Etude par spectrométrie infrarouge de l'action de solvants aprotiques sur l'association ester–eau et ester–Ba2+. Discussion du rôle catalytique du solvant et de l'ion Ba2+ dans l'hydrolyse alcaline du propionate de methyle
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The ir spectra of mixtures of methyl propionate/water and methyl propionate/Ba2+ in dimethylsulfoxide and in acetonitrile have been recorded in the region of the νCO mode of the ester. Evidence is presented to indicate the presence of different types of complexes; their concentration was determined as a function of the composition of the medium. The spectroscopic results are compared to those from the kinetics of the alkaline hydrolysis in the same conditions. It is demonstrated that the orbital control explains the experimental results better than does the charge density on the carbon of the carbonyl group. [Journal translation]
2016 ◽
Vol 1
(1)
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pp. 45-52
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2020 ◽
Vol 13
(5)
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pp. 884-892
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1980 ◽
Vol 45
(11)
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pp. 2873-2882
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Keyword(s):
2020 ◽
Vol 10
(3)
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pp. 44-59