scholarly journals Research on Crude Oil Demulsification Using the Combined Method of Ultrasound and Chemical Demulsifier

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Mingxu Yi ◽  
Jun Huang ◽  
Lifeng Wang

In this paper, experiments of crude oil demulsification using ultrasound, chemical demulsifier, and the combined method of ultrasound and chemical demulsifier, respectively, at different temperatures (40°C, 60°C, and 70°C) are carried out. The photos of water droplet distribution in crude oil, taken with microscopic imaging system, before and after demulsification using the above methods at 70°C are given. Research results show that the combined method of ultrasound and chemical demulsifier has the best demulsification effect, followed by chemical demulsifier. Ultrasound without using chemical demulsifier has the least demulsification effect. Furthermore, the impact of ultrasonic power, treatment time, and temperature on crude oil demulsification using the combined method of ultrasound and chemical demulsifier is studied. Results indicate that the final dehydration rate increases with the increase of temperatures and ultrasonic power and almost does not change with the increase of ultrasonic treatment time. These important conclusions will provide the foundation for an extensive application of the combined method of ultrasound and chemical demulsifier.

2015 ◽  
Vol 60 (3) ◽  
pp. 2131-2137 ◽  
Author(s):  
M. Gruber ◽  
S. Ploberger ◽  
G. Ressel ◽  
M. Wiessner ◽  
M. Hausbauer ◽  
...  

Abstract The stability of austenite is one of the most dominant factors affecting the toughness properties of high Co-Ni steels such as Aermet 100 and AF1410. Thus, the aim of this work was to get a deeper understanding on the impact of combined heat and cryogenic treatment on the stability of retained and reverted austenite. In order to characterize the evolution of the phase fraction of austenite during tempering at different temperatures and times, X-ray diffraction analyses were carried out. The stability of austenite, which was formed during tempering, was analyzed with dilatometric investigations by studying the transformation behavior of the austenite during cooling from tempering temperature down to −100°C. Additionally, transmission electron microscopy investigations were performed to characterize the chemical composition and phase distribution of austenite and martensite before and after tempering.


2008 ◽  
Vol 2008 (1) ◽  
pp. 801-804
Author(s):  
Kavitha R. Nagarajan ◽  
Niranjan Deshpande ◽  
George A. Sorial ◽  
James W. Weaver

ABSTRACT When a dispersant is applied to an oil slick, its effectiveness in dispersing the spilled oil depends on various factors such as oil properties, wave mixing energy, temperature of both oil and water, and salinity of the water. Estuaries represent water with varying salinities. In this study three salinity values in the range of 10–34 ppt were investigated, representing potential salinities found in typical estuaries. Three oils were chosen to represent light refined oil, light crude oil and medium crude oil. Each oil was tested at three weathering levels to represent maximum, medium and zero weathering. Two dispersants were chosen for evaluation. A modified trypsinizing flask termed the ‘Baffled Flask’ was used for conducting the experimental runs. A full factorial experiment was conducted for each oil to investigate the effect of salinity (3 levels), temperature (6 levels), oil weathering (3 levels) and mixing energy (150, 200, and 250 rpm) on dispersant effectiveness. Each experiment was replicated four times in order to evaluate the accuracy of the test. Statistical analyses of the experimental data were performed separately for each of the three oils three times (with or without dispersant). Viscosity of the three oils at the different temperatures and weathering conditions were determined. An empirical correlation of the viscosity for each of the three oils was then obtained. A linear regression model incorporating the viscosity correlations to represent temperature and weathering, the other remaining main factors (salinity and flask speed) and second order interactions among the factors was developed and was found to accurately represent the experimental data. The empirical approach to the interaction between the dispersant and oil slick developed could provide a useful or practical approach for including dispersants in a model to assess the impact of dispersant usage on oil spills.


Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4211
Author(s):  
Sylwester Bejger

Liquid fuels obtained in refining crude oil are one of the most important energies in economic activity. The domestic wholesale market for liquid fuels is of decisive importance for price formation in the national economy. The noncompetitive behavior of the market players at this level of the distribution chain can significantly affect all downstream price levels and the producer–consumer surplus balance. Therefore, the competitiveness of this market should be screened and assessed regularly, especially when significant external factors change. This article attempts to evaluate the impact of structural changes on the global market of crude oil and energy products after the outbreak of the COVID-19 pandemic on the competitiveness of the wholesale fuel market in Poland. Using asymmetry of the reaction of product prices to changes in the prices of inputs as a marker of noncompetitive behavior and the NARDL model as a test specification, the price paths of market players before and after the occurrence of structural changes in the inputs’ processes were examined. Significant changes in the competitive behavior of players were revealed after the occurrence of structural changes at the beginning of the pandemic period in the year 2020. These changes may indicate enhanced competition and mitigation of potential market power abuse.


The study aims at determining the effect of the treatment method of root crops before storage, as well as storage parameters, on the dynamics of their microflora, namely, the quantity of bacterial microflora, mesophilic aerobic and optionally anaerobic microorganisms (MAaOAM), as well as molds. When storing garden carrot at t = +(2±1) °C (during 56 days), the amount of bacterial microflora of the samples subjected to integrated treatment decreased by 2.5 times by the end of storage; the number of mold fungi decreased twice compared to the control. When storing garden carrot at t = +(25±1) °C (for 21 days) the amount of bacterial microflora in the samples treated by electromagnetic fields of extremely low frequencies (with the following parameters: frequency – 28 Hz, the treatment time – 5 min, the magnetic induction – 12 mTl), and by Vitaplan biologic preparation (at the concentration of 106 CFU/g, and in the amount of 2.5 ml/kg), decreased by 2.1 times, while the number of mold fungi reduced by 1.5 times. When storing garden beet at t = +(2±1) °C for 56 days, the amount of bacterial microflora of samples, subjected to integrated treatment for 5 min at a frequency of 15, 24, and 30 Hz, and magnetic induction of 9 mTl, as well as treatment with Bactofit biological preparation (at the concentration of 106 CFU/g in amount of 2.5 ml/kg), decreased by 1.5 times compared to the control, while the number of mold fungi decreased by 2.3 times. When storing garden beet at t = +(25±1) °C (for 21 days), the quantity of bacterial microflora of samples, subjected to integrated treatment, was by 2.8 times lower compared to the control, while the number of mold fungi reduced by 1.8 times. It has been revealed that the integrated treatment of root crops with biopreparations and extremely low frequency (ELF) electric and magnetic fields (EMF) more effectively inhibits the development of pathogenic microflora compared to treatment only with biopreparations or treatment only by ELF-EMF. Significant retardation of growth rates was revealed in both bacterial and fungal pathogenic microflora during storage of root crops at different temperatures.


2017 ◽  
Vol 898 ◽  
pp. 380-386
Author(s):  
Wei Yuan ◽  
Dong Mei Liu ◽  
Qiang Song Wang ◽  
Guo Liang Xie

In this paper, the effect of heat treatment on the microstructure and mechanical properties of hot forging Cu-Ni alloy was studied. Specimens of hot forged Cu-Ni alloy were subjected to first solution treated at 900oC for 2hrs and then aged at different temperatures for 2hrs. The mechanical properties including tensile performance and impact energy, and the microstructure were measured for specimens before and after heat treatment. The results show that both solution and aging treatment have an influence on the grain growth. After heat treatment, the tensile strength decreases very slightly but the yield strength decreases seriously from 235.96MPa to 136.12MPa, while the elongation increases sharply from 36% to 48%. It was also observed that hardness values of the heat-treated alloys are all lower than that of the hot forged alloy. The measurement of Charpy impact energy with V-type notch was performed at 298K and 77K for different specimens. At both temperatures, the impact energies of the specimens are higher than 200J. The microstructure results show that at both temperatures, the alloys are fractured in a ductile mode.


Life ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1144
Author(s):  
Denise de Melo-Marins ◽  
Juliano Boufleur Farinha ◽  
Franccesco Pinto Boeno ◽  
Alexandra Ferreira Vieira ◽  
Samuel Vargas Munhoz ◽  
...  

Background: Reduced glutathione (GSH) is one of the main thiols involved in antioxidant defense. Changes in circulatory levels of GSH during exercise are associated with hyperthermia and dehydration. The mechanisms by which these alterations occur are not entirely known. We hypothesize that erythrocytes could be an important source of circulatory GSH during heat stress conditions. We performed two separate experiments to address this hypothesis. Methods: In the first experiment, we sought to investigate the impact of exercise in the heat and dehydration on erythrocyte levels of GSH. A total of 10 men performed 60 min of cycling at 60% VO2peak in the heat (38.0 ± 0.9 °C) or in a control temperate environment (23.0 ± 1.0 °C), both with and without dehydration. Relative humidity ranged from 50 to 70%. Blood samples were taken before and after exercise to measure GSH and oxidized (GSSG) glutathione. In the second experiment, erythrocytes were isolated from blood samples taken at rest and heated in vitro to determine the impact of heat on erythrocyte glutathione content. Tubes with erythrocytes were exposed to water baths at different temperatures; one tube was exposed to a water bath at 35 °C and the other tube to a water bath at 41 °C for a period of 30 min. After exposure to heat, plasma and erythrocytes were extracted for GSH and GSSG analyses. Results: Dehydration decreased circulatory GSH, regardless of ambient temperature (temperate and heat decreased 15.35% and 30.31%, respectively), resulting in an altered redox balance. Heat increased GSH levels in vitro. Conclusion: Our data suggest that dehydration decreases circulatory GSH levels regardless of environmental temperature. In addition, in vitro data suggests that erythrocytes may contribute to the release of GSH during exposure to heat stress.


SPE Journal ◽  
2016 ◽  
Vol 21 (04) ◽  
pp. 1164-1177 ◽  
Author(s):  
Yingcheng Li ◽  
Weidong Zhang ◽  
Bailing Kong ◽  
Maura Puerto ◽  
Xinning Bao ◽  
...  

Summary Test results indicate that a lipophilic surfactant can be designed by mixing both hydrophilic anionic and cationic surfactants, which broaden the design of novel surfactant methodology and application scope for conventional chemical enhanced-oil-recovery (EOR) methods. These mixtures produced ultralow critical micelle concentrations (CMCs), ultralow interfacial tension (IFT), and high oil solubilization that promote high tertiary oil recovery. Mixtures of anionic and cationic surfactants with molar excess of anionic surfactant for EOR applications in sandstone reservoirs are described in this study. Physical chemistry properties, such as surface tension, CMC, surface excess, and area per molecule of individual surfactants and their mixtures, were measured by the Wilhelmy (1863) plate method. Morphologies of surfactant solutions, both surfactant/polymer (SP) and alkaline/surfactant/polymer (ASP), were studied by cryogenic-transmission electron microscopy (Cryo-TEM). Phase behaviors were recorded by visual inspection including crossed polarizers at different surfactant concentrations and different temperatures. IFTs between normal octane, crude oil, and surfactant solution were measured by the spinning-drop-tensiometer method. Properties of IFT, viscosity, and thermal stability of surfactant, SP, and ASP solutions were also tested. Static adsorption on sandstone was measured at reservoir temperature. IFT was measured before and after multiple contact adsorptions to recognize the influence of adsorption on interfacial properties. Forced displacements were conducted by flooding with water, SP, and ASP. The coreflooding experiments were conducted with synthetic brine with approximately 5,000 ppm of total dissolved solids (TDS), and with a crude oil from a Sinopec reservoir.


2010 ◽  
Vol 434-435 ◽  
pp. 113-115
Author(s):  
Yan Rong Bao ◽  
Bin Li ◽  
Zong De Liu ◽  
Zhi Jian Bao

The impact properties of TiC-Fe composite at different temperatures prepared by SHS / PHIP technique were investigated by impact test which was conducted in air from 20°C to 100020°C. Morphology of the impact fracture surface was observed by scanning electron microscope (SEM) and phase composition before and after the impact test was analyzed with X-Ray Diffraction. The results indicate that the impact toughness of TiC-Fe composite increases significantly with the temperature increasing above 700°C, representing a minimum value at 700°C. The impact fracture of TiC-Fe composite at room temperature, 700°C, 900°C and 1000°C is mainly brittle, showing certain plasticity with morphology of dimples as the temperature increases above 700°C. A small amount of Fe2O3 exists in the fracture surface, indicating TiC-Fe composite is oxidized partially during the impact test at elevated temperatures.


2018 ◽  
Vol 15 (1) ◽  
pp. 55-72
Author(s):  
Herlin Hamimi ◽  
Abdul Ghafar Ismail ◽  
Muhammad Hasbi Zaenal

Zakat is one of the five pillars of Islam which has a function of faith, social and economic functions. Muslims who can pay zakat are required to give at least 2.5 per cent of their wealth. The problem of poverty prevalent in disadvantaged regions because of the difficulty of access to information and communication led to a gap that is so high in wealth and resources. The instrument of zakat provides a paradigm in the achievement of equitable wealth distribution and healthy circulation. Zakat potentially offers a better life and improves the quality of human being. There is a human quality improvement not only in economic terms but also in spiritual terms such as improving religiousity. This study aims to examine the role of zakat to alleviate humanitarian issues in disadvantaged regions such as Sijunjung, one of zakat beneficiaries and impoverished areas in Indonesia. The researcher attempted a Cibest method to capture the impact of zakat beneficiaries before and after becoming a member of Zakat Community Development (ZCD) Program in material and spiritual value. The overall analysis shows that zakat has a positive impact on disadvantaged regions development and enhance the quality of life of the community. There is an improvement in the average of mustahik household incomes after becoming a member of ZCD Program. Cibest model demonstrates that material, spiritual, and absolute poverty index decreased by 10, 5, and 6 per cent. Meanwhile, the welfare index is increased by 21 per cent. These findings have significant implications for developing the quality of life in disadvantaged regions in Sijunjung. Therefore, zakat is one of the instruments to change the status of disadvantaged areas to be equivalent to other areas.


2014 ◽  
pp. 74-89 ◽  
Author(s):  
Vinh Vo Xuan

This paper investigates factors affecting Vietnam’s stock prices including US stock prices, foreign exchange rates, gold prices and crude oil prices. Using the daily data from 2005 to 2012, the results indicate that Vietnam’s stock prices are influenced by crude oil prices. In addition, Vietnam’s stock prices are also affected significantly by US stock prices, and foreign exchange rates over the period before the 2008 Global Financial Crisis. There is evidence that Vietnam’s stock prices are highly correlated with US stock prices, foreign exchange rates and gold prices for the same period. Furthermore, Vietnam’s stock prices were cointegrated with US stock prices both before and after the crisis, and with foreign exchange rates, gold prices and crude oil prices only during and after the crisis.


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