Flame stabilization by plasma jets

The possibility of increasing flame reaction rates, stability and hence the throughput of chemical energy achievable by the addition of a small proportion of electrical power is stuided. The power is added to a subsidiary stream of different gases by a magnetically rotated plasma jet. Rates of rotation of the order 10 5 rev/min contribute to uniform heating and mixing with the very much larger main stream flow (up to blow-out) of methane + air mixtures. The products are sampled by a traversing micro-probe and analysed. Quite small additions of electrical power (e. g. 10% of the chemical energy flux—equivalent to an increase of approx. 116 °C in final temperature) produce large increases in throughput— almost 700 % with N 2 plus argon as the carrier gas. This compares with about 50 % predicted for a perfectly stirred system on the basis of measured global kinetics. Even the effect of argon alone, as the carrier gas, cannot be accounted for by such predictions. Radicals known to be important in flame propagation, such as OH, H and O were deliberately produced by including H 2 O, O 2 and CH 4 in the carrier stream . These were an improvement over argon alone but none appreciably exceeded N 2 in effectiveness. The conclusion is that a limited amount of electrical power used to stabilize a large throughput of flame reactants is most effective if employed to generate energetic and long-lived molecular fragments by imparting it in high concentration to a species of large dissociation energy which is capable of producing, subsequently, radicals important in flame propagation. The practical implications may be important, e. g. for stabilizing large throughputs in jet propulsion.

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1279
Author(s):  
Rabeay Y.A. Hassan ◽  
Ferdinando Febbraio ◽  
Silvana Andreescu

Microbial electrochemical systems are a fast emerging technology that use microorganisms to harvest the chemical energy from bioorganic materials to produce electrical power. Due to their flexibility and the wide variety of materials that can be used as a source, these devices show promise for applications in many fields including energy, environment and sensing. Microbial electrochemical systems rely on the integration of microbial cells, bioelectrochemistry, material science and electrochemical technologies to achieve effective conversion of the chemical energy stored in organic materials into electrical power. Therefore, the interaction between microorganisms and electrodes and their operation at physiological important potentials are critical for their development. This article provides an overview of the principles and applications of microbial electrochemical systems, their development status and potential for implementation in the biosensing field. It also provides a discussion of the recent developments in the selection of electrode materials to improve electron transfer using nanomaterials along with challenges for achieving practical implementation, and examples of applications in the biosensing field.


2021 ◽  
Author(s):  
S. Paccati ◽  
L. Mazzei ◽  
A. Andreini ◽  
S. Patil ◽  
S. Shrivastava ◽  
...  

Abstract Due to the increasingly stringent international limitations in terms of NOx emissions, the development of new combustor concepts has become extremely important in order for aircraft engines to comply with these regulations. In this framework, lean-burn technology represents a promising solution and several studies and emission data from production engines have proven that it is more promising in reducing NOx emissions than rich-burn technology. Considering the drawbacks of this combustion strategy (flame stabilization, flashback or blowout or the occurrence of large pressure fluctuations causing thermo-acoustics phenomena) as well as the difficulties and the high costs related to experimental campaigns at relevant operating conditions, Computational Fluid Dynamics (CFD) plays a key role in deepening understanding of the complex phenomena that are involved in such reactive conditions. During last years, large research efforts have been devoted to develop new advanced numerical strategies for high-fidelity predictions in simulating reactive flows that feature strong unsteadiness and high levels of turbulence intensity with affordable computational resources. In this sense, hybrid RANS-LES models represent a good compromise between accurate prediction of flame behaviour and computational cost with respect to fully-LES approaches. Stress-Blended Eddy Simulation (SBES) is a new global hybrid RANS-LES methodology which ensures an improved shielding of RANS boundary layers and a more rapid RANS-LES “transition” compared to other hybrid RANS-LES formulations. In the present work, a full annular aeronautical lean-burn combustor operated at real conditions is investigated from a numerical point of view employing the new SBES approach using poly-hexcore mesh topology, which allows to adopt an isotropic grid for more accurate scale-resolving calculations by means of fully regular hexahedral elements in the main stream. The results are compared to experimental data and to previous reference numerical results obtained with Scale Adaptive Simulation formulation on a tetrahedral mesh grid in order to underline the improvements achieved with the new advanced numerical setup.


Author(s):  
Felix Gu¨the ◽  
Jaan Hellat ◽  
Peter Flohr

Reheat combustion has proven now in over 80 units to be a robust, and highly flexible gas turbine concept for power generation. This paper covers three key topics to explain the intrinsic advantage of reheat combustion to achieve ultra-low emission levels. First, the fundamental kinetic and thermodynamic emission advantage of reheat combustion is discussed analyzing in detail the emission levels of the first and second combustor stages, optimal firing temperatures for minimal emission levels, as well as benchmarking against single-stage combustion concepts. Secondly, the generic operational and fuel flexibility of the reheat system is emphasized, which is based on the presence of two fundamentally different flame stabilization mechanisms, namely flame propagation in the first combustor stage and auto-ignition in the second combustor stage. Finally, the present fleet status is reported by highlighting the latest combustor hardware upgrade and its emission performance.


1981 ◽  
Author(s):  
Gerald F Smith ◽  
Jacqueline L Sundboom

It is important to elucidate the effects of heparin on the α2-antithrombin (ATIII) inactivation of serine proteases in order to understand the pharmacological activity of heparin. We have studied the enzyme kinetics of the ATIII inactivation of these proteases, and the effects of heparin on these interactions, using a common amide peptide substrate and protein substrates. We also studied the interactions of heparin with the three proteases.We conclude that the mechanism of the catalytic effect of heparin (observed at 0. 005 unit/ml) toward the thrombin- ATIII reaction is different from the mechanism whereby heparin (only at very high concentration, e.g., 10 unit/ml) can induce an enhanced rate in the plasmin-ATIII reaction. We conclude that the first mechanism involves a heparinthrombin complex, while the mechanism with plasmin involves a heparin-ATIII complex which forms only at high heparin concentrations. This is consistent with known appropriate binding constants. We found that heparin has no effect on the very rapid inactivation of trypsin by ATIII. We further conclude that there is no common mechanism whereby clinically relevant levels of heparin cause general enhanced ATIII-protease reaction rates.We suggest ATIII depletion during heparin therapy might be avoided by using low heparin levels, which would not allow heparin-ATIII complexes to form, yet which would catalyze the thrombin-ATIII reaction. Our finding that ATIII inactivates trypsin at a rate similar to the heparin-catalyzed thrombin-ATIII reaction suggests a physiological role for ATIII in the control of trypsin-like enzymes.


Author(s):  
Mohan K. Bobba ◽  
Priya Gopalakrishnan ◽  
Karthik Periagaram ◽  
Jerry M. Seitzman

A novel combustor design, referred to as a stagnation-point reverse-flow (SPRF) combustor, was recently developed to overcome the stability issues encountered with most lean premixed combustion systems. The SPRF combustor is able to operate stably at very lean fuel-air mixtures with low NOx emissions. The reverse flow configuration causes the flow to stagnate and hot products to reverse and leave the combustor. The highly turbulent stagnation zone and internal recirculation of hot product gases facilitates robust flame stabilization in the SPRF combustor at very lean conditions over a range of loadings. Various optical diagnostic techniques are employed to investigate the flame characteristics of a SPRF combustor operating with premixed natural gas and air at atmospheric pressure. These include simultaneous planar laser-induced fluorescence imaging of OH radicals and chemiluminescence imaging, and spontaneous Raman scattering. The results indicate that the combustor has two stabilization regions, with the primary region downstream of the injector where there are low average velocities and high turbulence levels where most of the heat release occurs. High turbulence levels in the shear layer lead to increased product recirculation levels, elevating the reaction rates and thereby enhancing the combustor stability. The effect of product entrainment on the chemical time scales and the flame structure is quantified using simple reactor models. Turbulent flame structure analysis indicates that the flame is primarily in the thin reaction zone regime throughout the combustor. The flame tends to become more flameletlike, however, for increasing distance from the injector.


Author(s):  
Mohan K. Bobba ◽  
Priya Gopalakrishnan ◽  
Karthik Periagaram ◽  
Jerry M. Seitzman

A novel combustor design, referred to as a Stagnation Point Reverse Flow (SPRF) combustor, was recently developed to overcome the stability issues encountered with most lean premixed combustion systems. The SPRF combustor is able to operate stably at very lean fuel-air mixtures with low NOx emissions. The reverse flow configuration causes the flow to stagnate and hot products to reverse and leave the combustor. The highly turbulent stagnation zone and internal recirculation of hot product gases facilitates robust flame stabilization in the SPRF combustor at very lean conditions over a range of loadings. Various optical diagnostic techniques are employed to investigate the flame characteristics of a SPRF combustor operating with premixed natural gas and air at atmospheric pressure. These include simultaneous Planar Laser-Induced Fluorescence (PLIF) imaging of OH radicals, chemiluminescence imaging, Spontaneous Raman Scattering. The results indicate that the combustor has two stabilization regions, with the primary region downstream of the injector where there are low average velocities and high turbulence levels where most of the heat release occurs. High turbulence level in the shear layers lead to increased product recirculation levels, elevating the reaction rates and thereby, the combustor stability. The effect of product entrainment on the chemical timescales and the flame structure is quantified using simple reactor models. Turbulent flame structure analysis indicates that the flame is primarily in the thin reaction zones regime throughout the combustor. The flame tends to become more flamelet like, however, for increasing distance from the injector.


Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1843
Author(s):  
Sun-Hong Lee ◽  
Eun-Ji Shin ◽  
Kyung-Duk Zoh ◽  
Youn-Seok Kang ◽  
Jae-Won Choi

This study investigates the use of selected ion flow tube mass spectrometry with an automated headspace pretreatment system for the continuous surveillance of water quality at wastewater treatment plants (WWTPs) and rivers. The reaction rates of the target compounds introduced using the headspace method were similar to those of the mass scan library, with a margin of error of <10%. Novel quantitative formulae were derived for the water samples of the target compounds, and the linearity of the calibration curves for both the purified and effluent matrix (0.1–2.0 mg/L) showed a coefficient of determination of 0.98–0.99 for most compounds. The detection limit for 74% of the target substances was 0.02–0.10 mg/L, and the average recoveries were 111.6% and 104.7% for the low- and high-concentration spiked samples, respectively, which are comparable to those of the headspace gas chromatography-mass spectrometry system. However, the variability in individual concentrations was still large, due to the unstable control of sample injection flow and pressure. Herein, 79% of the 28 compounds met one-tenth of the proposed method detection limit criteria for emergency operations in WWTP. Field experiments showed that the system was easy to maintain and could be used to monitor chemical accidents.


Author(s):  
T Sulka ◽  
N Jenkins

A high concentration of micro-combined heat and power (mCHP) units leads to difficulties in predicting power flows in low-voltage electrical feeders. A simple model of a house with mCHP generation, which is combined with an estate model, is used to predict electrical network flows. The model of the estate includes representation of the residents’ behaviour and ambient weather conditions. Results for an individual house, as well as electrical power flows for the estate feeder, are shown for three different seasons of a year.


2011 ◽  
Vol 110-116 ◽  
pp. 2034-2037
Author(s):  
Subhash Gupta ◽  
S. Kalika ◽  
R. Cabigting Luisito

Solar energy systems have emerged as a viable source of renewable energy over the past two or three decades, and are now widely used for a variety of industrial and domestic applications. This paper shows the potential system benefits of simple tracking solar system using a stepper motor and light sensor. This method is increasing power collection efficiency by developing a device that tracks the sun to keep the panel at a right angle to its rays. Such systems are based on a solar collector, designed to collect the sun’s energy and to convert it into either electrical power or thermal energy The output power produced by high-concentration solar thermal and photovoltaic systems is directly related to the amount of solar energy acquired by the system, and it is therefore necessary to track the sun’s position with a high degree of accuracy. The power developed in such applications depends fundamentally upon the amount of solar energy captured by the collector, and thus the problem of developing tracking schemes capable of following the trajectory of the sun throughout the course of the day on a year-round basis has received significant coverage in the literature. A solar tracking system is designed, implemented and experimentally tested. The design details and the experimental results are incorporated in this paper.


Author(s):  
Thomas Sattelmayer ◽  
Christoph Mayer ◽  
Janine Sangl

An experimental study is presented on the interaction of flashback originating from flame propagation in the boundary layer (1), from combustion driven vortex breakdown (2) and from low bulk flow velocity (3). In the investigations, an aerodynamically stabilized swirl burner operated with hydrogen-air mixtures at ambient pressure and with air preheat was employed, which previously had been optimized regarding its aerodynamics and its flashback limit. The focus of the present paper is the detailed characterization of the observed flashback phenomena with simultaneous high speed PIV/Mie imaging, delivering the velocity field and the propagation of the flame front in the mid plane, in combination with line-of-sight integrated OH*-chemiluminescence detection revealing the flame envelope and with ionization probes which provide quantitative information on the flame motion near the mixing tube wall during flashback. The results are used to improve the operational safety of the system beyond the previously reached limits. This is achieved by tailoring the radial velocity and fuel profiles near the burner exit. With these measures the resistance against flashback in the center as well as in the near wall region is becoming high enough to make turbulent flame propagation the prevailing flashback mechanism. Even at stoichiometric and preheated conditions this allows safe operation of the burner down to very low velocities of approx. 1/3 of the typical flow velocities in gas turbine burners. In that range the high turbulent burning velocity of hydrogen approaches the low bulk flow speed and, finally, the flame begins to propagate upstream once turbulent flame propagation becomes faster than the annular core flow. This leads to the conclusions that finally the ultimate limit for the flashback safety was reached with a configuration, which has a swirl number of approx. 0.45 and delivers NOx-emissions near the theoretical limit for infinite mixing quality, and that high fuel reactivity does not necessarily rule out large burners with aerodynamic flame stabilization by swirling flows.


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