scholarly journals Zinc Oxide Nanoparticles for Revolutionizing Agriculture: Synthesis and Applications

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Sidra Sabir ◽  
Muhammad Arshad ◽  
Sunbal Khalil Chaudhari

Nanotechnology is the most innovative field of 21st century. Extensive research is going on for commercializing nanoproducts throughout the world. Due to their unique properties, nanoparticles have gained considerable importance compared to bulk counterparts. Among other metal nanoparticles, zinc oxide nanoparticles are very much important due to their utilization in gas sensors, biosensors, cosmetics, drug-delivery systems, and so forth. Zinc oxide nanoparticles (ZnO NPs) also have remarkable optical, physical, and antimicrobial properties and therefore have great potential to enhance agriculture. As far as method of formation is concerned, ZnO NPs can be synthesized by several chemical methods such as precipitation method, vapor transport method, and hydrothermal process. The biogenic synthesis of ZnO NPs by using different plant extracts is also common nowadays. This green synthesis is quite safe and ecofriendly compared to chemical synthesis. This paper elaborates the synthesis, properties, and applications of zinc oxide nanoparticles.

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Bulcha Bekele ◽  
Anatol Degefa ◽  
Fikadu Tesgera ◽  
Leta Tesfaye Jule ◽  
R. Shanmugam ◽  
...  

Comparison of green and chemical precipitation method syntheses of zinc oxide nanoparticles (ZnO NPs) was performed, and antimicrobial properties were investigated. Avocado, mango, and papaya fruit extracts were carried out for the green synthesising methods, while the chemical precipitation method was chosen from chemical synthesis methods. Zinc nitrate was used as a salt precursor, whereas leaf extract was served as a reducing agent for green synthesising methods. In addition, sodium hydroxide, polyvinyl alcohol, and potassium hydroxide were used as reducing agents in the case of chemical precipitation synthesis methods. ZnO NPs were characterised by characterizing techniques such as Fourier transform infrared (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The antimicrobial activities of prepared nanoparticles were evaluated on Bacillus subtilis (B. subtilis), Staphylococcus aureus (S. aureus), and Salmonella typhimurium (S. typhimurium). The particle sizes of the prepared samples which were evaluated by the Scherrer equation were in the range of 11-21 nm for green synthesis, while 30-40 nm for chemical precipitation synthesis methods. Small agglomerations were observed from SEM results of prepared ZnO NPs from both methods. Prepared ZnO NPs were showed strong antimicrobial properties. From the result, the inhibition zone was in the range of 15-24 mm for the green route and 7–15 mm for chemical precipitation methods, where the standard drugs have 25 mm of the zone of inhibition. A green synthesised method of preparing ZnO NPs gives promising antimicrobial properties compared to chemical synthesis and is also eco-friendly and safe compared to the chemical synthesis.


2021 ◽  
Vol 10 (1) ◽  
pp. 1079-1091
Author(s):  
Mahboob Alam

Abstract The biogenic synthesis of zinc oxide nanoparticles (ZnO NPs) with pinecone extract (PCE) as a reducing agent and antibacterial agent was explored. The current study aims to investigate the biosynthesis of ZnO NPs and their effect on photocatalytic dye degradation and antimicrobial properties. The physical, chemical, and morphological properties of biogenic ZnO NPs synthesized using PCE were investigated using advanced spectroscopy techniques such as Fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy, transmission electron microscopy (TEM) analysis, selected area electron diffraction (SAED), and X-ray diffraction (XRD) techniques. The photocatalytic degradation of methylene blue was measured spectrophotometrically using biogenic ZnO NPs as nanocatalysts, and decolonization of solution indicates dye degradation gradually as exposure duration increases. The antimicrobial properties of ZnONPs against the tested pathogenic strains were demonstrated using the disc diffusion method. The antimicrobial efficacy of ZnONPs was further explained using molecular docking analysis. Confirmation of the lowest binding energy was used to predict receptor binding site with NPs in order to understand the mechanistic approach. ZnONPs are likely to interact with pathogens via mechanical enfolding, which could be one of the major toxicity actions of ZnONPs against strains. Furthermore, the nontoxicity and biocompatibility of ZnO NPs were studied, revealing impressive hemocompatibility with red blood cells (RBCs) and no significant toxicity to Brine shrimps at lower ZnONP concentrations.


2016 ◽  
Vol 107 (2) ◽  
pp. 299 ◽  
Author(s):  
Zahra KHOOSHE-BAST ◽  
Najmeh Sahebzadeh ◽  
Mansour GHAFFARI-MOGHADDAM ◽  
Ali MIRSHEKAR

<p><em></em>Greenhouse whitefly,<em> Trialeurodes vaporariorum</em> is a major pest of horticultural and ornamental plants and is usually controlled with insecticides or biological control agents. In the current study, we examined the effects of synthesized zinc oxide nanoparticles (ZnO NPs) and <em>Beauveria bassiana</em> TS11 on <em>T. vaporariorum</em> adults. ZnO NPs were synthesized by precipitation method. Field emission scanning electron microscope images indicated that ZnO NPs were non-compacted uniformly. X-ray diffraction results confirmed the hexagonal wurtzite structure of ZnO NPs. Fourier transform infrared analysis showed an intense absorption peak at a range of 434-555 cm<sup>-1</sup> related to Zn-O bond. In bioassays, adults were exposed to different concentrations of ZnO NPs (3, 5, 10, 15, 20 mg l<sup>-1</sup>) and fungi (10<sup>4</sup>, 10<sup>5</sup>, 10<sup>6</sup>, 10<sup>7</sup>, 10<sup>8</sup> spores ml<sup>-1</sup>). LC<sub>50</sub> values for ZnO NPs and fungi were 7.35 mg l<sup>-1</sup>and 3.28×10<sup>5</sup> spores ml<sup>-1</sup>, respectively. Mortality rates obtained with ZnO NPs and fungi at the highest concentration were 91.6 % and 88.8 %, respectively. The results indicate a positive effect of ZnO NPs and <em>B. bassiana </em>TS11on adults. The current study was conducted under laboratory conditions, therefore, more studies are needed in field.</p>


2021 ◽  
Author(s):  
Carolina Rosai Mendes ◽  
Guilherme Dilarri ◽  
Carolina Froes Forsan ◽  
Vinícius de Moraes Ruy Sapata ◽  
Paulo Renato Matos Lopes ◽  
...  

Abstract Zinc oxide nanoparticles (ZnO NPs) are one of the most widely used nanoparticulate materials due to their antimicrobial properties, but their main mechanism of action (MOA) has not been fully elucidated. The study characterized ZnO NPs using X-ray diffraction, FT-IR spectroscopy and scanning electron microscopy. Antimicrobial activity of clinically bacteria Escherichia coli, Staphylococcus aureus, Bacillus subtilis and Pseudomonas aeruginosa was evaluated by REMA after exposure to the ZnO NP at concentrations from 0.2 to 1.4 mM. Sensitivity was achieved at 0.6 mM for the Gram-negatives and 1.0 mM for Gram-positives cells. The effect of ZnO NPs on the membrane integrity and in the interference of cell division was investigated by its effect on the divisional ring, through fluorescence microscopy assays using B. subtilis (amy::pspac-ftsZ-gfpmut1) expressing FtsZ-GFP. Results showed that ZnO NPs did not interfere with the assembly of the divisional Z-ring. However, 70% of the cells showed damage in the cytoplasmic membrane after 15 min of exposure to the ZnO NPs. Electrostatic forces, production of Zn2+ ions, generation of reactive oxygen species were described as pathways of bactericidal action by ZnO. Thus, understanding bactericidal MOA can produce predictive models to prevent bacterial resistance and lead to further research.


Nanomaterials ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 42
Author(s):  
Tentu Nageswara Rao ◽  
T. Manohra Naidu ◽  
Min Soo Kim ◽  
Botsa Parvatamma ◽  
Y. Prashanthi ◽  
...  

Zinc oxide nanoparticles (ZnO NPs) were synthesized by a precipitation method, and a new charring–foaming agent (CFA) N-ethanolamine triazine-piperazine, melamine polymer (ETPMP) was synthesized via nucleophilic substitution reaction by using cyanuric chloride, ethanolamine, piperazine, and melamine as precursor molecules. FTIR and energy-dispersive X-ray spectroscopy (EDS) studies were employed to characterize and confirm the synthesized ETPMP structure. New intumescent flame retardant epoxy coating compositions were prepared by adding ammonium polyphosphate (APP), ETPMP, and ZnO NPs into an epoxy resin. APP and ETPMP were fixed in a 2:1 w/w ratio and used as an intumescent flame-retardant (IFR) system. ZnO NPs were loaded as a synergistic agent in different amounts into the IFR coating system. The synergistic effects of ZnO NPs on IFR coatings were systematically evaluated by limited oxygen index (LOI) tests, vertical burning tests (UL-94 V), TGA, cone calorimeter tests, and SEM. The obtained results revealed that a small amount of ZnO NPs significantly increased the LOI values of the IFR coating and these coatings had a V-0 ratings in UL-94 V tests. From the TGA data, it is clear that the addition of ZnO NPs could change the thermal degradation behaviors of coatings with increasing char residue percentage at high temperatures. Cone calorimeter data reported that ZnO NPs could decrease the combustion parameters including peak heat release rates (PHRRs), and total heat release (THR) rates. The SEM results showed that ZnO NPs could enhance the strength and the compactness of the intumescent char, which restricted the flow of heat and oxygen.


2018 ◽  
Vol 34 (11) ◽  
pp. 753-763 ◽  
Author(s):  
Zulfia Hussain ◽  
Junaid Ali Khan ◽  
Hafeez Anwar ◽  
Naila Andleeb ◽  
Sehrish Murtaza ◽  
...  

Zinc oxide nanoparticles (ZnONPs) are being used extensively in manufacturing skin lotions and food products and in various biological and pharmaceutical industries because of their immunomodulatory and antimicrobial properties. In this study, ZnONPs were synthesized by a precipitation method and characterized by X-ray diffraction (XRD) techniques, scanning electron microscopy (SEM), and ultraviolet–visible spectroscopy to investigate their structural, morphological, and optical properties. For in vivo evaluation, 40 healthy albino mice were randomly allocated to four equal groups among which the first one was the control group, while the second, third, and fourth were treated with carbon tetrachloride (CCl4), a blend of CCl4 and ZnONPs, and ZnONPs alone, respectively, for 21 days. The XRD analysis confirmed hexagonal wurtzite type structures having an average crystallite size of 41.54 nm. The morphology of ZnONPs analyzed through SEM showed uniform distribution of the grains and shape of the synthesized oxide. The energy band gap of the ZnONPs was found to be 3.498 eV. Hepatic and renal damage following CCl4 administration was apparent after 14 days and was increased at the 21st day, showing nodular fibrotic masses in the liver and bumpy surfaces in the kidney as observed by gross and histological examination. Coadministration of ZnONPs (15 mg/kg b.w. intragastrically 5 days a week) significantly prevented the CCl4-dependent increases in alanine transaminase, aspartate transaminase, creatinine, and urea levels, suggesting a protective potential of ZnONPs.


RSC Advances ◽  
2019 ◽  
Vol 9 (51) ◽  
pp. 29541-29548 ◽  
Author(s):  
Wali Muhammad ◽  
Naimat Ullah ◽  
Muhammad Haroon ◽  
Bilal Haider Abbasi

Biogenic synthesis of ZnO-NPs using P. somniferum.


2021 ◽  
Vol 6 (3) ◽  
pp. 91-99
Author(s):  
Safoora Bazzi ◽  
Jafar Valizadeh ◽  
Moharam Valizadeh ◽  
Ali Movafeghi

Introduction: The plant species Cyamopsis tetragonoloba L. (Fabaceae) is a source of guar gum that has a variety of applications in the pharmaceutical industry because of its therapeutic properties. Other parts of the plant are also used as food and fodder. This study was conducted to evaluate some physiological changes and gum production of guar in response to foliar spraying with synthesized zinc oxide nanoparticles (ZnO-NPs).Methods: ZnO-NPs were synthesized using guar gum by the co-precipitation method. The properties of the ZnO-NPs were investigated using various analytical techniques, including ultraviolet-visible spectroscopy (UV-Vis), scanning electron microscopy (SEM), transmission electron microscope (TEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The nanoparticles were sprayed on the leaves of the Saravan landrace of guar to study their effects on the physiological properties of the plant. The experiments were performed in a completely randomized design with three replications.Results: Treatment of plants with ZnO-NPs resulted in an improvement of some physiological properties. After exposure to 500 mg/L of ZnO-NPs, the contents of chlorophyll a, chlorophyll b, total chlorophyll, carotenoids, gum, and soluble protein were increased by 47.88%, 78.43%, 54.37T, 29.41%, 55.08%, and 52.12%, respectively. Additionally, the amount of Zn and insoluble sugars showed the highest increase, by 3.96 and 4.31 times, respectively. In contrast, soluble sugars content as well as the activity of catalase (CAT), peroxidase (POX), and ascorbate peroxidase (APX) reduced 0.69-, 2.23-, 1.60-, and 3.91-fold, respectively.Conclusion: ZnO-NPs improved the physiological properties of guar at different concentrations, with the best effects obtained at the maximum concentration of 500 mg/L. The results of this study suggest that the ZnO-NPs synthesized by the biocompatible process are appropriate candidates to prepare guar gum to be used in pharmaceutical and therapeutic-based approaches.


2019 ◽  
Vol 20 (7) ◽  
pp. 542-550 ◽  
Author(s):  
Nahla S. El-Shenawy ◽  
Reham Z. Hamza ◽  
Fawziah A. Al-Salmi ◽  
Rasha A. Al-Eisa

Background: Zinc oxide nanoparticles (ZnO NPs) are robustly used biomedicine. Moreover, no study has been conducted to explore the consequence of green synthesis of ZnO NPs with Camellia sinensis (green tea extract, GTE) on kidneys of rats treated with monosodium glutamate (MSG). Methods: Therefore, the objective of the research was designed to explore the possible defensive effect of GTE/ZnO NPs against MSG-induced renal stress investigated at redox and histopathological points. Results: The levels of urea and creatinine increased as the effect of a high dose of MSG, in addition, the myeloperoxidase and xanthine oxidase activates were elevated significantly with the high dose of MSG. The levels of non-enzymatic antioxidants (uric acid, glutathione, and thiol) were decreased sharply in MSG-treated rats as compared to the normal group. Conclusion: The data displayed that GTE/ZnO NPs reduced the effects of MSG significantly by reduction of the level peroxidation and enhancement intracellular antioxidant. These biochemical findings were supported by histopathology evaluation, which showed minor morphological changes in the kidneys of rats.


Author(s):  
Mohammad Faizan ◽  
Fangyuan Yu ◽  
Chen Chen ◽  
Ahmad Faraz ◽  
Shamsul Hayat

: Abiotic stresses arising from atmosphere change belie plant growth and yield, leading to food reduction. The cultivation of a large number of crops in the contaminated environment is a main concern of environmentalists in the present time. To get food safety, a highly developed nanotechnology is a useful tool for promoting food production and assuring sustainability. Nanotechnology helps to better production in agriculture by promoting the efficiency of inputs and reducing relevant losses. This review examines the research performed in the past to show how zinc oxide nanoparticles (ZnO-NPs) are influencing the negative effects of abiotic stresses. Application of ZnO-NPs is one of the most effectual options for considerable enhancement of agricultural yield globally under stressful conditions. ZnO-NPs can transform the agricultural and food industry with the help of several innovative tools in reversing oxidative stress symptoms induced by abiotic stresses. In addition, the effect of ZnO-NPs on physiological, biochemical, and antioxidative activities in various plants have also been examined properly. This review summarizes the current understanding and the future possibilities of plant-ZnO-NPs research.


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