Effects of a novel acrylic-based compatibilizer on the mechanical properties, contact angle, water absorption, density and processibility of polyvinyl chloride/wood flour composite

2012 ◽  
Vol 31 (15) ◽  
pp. 1025-1036 ◽  
Author(s):  
Deqin Zhu ◽  
Yu Sheng ◽  
Xirong Liu ◽  
Qianhuo Chen
Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).


2015 ◽  
Vol 38 (5) ◽  
pp. 863-869 ◽  
Author(s):  
Nadir Ayrilmis ◽  
Münir Taşdemir ◽  
Turgay Akbulut

Holzforschung ◽  
2014 ◽  
Vol 68 (8) ◽  
pp. 933-940 ◽  
Author(s):  
Yao Chen ◽  
Nicole M. Stark ◽  
Mandla A. Tshabalala ◽  
Jianmin Gao ◽  
Yongming Fan

Abstract The water sorption and mechanical properties of wood-plastic composites (WPCs) made of extracted and delignified wood flour (WF) has been investigated. WF was prepared by extraction with the solvent systems toluene/ethanol (TE), acetone/water (AW), and hot water (HW), and its delignification was conducted by means of sodium chlorite/acetic acid (AA) solution. A 24 full-factorial experimental design was employed to determine the effects of treatments and treatment combinations. WPCs were prepared with high-density polyethylene (HDPE) and treated WF was prepared by means of extrusion followed by injection molding, and the water absorption characteristics and mechanical properties of the products were evaluated. WPCs produced with extracted WF had lower water absorption rates and better mechanical properties than those made of untreated WF. WPCs containing delignified WF had higher water absorption rates and improved mechanical performance compared with those made of untreated WF.


Author(s):  
ANDRÉS PACHECO LANCHEROS ◽  
AURA LOMBANA PUERTA ◽  
ÁLVARO REALPE JIMÉNEZ ◽  
DINA MENDOZA BELTRAN ◽  
MARÍA TERESA ACEVEDO MORANTES

Proton Exchange Membranes (PEMs) are materials developed with a focus on high-performance, low-cost features to achieve promising fuel cell technology in stationary, portable, and transportation facilities. In this study, we synthesized membranes from Poly (oxy-1,4-phenylenesulfonyl-1,4-phenylene) (PES) sulfonated with modification by adding nanoclay to improve the mechanical properties of PEMs. The sulfonation time and the concentration of nanoclays directly favored properties such as contact angle, water absorption, porosity, and mechanical properties. However, a higher concentration of nanoclays (e.g., 10% by weight) damages the mechanical properties of PES membranes specifically. The membrane with 5% by weight of nanoclay and a sulfonation time of 2 h achieved the best performance.


BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 789-804
Author(s):  
Qiang Jin ◽  
Lin Zhu ◽  
Jiedeerbieke Madiniyeti ◽  
Chunxia He ◽  
Li Li

Hydration-active steel slag and slag micropowder were used as inorganic fillers with silane coupling agent (KH550) to prepare wheat straw/polyvinyl chloride wood-plastic composites (WPCs) by extrusion molding. A 35-day immersion and a pre-immersion test were carried out to analyze the influence of steel slag and slag micropowder on the physical and mechanical properties of the WPCs under wet conditions. Results showed the following: (1) KH-550 exhibited a good surface modification effect on the activated steel slag and slag micropowder, (2) an increase in the activated steel slag and slag micropowder content could effectively reduce the percent water absorption of the WPCs by 20% to 25% and the expansion by 20% to 24%, respectively, compared with the control group, but had a limited effect on the tensile strength retention, and (3) pre-immersion could effectively induce the synergistic reinforcement effect of the active fillers, resulting in reaching the saturated water absorption within 20 days. The water absorption and tensile strength were respectively 18% to 25% lower and 1.5% to 3% higher than those of the composites without pre-immersion. The results of this study could provide experimental data and theoretical references for the influence of hydration-active inorganic fillers on WPC properties.


2021 ◽  
pp. 096739112110271
Author(s):  
Reyhaneh Fatahian ◽  
Mohammad Mirjalili ◽  
Ramin Khajavi ◽  
Mohammad Karim Rahimi ◽  
Navid Nasirizadeh

Differences in the properties of poly(vinyl alcohol) (PVA) and poly (lactic acid) (PLA) polymers have attracted much attention today. In this research, the aim is to produce PVA/PLA nanofibers with hydrophilicity and good mechanical properties using a mutual solvent. In this regard, the ability to produce PVA/PLA nanofibers using a mutual solvent was evaluated. The effect of electrospinning parameters on the morphology of nanofibers, hydrophilicity of nanofibers produced by measuring water absorption and contact angle as well as mechanical properties of nanofibers were considered. The results obtained from scanning electron microscopy analyses of the structure of these fibers showed that PVA had the highest viscosity of 5.64 Pa.s and the highest diameter of 260 nm, which decreased the thickness of the nanofibers with increasing PLA. And pure PLA had the lowest mean diameter of 76 nm. In the consideration of the mechanical properties of the prepared nanofibers, it was found that the combination of PLA and PVA nanofibers will lead to overlap the properties of each other and the creation of desirable mechanical properties. Moreover, in the investigation of water absorption and contact angle, it was concluded that the PVA/PLA was fully absorbed in less than 200 seconds and the samples have a contact angle of less than 52°. Finally, it was found that the average diameter of the produced nanofibers was decreased by increasing the voltage and the needle tip to collector distance by considering the PVA/PLA samples with a ratio of 50:50.


2016 ◽  
Vol 23 (2) ◽  
pp. 209-216 ◽  
Author(s):  
Hakan Bolat ◽  
Pınar Erkus

AbstractConcrete is one of the materials in which polymer wastes are utilized. Generally, these wastes are added at specific rates in scientific studies but an important problem of waste polymers is size irregularity. Even when consistent dosage rates are used, variations in polymer size can lead to variability in the physical and mechanical properties of the concrete produced. The aim of this study is to determine physical and mechanical properties of polyvinyl chloride (PVC)-containing concretes. In order to produce normal and high strength concretes, 10%, 20%, and 30% replacement ratios of PVC powder and granules by volume of aggregate are used. Slump, fresh and hardened densities, compressive strength, capillary water absorption, and abrasion were tested on all concrete types. As the PVC ratio increases, important changes are seen in all physical and mechanical concrete properties. The unit weights of the 10%, 20%, and 30% replacement PVC powder concretes are lower by ∼4%, 8%, and 13%, respectively, as compared to the reference mixtures, and the replacement PVC granule concretes are lower by ∼2%, 4%, and 7%. Compressive strength test results showed similar trends. As PVC replacement increases, the capillary water absorption decreases between 10% and 50%, and abrasion decreases between 27% and 77%.


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