scholarly journals A Review of Carbon Nanotubes-Based Gas Sensors

2009 ◽  
Vol 2009 ◽  
pp. 1-24 ◽  
Author(s):  
Yun Wang ◽  
John T. W. Yeow

Gas sensors have attracted intensive research interest due to the demand of sensitive, fast response, and stable sensors for industry, environmental monitoring, biomedicine, and so forth. The development of nanotechnology has created huge potential to build highly sensitive, low cost, portable sensors with low power consumption. The extremely high surface-to-volume ratio and hollow structure of nanomaterials is ideal for the adsorption of gas molecules. Particularly, the advent of carbon nanotubes (CNTs) has fuelled the inventions of gas sensors that exploit CNTs' unique geometry, morphology, and material properties. Upon exposure to certain gases, the changes in CNTs' properties can be detected by various methods. Therefore, CNTs-based gas sensors and their mechanisms have been widely studied recently. In this paper, a broad but yet in-depth survey of current CNTs-based gas sensing technology is presented. Both experimental works and theoretical simulations are reviewed. The design, fabrication, and the sensing mechanisms of the CNTs-based gas sensors are discussed. The challenges and perspectives of the research are also addressed in this review.

2021 ◽  
Vol 30 (1) ◽  
pp. 257-264
Author(s):  
Muna H. Kareem ◽  
Adi M. Abdul Hussein ◽  
Haitham Talib Hussein

Abstract In this study, porous silicon (PSi) was used to manufacture gas sensors for acetone and ethanol. Samples of PSi were successfully prepared by photoelectrochemical etching and applied as an acetone and ethanol gas sensor at room temperature at various current densities J= 12, 24 and 30 mA/cm2 with an etching time of 10 min and hydrofluoric acid concentration of 40%. Well-ordered n-type PSi (100) was carefully studied for its chemical composition, surface structure and bond configuration of the surface via X-ray diffraction, atomic force microscopy, Fourier transform infrared spectroscopy and photoluminescence tests. Results showed that the best sensitivity of PSi was to acetone gas than to ethanol under the same conditions at an etching current density of 30 mA/cm2, reaching about 2.413 at a concentration of 500 parts per million. The PSi layers served as low-cost and high-quality acetone gas sensors. Thus, PSi can be used to replace expensive materials used in gas sensors that function at low temperatures, including room temperature. The material has an exceptionally high surface-to-volume ratio (increasing surface area) and demonstrates ease of fabrication and compatibility with manufacturing processes of silicon microelectronics.


2020 ◽  
Vol 8 (16) ◽  
pp. 3231-3248 ◽  
Author(s):  
Xinyuan Zhou ◽  
Zhenjie Xue ◽  
Xiangyu Chen ◽  
Chuanhui Huang ◽  
Wanqiao Bai ◽  
...  

Gas-sensing applications commonly use nanomaterials (NMs) because of their unique physicochemical properties, including a high surface-to-volume ratio, enormous number of active sites, controllable morphology, and potential for miniaturisation.


2009 ◽  
Vol 1204 ◽  
Author(s):  
Paolo Bondavalli ◽  
Louis Gorintin ◽  
Pierre Legagneux ◽  
Didier Pribat ◽  
Laurent Caillier ◽  
...  

AbstractThe first paper showing the great potentiality of Carbon Nanotubes Field Effect transistors (CNTFETs) for gas sensing applications was published in 2000 [1]. It has been demonstrated that the performances of this kind of sensors are extremely interesting: a sensitivity of around 100ppt (e.g. for NO2 [2]) has been achieved in 2003 and several techniques to improve selectivity have been tested with very promising results [2]. The main issues that have not allowed, up to now, these devices to strike more largely the market of sensors, have been the lack of an industrial method to obtain low-cost devices, a demonstration of their selectivity in relevant environments and finally a deeper study on the effect of humidity and the possible solutions to reduce it. This contribution deals with CNTFETs based sensors fabricated using air-brush technique deposition on large surfaces. Compared to our last contribution [3], we have optimized the air-brush technique in order to obtain high performances transistors (Log(Ion)/Log(Ioff) ∼ 5/6) with highly reproducible characteristics : this is a key point for the industrial exploitation. We have developed a machine which allows us the dynamic deposition on heated substrates of the SWCNT solutions, improving dramatically the uniformity of the SWCNT mats. We have performed tests using different solvents that could be adapted as a function of the substrates (e.g. flexible substrates). Moreover these transistors have been achieved using different metal electrodes (patented approach [4]) in order to improve selectivity. Results of tests using NO2, NH3 with concentrations between ∼ 1ppm and 10ppm will be shown during the meeting.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingying Jian ◽  
Wenwen Hu ◽  
Zhenhuan Zhao ◽  
Pengfei Cheng ◽  
Hossam Haick ◽  
...  

AbstractChemi-resistive sensors based on hybrid functional materials are promising candidates for gas sensing with high responsivity, good selectivity, fast response/recovery, great stability/repeatability, room-working temperature, low cost, and easy-to-fabricate, for versatile applications. This progress report reviews the advantages and advances of these sensing structures compared with the single constituent, according to five main sensing forms: manipulating/constructing heterojunctions, catalytic reaction, charge transfer, charge carrier transport, molecular binding/sieving, and their combinations. Promises and challenges of the advances of each form are presented and discussed. Critical thinking and ideas regarding the orientation of the development of hybrid material-based gas sensor in the future are discussed.


Author(s):  
Jian Le ◽  
Qian Zhou ◽  
Cao Wang ◽  
Zhi-chun Yang ◽  
Hao Zhang

Abstract Existing over-temperature supervising (OTS) systems available for switch cabinet, even those based on advanced optical fiber sensing technology, are unable to satisfy the critical requirements such as reliability, safety, practicability and economy simultaneously. In this paper, a novel OTS scheme that take a special kind of gas to carry the signal indicating the over-temperature state of a switch cabinet is developed elaborately. Serving for the CO2 gas which has comprehensive and overwhelming superiorities in situation of OTS, a gas storage unit that is composed of a hard plastic crust and an inner tubular airbag, a gas releasing mechanism that consists of bimetallic and acupuncture, and a gas sensing terminal are designed artfully. The overall OTS system is finally developed by integrating these three parts with a background server via wireless communication technology. The advantages of the proposed system, such as high reliability and safety, fast response speed and universal applicability have been proven by lab tests and field experiments. Moreover, the inherent low cost and easy installation and maintenance features of our scheme facilitate the development of OTS systems for other electrical devices in power system.


This paper provides a complete idea about metal oxide semiconductors ((MOSs) for gas sensing application. Metal oxide semiconductor nano-materials are showing much higher strength in many industries, research laboratories and public health and so on with their effective chemical, physical, and electronic properties. The morphology, band gap, porosity, conductivity properties, low cost and high surface area etc. are few of the properties of MOSs that are responsible for the enhancement of sensing properties in various applications. Besides these, now-a-days MOSs are grown in different nanostructures like nano rods, nano flowers, nano sheets, nanowires etc. using the various growth techniques which are further responsible for their betterment as gas sensors. Therefore, this paper gives a complete idea about the different methods of synthesis of MOSs.


2021 ◽  
Vol 21 (7) ◽  
pp. 3707-3710
Author(s):  
Jae Keon Kim ◽  
Maeum Han ◽  
Yeongsam Kim ◽  
Hee Kyung An ◽  
Suwoong Lee ◽  
...  

As hydrogen (H2) gas is highly reactive and explosive in ambient atmosphere, its prompt detection in industrial areas is imperative to prevent serious accidents. In particular, high-performance H2 sensors that can promptly detect even low-concentrations of H2 gas are necessary for safety. Carbon nanotubes (CNTs) have a large surface area and a high surface-to-volume ratio, and therefore, they are suitable for use as sensing materials in gas sensors. Moreover, gold, platinum, and palladium are known to be excellent catalyst metals that increase reactivity with H2 gas through the catalytic effect referred to as spill-over mechanism. In this study, a CNT felt sensor with a palladium (Pd) layer was fabricated, and its reactivity with H2 was evaluated. The sensitivity of a CNT felt sensor to H2 gas at room temperature was found to improve when coated with Pd layer.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Nishchay A. Isaac ◽  
Johannes Reiprich ◽  
Leslie Schlag ◽  
Pedro H. O. Moreira ◽  
Mostafa Baloochi ◽  
...  

AbstractThis study demonstrates the fabrication of self-aligning three-dimensional (3D) platinum bridges for ammonia gas sensing using gas-phase electrodeposition. This deposition scheme can guide charged nanoparticles to predetermined locations on a surface with sub-micrometer resolution. A shutter-free deposition is possible, preventing the use of additional steps for lift-off and improving material yield. This method uses a spark discharge-based platinum nanoparticle source in combination with sequentially biased surface electrodes and charged photoresist patterns on a glass substrate. In this way, the parallel growth of multiple sensing nodes, in this case 3D self-aligning nanoparticle-based bridges, is accomplished. An array containing 360 locally grown bridges made out of 5 nm platinum nanoparticles is fabricated. The high surface-to-volume ratio of the 3D bridge morphology enables fast response and room temperature operated sensing capabilities. The bridges are preconditioned for ~ 24 h in nitrogen gas before being used for performance testing, ensuring drift-free sensor performance. In this study, platinum bridges are demonstrated to detect ammonia (NH3) with concentrations between 1400 and 100 ppm. The sensing mechanism, response times, cross-sensitivity, selectivity, and sensor stability are discussed. The device showed a sensor response of ~ 4% at 100 ppm NH3 with a 70% response time of 8 min at room temperature.


2015 ◽  
Vol 10 (1) ◽  
pp. 13-20
Author(s):  
Elisabete Galeazzo ◽  
Marcos C. Moraes ◽  
Henrique E. M. Peres ◽  
Michel O. S. Dantas ◽  
Victor G. C. Lobo ◽  
...  

Intensive research has been focused on investigating new sensing materials, such as carbon nanotubes (CNT) because of their promising characteristics. However, there are challenges related to their application in commercial devices such as sensitivity, compatibility, and complexity of miniaturization, among others. We report the study of the electrical behavior of devices composed by multi-walled carbon nanotubes (MWCNT) deposited between aluminum electrodes on glass substrates by means of dielectrophoresis (DEP), which is a simple and cost-effective method. The devices were fabricated by varying the DEP process time. Remarkable changes in their electric resistance were noticed depending on the MWCNT quantities deposited. Other electrical properties of devices such as high sensitivity, fast response time and stability are also characterized in humid environment. A humidity sensing mechanism is proposed on the basis of charge transfer between adsorbed water molecules and the MWNTC surface or between water and the glass surface.


Author(s):  
Yaofeng Wang ◽  
Fan Wang ◽  
Yang Kong ◽  
Lei Wang ◽  
Qinchuan Li

Abstract High-performance bioartificial muscles with low-cost, large bending deformation, low actuation voltage, and fast response time have drawn extensive attention as the development of human-friendly electronics in recent years. Here, we report a high-performance ionic bioartificial muscle based on the bacterial cellulose (BC)/ionic liquid (IL)/multi-walled carbon nanotubes (MWCNT) nanocomposite membrane and PEDOT:PSS electrode. The developed ionic actuator exhibits excellent electro-chemo-mechanical properties, which are ascribed to its high ionic conductivity, large specific capacitance, and ionically crosslinked structure resulting from the strong ionic interaction and physical crosslinking among BC, IL, and MWCNT. In particular, the proposed BC-IL-MWCNT (0.10 wt%) nanocomposite exhibited significant increments of Young's modulus up to 75% and specific capacitance up to 77%, leading to 2.5 times larger bending deformation than that of the BC-IL actuator. More interestingly, bioinspired applications containing artificial soft robotic finger and grapple robot were successfully demonstrated based on high-performance BC-IL-MWCNT actuator with excellent sensitivity and controllability. Thus, the newly proposed BC-IL-MWCNT bioartificial muscle will offer a viable pathway for developing next-generation artificial muscles, soft robotics, wearable electronic products, flexible tactile devices, and biomedical instruments.


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