the underlying substrate for transmission electron microscope (TEM) imaging and diffraction studies. For each individual SWNT, its electrical resistance was measured by the four-probe method at room temperature and the chiral indices of the same SWNT were determined by nano-beam electron diffraction. The contact resistances were reduced by annealing to typically 3-5 kΩ. We have measured the I-V curve and determined the chiral indices of each nanotube individually from four SWNTs selected randomly – two are metallic and two are semiconducting. We will present the electrical resistances in correlation with the carbon nanotube diameter as well as the band gap calculated from the determined chiral indices for the semiconducting carbon nanotubes. These experimental results are also discussed in connection with theoretical estimations.


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