scholarly journals II. Ignition phenomena in mixtures of carbon monoxide and oxygen sensitized by hydrogen

1938 ◽  
Vol 167 (930) ◽  
pp. 292-318 ◽  
Keyword(s):  
Carbon Monoxide ◽  
Chemical Reaction ◽  
Special Interest ◽  
Combustion Process ◽  
Proper Understanding ◽  
Factors Affecting ◽  
Chain Reactions ◽  
Gaseous Fuels ◽  
Combustion Processes ◽  
Combustion Of Hydrogen

Not the least important factors affecting the utilization of gaseous fuels are the remarkable effects of small quantities of catalytic substances, the presence of which may initiate or entirely change the nature of a combustion process. A proper understanding of these factors is therefore of great importance in the control of processes which are fundamental to many parts of applied chemistry. Such processes, however, are also intrinsically interesting for the insight they give into the ultimate mechanism of chemical reaction, and as a result of their study in the light of the theory of chain reactions, many empirical facts relating to combustion processes which previously were obscure now acquire a new significance. Of all these reactions the combustion of hydrogen and carbon monoxide stand in a unique position, for these substances more than any others occur as intermediaries in the burning of gaseous fuels; it is therefore of special interest to realize that the presence of traces of hydrogen may have a profound effect on the combustion of carbon monoxide, not only in lowering the temperature of ignition, but also in influencing the rate of propagation of the flame. This becomes of particular importance when it is remembered that carbon monoxide as used industrially nearly always contains traces of hydrogen.

The Combustion Characteristics of n-Heptane Fueled HCCI Engine Operation With Gaseous Fuels Admission

2006 ◽  
Author(s):  
C. Liu ◽  
G. A. Karim ◽  
A. Sohrabi ◽  
F. Xiao
Keyword(s):  
Carbon Monoxide ◽  
High Temperature ◽  
Combustion Process ◽  
Cylinder Pressure ◽  
Engine Operation ◽  
Hcci Engine ◽  
Gaseous Fuels ◽  
High Temperature Reaction ◽  
Temperature Combustion ◽  
Combustion Region

The effects of the introduction of the gaseous fuels, methane, hydrogen and carbon monoxide into the intake of a variable compression ratio n-heptane fuelled HCCI, CFR engine were investigated. The variations in some of the key combustion and operational parameters were determined experimentally. These included cylinder pressure and its rise rate temporal developments, autoignition timing, combustion durations for both the low and high temperature reaction regions, COV values for IMEP and maximum cylinder pressure, and the incidence of knock and its intensity. In parallel with the experimental investigation, results of a numerical simulation of the processes involved obtained by employing a KIVA based approach while incorporating sufficiently detailed chemical kinetics are presented. It was found that supplementing n-heptane HCCI with gaseous fuels could inhibit the low temperature combustion region and delay to varying extents the high temperature combustion region. Methane admission produced lengthening of the delay to autoignition and extended the combustion durations. It is suggested that supplementing the liquid fuel with methane may be a means for controlling the combustion process of a liquid fuelled HCCI engine while obtaining higher power and acceptable levels of emissions without producing unacceptably heavy knock. However, the addition of hydrogen or carbon monoxide could not reduce the intensity of knock while improving power output.

Effect of H2 and CO Content in Syngas on the Performance and Emission of Syngas-Diesel Dual Fuel Engine - A Review

2014 ◽  
Vol 699 ◽  
pp. 648-653 ◽  
Author(s):  
Bahaaddein K.M. Mahgoub ◽  
Suhaimi Hassan ◽  
Shaharin Anwar Sulaiman
Keyword(s):  
Carbon Monoxide ◽  
Diesel Engines ◽  
Combustion Process ◽  
Exhaust Emission ◽  
Dual Fuel ◽  
Pure Liquid ◽  
Compression Ignition ◽  
Performance And Emission ◽  
Combustion Duration ◽  
Combustible Gases

In this review, a series of research papers on the effects of hydrogen and carbon monoxide content in syngas composition on the performance and exhaust emission of compression ignition diesel engines, were compiled. Generally, the use of syngas in compression ignition (CI) diesel engine leads to reduce power output due to lower heating value when compared to pure liquid diesel mode. Therefore, variation in syngas composition, especially hydrogen and carbon monoxide (Combustible gases), is suggested to know the appropriate syngas composition. Furthermore, the simulated model of syngas will help to further explore the detailed effects of engine parameters on the combustion process including the ignition delay, combustion duration, heat release rate and combustion phasing. This will also contribute towards the efforts of improvement in performance and reduction in pollutants’ emissions from CI diesel engines running on syngas at dual fuel mode. Generally, the database of syngas composition is not fully developed and there is still room to find the optimum H2 and CO ratio for performance, emission and diesel displacement of CI diesel engines.

scholarly journals The flame spectrum of carbon monoxide

1940 ◽  
Vol 176 (967) ◽  
pp. 505-521 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Electronic State ◽  
Excited Electronic State ◽  
Combustion Process ◽  
Wave Number ◽  
Band Spectrum ◽  
Liquid Form ◽  
Triangular Form ◽  
Reduced Pressure

The spectrum of the flame of carbon monoxide burning in air and in oxygen at reduced pressure has been photographed on plates of high contrast which display the band spectrum clearly above the continuous background. Greater detail has been obtained than has been recorded previously and new measurements are given. The structure of the spectrum has been studied systematically. It is shown that the bands occur in pairs with a separation of about 60 cm. -1 , this separation being due probably to the rotational structure. Various wave-number differences are found to occur frequently, and many of the strong bands are arranged in arrays using intervals of 565 and 2065 cm. -1 . The possible origin of the spectrum is discussed. The choice of emitter is limited to a polyatomic oxide of carbon, of which carbon dioxide is the most likely. The spectrum of the suboxide C 3 O 2 shows some resemblance to the flame bands, but this molecule is improbable as the emitter on other grounds. A peroxide C0 3 is also a possibility, but no evidence for the presence of this has been obtained from experiments on the slow combustion of carbon monoxide. Carbon dioxide in gaseous or liquid form is transparent through the visible and quartz ultra-violet, and the flame bands are not obtained from CO 2 in discharge tubes. Comparison with the Schumann-Runge bands of oxygen shows that it is possible that the flame bands may form part of the absorption band system of CO 2 which is known to exist below 1700 A if there is a big change in shape or size of the molecule in the two electronic states. The electronic energy levels of CO 2 are discussed. Since normal CO 2 is not built up from normal CO and oxygen, an electronic rearrangement of the CO 2 must occur after the combustion process. Mulliken has suggested that the molecule in the first excited electronic state, corresponding to absorption below 1700 A, may have a triangular form. The frequencies obtained from the flame bands are compared with the infra-red frequencies of CO 2 . The 565 interval may be identified with the transverse vibration v 2 , indicating that the excited electronic state is probably triangular in shape. The 2065 interval cannot, however, be identified with the asymmetric vibration v 3 with any certainty. If the excited electronic state of CO 2 is triangular, then molecules formed during the combustion by transitions from this level to the ground state may be “vibrationally activated”. This is probably the reason for many of the peculiarities of the combustion of carbon monoxide.

scholarly journals Effects of Catalysts on Emissions of Pollutants from Combustion Processes of Liquid Fuels

2014 ◽  
Vol 13 (2) ◽  
pp. 5-17
Author(s):  
Agnieszka Bok ◽  
Joanna Guziałowska-Tic ◽  
Wilhelm Jan Tic
Keyword(s):  
Combustion Process ◽  
Combustion Products ◽  
Organometallic Complexes ◽  
Liquid Fuels ◽  
Motor Fuels ◽  
Harmful Emissions ◽  
Fuel Oils ◽  
Sulphur Oxides ◽  
Dynamic Growth ◽  
Combustion Processes

Abstract The dynamic growth of the use of non-renewable fuels for energy purposes results in demand for catalysts to improve their combustion process. The paper describes catalysts used mainly in the processes of combustion of motor fuels and fuel oils. These catalysts make it possible to raise the efficiency of oxidation processes simultanously reducing the emission of pollutants. The key to success is the selection of catalyst compounds that will reduce harmful emissions of combustion products into the atmosphere. Catalysts are introduced into the combustion zone in form of solutions miscible with fuel or with air supplied to the combustion process. The following compounds soluble in fuel are inclused in the composition of the described catalysts: organometallic complexes, manganese compounds, salts originated from organic acids, ferrocen and its derivatives and sodium chloride and magnesium chloride responsible for burning the soot (chlorides). The priority is to minimize emissions of volatile organic compounds, nitrogen oxides, sulphur oxides, and carbon monoxide, as well as particulate matter.

A Control-Oriented Reaction-Based SI Engine Combustion Model

2018 ◽  
Author(s):  
Ruixue C. Li ◽  
Guoming G. Zhu
Keyword(s):  
Chemical Reaction ◽  
Mass Fraction ◽  
Combustion Process ◽  
Combustion Model ◽  
Spark Ignition Engines ◽  
Si Engine ◽  
Chemical Reaction Mechanism ◽  
Engine Combustion ◽  
Rate Of Heat Release ◽  
Mass And Heat Transfer

This paper proposes a control-oriented chemical reaction-based two-zone combustion model designed to accurately describe the combustion process and thermal performance for spark-ignition engines. The combustion chamber is assumed to be divided into two zones: reaction and unburned zones, where the chemical reaction takes place in the reaction zone and the unburned zone contains all the unburned mixture. In contrast to the empirical pre-determined Wiebe-function-based combustion model, an ideal two-step chemical reaction mechanism is used to reliably model the detailed combustion process such as mass-fraction-burned (MFB) and rate of heat release. The interaction between two zones includes mass and heat transfer at the zone interface to have a smooth combustion process. This control-oriented model is extensively calibrated based on the experimental data to demonstrate its capability of predicting the combustion process and thermodynamic states of the in-cylinder mixture.

Mechanisms and kinetics of initial pyrolysis and combustion reactions of 1,1-diamino-2,2-dinitroethylene from density functional tight-binding molecular dynamics simulations

2019 ◽  
Vol 97 (11) ◽  
pp. 795-804 ◽  
Author(s):  
Dong Xiang ◽  
Weihua Zhu
Keyword(s):  
Activation Energy ◽  
Molecular Dynamics ◽  
Density Functional ◽  
Tight Binding ◽  
Combustion Process ◽  
Exponential Factor ◽  
Three Stages ◽  
Dynamics Simulations ◽  
Combustion Processes ◽  
Kinetics Of

The density functional tight-binding molecular dynamics approach was used to study the mechanisms and kinetics of initial pyrolysis and combustion reactions of isolated and multi-molecular FOX-7. Based on the thermal cleavage of bridge bonds, the pyrolysis process of FOX-7 can be divided into three stages. However, the combustion process can be divided into five decomposition stages, which is much more complex than the pyrolysis reactions. The vibrations in the mean temperature contain nodes signifying the formation of new products and thereby the transitions between the various stages in the pyrolysis and combustion processes. Activation energy and pre-exponential factor for the pyrolysis and combustion reactions of FOX-7 were obtained from the kinetic analysis. It is found that the activation energy of its pyrolysis and combustion reactions are very low, making both take place fast. Our simulations provide the first atomic-level look at the full dynamics of the complicated pyrolysis and combustion process of FOX-7.

scholarly journals Improvement of CFD models of tunnel fire development based on experimental data

2017 ◽  
Vol 21 (suppl. 3) ◽  
pp. 705-716 ◽  
Author(s):  
Barbara Vidakovic ◽  
Milos Banjac
Keyword(s):  
Experimental Data ◽  
Combustion Process ◽  
Burning Surface ◽  
Physical Structure ◽  
Cfd Model ◽  
Change Rate ◽  
Flamelet Model ◽  
Tunnel Fire ◽  
Cfd Models ◽  
Combustion Processes

This paper, dealing with the problems of mathematical description of the tunnel fire development process with the use of experimental data, outlines the procedure of correction of the existing and obtaining of an improved CFD model package. The improved CFD model was developed on the basis of detailed analysis and comparison of experimental and numerical results, through consideration of the physical structure of all processes affecting combustion. During the analysis it was noticed that the existing CFD model in the part covering combustion based on the so-called steady laminar flamelet model, treats the combustion process almost as a direct correlation between the processes of mixing gasses and heat release rate. This potential deficiency has been overcome by correction of the model in the section defining boundary condition for the burning surface and by establishing a direct correlation between the measured value of the fuel mass change rate and the amount of heat released from burning surface. In this way a modification of complex stoichiometric combustion processes was avoided, while providing the model that better describes and predicts the course of events in this type of complex, anisotropic and turbulent flow of gases in the tunnel.

scholarly journals Reduction of Major Pollutants via Air-staged Commbustion on Burner System

2013 ◽  
Vol 64 (1) ◽  
Author(s):  
Mohammad Nazri Mohd. Jaafar ◽  
Mohd Nur Hanafi Zaini
Keyword(s):  
Combustion Process ◽  
Primary Concern ◽  
Nox Emissions ◽  
Percent Reduction ◽  
Secondary Air ◽  
Secondary Zone ◽  
Combustion Processes ◽  
Different Gases ◽  
Air Staging ◽  
Co Emission

Emission from the combustion processes can cause adverse effect to the environment.  The formation of pollutants such as NOx, CO, CO2 and SOx are hazardous and harmful to the ecosystem.  The awareness about the pollution due to the combustion activities, particularly in industrial field has set off an effort to find more comprehensive and enhanced technologies to reduce these pollutants.  There are several methods that can be used to reduce the emissions of these pollutants either by combustion modifications or post combustion treatment.  In this research, the method used is the post combustion treatment, i.e. the air staging method.  By air staging techniques, some of the combustion air will be directed into the primary combustion zone, while the remaining air is directed into the secondary zone.  The function of the secondary air is to reduce the peak flame temperatures, which theoretically reduce the emissions of NOx emissions.  The primary concern for this research is to study the effectiveness of the air staging in reducing NOx, CO, SO2, and UHC emissions from the combustion process.  The results obtained showed significant reduction in all major pollutants, i.e., a 31.8 percent reduction for CO emission, 16.8 percent for NOx, 12.7 percent for SO2 and 10.3 percent for UHC.  These reductions were obtained at different equivalence ratios for different gases.

scholarly journals LASER SYSTEM FOR STUDYING THE DYNAMICS OF HIGH TEMPERATURE COMBUSTION

2019 ◽  
Vol 4 (2) ◽  
pp. 154-162
Author(s):  
Lin Li ◽  
Fedor Gubarev ◽  
Andrei Mostovshchikov ◽  
Alexander Ilyin
Keyword(s):  
High Temperature ◽  
Narrow Band ◽  
Laser System ◽  
Combustion Process ◽  
Visual Observation ◽  
Copper Bromide ◽  
Temperature Combustion ◽  
Temporal And Spatial ◽  
Combustion Processes ◽  
High Temperature Combustion

The paper is devoted to development of methods for studying the dynamics of high-temperature combustion of aluminum nanopowder.The difficulty in studying the combustion of nanopowders is the high temperature and intensity of light emissionduring the combustion process, which makes the visual observation virtually impossible.The paper discusses various schemes using laser radiation to study the combustion processes of metal nanopowders.Particular mentions the use of the laser monitor based on an active medium on copper bromide vapor to study the combustion process of various powders and mixtures.The laser monitor combines the functions of the narrow-band laser illuminator and the brightness amplifier, thereby achieving the visualization at a narrow gain wavelength. Therefore, the laser monitor can be used to observe the changes in the surface of a burning sample with high temporal and spatial resolution.

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