scholarly journals The role of shrinkage reducing admixtures and supplementary cementitious materials in volume stability and strength development

2019 ◽  
Vol 289 ◽  
pp. 02005
Author(s):  
Ioanna Papayianni ◽  
Fotini Kesikidou ◽  
Philip Henes Alt

Shrinkage is one of the main reasons for mortar and concrete failures like curling, crack formation and de-bonding. It is a complex phenomenon due to many factors involved, such as the type and amount of cement, water to binder ratio, binder to aggregates ratio and the type and granulometry of the aggregates, relative humidity, air temperature and the temperature of concrete. To reduce this phenomenon, Shrinkage Reducing Admixtures (SRAs) have been studied over the last 30 years. On the other hand, investigation in the field of Supplementary Cementitious Materials (SCMs) has indicated that their use in concrete may improve its volume stability depending on their percentage and the type of the material. In this paper, the addition of a Shrinkage Reducing Admixture and Supplementary Cementitious Materials like ladle furnace slag, calcareous fly ash and limestone filler, were investigated. Their influence, separately and in combination, in volume stability and strength development of cement mortars was identified. Capillary absorption and open porosity were also determined.

2018 ◽  
Vol 69 (4) ◽  
pp. 860-863 ◽  
Author(s):  
Carmen Oproiu ◽  
Georgeta Voicu ◽  
Adrian Ionut Nicoara ◽  
Alina Ioana Badanoiu

The use of wastes in cement industry have impact both from economic and environmental point of views. Wastes can be used in clinker manufacture (to substitute raw materials or as alternative fuel) as well as supplementary cementitious materials in cement. This paper presents results regarding the use of heavy ash (bottom ash) as component of raw mix used for the clinker manufacture. Two types of cements were obtained by the milling of clinker produced with/without heavy ash (HA) as component of raw mix and gypsum (2%). The compressive strengths of these cements was assessed on plastic mortars (water:binder = 1:2 ratio and binder:aggregate = 1:3 ratio), cast in prismatic moulds (14x14x160 mm3), hardened different periods of time comprised between 1 to 28 days. The hydration and hardening processes which occur in the cementitious systems with/without waste content were assessed on pastes with water to binder ratio of 0.5, hardened for 1 up to 90 days. X-ray diffraction (XRD) and complex thermal analysis (DTA-TG) were used for pastes� characterization. The composition of clinker was assessed by XRD and microstructure by scanning electron microscopy (SEM). The results obtained in the framework of this research do not show any important difference between the clinkers� characteristics produced with alternative raw material (heavy ash) as compared with the ones produced with natural raw materials. Also, the properties of cements produced of these clinkers are similar.


2021 ◽  
Vol 17 ◽  
pp. 271-281
Author(s):  
Efstratios Badogiannis ◽  
Eirhnh Makrinou ◽  
Marianna Fount

A study on the durability parameters of normal and lightweight aggregate mortars, incorporated different supplementary cementitious materials (SCM) is presented. Mortars were prepared using limestone or pumice as aggregates and Metakaolin, Fly ash, Granulated Blast Furnace Slag and Silica Fume, as SCM, that they replaced cement, at 10 % by mass. Ten different mortars, having same water to binder ratio and aggregate to cement volumetric ratio, they were compared mainly in terms of durability. The use of pumice sand was proved to be effective not only to the density of the mortars as it was expected, but also in durability, fulfilling at the same time minimum strength requirements. The addition of the different SCM further enhanced the durability of the mortars, where Metakaolin was found to be the most effective one, especially against chloride’s ingress.


2021 ◽  
Vol 11 (9) ◽  
pp. 4028
Author(s):  
Asghar Gholizadeh Vayghan ◽  
Liesbeth Horckmans ◽  
Ruben Snellings ◽  
Arne Peys ◽  
Priscilla Teck ◽  
...  

This research investigated the possibility of using metallurgical slags from the copper and lead industries as partial replacement for cement. The studied slags were fayalitic, having a mainly ferro-silicate composition with minor contents of Al2O3 and CaO. The slags were treated at 1200–1300 °C (to reduce the heavy metal content) and then granulated in water to promote the formation of reactive phases. A full hydration study was carried out to assess the kinetics of reactions, the phases formed during hydration, the reactivity of the slags and their strength activity as supplementary cementitious material (SCM). The batch-leaching behaviour of cementitious mixtures incorporating treated slags was also investigated. The results showed that all three slags have satisfactory leaching behaviour and similar performance in terms of reactivity and contribution to the strength development. All slags were found to have mediocre reactivity and contribution to strength, especially at early ages. Nonetheless, they passed the minimum mechanical performance requirements and were found to qualify for use in cement.


2019 ◽  
Vol 4 ◽  
pp. 9-15
Author(s):  
Md Shamsuddoha ◽  
Götz Hüsken ◽  
Wolfram Schmidt ◽  
Hans-Carsten Kühne ◽  
Matthias Baeßler

Grouts have numerous applications in construction industry such as joint sealing, structural repair, and connections in precast elements. They are particularly favoured in rehabilitation of structures due to penetrability and convenience of application. Grouts for repair applications typically require high-performance properties such as rapid strength development and superior shrinkage characteristics. Sometimes industrial by-products referred as supplementary cementitious materials (SCM) are used with neat cement due to their capabilities to provide binding properties at delayed stage. Micro silica, fly ash and metakaolin are such SCMs, those can modify and improve properties of cement products. This study aims at investigating long-term mass loss and linear shrinkage along with long-term compressive and flexural strength for grouts produced from ultrafine cement and SCMs. A series of mixtures were formulated to observe the effect of SCMs on these grout properties. Properties were determined after 365 days of curing at 23oC and 55% relative humidity. The effect of SCMs on the properties are characterised by statistical models. Response surfaces were constructed to quantify these properties in relation to SCMs replacement. The results suggested that shrinkage was reduced by metakaolin, while micro silica and fly ash had positive effects on compressive and flexural strength, respectively.


Author(s):  
Khashayar Jafari ◽  
Farshad Rajabipour

Supplementary cementitious materials (SCMs) are natural or industrial by-product materials which are used to improve the performance, durability, and sustainability of concrete mixtures. Motivated by the recent reports on shortage of conventional SCMs, impure calcined clays (CCs) are receiving attention as abundant alternative pozzolans for concrete. In this study, a clay slurry resulting from washing aggregates in a commercial sand and gravel pit was investigated. This source clay was dried and calcined, and the properties and pozzolanic performance of the resulting CC was evaluated. It was observed that despite having a large (>50%wt.) inert quartz content, the CC met all ASTM C618-19 (AASHTO M295) requirements for natural pozzolan. A pavement-grade concrete mixture containing 20%CC as a cement replacement (by weight) produced desired workability and fresh and hardened air content. Strength development was slightly below the control. The use of CC improved the durability of concrete with respect to chloride penetration, alkali–silica reaction, and drying shrinkage in comparison with a control (100% Portland cement) mixture. In addition, ternary limestone-calcined clay–cement and slag-calcined clay–cement mortar mixtures showed excellent strength development while replacing nearly 50% of the Portland cement.


Author(s):  
W. Micah Hale ◽  
Thomas D. Bush ◽  
Bruce W. Russell ◽  
Seamus F. Freyne

Often, concrete is not mixed or placed under ideal conditions. Particularly in the winter or the summer months, the temperature of fresh concrete is quite different from that of concrete mixed under laboratory conditions. This paper examines the influence of supplementary cementitious materials on the strength development (and other hardened properties) of concrete subjected to different curing regimens. The supplementary cementitious materials used in the research program were ground granulated blast furnace slag (GGBFS), fly ash, and a combination of both materials. The three curing regimens used were hot weather curing, standard curing, and cold weather curing. Under the conditions tested, the results show that the addition of GGBFS at a relatively low replacement rate can improve the hardened properties for each curing regimen. This improvement was noticeable not only at later ages but also at early ages. Mixtures that contained both materials (GGBFS and fly ash) performed as well as and, in most cases, better than mixtures that contained only portland cement in all curing regimens.


Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2590 ◽  
Author(s):  
Karol Federowicz ◽  
Maria Kaszyńska ◽  
Adam Zieliński ◽  
Marcin Hoffmann

Technological developments in construction have led to an increase in the use of 3D modelling using CAD environments. The popularity of this approach has increased in tandem with developments in industry branches which use 3D printers to print concrete based printing materials in construction, as these allow freedom in shaping the dimensions of supporting elements. One of the biggest challenges for researchers working on this highly innovative technology is that of cement material shrinkage. This article presents the findings of research on an original method of measuring deformations caused by shrinkage in 3D-printed concrete elements. It also discusses the results of tests on base mixes, as well as comparisons between the influence of internal and external curing methods on the development of deformations and their final outcomes. Furthermore, the article discusses differences between deformations formed after seven days of hardening without curing, with those which occur when two common, traditional concrete curing methods are used: foil insulation and shrinkage reducing admixtures. In addition, the article examines the effects of internal curing on the 1, 7, 14, 21 and 28 day mechanical properties of concrete, in accordance with EN 196-1 and EN 12390-2. Studies have shown that the optimal amount of shrinkage reducing admixtures is 4% (in relation to the mass of cement), resulting in a reduction in total shrinkage of 23%. The use of a shrinkage reducing admixture in 3D-printed concrete does not affect their strength after 28 days, but slows the strength development during the first 7 days.


Author(s):  
Cameron Wilson ◽  
W. Jason Weiss

High early strength (HES) concrete patching materials are increasingly used to repair damaged pavements. The use of HES concrete enables the repaired pavement to be opened to traffic shortly after the repair has been installed; for example, opening pavements to traffic 4–6 h after the concrete is placed is becoming more common. HES concrete mixtures are typically designed with a low water-to-cement ratio and a high cement content; they contain accelerating admixtures and limited supplementary cementitious materials. As a result, these HES patches may be susceptible to self-desiccation, causing autogenous shrinkage and early age cracking. Self-desiccation can lead to reduced hydration, limited strength gain, and overestimation of strength development in maturity-based predictions. The objectives of this study are threefold. First, the paper will illustrate how self-desiccation can lead to the premature cessation of hydration and increased potential for shrinkage cracking. Second, the paper will illustrate how maturity-based predictions can be modified to account for self-desiccation. Third, internal curing is discussed as a way to mitigate self-desiccation and shrinkage ultimately improving the performance of HES concrete patching materials.


Solids ◽  
2021 ◽  
Vol 2 (4) ◽  
pp. 331-340
Author(s):  
Zoltán Gyurkó ◽  
Rita Nemes

The present paper deals with the hardness of cement mortars prepared with recycled materials that are potential supplementary cementitious materials (SCM). Two potential SCMs (aerated concrete powder (ACP) and concrete powder) were investigated and compared with a reference (neat cement) sample and a sample containing metakaolin (MK). The long-term performance of the mortars was studied up to the age of one year. Based on the compressive strength tests at different ages, neither concrete powder nor ACP significantly decreases the compressive strength at a 10% substitution ratio. The samples were studied with two types of static hardness tests: the Brinell hardness test and the depth sensing indentation test at two different load levels. The hardness test results indicated that the standard deviation of the results is lower at a higher load level. In the case of metakaolin and concrete powder, the change in the compressive strength was observable in the hardness test results. However, in case of the ACP, the compressive strength decreased, while the hardness increased, which can be traced back to the filler effect of aerated concrete powder. Finally, using the DSI test, the hardness results were analyzed on an energy basis. The analysis highlighted that the change in the hardness is connected to the elastic indentation energy, while it is independent from the dissipated (plastic) indentation energy.


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