scholarly journals nanocrystals (0 ≤ x ≤ 1): growth, size control and shell formation on β-NaCeF4:Tb core particles

CrystEngComm ◽  
2020 ◽  
Vol 22 (46) ◽  
pp. 8036-8044
Author(s):  
Jannis Wehmeier ◽  
Markus Haase
Keyword(s):  
Size Control ◽  
Lattice Parameters ◽  
Core Material ◽  
Shell Formation ◽  
Shell Material ◽  
Strontium Content ◽  
The Core ◽  
Lighter Lanthanides ◽  
Core Particles

is an interesting shell material for β-NaREF4 particles of the lighter lanthanides (RE = Ce, Pr, Nd), as variation of its strontium content x allows to vary its lattice parameters and match those of the core material.

SHELL MATERIAL'S PERFORMANCE OF THE MICROCAPSULE FOR ELECTROLYTIC CO-DEPOSITION

2010 ◽  
Vol 24 (15n16) ◽  
pp. 3124-3130 ◽  
Author(s):  
HUI CONG LIU ◽  
XIU QING XU ◽  
WEI PING LI ◽  
YAN HONG GUO ◽  
LI-QUN ZHU
Keyword(s):  
Composite Coating ◽  
Methyl Cellulose ◽  
Water Vapor Permeability ◽  
Core Material ◽  
Vapor Permeability ◽  
Shell Material ◽  
The Core ◽  
Surface Performance ◽  
The Stability ◽  
Positive Effect

The shell material of microcapsules has an important effect on the electrolytic co-deposition behavior, the release of core material and the surface performance of composite coating. This paper discussed the tensile property and the stability of three shell materials including polyvinyl alcohol (PVA), gelatin and methyl cellulose (MC). It is found that these three shell materials have good mechanical strength and flexibility which are favorable to electrolytic co-deposition and stability of microcapsules in composite coating and that MC has well permeability and porosity which has a positive effect on the release of the core material in composite coating. Moreover, the study of the thermal properties and water vapor permeability of the three shell materials showed that their permeability improved with increase of temperature and humidity. In addition, the composite copper coating containing microcapsules with PVA, gelatin or MC as shell material was prepared respectively.

Microencapsulation of Thermochromic Material by Silicon Oxide Nanoparticles

2021 ◽  
Vol 878 ◽  
pp. 41-48
Author(s):  
Abdullatif Hakami ◽  
Sharan Indrakar ◽  
Ashwini Krishnegowda ◽  
Ming Yang Huang ◽  
Keon Sahebkar ◽  
...  
Keyword(s):  
Energy Savings ◽  
Silicon Oxide ◽  
Core Material ◽  
Particle Sizes ◽  
Shell Material ◽  
Thermal Stabilities ◽  
The Core ◽  
Thermochromic Material ◽  
Silicon Oxide Nanoparticles ◽  
The Mean

This study is mainly focused on the fabrication of SiO2 as an inorganic shell material encapsulated an organic thermochromic (TC) core material comprises of either the (i) three-component as-synthesized blue dyes [BDTCM@SiO2] or (ii) off-the-shelf (commercial) black dyes [CDTCM@SiO2]. Both the SiO2 encapsulated thermochromic systems have successfully demonstrated the color transition at around 31 °C. For the three-component thermochromic microcapsules, we have used the crystal violet lactone (CVL) as a leuco dye, bisphenol-A (BPA) as a color developer, and 1-tetradecanol (TD) as a solvent. Different ratios of the thermochromic dye and the metal oxide were prepared to examine the effect of the core@shell ratio on the microstructural and thermal properties of the encapsulated microcapsules. The mean particles sizes of the BDTCM@SiO2 are below 100 nm, whereas, the CDTCM@SiO2 samples exhibited the mean particle sizes varied in a range of 100-1000 nm. The endothermic phase transition due to melting and in general, the thermal stabilities of these SiO2 encapsulated TCMs have been explored for the purpose of deploying these systems for thermal energy savings or storage applications.

Preparation of Infrared Stealthy Coatings

2013 ◽  
Vol 275-277 ◽  
pp. 1934-1937
Author(s):  
Jin Feng Cui ◽  
Yongqiang Ma ◽  
Bao Ping Yang ◽  
Jun Hong Guo ◽  
Ying Ping Zhou
Keyword(s):  
Core Material ◽  
Shell Material ◽  
Melamine Formaldehyde ◽  
Test Device ◽  
Hollow Glass Microspheres ◽  
Infrared Thermometer ◽  
The Core ◽  
Radiation Rate ◽  
Rate Test ◽  
The Common

Two kinds of microcapsules were synthesized with paraffin and the mixture of n-butyl stearate and n-tetradecyl alcohol as the core material, and the melamine-formaldehyde (MF) resin as shell material, respectively. In this way, the infrared stealthy coatings were prepared by using the as-synthesized microcapsules, the hollow glass microspheres and other auxiliaries. The surface morphology of the microcapsules were investigated by using scanning electron microscopy (SEM). By using the contactless infrared thermometer measurement and radiation rate test device, the radiation exitances of coatings were determined. The radiation exitance of infrared stealthy coatings is lower than the common coatings, which improved the performance of infrared stealthy of destination.

Imaging of ribosomal RNA-protein interactions by dark-field STEM

1989 ◽  
Vol 47 ◽  
pp. 250-251
Author(s):  
M. Boublik ◽  
V. Mandiyan ◽  
S. Tumminia ◽  
J.F. Hainfeld ◽  
J.S. Wall
Keyword(s):  
Nucleic Acid ◽  
16S Rrna ◽  
Dark Field ◽  
Radius Of Gyration ◽  
Central Domain ◽  
The Core ◽  
16S Rna ◽  
30S Subunit ◽  
Core Particles

Success in protein-free deposition of native nucleic acid molecules from solutions of selected ionic conditions prompted attempts for high resolution imaging of nucleic acid interactions with proteins, not attainable by conventional EM. Since the nucleic acid molecules can be visualized in the dark-field STEM mode without contrasting by heavy atoms, the established linearity between scattering cross-section and molecular weight can be applied to the determination of their molecular mass (M) linear density (M/L), mass distribution and radius of gyration (RG). Determination of these parameters promotes electron microscopic imaging of biological macromolecules by STEM to a quantitative analytical level. This technique is applied to study the mechanism of 16S rRNA folding during the assembly process of the 30S ribosomal subunit of E. coli. The sequential addition of protein S4 which binds to the 5'end of the 16S rRNA and S8 and S15 which bind to the central domain of the molecule leads to a corresponding increase of mass and increased coiling of the 16S rRNA in the core particles. This increased compactness is evident from the decrease in RG values from 114Å to 91Å (in “ribosomal” buffer consisting of 10 mM Hepes pH 7.6, 60 mM KCl, 2 m Mg(OAc)2, 1 mM DTT). The binding of S20, S17 and S7 which interact with the 5'domain, the central domain and the 3'domain, respectively, continues the trend of mass increase. However, the RG values of the core particles exhibit a reverse trend, an increase to 108Å. In addition, the binding of S7 leads to the formation of a globular mass cluster with a diameter of about 115Å and a mass of ∽300 kDa. The rest of the mass, about 330 kDa, remains loosely coiled giving the particle a “medusa-like” appearance. These results provide direct evidence that 16S RNA undergoes significant structural reorganization during the 30S subunit assembly and show that its interactions with the six primary binding proteins are not sufficient for 16S rRNA coiling into particles resembling the native 30S subunit, contrary to what has been reported in the literature.

scholarly journals Acoustic Panels Made of Paper Sludge and Clay Composites

2021 ◽  
Vol 13 (2) ◽  
pp. 637
Author(s):  
Tomas Astrauskas ◽  
Tomas Januševičius ◽  
Raimondas Grubliauskas
Keyword(s):  
Absorption Coefficient ◽  
Sound Absorption ◽  
Composite Panel ◽  
Sound Absorption Coefficient ◽  
Core Material ◽  
Paper Sludge ◽  
Frequency Range ◽  
Absorption Properties ◽  
Air Gaps ◽  
The Core

Studies on recycled materials emerged during recent years. This paper investigates samples’ sound absorption properties for panels fabricated of a mixture of paper sludge (PS) and clay mixture. PS was the core material. The sound absorption was measured. We also consider the influence of an air gap between panels and rigid backing. Different air gaps (50, 100, 150, 200 mm) simulate existing acoustic panel systems. Finally, the PS and clay composite panel sound absorption coefficients are compared to those for a typical commercial absorptive ceiling panel. The average sound absorption coefficient of PS-clay composite panels (αavg. in the frequency range from 250 to 1600 Hz) was up to 0.55. The resulting average sound absorption coefficient of panels made of recycled (but unfinished) materials is even somewhat higher than for the finished commercial (finished) acoustic panel (αavg. = 0.51).

scholarly journals Iron Based Core-Shell Structures as Versatile Materials: Magnetic Support and Solid Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 72
Author(s):  
Christian Zambrzycki ◽  
Runbang Shao ◽  
Archismita Misra ◽  
Carsten Streb ◽  
Ulrich Herr ◽  
...  
Keyword(s):  
Water Purification ◽  
Functional Materials ◽  
Core Material ◽  
Solid Catalyst ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
The Core ◽  
Shell Nanostructures ◽  
Sio2 Shell ◽  
Iron Based

Core-shell materials are promising functional materials for fundamental research and industrial application, as their properties can be adapted for specific applications. In particular, particles featuring iron or iron oxide as core material are relevant since they combine magnetic and catalytic properties. The addition of an SiO2 shell around the core particles introduces additional design aspects, such as a pore structure and surface functionalization. Herein, we describe the synthesis and application of iron-based core-shell nanoparticles for two different fields of research that is heterogeneous catalysis and water purification. The iron-based core shell materials were characterized by transmission electron microscopy, as well as N2-physisorption, X-ray diffraction, and vibrating-sample magnetometer measurements in order to correlate their properties with the performance in the target applications. Investigations of these materials in CO2 hydrogenation and water purification show their versatility and applicability in different fields of research and application, after suitable individual functionalization of the core-shell precursor. For design and application of magnetically separable particles, the SiO2 shell is surface-functionalized with an ionic liquid in order to bind water pollutants selectively. The core requires no functionalization, as it provides suitable magnetic properties in the as-made state. For catalytic application in synthesis gas reactions, the SiO2-stabilized core nanoparticles are reductively functionalized to provide the catalytically active metallic iron sites. Therefore, Fe@SiO2 core-shell nanostructures are shown to provide platform materials for various fields of application, after a specific functionalization.

Damage behavior of potting materials in sandwich composites with pinned joints

2015 ◽  
Vol 22 (5) ◽  
Author(s):  
Cesim Atas ◽  
Alper Basmaci
Keyword(s):  
Core Material ◽  
Sandwich Composite ◽  
Composite Panels ◽  
Sandwich Composites ◽  
Resin Infusion ◽  
Damage Behavior ◽  
Mechanical Joints ◽  
The Core ◽  
Bottom Face ◽  
Infusion Technique

AbstractThe damage behavior of the potting materials around a pinhole, being used in the mechanical joints of sandwich composites, is investigated experimentally. The sandwich composite panels used in the tests were manufactured by the vacuum-assisted resin infusion technique. Each of the top and bottom face sheets of the panels consisted of two woven E-glass/epoxy layers. As the core material, PVC foam (AIREX

Release Profile of a Model Protein Drug Depending on the Stability of Microspheres Based on Polyelectrolyte Complex

2007 ◽  
Vol 342-343 ◽  
pp. 505-508
Author(s):  
Sung Won Kim ◽  
Yun Sik Nam ◽  
Yeon Jin Min ◽  
Jong Ho Kim ◽  
Kwang Meyong Kim ◽  
...  
Keyword(s):  
Polyelectrolyte Complex ◽  
Coating Layer ◽  
Great Influence ◽  
Release Profile ◽  
Core Material ◽  
Glycol Chitosan ◽  
The Core ◽  
Key Factor ◽  
Model Protein ◽  
The Stability

Stability and disintegration of natural polyelectrolyte complex microspheres for protein drugs delivery have been extensively investigated because of their great influence on the drug release patterns. In this study, we tested stability of microspheres with alginate (Alg) core layered by either chitosan (Chi) or glycol chitosan (GChi) by examining release profiles of fluorophorelabeled bovine serum albumin (BSA) and lysozyme (Lys) from the microspheres. While GChi shell was disintegrated quickly, Chi-shell microspheres showed good stability in PBS. Disintegration of the coated layer induced the core material instable. The results indicated that while the charges of the shell material provided additional diffusion barrier against the protein release, the key factor to hold the proteins inside the microspheres was the integrity of the outer coating layer.

Injectivity and Propagation of Sulfonated Acrylamide-Based Copolymers in Low Permeability Carbonate Reservoir Cores in Harsh Salinity and Temperature Conditions : Challenges and Learnings from a Middle East Onshore Case Study

2021 ◽  
Author(s):  
Nicolas Gaillard ◽  
Matthieu Olivaud ◽  
Alain Zaitoun ◽  
Mahmoud Ould-Metidji ◽  
Guillaume Dupuis ◽  
...  
Keyword(s):  
Middle East ◽  
Polymer Solutions ◽  
Carbonate Reservoir ◽  
Core Material ◽  
Low Permeability ◽  
The Core ◽  
Reservoir Conditions ◽  
Carbonate Cores ◽  
The Impact ◽  
Mobility Reduction

Abstract Polymer flooding is one of the most mature EOR technology applied successfully in a broad range of reservoir conditions. The last developments made in polymer chemistries allowed pushing the boundaries of applicability towards higher temperature and salinity carbonate reservoirs. Specifically designed sulfonated acrylamide-based copolymers (SPAM) have been proven to be stable for more than one year at 120°C and are the best candidates to comply with Middle East carbonate reservoir conditions. Numerous studies have shown good injectivity and propagation properties of SPAM in carbonate cores with permeabilities ranging from 70 to 150 mD in presence of oil. This study aims at providing new insights on the propagation of SPAM in carbonate reservoir cores having permeabilities ranging between 10 and 40 mD. Polymer screening was performed in the conditions of ADNOC onshore carbonate reservoir using a 260 g/L TDS synthetic formation brine together with oil and core material from the reservoir. All the experiments were performed at residual oil saturation (Sor). The experimental approach aimed at reproducing the transport of the polymer entering the reservoir from the sand face up to a certain depth. Three reservoir coreflood experiments were performed in series at increasing temperatures and decreasing rates to mimic the progression of the polymer in the reservoir with a radial velocity profile. A polymer solution at 2000 ppm was injected in the first core at 100 mL/h and 40°C. Effluents were collected and injected in the second core at 20 mL/h and 70°C. Effluents were collected again and injected in the third core at 4 mL/h and 120°C. A further innovative approach using reservoir minicores (6 mm length disks) was also implemented to screen the impact of different parameters such as Sor, molecular weight and prefiltration step on the injectivity of the polymer solutions. According to minicores data, shearing of the polymer should help to ensure good propagation and avoid pressure build-up at the core inlet. This result was confirmed through an injection in a larger core at Sor and at 120°C. When comparing the injection of sheared and unsheared polymer at the same concentration, core inlet impairment was suppressed with the sheared polymer and the same range of mobility reduction (Rm) was achieved in the internal section of the core although viscosity was lower for the sheared polymer. Such result indicates that shearing is an efficient way to improve injectivity while maximizing the mobility reduction by suppressing the loss of product by filtration/retention at the core inlet. This paper gives new insights concerning SPAM rheology in low permeability carbonate cores. Additionally, it provides an innovative and easier approach for screening polymer solutions to anticipate their propagation in more advanced coreflooding experiments.

Solar-flare exposure and thermoluminescence of Luna 24 core material

1980 ◽  
Vol 297 (1428) ◽  
pp. 41-50 ◽  
Keyword(s):  
Solar Flare ◽  
Core Material ◽  
Substantial Fraction ◽  
Natural Radiation ◽  
Mixing Properties ◽  
Local Component ◽  
The Core ◽  
Radiation History ◽  
Solar Flare Tracks ◽  
Over Time

Mineral grains from three depths within the Luna 24 drill core ( ca . 90, 125 and 196 cm) have been examined for solar-flare tracks. Large proportions (55-100%) of grains from all three levels are found to be track-rich (with central track densities p e > 10 8 cm -2 ), and a substantial fraction ( ca . 25-50%) of all grains display trackdensity gradients. These observations indicate that most of the mineral grains have been cycled through the top ca . 1 mm of the lunar surface at some time in their history. Some degree of submaturity is observed towards the bottom of the core. The most likely depositional model envisages rapid infall of highly irradiated material into a less mature local component with rather little subsequent reworking. Thermoluminescence (t.l.) studies indicate a lower natural radiation dose in samples from the 196 cm level compared with those from the two upper levels. This can result either from random variations in the local internal radioactivity or from mixing properties of the pre-irradiated material over time scales of less than ca . 100 ka. Radiation sensitization of samples suggests a possible use of t.l. sensitivity for the interpretation of lunar radiation history.

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