scholarly journals Ethyl Formate as a Methyl Bromide Alternative for Fumigation of Citrus: Efficacy, Fruit Quality, and Workplace Safety

Author(s):  
Min-Goo Park ◽  
Byung-Ho Lee ◽  
Jeong-Oh Yang ◽  
Bong-Soo Kim ◽  
Gwang Hyun Roh ◽  
...  

Abstract Ethyl formate (EF) was evaluated as a potential alternative to methyl bromide (MB) for phytosanitary treatment of imported citrus fruit in the Republic of Korea. Planococcus citri (Risso) (Hemiptera: Pseudococcidae), a mealybug with known tolerance against EF and MB, was used as a representative pest to test efficacy of the two fumigants against eggs. In nine commercial-scale refrigerated container (67.5 m3) trials using imported orange, lemon and grapefruit, EF applied at the currently approved dose for citrus (70 g·m-3 at 5°C for 4 h, developed for Aspidiotus excisus Green (Hemiptera: Diaspididae), a species less EF tolerant than P. citri) resulted in 76.9–98.3% mortality of P. citri eggs. The EF treatment did not affect the sugar content or the color of peel and pulp of the treated fruit. When oranges were treated according to the current MB (64 g·m-3 at >5°C for 2 h) or EF treatment guidelines, the concentration of fumigant around the fruit fluctuated between 9.4 and 185.1 ppm for EF and 9.5–203.0 ppm for MB during the 72-h post-fumigation processes (venting [0–2 h], transportation to storage [2–24 h], and storage periods [24–72 h]) with both EF and MB maintained between 10 and 100 ppm during the storage period. Considering the efficacy of EF, its apparent lack of phytotoxicity, and its more manageable threshold limit value for humans (100 ppm EF compared to 1 ppm MB for an 8-h time weighted average exposure), our results suggest that EF may be a promising alternative to MB for the phytosanitary treatment of imported citrus in Korea.

2020 ◽  
Vol 113 (4) ◽  
pp. 1711-1717
Author(s):  
Min-Goo Park ◽  
Chung-Gyoo Park ◽  
Jeong-Oh Yang ◽  
Gil-Hah Kim ◽  
Yonglin Ren ◽  
...  

Abstract Methyl bromide (MB) use for quarantine and phytosanitary purposes is being phased out. Several effective MB alternatives have been identified depending on the target system. Industry commitment for the shift to new technologies will depend not only on the efficacy of alternatives but also on their compatibility and integrability into existing operations. We compared the efficacy of MB and ethyl formate (EF) for disinfestation of Planococcus citri (Risso) (Hemiptera: Pseudococcidae) as a representative surface pest on banana and evaluated whether EF fumigation is compatible with the current packaging materials and loading ratio used by the South Korean banana import industry. Fumigation trials with P. citri adults and eggs showed that EF was at least as effective as MB at the EF and MB concentrations recommended under the current phytosanitary disinfestation guidelines. From a logistical standpoint, EF gas could not effectively penetrate plastic bagging typically used in banana cartons during commercial shipping. Also, EF sorption to bananas and packing materials (used as cushioning inside bagging) further lowered realized EF concentrations around bananas. These reductions in EF concentration translated into reduced mortality of P. citri eggs, indicating that despite similar efficacy of MB and EF for controlling P. citri, further consideration and optimization of other industry logistics such as packaging and loading ratio is necessary to enhance the adoption of this MB alternative.


Author(s):  
Zhongqi Zhu ◽  
Zhiyuan Gong ◽  
Piao Qu ◽  
Ziyong Li ◽  
Sefiu Abolaji Rasaki ◽  
...  

AbstractInkjet printing is a promising alternative for the fabrication of thin film components for solid oxide fuel cells (SOFCs) due to its contactless, mask free, and controllable printing process. In order to obtain satisfying electrolyte thin layer structures in anode-supported SOFCs, the preparation of suitable electrolyte ceramic inks is a key. At present, such a kind of 8 mol% Y2O3-stabilized ZrO2 (8YSZ) electrolyte ceramic ink with long-term stability and high solid loading (> 15 wt%) seems rare for precise inkjet printing, and a number of characterization and performance aspects of the inks, such as homogeneity, viscosity, and printability, should be studied. In this study, 8YSZ ceramic inks of varied compositions were developed for inkjet printing of SOFC ceramic electrolyte layers. The dispersing effect of two types of dispersants, i.e., polyacrylic acid ammonium (PAANH4) and polyacrylic acid (PAA), were compared. The results show that ultrasonic dispersion treatment can help effectively disperse the ceramic particles in the inks. PAANH4 has a better dispersion effect for the inks developed in this study. The inks show excellent printable performance in the actual printing process. The stability of the ink can be maintained for a storage period of over 30 days with the help of initial ultrasonic dispersion. Finally, micron-size thin 8YSZ electrolyte films were successfully fabricated through inkjet printing and sintering, based on the as-developed high solid loading 8YSZ inks (20 wt%). The films show fully dense and intact structural morphology and smooth interfacial bonding, offering an improved structural quality of electrolyte for enhanced SOFC performance.


2020 ◽  
Vol 2020 ◽  
pp. 1-12 ◽  
Author(s):  
İbrahim Kahramanoğlu ◽  
Chuying Chen ◽  
Yao Chen ◽  
Jinyin Chen ◽  
Zengyu Gan ◽  
...  

The current research aimed at studying the possibility of improving the postharvest storability of “Nanfeng” mandarins by hot water dipping (HWD) treatment. The research was conducted in two phases. Firstly, two different temperatures (50 and 55°C) were tested for three different dipping durations (2, 3, and 4 min) on the mandarin fruits, and the best combination was defined for the prevention of weight loss and fruit decay. Next, the optimal treatment (HWD at 50°C for 3 min) was used in further studies to test the effects on the postharvest fruit quality attributes. Regular measurements were performed to determine total soluble solid (TSS) content, titratable acid (TA) content, vitamin C (VC) content, total sugar content, respiration rate, malondialdehyde (MDA) content, and activities of superoxide dismutase (SOD) enzyme, polyphenoloxidase (PPO) enzyme, and peroxidase (POD) enzyme. According to the results obtained, HWD treatment was found to prevent the loss of TSS, TA, and VC contents during the storage period. The HWD-treated fruits were also found to have a lower respiration rate and MDA content as compared with control treatment. Furthermore, HWD treatment significantly enhanced the activities of SOD, POD, and PPO which are known to enhance tolerance to lipid peroxidation and are associated with the fruit protection from injuries and pathogens. Present results also suggest that the activation of the SOD and POD enzymes is highly related to the respiratory activities of the fresh produce. This suggests that the HWD can be used to improve the storability of “Nanfeng” mandarins by maintaining the postharvest physical and biochemical quality.


2019 ◽  
Vol 112 (5) ◽  
pp. 2149-2156 ◽  
Author(s):  
Yejin Kyung ◽  
Hyun Kyung Kim ◽  
Sung Woo Cho ◽  
Bong-Su Kim ◽  
Jeong-Oh Yang ◽  
...  

Abstract The fumigation activity of phosphine (PH3) and ethyl formate (EF) and their phytotoxicity to 13 imported foliage nursery plant species were evaluated. The lethal concentration and time (LCT99) values of the PH3 indicated that the susceptibility of the nymphs (3.95 and <0.45 mg·h/liter, respectively) was higher than that of the adults (5.29 and 3.66 mg·h/liter, respectively) of two mealybugs [Pseudococcus longispinus (Targioni-Tozzetti) and P. orchidicola Takahashi]. The highest concentration reduction rate of PH3 and EF on the 13 foliage nursery plants in the 12-liter desiccator was 41.5% for Heteropanax fragrans and 71.7% for Schefflera arboricola, respectively, which indicates that PH3 has a lower sorption rate than EF. The phytotoxicities of PH3-treated foliage nursery plants did not significantly differ from those of the nontreated plants, but EF caused phytotoxicity in 11 foliage nursery plants a week after treatment. When the exposure time of PH3 increased to 24 h, the adults and nymphs of both mealybug species showed 100% mortality in the 0.5 m3 fumigation chamber. In the 10 m3 fumigation container used in the field, there was 100% mortality of both mealybugs after treatment with 2 g/m3 PH3 for 24 h at 16°C. These results indicate that EF is not a suitable mealybug fumigant due to its high sorption and phytotoxicity to foliage nursery plants, despite fumigation activity against the two species. However, PH3 seems to be suitable for mealybug fumigation in foliage nursery plants and can be used as a substitute for methyl bromide.


2018 ◽  
Vol 44 ◽  
pp. 00114 ◽  
Author(s):  
Natalia Mioduszewska ◽  
Mariusz Adamski ◽  
Anna Smurzyńska ◽  
Jacek Przybył ◽  
Krzysztof Pilarski

The aim of the study was to evaluate the usefulness of sugar beet for biogas production, taking into account the duration time of storage and sugar content in the roots. The research has included analysis of methane and biogas yield of sugar beet. The relations between the sugar content in the roots and the length of storage period and the course of the methane fermentation process were determined. Sugar beets with sugar content of 17.6% and 19.6% were used for this experiment. In order to analyse the fermentation process, the fresh beets and the beets stored in flexible, hermetic tanks in the period of 43 and 89 days were used. Based on the analysis of the obtained results, it was found that the sugar content and the storage time of sugar beet roots can differentiate the production of biomethane and that it influences the methane fermentation process and the quality of the produced biogas.


2018 ◽  
Vol 15 (3) ◽  
pp. 797-808 ◽  
Author(s):  
Yuewei Guo ◽  
Yunge Zhao

Abstract. Mosses, as major components of later successional biological soil crusts (biocrusts), play many critical roles in arid and semiarid ecosystems. Recently, some species of desiccation-tolerant mosses have been artificially cultured with the aim of accelerating the recovery of biocrusts. Revealing the factors that influence the vegetative propagation of mosses, which is an important reproductive mode of mosses in dry habitats, will benefit the restoration of moss crusts. In this study, three air-dried desiccation-tolerant mosses (Barbula unguiculata, Didymodon vinealis, and Didymodon tectorum) were hermetically sealed and stored at five temperature levels (0, 4, 17, 25, and 30 °C) for 40 days. Then, the vegetative propagation and physiological characteristics of the three mosses were investigated to determine the influence of storage temperature on the vegetative propagation of desiccation-tolerant mosses and the mechanism. The results showed that the vegetative propagation of the three mosses varied with temperature. The most variation in vegetative propagation among storage temperatures was observed in D. tectorum, followed by the variation observed in B. unguiculata. In contrast, no significant difference in propagation among temperatures was found in D. vinealis. The regenerative capacity of the three mosses increased with increasing temperature from 0 to 17 °C, accompanied by a decrease in malondialdehyde (MDA) content, and decreased thereafter. As the temperature increased, the chlorophyll and soluble protein contents increased in B. unguiculata but decreased in D. vinealis and D. tectorum. As to storage, the MDA and soluble sugar contents increased after storage. The MDA content of the three mosses increased at each of the investigated temperatures by more than 50 % from the initial values, and the soluble sugar content became higher than before in the three mosses. The integrity of cells and cell membranes is likely the most important factor influencing the vegetative propagation of desiccation-tolerant mosses. A 40-day storage period caused cell injury. Our results suggest that storage temperature can enhance or suppress such injury and change the regenerative capacity of the three mosses. The data indicate that the suitable storage temperature is 4 °C for B. unguiculata and 17 °C for both D. vinealis and D. tectorum.


2016 ◽  
Vol 5 (1) ◽  
pp. 96-106
Author(s):  
Hussien Al Zubi ◽  
Entessar Al Jbawi ◽  
Sameer Al Jeddawi ◽  
Mohammad Khair Tahla ◽  
Raafat Ismaiel ◽  
...  

An experiment was conducted at the Agricultural Research Center of Al Ghab, General Commission for Scientific Agricultural Research (GCSAR), Syria, to evaluate the effect of some chemical application on the sugar losses reduction, and some quality traits in 2014/2015 season. Three slaked lime concentrations of 5, 10 and 15 percent, and three concentrations of calcium chloride of 2, 4, and 6%, and a mix of 5% slaked lime with 2% calcium chloride, beside the check (no treatment) (factor C). The second factor (D) was the storage durations of 6 days, and tow varieties (Factor V) were arranged as factorial experiment in RCBD with four replications. The varieties one of them was monogerm (Vico), while the other was multigerm (Reda), they were drilled in mid November, and storage roots were harvested late August. Weight percent loss and quality of beet samples such as sugar content, total soluble solids (TSS %), and purity% were determined throughout storage period. The results of analysis of variance ANOVA showed that effect of varieties was significant for TSS (brix %), sucrose%, root weight loss (P<0.05). All the studied traits were affected significantly (P<0.05) by storage duration. Chemical treatments had significant effect on all the studied traits (P<0.05), and the best treatment was with calcium chloride 6%. The percentage of variance confirmed that the most effective factor for the all studied traits was the storage period, followed by the varieties, and finally in a very low percent was the chemical treatments, because of that it is very urgent to send the harvested roots immediately to the factories to be processed within 24 hours, or treated with calcium chloride of 6% to preserve the sugar content as possible till manufacturing. Also the study concluded that the mutigerm variety Reda deteriorated less that the monogerm variety Vico, so Reda is recommended to be stored if necessary.International Journal of Environment Vol. 5 (1) 2016,  pp: 96-106


Author(s):  
F. Sánchez Nieva ◽  
I. Hernández ◽  
L. M. Iguina de George

The effect of the processing temperature, of the addition of sugar to 45° and 59° Brix and of the addition of four levels of ascorbic acid, 0.5, 0.75, 1.0, and 1.5 g. per pound, on the quality, shelf-life, and ascorbic acid retention of frozen soursop pulp was investigated. When unsweetened soursop pulps were processed at temperatures ranging from 74° to 200° F., no appreciable change in organoleptic properties were observed during a period of storage at —10° F. for over 400 days, in the pulps heated below 200° F. The pulp heated to 200° F. was found inferior to the others. No change in chemical composition or color was observed. The data for the ascorbic acid retention during storage do not show any definite trend which could be related to a temperature effect. Ascorbic acid retention varied from 70.8 to 94.3 percent. Pulps with cane sugar added to 45° to 59° Brix, respectively, and heated to temperatures ranging from 72° to 225° F. behaved like the unsweetened pulps when stored at —10° F. for about 400 days. No change in total acidity, pH, total and reducing-sugar content, or color was observed during the storage period. In the samples sweetened to 45° Brix, ascorbic retention values ranged from 98.18 to 133.9 percent. The retention of ascorbic acid in the 59° Brix pulps ranged from 75.0 to 91.7 percent, with the lower retention found in the sample processed at 225° F. Neither heating to different temperatures nor the addition of two levels of sugar were found to affect the shelf-life. Pulps processed at 175° F. and enriched by the addition of 0.5, 0.75, 1.0, and 1.5 g. of ascorbic acid per pound retained their flavor very well during the storage period showing less change in the organoleptic rating than the unriched sweetened and unsweetened pulps. The level of ascorbic acid had no effect on shelf-life or sample quality. Ascorbic acid retention ranged from 94.1 to 104.6 percent. No change in other chemical constituents or color were observed during the period of observation. Heating of the pulps reduced the plate counts of microorganisms. When the pulps were heated to about 175° F., almost sterile packs were obtained. Peroxidases were inactivated at 150° F. in the unsweetened pulps and at 185° F. in the sweetened. The results of this work indicate that two types of products can be prepared from soursop pulp: 1, A frozen pulp without sugar added, to be used for the manufacture of nectars, drinks, ice creams, and other similar products; and 2, a nectar base for direct consumer use prepared by the addition of sugar to 45° or 59° Brix which can be reconstituted for serving by the addition of 3 volumes of water. The addition of ascorbic acid to the nectar base would improve the shelf-life and the resulting product would have a vitamin C content higher than that contained in orange juice.


Author(s):  
Dorin Sumedrea ◽  
Alina Florea ◽  
Mihaela Sumedrea ◽  
Adrian Asănica ◽  
Radu Coman ◽  
...  

Abstract The objective of preservation is to keep fruit fresh as long as possible after harvesting, without major physical, chemical or biological changes in their composition. The experimental factors underlying it the organization scheme are: A Factor - apple varieties: ‘Idared’, ‘Goldrush’, ‘Florina’, ‘Pinova’, ‘Dalinette’, ‘Golden reinderes‘,‘Golden lassa‘,‘Ariane‘; B factor - storage methods, with three graduations: classical method - low temperature and high humidity (1-4ºC; humidity 85-90%), Janny MT box storage method (1-4 ºC; 95-100% humidity; O2 1-3%; CO2 2-5%), fruit control equipment box-pallets (1- 4ºC; 90-95% humidity; O2 1-3%; CO2 2-5%) and factor C - fruit storage period -at 3, 4 and 5 months after harvest respectively. On the average of the cultivars taken in the study, on observe the tendency to increase the total dry mater and total sugar content, and decrease the total tritrable acidity and vitamin C with the prolongation of the fruit storage period.


2017 ◽  
Vol 17 (1) ◽  
pp. 37 ◽  
Author(s):  
Zvezda Bogevska ◽  
Rukie Agic ◽  
Gordana Popsimonova ◽  
Margarita Davitkovska ◽  
Igor Iljovski

In Macedonia, sweet onion landrace ‘buchinska arshlama’ is traditionally stored during winter period from October until April. The objective of this research was to determine the content of reducing sugar and total sugar in onion bulbs during storage period in a traditional way and in cold rooms. Every month, samples were taken for chemical analysis. The results were statistically processed and tested with t-test. The average reducing sugar content in onion stored in a traditional way was 4.8%, while the average reducing sugar content in onion stored in cold rooms was 4.6%. The average total sugar content in onion stored in a traditional way was 6.0%, while the average total sugar content in onion stored in a cold room was 5.6%. These results showed that onion `buchinska arshlama` can be successfully stored in a traditional way until the beginning of February or longer in cold rooms.


Sign in / Sign up

Export Citation Format

Share Document