scholarly journals Estimation of corrosion resistance of modifying concrete in a solution of sulfuric acid

2018 ◽  
Vol 230 ◽  
pp. 03006 ◽  
Author(s):  
Oleksii Kabus ◽  
Yulyia Kolomiiets ◽  
Viktoriia Lykhohrai
Keyword(s):  
Compressive Strength ◽  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
Acid Solution ◽  
Test Results ◽  
Initial Value ◽  
Test Beam ◽  
Binder Ratio ◽  
Structure Modifier ◽  
Water Binder Ratio

This study presents the test results of 8 concrete series in 5% sulfuric acid solution for 28, 56 and 180 days. Each series was made using two mixtures based on CEM II/A-S 32.5 and CEM III/A 32.5 cements. Modification of the properties of concrete was obtained by the introduction of superplasticizer, silica fume, complex of structure modifier and hydrophobic admixture. The water-binder ratio varied from 0.27 to 0.63, the compressive strength was 26 to 83 MPa, and water absorption from 3.4 to 8.4 %. Samples of test cubes (10x10x10 cm) and test beam (16x4x4 cm) were prepared to immersion in the acid solution. The assessment of corrosion resistance was carried out on the weight loss and strength of concrete in relation to the initial value of 28 days. The obtained results showed that the surface layer of concrete in all samples was destroyed after 28 days of exposure. The deterioration of the corrosion resistance of modified concrete in relation to ordinary concrete without additives was observed regardless of the type of cement. An exception was a series of concrete, which had a water-binder ratio of 0.27–0.28 and a compressive strength of 77–83 MPa.

scholarly journals RESISTANCE OF MORTAR WITH PPC CEMENT AND GEOPOLYMER MORTAR WITH WHITE SOIL SUBSTITUTION IN H2SO4 IMMERSION

ASTONJADRO ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 213
Author(s):  
Yulita Arni Priastiwi ◽  
Arif Hidayat ◽  
Rinaldo Tamrin ◽  
Difa Bagus Sendrika
Keyword(s):  
Compressive Strength ◽  
Sulfuric Acid ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Fine Aggregate ◽  
Test Results ◽  
Binder Ratio ◽  
Density Values ◽  
Materials Used ◽  
Made In

<p class="IsiAbstrak">This study analyzes the effect of immersion of H<sub>2</sub>SO<sub>4</sub> (sulfuric acid) solution with a concentration of 10% on porosity, density and compressive strength of mortar with PPC cement and geopolymer with white soil substitution mortar. The purpose of this study was to determine the resistance of mortar with PPC cement and geopolymer with white soil substitution mortar when immersed in 10% H<sub>2</sub>SO<sub>4</sub> solution. The test object was 5x5x5 cm mortar with materials used including fly ash from PLTU Tanjung Jati B Jepara, white soil from Kupang, fine aggregate, water and alkaline activator in the form of a mixture of 8M NaOH and Na<sub>2</sub>SiO<sub>3</sub> and also PPC cement. The composition of the geopolymer mortar mixture is 1binder: 3Fine Aggregate: 0,5Water-Binder Ratio, while the mortar with PPC cement is made with a composition of 1PPC: 3Fine Aggregate: 0,5Water-Cement Ratio. The geopolymer mortar was made in 6 variations with a white soil substitution percentage of 0-25% with an increase of 5% for each variation. Compressive strength testing using a compression test apparatus. The test results show that the variation in the percentage of white soil substitution has less effect on the size of the porosity value. As for the value of compressive strength and density, white soil substitution has an effect, the higher the white soil substitution, the higher the compressive strength and mortar density values. Geopolymer mortar was better to withstand 10% sulfuric acid solution, while mortar with PPC cement had no resistance to 10% sulfuric acid solution because it continued to deteriorate over the course of the day. The greatest compressive strength is in variation IV (15% white soil substitution) of 15,31 MPa at 28 days of age, while the smallest porosity and greatest density are in variation VI (25% white soil substitution) of 0,17% and 2,205 grams/cm<sup>3</sup>.</p>

scholarly journals STUDI PENDAHULUAN BATAS MAKSIMUM KADAR LUMPUR PADA AGREGAT BETON GEOPOLIMER

2019 ◽  
Vol 18 (1) ◽  
Author(s):  
Djedjen Achmad ◽  
Desi Supriyan
Keyword(s):  
Compressive Strength ◽  
Concrete Aggregate ◽  
Fine Aggregate ◽  
Geopolymer Concrete ◽  
Test Results ◽  
Cement Concrete ◽  
Flexural Tensile Strength ◽  
Binder Ratio ◽  
The Impact ◽  
Water Binder Ratio

ABSTRACTHas been researched the impact of mud in aggregate on geopolymer concrete with studies using the cement concrete as a reference. In this study both of concrete are mixed with a variation of mud of 0%, 0.75%, 3% and 5.75% of the combined aggregate weight. Compressive strength of cement concrete is designed with a target of 300 kg / cm2 and geopolymer concrete is made with water binder ratio (w/b) 0.25, Molarity 12 M, the ratio of sodium silicate and sodium hydroxide 1.5. At the age of 3, 7, 14 and 28 day tested of compressive strength, while the spliting test, flexural tensile strength, and modulus of elasticity are tested at 28 days. From the test results, the higher mud content in aggregate , the mechanical properties of the concrete are decreased. Based on testing of compressive strength in cement concrete at 28 days, with a 3% mud content (the content of the reference mud) turns of compressive strength decreased by 77.356%. Of the percentage reduction on the compressive strength of the cement concrete, can be compared to the mud content in geopolymer concrete at 2.04%. Thus the maximum mud on geopolymer concrete aggregate is, for coarse aggregate of 0.68% and a maximum mud content for fine aggregate was 3.4%.Key words : Mud, aggregate, concrete, cement, geopolimer, strengthABSTRAKTelah diteliti dampak kadar lumpur pada agregat untuk beton geopolimer dengan penelitian menggunakan benda uji beton semen sebagai acuan dan beton geopolimer. Dalam penelitian ini ke dua beton tersebut dicampur dengan lumpur gabungan agregat kasar dan agregat halus dengan variasi 0 %, 0.75 %, 3 % dan 5,75 % dari berat agregat gabungan. Beton semen dirancang dengan target kuat tekan 300 kg/cm2 dan beton geopolimer dibuat dengan campuran water binder ratio (w/b) 0.25, Molaritas 12 M, perbandingan sodium silikat dan sodium hidroksida 1.5. Pada umur 3, 7, 14 dan 28 hari dilakukan uji kuat tekan, sedangkan uji kuat tarik belah, uji kuat tarik lentur, dan modulus elastisitas dilakukan pada umur 28 hari. Dari hasil uji terlihat bahwa semakin tinggi kadar lumpur pada agregat, karakteristik mekanis kedua beton tersebut mengalami penurunan. Berdasarkan pengujian kuat tekan pada beton semen umur 28 hari, dengan kadar lumpur 3 % (kadar lumpur referensi) ternyata beton semen mengalami penurunan kuat tekan sebesar 77.356 %. Dari persentase penurunan kuat tekan beton semen tersebut, diplot pada grafik kuat tekan beton geopolimer maka persentase kadar lumpur gabungan yang mengalami penurunan 77.356 % adalah 2.04 %. Dengan demikian kadar lumpur maksimum pada agregat beton geopolimer adalah, untuk agregat kasar sebesar 0.68 % dan kadar lumpur maksimum untuk agregat halus adalah 3.4 %.Kata kunci : Lumpur, agregat, beton, semen, geopolimer, kekuatan

scholarly journals Design of Concrete Mix Proportion Based on Particle Packing Voidage and Test Research on Compressive Strength and Elastic Modulus of Concrete

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 623
Author(s):  
Yun-Hong Cheng ◽  
Bao-Long Zhu ◽  
Si-Hui Yang ◽  
Bai-Qiang Tong
Keyword(s):  
Compressive Strength ◽  
Elastic Modulus ◽  
Volume Fraction ◽  
Design Method ◽  
Particle Packing ◽  
Test Results ◽  
Concrete Mix Design ◽  
Concrete Mix ◽  
Binder Ratio ◽  
Water Binder Ratio

According to the basic principle of dense packing of particles, and considering the interaction between particles, a dense packing model of granular materials in concrete was proposed. During the establishment of this model, binary particle packing tests of crushed stone and sand were carried out. The fitting analysis of the test results determines the relationship between the particle size ratio and the remaining volume fraction of the particle packing, and then the actual void fraction of the particle packing was obtained, based on which the water–binder ratio was combined to determine the amount of various materials in the concrete. The proposed concrete mix design method was used to prepare concrete, and its compressive strength and elastic modulus were tested experimentally. The test results show that the aggregate volume fraction of the prepared concrete increased, and the workability of the concrete mixture with the appropriate amount of water reducing agent meets the design requirements. When the water–binder ratio was 0.42, 0.47, or 0.52, the compressive strength of the concrete increased compared with the control concrete, and the degree of improvement in compressive strength increased with the decrease in water–binder ratio; when the water-binder ratio was 0.42, 0.47, or 0.52, the static elastic modulus of the concrete increased compared with the control concrete, and the degree of improvement in elastic modulus also increased with the decrease in water–binder ratio. The elastic modulus and compressive strength of the prepared concrete have a positive correlation. Findings show that the concrete mix design method proposed by this research is feasible and advanced in a sense.

Compressive Strength and High-Temperature Residual Strength of Cement Specimens Containing Bagasse Ash

2016 ◽  
Vol 723 ◽  
pp. 813-818
Author(s):  
I Feng Wang ◽  
Cheng Haw Lee ◽  
Chun Ku Lu
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Cement Mortar ◽  
Waste Product ◽  
High Water ◽  
Test Results ◽  
High Carbon ◽  
Cement Replacement ◽  
Binder Ratio ◽  
Water Binder Ratio

Cement is currently the most versatile and widely used material in construction. However, the high carbon emissions and energy consumption associated with the manufacture of cement remains a serious concern. bagasse ash (BA) is a secondary waste product of bagasse-fired power generation. This study investigated the use of BA as a replacement for cement as a means of reducing the environmental impact of concrete-based construction. At 28 days, we measured the water absorption of cement mortar specimens as well as the compressive strength at room-temperature and after heating. Experiments were conducted involving the replacement of various proportions of cement using BA and fly ash (FA), followed by a comparison of the physical properties. Our test results demonstrate the applicability of BA in the production of cement mortar mixtures with high water-binder ratios. It was found that the water-binder ratio determines the optimal proportion of BA when used as a replacement for cement, wherein a higher water-binder ratio means that more of the cement can be replaced with BA. In compressive strength respect, the optimal cement replacement with BA was 15 % to 25 %, whereas the optimal cement replacement with FA was 20 %. BA was shown to have a more pronounced effect in reducing water absorption in cement mortar specimens with high water-binder ratios (0.55 to 0.65). The compactness of specimens with lower water absorption enables them to retain more of their initial compressive strength following exposure to high temperatures.

scholarly journals Corrosion Behavior of AA 1100 Anodized in Gallic-Sulfuric Acid Solution

Coatings ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 405
Author(s):  
Marlon L. Mopon ◽  
Jayson S. Garcia ◽  
Dexter M. Manguerra ◽  
Cyril John C. Narisma
Keyword(s):  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
Acid Solution ◽  
Gallic Acid ◽  
Acid Concentration ◽  
Sulfuric Acid Solution ◽  
Current Density ◽  
Electrochemical Impedance ◽  
Anodized Aluminum ◽  
The Common

Sulfuric acid anodization is one of the common methods used to improve corrosion resistance of aluminum alloys. Organic acids can be added to the sulfuric acid electrolyte in order to improve the properties of the anodized aluminum produced. In this study, the use of gallic acid as an additive to the sulfuric acid anodization of AA1100 was explored. The effect of varying anodization current density and gallic acid concentration on the properties of anodized aluminum samples was observed using electrochemical impedance spectroscopy, linear polarization, and scanning electron microscopy. It was observed that the corrosion resistance of samples anodized in gallic-sulfuric acid solution at 10 mA·cm−2 is lower than samples anodized in sulfuric acid. It was also observed that higher anodization current density can lead to lower corrosion resistances for aluminum samples anodized in gallic-sulfuric acid solution. However, samples anodized at 5 mA·cm−2 and at a gallic acid concentration of 5 g·L−1 showed better corrosion performance than the samples anodized in sulfuric acid only. This suggests that the use of low amounts of gallic acid as an additive for sulfuric acid anodization can lead to better corrosion resistances for anodized aluminum.

scholarly journals Resistance to Sulfuric Acid Corrosion of Geopolymer Concrete Based on Different Binding Materials and Alkali Concentrations

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7109
Author(s):  
Wei Yang ◽  
Pinghua Zhu ◽  
Hui Liu ◽  
Xinjie Wang ◽  
Wei Ge ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
Fly Ash ◽  
Acid Corrosion ◽  
Geopolymer Concrete ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Naoh Solution ◽  
Sulfuric Acid Corrosion

Geopolymer binder is expected to be an optimum alternative to Portland cement due to its excellent engineering properties of high strength, acid corrosion resistance, low permeability, good chemical resistance, and excellent fire resistance. To study the sulfuric acid corrosion resistance of geopolymer concrete (GPC) with different binding materials and concentrations of sodium hydroxide solution (NaOH), metakaolin, high-calcium fly ash, and low-calcium fly ash were chosen as binding materials of GPC for the geopolymerization process. A mixture of sodium silicate solution (Na2SiO3) and NaOH solution with different concentrations (8 M and 12 M) was selected as the alkaline activator with a ratio (Na2SiO3/NaOH) of 1.5. GPC specimens were immersed in the sulfuric acid solution with the pH value of 1 for 6 days and then naturally dried for 1 day until 98 days. The macroscopic properties of GPC were characterized by visual appearance, compressive strength, mass loss, and neutralization depth. The materials were characterized by SEM, XRD, and FTIR. The results indicated that at the immersion time of 28 d, the compressive strength of two types of fly ash-based GPC increased to some extent due to the presence of gypsum, but this phenomenon was not observed in metakaolin-based GPC. After 98 d of immersion, the residual strength of fly ash based GPC was still higher, which reached more than 25 MPa, while the metakaolin-based GPC failed. Furthermore, due to the rigid 3D networks of aluminosilicate in fly ash-based GPC, the mass of all GPC decreased slightly during the immersion period, and then tended to be stable in the later period. On the contrary, in metakaolin-based GPC, the incomplete geopolymerization led to the compressive strength being too low to meet the application of practical engineering. In addition, the compressive strength of GPC activated by 12 M NaOH was higher than the GPC activated by 8 M NaOH, which is owing to the formation of gel depended on the concentration of alkali OH ion, low NaOH concentration weakened chemical reaction, and reduced compressive strength. Additionally, according to the testing results of neutralization depth, the neutralization depth of high-calcium fly ash-based GPC activated by 12 M NaOH suffered acid attack for 98 d was only 6.9 mm, which is the minimum value. Therefore, the best performance was observed in GPC prepared with high-calcium fly ash and 12 M NaOH solution, which is attributed to gypsum crystals that block the pores of the specimen and improve the microstructure of GPC, inhibiting further corrosion of sulfuric acid.

Research in the Preparation of Paving Bricks with Construction Garbage

2013 ◽  
Vol 712-715 ◽  
pp. 917-920
Author(s):  
Lian Xi Wang ◽  
Guang Hui Pan ◽  
Fu Yong Li ◽  
Hai Ming Wang ◽  
Guo Zhong Li
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Experimental Results ◽  
Replacement Rate ◽  
Coarse Aggregates ◽  
Waste Concrete ◽  
Fine Aggregates ◽  
Binder Ratio ◽  
Water Binder Ratio

Construction garbage paving bricks were made of recycled coarse and fine aggregates which were prepared by the waste concrete. The influence of replacement rate of recycled coarse aggregates, water-binder ratio and excitation agent dosage on the compressive strength and flexural strength of construction garbage paving bricks were researched. The experimental results show that optimum replacement rate of recycled coarse aggregates, water-binder ratio and excitation agent dosage were 100%, 0.43 and 1.5% respectively. In this proportion, the 7d, 28d compressive strength of the products were 15.6MPa, 37.5MPa respectively, and the 7d, 28d flexural strength were 2.0MPa, 4.3MPa respectively, which fit the requirements of the Cc30 level of compressive strength and the Cf4.0 level of flexural strength involved in JCT 446-2000 "concrete pavers".

scholarly journals Mechanical Properties and Environmental Evaluation of Ultra-High-Performance Concrete with Aeolian Sand

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3148 ◽  
Author(s):  
Hongyan Chu ◽  
Fengjuan Wang ◽  
Liguo Wang ◽  
Taotao Feng ◽  
Danqian Wang
Keyword(s):  
Compressive Strength ◽  
Environmental Impact ◽  
Young’S Modulus ◽  
High Performance ◽  
High Performance Concrete ◽  
Young's Modulus ◽  
Ultra High Performance Concrete ◽  
Aeolian Sand ◽  
Binder Ratio ◽  
Water Binder Ratio

Ultra-high-performance concrete (UHPC) has received increasing attention in recent years due to its remarkable ductility, durability, and mechanical properties. However, the manufacture of UHPC can cause serious environmental issues. This work addresses the feasibility of using aeolian sand to produce UHPC, and the mix design, environmental impact, and mechanical characterization of UHPC are investigated. We designed the mix proportions of the UHPC according to the modified Andreasen and Andersen particle packing model. We studied the workability, microstructure, porosity, mechanical performance, and environmental impact of UHPC with three different water/binder ratios. The following findings were noted: (1) the compressive strength, flexural strength, and Young’s modulus of the designed UHPC samples were in the ranges of 163.9–207.0 MPa, 18.0–32.2 MPa, and 49.3–58.9 GPa, respectively; (2) the compressive strength, flexural strength, and Young’s modulus of the UHPC increased with a decrease in water/binder ratio and an increase in the steel fibre content; (3) the compressive strength–Young’s modulus correlation of the UHPC could be described by an exponential formula; (4) the environmental impact of UHPC can be improved by decreasing its water/binder ratio. These findings suggest that it is possible to use aeolian sand to manufacture UHPC, and this study promotes the application of aeolian sand for this purpose.

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