scholarly journals A design strategy to match the band gap of periodic and aperiodic metamaterials

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Luca D’Alessandro ◽  
Anastasiia O. Krushynska ◽  
Raffaele Ardito ◽  
Nicola M. Pugno ◽  
Alberto Corigliano

Abstract The focus of this paper is on elastic metamaterials characterised by the presence of wide sub-wavelength band gap. In most cases, such mechanical property is strictly connected to the periodic repetition of the unit cell. Nonetheless, the strict periodicity requirement could represent a drawback. In this paper, we present a design strategy for aperiodic elastic metamaterials in order to achieve the same performances as for the periodic counterparts. This is done by exploiting the concept of separation of modes for different building blocks, arranged in aperiodic fashion. A theoretical explanation is provided, as well as numerical simulations; the concept is validated by means of a set of experimental tests on prototypes that are realized via additive manufacturing.

2018 ◽  
Author(s):  
Sherif Tawfik ◽  
Olexandr Isayev ◽  
Catherine Stampfl ◽  
Joseph Shapter ◽  
David Winkler ◽  
...  

Materials constructed from different van der Waals two-dimensional (2D) heterostructures offer a wide range of benefits, but these systems have been little studied because of their experimental and computational complextiy, and because of the very large number of possible combinations of 2D building blocks. The simulation of the interface between two different 2D materials is computationally challenging due to the lattice mismatch problem, which sometimes necessitates the creation of very large simulation cells for performing density-functional theory (DFT) calculations. Here we use a combination of DFT, linear regression and machine learning techniques in order to rapidly determine the interlayer distance between two different 2D heterostructures that are stacked in a bilayer heterostructure, as well as the band gap of the bilayer. Our work provides an excellent proof of concept by quickly and accurately predicting a structural property (the interlayer distance) and an electronic property (the band gap) for a large number of hybrid 2D materials. This work paves the way for rapid computational screening of the vast parameter space of van der Waals heterostructures to identify new hybrid materials with useful and interesting properties.


2021 ◽  
Vol 11 (9) ◽  
pp. 4272
Author(s):  
Stefano Invernizzi ◽  
Francesco Montagnoli ◽  
Alberto Carpinteri

The present paper investigates the influence of the specimen size of EN-AW6082 wrought aluminium alloy subjected to very high cycle fatigue (VHCF) tests. The hourglass specimens were tested under fully reversed loading condition, up to 109 cycles, by means of the ultrasonic fatigue testing machine developed by Italsigma® (Italy). Three specimens groups were considered, with a diameter in the middle cross-section ranging from 3 mm up to 12 mm. The stress field in the specimens was determined numerically and by strain gauge measurements in correspondence of the cross-section surface. The dispersion of experimental results has been accounted for, and data are reported in P-S-N diagrams. The decrease in fatigue resistance with increasing specimen size is evident. Theoretical explanation for the observed specimen-size effect is provided, based on Fractal Geometry concepts, allowing to obtain scale independent P-S*-N curves. The fatigue life expectation in the VHCF regime of the EN-AW6082 aluminium alloy full-scale components is rather overestimated if it is assessed only from standard small specimens of 3 mm in diameter. Experimental tests carried out on larger specimens, and a proper extrapolation, are required to assure safe structural design.


2021 ◽  
Author(s):  
Thomas Ohnemus ◽  
Hannes Mollenhauer ◽  
Michael Mirtl ◽  
Steffen Zacharias

<p>The integrated European Long-Term Ecosystem, critical zone and socio-ecological Research Infrastructure (eLTER RI) was accepted onto the ESFRI roadmap in 2018. While several existing thematic environmental RIs in Europe focus on impacts of climate change and/or other elements of environmental change, eLTER RI will be the only research infrastructure embracing holistically the integrated impacts of such stressors on a wide variety of European benchmark ecosystems (major geo-eco-sociological systems across the continent’s ecoclimatological zones and Earth’s critical zone). In the beginning of 2020 eLTER RI entered the preparatory phase aiming at the development of the legal, financial and technical maturity required for an ESFRI Research Infrastructure.</p><p>The core of the eLTER RI will be ca. 200 selected sites covering all biogeographical zones in Europe, where biological, biogeochemical, hydrological and socio-ecological data will be collected - according to common standards - and analyzed. The European landscape of LTER sites and national networks has mainly been developed in a bottom-up manner. The sites have mostly been established for different monitoring and research purposes and are heterogeneous in terms of investigated ecosystem types, scales of investigation, complexity and instrumentation. Consequently, the transformation of the selected elements of the eLTER RI into a harmonized, high-performance, complementary and interoperable infrastructure is one of the key challenges of eLTER. Achieving the best possible representativity is on the major building blocks in eLTER’s design strategy.</p><p>To evaluate the representativity of eLTER a novel statistical approach combining information on biogeographical, ecological and socio-economic gradients with the management-relevant distribution of established sites was developed aiming at  i) identification of areas in Europe that are geographically underrepresented by the existing eLTER RI site network, ii) definition of priority regions for the geographical extension of the eLTER site network and, iii) development of suggestions for conceptual and infrastructural upgrades for existing less developed eLTER sites.</p><p>Reference datasets depicting biogeographical, ecological and socio-economical gradients were used to describe underrepresentation with a summation parameter called Aggregated Representedness. This statistical criterion was then used to classify five types of “priority regions” from very low to very high priority for geographical and/or conceptual extension. In a second step this information on priority regions was refined using additional information describing the geographical distribution based on Euclidean distances between established eLTER sites.  The combination of these two analyses allowed to identify less developed eLTER sites most suitable for conceptual and infrastructural upgrades. Thus, the presented analysis provides important information for the development of the design strategy for eLTER RI on the continental scale.</p><p>Concluding, a novel approach combining information on biogeographical, ecological and socio-economic gradients with the management-relevant information on the geographical distribution of established sites was developed. This tool allows to evaluate the strategies for further extension of established site networks. </p>


Author(s):  
John J. McCoy ◽  
Ben Zion Steinberg

Abstract A spatially local region of mechanical property heterogeneity is a source of scattering, by which a structure-borne mechanical wavefield is released as sound, to a surrounding fluid. We consider the case of a scatterer which is of the order of the size of the wavelength of a plate-wave field for a frequency which is below coincidence. A design strategy for reducing the strength of the scattered sound field in the fluid, at far-field distances from the scatterer, by adding a small-scale structure to the heterogenity, is presented. The design is accomplished in a wavelet-based phase-space. Emphasized is a significant distinction required of the added structure, depending on the heterogeneity applying to a measure of the local mass density or the local bending stiffness.


2018 ◽  
Vol 10 (10) ◽  
pp. 1850105 ◽  
Author(s):  
Xiao Li Ruan ◽  
Jie Jie Li ◽  
Xiao Ke Song ◽  
Hong Jian Zhou ◽  
Wei Xing Yuan ◽  
...  

Chiral and reentrant metastructures with auxetic deformation abilities can serve as the building blocks in many industrial applications because of their light weight, high specific strength, energy absorption properties. In this paper, we report an innovative tubular-like structure by a combined mechanical effect of antichiral and reentrant. 2D antichiral-reentrant hybrid structures consisting of circular nodes and tangentially-connected ligaments are predesigned and fabricated using laser cutting technology with high-resolution. The elastic properties and auxeticity of the plane structure are analyzed and compared based on finite element analysis (FEA) and experimental results. For the first time, the antichiral-reentrant hybrid intravascular stents with the auxetic feature are proposed and parametric models are devised with good geometrical structure demonstrated. A series of large-scale stents are manufactured with stereolithography apparatus (SLA) additive manufacturing technique, and their mechanical behaviors are investigated in both experimental tests and FEA. As the selected antichiral-reentrant hybrid stents with tailored expansion ability are subjected to radial loading by the dilation of the balloon, stents undergo identifiable deformation mechanism due to the beam-like ligaments and circular node elements in the varied geometrical design, resulting in the distinct stress outcomes in plaque. It is also demonstrated that the antichiral-reentrant hybrid stents with tunable auxeticity possess robust mechanical properties through implantation inside the obstructed lesion.


2018 ◽  
Vol 9 (3) ◽  
pp. 279-283 ◽  
Author(s):  
Cheng Qian ◽  
En-Cheng Liu ◽  
Qiao-Yan Qi ◽  
Kaijia Xu ◽  
Guo-Fang Jiang ◽  
...  

A strategy to construct heteropore covalent organic frameworks has been developed based on a desymmetrization design which takes advantage of the combination of C2v and D3h symmetries.


2014 ◽  
Vol 136 (6) ◽  
Author(s):  
Y. Y. Chen ◽  
G. L. Huang ◽  
C. T. Sun

Elastic metamaterials have been extensively investigated due to their significant effects on controlling propagation of elastic waves. One of the most interesting properties is the generation of band gaps, in which subwavelength elastic waves cannot propagate through. In the study, a new class of active elastic metamaterials with negative capacitance piezoelectric shunting is presented. We first investigated dispersion curves and band gap control of an active mass-in-mass lattice system. The unit cell of the mass-in-mass lattice system consists of the inner masses connected by active linear springs to represent negative capacitance piezoelectric shunting. It was demonstrated that the band gaps can be actively controlled and tuned by varying effective stiffness constant of the linear spring through appropriately selecting the value of negative capacitance. The promising application was then demonstrated in the active elastic metamaterial plate integrated with the negative capacitance shunted piezoelectric patches for band gap control of both the longitudinal and bending waves. It can be found that the location and the extent of the induced band gap of the elastic metamaterial can be effectively tuned by using shunted piezoelectric patch with different values of negative capacitance, especially for extremely low-frequency cases.


2019 ◽  
Vol 91 (6) ◽  
pp. 983-995
Author(s):  
Thi-Thanh-Tam Nguyen ◽  
Sabrina Belbekhouche ◽  
Rémi Auvergne ◽  
Benjamin Carbonnier ◽  
Daniel Grande

Abstract Polyelectrolytes (PEs) bearing easily derivatizable functions for possible post-modification under mild conditions can find a broad range of applications in various fields. The present paper describes the successful controlled side-chain allylation of two types of PEs: polyamine-based polycations, i.e. poly(allylamine hydrochloride) (PAH) and branched polyethyleneimine (PEI), and strong polyanions, i.e. poly(sodium vinyl sulfonate) (PVS) and poly(sodium 4-styrene sulfonate) (PSS). PSS has been largely investigated in the literature, while PVS is much less commonly explored. The allylation of each type presents its own drawback, i.e. heterogeneous reaction in the case of strong polyanions and instability of partially protonated allylated polyamine products. Nevertheless, all encountered difficulties could be solved and thoroughly elucidated by different experimental tests. This partial allyl-functionalization does not affect the electrolytic properties of the newly allylated PEs, as evidenced by the effective construction of two series of polyelectrolyte multilayer (PEM) films, namely PEI-ene (PSS-ene/PAH-ene)4 and PEI-ene (PVS-ene/PAH-ene)4, the latter being one of the rare examples developed in the literature. The presence of allyl groups on the PE side-chains allows for the stabilization of the resulting PEM films via thiol-ene photo-crosslinking in the presence of a water-soluble dithiol crosslinker. In order to fix permanently the resulting crosslinked PEM films on substrates, the covalent crosslinking occurs not only between different C=C bonds on PE layers but also with those present on substrates preliminarily functionalized with allyl groups via sulfur–gold chemistry. The robustness of both resulting crosslinked PEM films under strongly basic solution (pH 14) is validated by Quartz Crystal Microbalance (QCM) measurements. The versatility and effectiveness of the present approach is expected to find potential applications in different scientific and technological fields.


2016 ◽  
Vol 3 (5) ◽  
pp. 545-555 ◽  
Author(s):  
Agnieszka Nowak-Król ◽  
Reinhard Wagener ◽  
Felix Kraus ◽  
Amaresh Mishra ◽  
Peter Bäuerle ◽  
...  

By variation of donor and acceptor building blocks in acceptor–donor–acceptor dyes a transition from p- to n-type semiconductor has been achieved.


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