scholarly journals Review—Sensor Evaluation for Thiamethoxam Detection in Different Matrices

Author(s):  
Noureddine Ajermoun ◽  
A Loudiki ◽  
Abdelfattah Farahi ◽  
Sara Lahrich ◽  
Sana Saqrane ◽  
...  

Abstract Thiamethoxam (3-[(2-chloro-5-thiazolyl)methyl] tetrahydro-5-methyl-N-nitro-4H-1,3,5-oxadiazin-4- imine) is a representative compound of new neonicotinoid insecticides, which can selectively act on the central nervous system of insects and is widely used to control sucking insect pests. Due to its extensive usage, high water solubility, high leaching capability, low soil adsorption, and poor biodegradability, the residues of the thiamethoxam persist in the environment with adverse effects. Therefore, it is necessary to develop analytical tools for the monitoring of thiamethoxam. An electrochemical sensor is suitable for rapid and simple analyses of pesticides, which are likely to persist at a trace level in agro-environments, including agricultural products, soil, and water. Here, the new trends in sensors development and the application for the detection of thiamethoxam in the environmental are described. The fundamental analytical performance of the electrodes is discussed. The application of these sensors for thiamethoxam monitoring in different matrices is reported.Electrochemical sensor is suitable for rapid and simple analyses of pesticides, which are likely to persist at a trace level in agro-environments, including agricultural products, soil, and water. In this review, the new trends in sensors development and the application for the detection of thiamethoxam in the environmental are described. The fundamental analytical performance of the electrodes is discussed. The application of these sensors for thiamethoxam monitoring in different matrices is reported

2017 ◽  
Vol 71 (11) ◽  
pp. 2512-2518 ◽  
Author(s):  
Ryan P. Ferrie ◽  
Gregory E. Hewitt ◽  
Bruce D. Anderson

Fluorescence quenching was used to investigate the interaction of six fluoroquinolones with humic acid. Static quenching was observed for the binding of ciprofloxacin, enoxacin, fleroxacin, levofloxacin, norfloxacin, and ofloxacin to humic acid. The equilibrium binding constants were found from Stern–Volmer plots of the data. The quenching experiments were repeated over a temperature range of 25–45 ℃ and van’t Hoff plots were generated. From these linear plots, thermodynamic values were calculated for Δ H, Δ G, and Δ S for each of the fluoroquinolones. The equilibrium binding constants were found to be <1 for all the antibiotics studied. The calculated ΔH values were all negative and ranged from −9.5 to −27.6 kJ/mol. The high water solubility of the antibiotics and low ΔH of binding suggests that the antibiotics will be transported easily through the environment. Finally, whether the fluoroquinolones are in a protonated, deprotonated, or partially protonated state is found to correlate to the strength of binding to humic acid.


Author(s):  
Tatiyana V. Serebryanskaya ◽  
Alexander S. Lyakhov ◽  
Ludmila S. Ivashkevich ◽  
Yuri V. Grigoriev ◽  
Andreii S. Kritchenkov ◽  
...  

AbstractNovel platinum(II) and palladium(II) chlorido complexes with tetrazole derivatives 1-(2-hydroxyethyl)tetrazole (het) and 1-[tris(hydroxymethyl)methyl]tetrazole (thm), viz. cis-[Pt(het)2Cl2], trans-[Pt(het)2Cl2], trans-[Pt(thm)2Cl2], trans-[Pd(het)2Cl2], and trans-[Pd(thm)2Cl2], were synthesized. The compounds were characterized by elemental and high-resolution electrospray ionization (HRESI) mass spectrometry, high-performance liquid chromatography (HPLC), 1H, 13C and 195Pt nuclear magnetic resonance (NMR) spectroscopy, thermal analyses, and Infrared (IR) spectroscopy. Molecular and crystal structures of trans-[PdL2Cl2] and trans-[PtL2Cl2] (L = het, thm) were established by single-crystal X-ray analysis. The complex cis-[Pt(het)2Cl2] was found to undergo cis–to–trans isomerization upon heating in acetonitrile solution and in the solid state. The synthesized complexes show rather high water solubility lying in the range of 2–10 mg/L.


1971 ◽  
Vol 61 (3) ◽  
pp. 579-590 ◽  
Author(s):  
William Enkeboll

abstract Soil and water conditions had an effect on the degree of damage to structures. Most structures were located on alluvium with a high water table. Settlements occurred in dike and causeway fill in Chimbote harbor. Severe problems to communication occurred in some areas through embankment failures and road slides.


2021 ◽  
Author(s):  
◽  
Tapuwa Marapara

<p>During the last two decades there has been increasing interest in the role of forests and wetlands as flood mitigating tools due to growing concerns regarding the sustainability of many traditional engineering flood defences such as dykes, sea walls and dams. In forests, the role is facilitated by the interaction between trees, soil and water. Specifically trees reduce surface runoff and prevent flooding through increased evapotranspiration and canopy interception and enhance physical and hydraulic properties of soil that are critical for the absorption and retention of flood waters by the soil. It is increasingly realised that the answer to flood mitigation is not a blanket recommendation to “plant trees”. This is because the role of trees varies spatially and temporally as a function of climate, topography, rainfall properties, soil type and condition, catchment scale and geology, among others. For example, where trees are present in wetlands, particularly forested wetlands, the mechanisms by which trees interact with soil and water are similar to that in forests but because of a high water table, the impact of trees may be reduced. Therefore, the mere presence of forests and forested wetlands will not necessarily deliver flood risk management.  The purpose of this study was to explore the effectiveness of trees as flood mitigating tools under various bio-geo climatic factors in forests and forested wetland environments. Three forms of investigation were followed to fulfil this purpose.  A detailed literature review was carried out to assess the role of trees and forests as flood mitigation tools under changing climate, topography, species type, rainfall properties, soil type and condition, catchment scale and geology. A field experiment was carried out to collect data and analyse the effect of trees on soil physical and hydraulic properties that include bulk density, saturated hydraulic conductivity, soil organic carbon, soil moisture content, matric potential and soil moisture retention in a previously forested wetland undergoing restoration in New Zealand. A spatially explicit decision support tool, the Land Use Capability Indicator (LUCI) was then used to determine appropriate areas where intervention can be targeted to optimise the role of trees as flood mitigating tools in previously forested wetlands undergoing restoration.  The detailed review identified a major data gap in the role of trees under hydric conditions (high water table), along with uncertainties on their effectiveness in large catchments (>˜40 km²) and in extreme rainfall events. The field experiment provided the first set of soil hydrology data from an ephemeral wetland in New Zealand showing the benefits of newly established trees in improving hydraulic conductivity of soils. The soil hydrology data is a useful baseline for continuous monitoring of the forested wetlands undergoing restoration. The use of the Land Use Capability Indicator was its first application for the optimisation of flood mitigation in a forested wetland. Its suggested target areas are not necessarily conducive for survival of some tree species, although if suitable species are established, flood risk mitigation could be maximised. Further research on what native species are best for what conditions and in what combinations is recommended, to increase survival in the proposed target areas.</p>


The Analyst ◽  
2020 ◽  
Vol 145 (22) ◽  
pp. 7380-7387 ◽  
Author(s):  
Huming Yan ◽  
Fangjun Huo ◽  
Yongkang Yue ◽  
Jianbin Chao ◽  
Caixia Yin

The excellent water solubility of hydrazine (N2H4) allows it to easily invade the human body through the skin and respiratory tract, thereby damaging human organs and the central nervous system.


2021 ◽  
Author(s):  
Narges Ghadi

A mathematical model was developed to simulate emulsion polymerization in batch, semi-batch and continuous reactors for monomers with high water solubility and significant desorption such as vinyl acetate. The effects of operating conditions such as initiator and emulsifier concentration as well as reactor temperature have been studied. The simulation results revealed the sensitivity of polymer properties and monomer conversion to variation of these operating conditions. Furthermore, the impact of monomer soluble impurities on reduction of monomer conversion has been investigated. In order to control polymer molecular weight, application of chain transfer agents such as t-nonyl mercaptan was suggested. Generally, the simulation results fitted well [with] experimental data from the literature. Several optimizing policies were considered to enhance the reaction operation for better product quality. During continuous polymerization, the reactor demonstrates oscillatory behavior throughout the operation. A new reactor train configuration was consistent with the aim of damping the oscillations and producing high-quality latex.


2013 ◽  
Vol 13 (4) ◽  
pp. 9355-9399 ◽  
Author(s):  
F. Mei ◽  
A. Setyan ◽  
Q. Zhang ◽  
J. Wang

Abstract. During the Carbonaceous Aerosols and Radiative Effects Study (CARES), activation fraction of size-resolved aerosol particles and aerosol chemical composition were characterized at the T1 site (~60 km downwind of Sacramento, California) from 10 June to 28 June 2010. The hygroscopicity of CCN-active particles (κCCN) with diameter from 100 to 171 nm, derived from the size-resolved activated fraction, varied from 0.10 to 0.21, with an average of 0.15, which was substantially lower than that proposed for continental sites in earlier studies. The low κCCN value was due to the high organic volume fraction, averaged over 80% at the T1 site. The derived κCCN exhibited little diurnal variation, consistent with the relatively constant organic volume fraction observed. At any time, over 90% of the size selected particles with diameter between 100 and 171 nm were CCN active, suggesting most particles within this size range were aged background particles. Due to the large organic volume fraction, organic hygroscopicity (κorg) strongly impacted particle hygroscopicity and therefore calculated CCN concentration. For vast majority of the cases, an increase of κorg from 0.03 to 0.18, which are within the typical range, doubled the calculated CCN concentration. Organic hygroscopicity was derived from κCCN and aerosol chemical composition, and its variations with the fraction of total organic mass spectral signal at m/z 44 (f44) and O : C were compared to results from previous studies. Overall, the relationships between κorg and f44 are quite consistent for organic aerosol (OA) observed during field studies and those formed in smog chamber. Compared to the relationship between κorg and f44, the relationship between κorg and O : C exhibits more significant differences among different studies, suggesting κorg may be better parameterized using f44. A least squares fit yielded κorg = 2.04 (± 0.07) × f44 − 0.11 (± 0.01) with the Pearson R2 value of 0.71. One possible explanation for the stronger correlation between κorg and f44 is that the m/z 44 signal (mostly contributed by the CO2+ ion) is more closely related to organic acids, which may dominate the overall κorg due to their relatively high water solubility and hygroscopicity.


Author(s):  
Laura M. DALE ◽  
André THEWIS ◽  
Ioan ROTAR ◽  
Juan A. FERNANDEZ PIERNA ◽  
Christelle BOUDRY ◽  
...  

Nowadays in agriculture, new analytical tools based on spectroscopic technologies are developed. Near Infrared Spectroscopy (NIRS) is a well known technology in the agricultural sector allowing the acquisition of chemical information from the samples with a large number of advantages, such as: easy to use tool, fast and simultaneous analysis of several components, non-polluting, noninvasive and non destructive technology, and possibility of online or field implementation. Recently, NIRS system was combined with imaging technologies creating the Near Infrared Hyperspectral Imaging system (NIR-HSI). This technology provides simultaneously spectral and spatial information from an object. The main differences between NIR-HSI and NIRS is that many spectra can be recorded simultaneously from a large area of an object with the former while with NIRS only one spectrum was recorded for analysis on a small area. In this work, both technologies are presented with special focus on the main spectrum and images analysis methods. Several qualitative and quantitative applications of NIRS and NIR-HSI in agricultural products are listed. Developments of NIRS and NIR-HSI will enhance progress in the field of agriculture by providing high quality and safe agricultural products, better plant and grain selection techniques or compound feed industry’s productivity among others.


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