Electrical impedance investigation of gamma-irradiated TlInS2〈5%C〉 crystals

Author(s):  
O. A. Samedov ◽  
O. Z. Alekperov ◽  
Kh. B. Orudjova ◽  
N. M. Mehtiyev ◽  
A. I. Nadjafov ◽  
...  

In this article, the authors carry out a pioneering study of monocrystalline TlInS[Formula: see text] at higher than room-temperatures using impedance spectroscopy. It is shown that in TlInS[Formula: see text] crystals at temperatures higher than 400 K, the nature of conductivity is predominantly ionic. Moreover, characteristics of impedance spectra behavior of TlInS[Formula: see text] monocrystal samples were studied using the measurement frequency range of 25–106 Hz. For the measured frequency range, it is shown that curves of active and reactive impedance components undergo a dispersion characterized by decreasing values of [Formula: see text] and [Formula: see text], as the frequency of the electric field and radiation dose increases.

Sensors ◽  
2020 ◽  
Vol 20 (7) ◽  
pp. 1889
Author(s):  
Sounghun Shin ◽  
Yoontae Jung ◽  
Soon-Jae Kweon ◽  
Eunseok Lee ◽  
Jeong-Ho Park ◽  
...  

This paper presents a reconfigurable time-to-digital converter (TDC) used to quantize the phase of the impedance in electrical impedance spectroscopy (EIS). The TDC in the EIS system must handle a wide input-time range for analysis in the low-frequency range and have a high resolution for analysis in the high-frequency range. The proposed TDC adopts a coarse counter to support a wide input-time range and cascaded time interpolators to improve the time resolution in the high-frequency analysis without increasing the counting clock speed. When the same large interpolation factor is adopted, the cascaded time interpolators have shorter measurement time and smaller chip area than a single-stage time interpolator. A reconfigurable time interpolation factor is adopted to maintain the phase resolution with reasonable measurement time. The fabricated TDC has a peak-to-peak phase error of less than 0.72° over the input frequency range from 1 kHz to 512 kHz and the phase error of less than 2.70° when the range is extended to 2.048 MHz, which demonstrates a competitive performance when compared with previously reported designs.


2015 ◽  
Vol 29 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Ákos Kertész ◽  
Zuzana Hlaváčová ◽  
Eszter Vozáry ◽  
Lenka Staroňová

Abstract Electrical properties of food materials can give information about the inner structure and physiological state of biological tissues. Generally, the process of drying of fruits and vegetables is followed by weight loss. The aim of this study was to measure the impedance spectra of carrot slices during drying and to correlate impedance parameters to moisture content in different drying periods. Cylindrical slices were cut out from the carrot root along the axis. The slices were dried in a Venticell 111 air oven at 50°C. The weight of the slices was measured with a Denver SI-603 electronic analytical and precision balance. The weighing of the samples was performed every 30 min at the beginning of drying and every 60 min after the process. The moisture content of the samples was calculated on wet basis. The magnitude and phase angle of electrical impedance of the slices were measured with HP 4284A and 4285A precision LCR meters in the frequency range from 30 Hz to 1 MHz and from 75 kHz to 30 MHz, respectively, at voltage 1 V. The impedance measurement was performed after weighting. The change in the magnitude of impedance during drying showed a good correlation with the change in the moisture content.


2018 ◽  
Vol 6 (29) ◽  
pp. 7790-7796 ◽  
Author(s):  
Xiaofeng Shi ◽  
Zhengwang Liu ◽  
Wenbin You ◽  
Xuebing Zhao ◽  
Renchao Che

Fe3O4/PDA vesicle Janus nanospheres were successfully synthesized, and they exhibited an ultra-wide effective band as wide as 11.6 GHz, covering 73% of the whole measured frequency range (2–18 GHz), and a strong absorption intensity as high as −50.0 dB due to the asymmetric polarization and magnetic coupling effect.


Author(s):  
В.М. Капралова ◽  
И.Ю. Сапурина ◽  
Н.Т. Сударь ◽  
А.А. Третьяков ◽  
O. Gryshkov ◽  
...  

The impedance spectra of composite nonwoven materials based on nano- and microfibers of polyvinylidene fluoride-trifluoroethylene copolymer modified by polypyrrole with different doping degree were studied in the frequency range 1000 Hz-5 MHz. It was found that an increase in the doping degree of polypyrrole coating of nanofibers leads to a decrease in the imaginary and real components of the electrical impedance. Regardless of their magnitude, the shape of the hodographs is close to circular arc resting on the ReZ axis, which allows us to consider the studied material as a nanocomposite polymer electrolyte whose dielectric characteristics can be reversibly changed.


2021 ◽  
Vol 2008 (1) ◽  
pp. 012008
Author(s):  
L G Teixeira ◽  
P Bertemes-Filho ◽  
M. Keith Cox

Abstract The consumption of seafood has increased over the last 10 years. This article analyses impedance changes of tilapia (Oreochromis niloticus) sample measured over 36 hours by using electrical impedance spectroscopy (EIS). It was also investigated the correlations between variables in order to predictive models to degradation studies. Measurements were collected every 12 hours in order to verify any change due to deterioration. The results show that measurements in both longitudinal and transverse axes are equivalent and that the sample undergoes gradual variations in the impedance. The first set of data collected in the frequency range from 0.1 to 1,000 kHz showed that resistance varied from 310.9 (@ 0.1 kHz) to 86.8 Ω (@1 MHz) and capacitive reactance varied from -8.6 to 11.5 Ω, respectively. The forth set of data showed a decrease of 79.3% (@0.1 kHz) in the resistance part of the impedance, whereas 98.8% in capacitive reactance at 0.1 kHz. These results might suggest that there was a nutritional loss of the sample over time. Further experiments must be done over a long period of time in order to fully understand the process. EIS might be pointed out as a potential technique for fish shelf live quality control.


2020 ◽  
Vol 10 (18) ◽  
pp. 6576
Author(s):  
Manuel Vázquez-Nambo ◽  
José-Antonio Gutiérrez-Gnecchi ◽  
Enrique Reyes-Archundia ◽  
Wuqiang Yang ◽  
Marco-A. Rodriguez-Frias ◽  
...  

The physicochemical characterization of pharmaceutical materials is essential for drug discovery, development and evaluation, and for understanding and predicting their interaction with physiological systems. Amongst many measurement techniques for spectroscopic characterization of pharmaceutical materials, Electrical Impedance Spectroscopy (EIS) is powerful as it can be used to model the electrical properties of pure substances and compounds in correlation with specific chemical composition. In particular, the accurate measurement of specific properties of drugs is important for evaluating physiological interaction. The electrochemical modelling of compounds is usually carried out using spectral impedance data over a wide frequency range, to fit a predetermined model of an equivalent electrochemical cell. This paper presents experimental results by EIS analysis of four drug formulations (trimethoprim/sulfamethoxazole C14H18N4O3-C10H11N3O3, ambroxol C13H18Br2N2O.HCl, metamizole sodium C13H16N3NaO4S, and ranitidine C13H22N4O3S.HCl). A wide frequency range from 20 Hz to 30 MHz is used to evaluate system identification techniques using EIS data and to obtain process models. The results suggest that arrays of linear R-C models derived using system identification techniques in the frequency domain can be used to identify different compounds.


2020 ◽  
Vol 12 (3) ◽  
pp. 566 ◽  
Author(s):  
Rinku Basak ◽  
Khan Wahid ◽  
Anh Dinh

In this work, crop leaf nitrogen concentration (LNC) is predicted by leaf impedance measurements made by electrical impedance spectroscopy (EIS). This method uses portable equipment and is noninvasive, as are other available nondestructive methods, such as hyperspectral imaging, near-infrared spectroscopy, and soil-plant analyses development (SPAD). An EVAL-AD5933EBZ evaluation board is used to measure the impedances of four different crop leaves, i.e., canola, wheat, soybeans, and corn, in the frequency range of 5 to 15 kHz. Multiple linear regression using the least square method is employed to obtain a correlation between leaf nitrogen concentrations and leaf impedances. A strong correlation is found between nitrogen concentrations and measured impedances for multiple features using EIS. The results are obtained by PrimaXL Data Analysis ToolPak and validated by analysis of variance (ANOVA) tests. Optimized regression models are determined by selecting features using the backward elimination method. After a comparative analysis among the four different crops, the best multiple regression results are found for canola with an overall correlation coefficient (R) of 0.99, a coefficient of determination (R2) of 0.98, and root mean square (RMSE) of 0.54% in the frequency range of 8.7–12 kHz. The performance of EIS is also compared with an available SPAD reading which is moderately correlated with LNC. A high correlation coefficient of 0.94, a coefficient of determination of 0.89, and RMSE of 1.12% are obtained using EIS, whereas a maximum correlation coefficient of 0.72, a coefficient of determination of 0.53, and RMSE of 1.52% are obtained using SPAD for the same number of combined observations. The proposed multiple linear regression models based on EIS measurements sensitive to LNC can be used on a very local scale to develop a simple, rapid, inexpensive, and effective instrument for determining the leaf nitrogen concentrations in crops.


Author(s):  
Jie Wu ◽  
Hsueh-Chia Chang

Microfludic devices with integrated electrical detection will enable fast, low-cost or portable sensing and processing of biological and chemical samples. As an inherent property of microfabrication, micro-electrical impedance spectroscopy detectors can take advantage of AC electrokinetics for particle manipulation, leading to enhanced sensitivity. Preliminary experiments on particle detection were carried out using microelectrode pairs, and impedance spectra are compared with respect to opposite effects of dielectrophoresis and electrode polarization. The values of cell equivalent circuit are extracted for electrode optimization.


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