Adsorption of Cu(II) from Aqueous Solutions by Ammoniated Cotton Fiber

2016 ◽  
Vol 11 (4) ◽  
pp. 155892501601100
Author(s):  
Chuanfeng Zang ◽  
Yu Ren ◽  
Fangfang Wang ◽  
Hong Lin ◽  
Yuyue Chen
Keyword(s):  
Aqueous Solutions ◽  
Cotton Fiber ◽  
Photoelectron Spectroscopy ◽  
Metal Ion ◽  
Second Order ◽  
Order Model ◽  
Amine Content ◽  
Pseudo Second Order ◽  
Adsorption Amount ◽  
Second Order Model

This study describes the preparation of a novel chelating cotton fiber adsorbent, ammoniated cotton fiber (ACF), which was prepared by modifying cotton fiber with amino-HBP using glutaraldehyde as a cross-linking agent. This new adsorbent was characterized and analyzed for amine content, and by scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The capacity of ACF to adsorb Cu(II) from aqueous solution was evaluated at different pHs, contact times and initial metal ion concentrations. The results showed that ACF was effective in removing of Cu(II) from aqueous solutions and the adsorption amount of Cu(II) reached 16.7374 mg g-1. The adsorption isotherm and kinetics were well fitted to the Langmuir model and the pseudo-second-order model, respectively. The adsorption amount calculated using the pseudo-second-order model was in good agreement with the experimental data.

Adsorption Kinetics of Zn(II) from Aqueous Solutions onto Epichlorohydrin Crosslinked Chitosan

2012 ◽  
Vol 463-464 ◽  
pp. 7-11 ◽  
Author(s):  
Ming Yan Dang ◽  
Hong Min Guo ◽  
Yan Kun Tan
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Kinetics ◽  
Ph Value ◽  
Crosslinking Agent ◽  
Second Order ◽  
Order Model ◽  
Pseudo Second Order ◽  
Crosslinked Chitosan ◽  
Kinetics Of ◽  
Second Order Model

Chitosan was crosslinked using epichlorohydrin as crosslinking agent to prepare crosslinked chitosan which was used as an adsorbent for the removal of Zn(II) from aqueous solutions. The adsorption prosperities of Zn(II) on crosslinked chitosan were studied, including the influence of pH value and the adsorption kinetics. The kinetics of adsorption was discussed using two kinetic models, the pseudo first-order and the pseudo second-order model. Results reveal that the crosslinked chitosan is suitable as adsorbent to remove Zn(II) from dilute solution. The rate parameters for the Zn(II) by crosslinked chitosan were also determined. It was shown that the adsorption kinetics of Zn(II) could be best described by the pseudo second-order model and the adsorption process may involve a physical adsorption.

scholarly journals Eco-Friendly Materials Obtained by Fly Ash Sulphuric Activation for Cadmium Ions Removal

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3584
Author(s):  
Gabriela Buema ◽  
Nicoleta Lupu ◽  
Horia Chiriac ◽  
Tiberiu Roman ◽  
Marieta Porcescu ◽  
...  
Keyword(s):  
Fly Ash ◽  
Sulphuric Acid ◽  
Metal Ion ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Acid Activation ◽  
Order Model ◽  
Intraparticle Diffusion Model ◽  
Pseudo Second Order ◽  
Second Order Model

Wastes are the sustainable sources of raw materials for the synthesis of new adsorbent materials. This study has as objectives the advanced capitalization of fly ash, by sulphuric acid activation methods, and testing of synthesized materials for heavy metals removal. Based on the previous studies, the synthesis parameters were 1/3 s/L ratio, 80 °C temperature and 10% diluted sulphuric acid, which permitted the synthesis of an eco-friendly adsorbent. The prepared adsorbent was characterized through SEM, EDX, FTIR, XRD and BET methods. Adsorption studies were carried out for the removal of Cd2+ ions, recognized as ions dangerous for the environment. The effects of adsorbent dose, contact time and metal ion concentrations were studied. The data were tested in terms of Langmuir and Freundlich isotherm and it was found that the Langmuir isotherm fitted the adsorption with a maximum adsorption capacity of 28.09 mg/g. Kinetic data were evaluated with the pseudo-first-order model, the pseudo-second-order model and the intraparticle diffusion model. The kinetics of cadmium adsorption into eco-friendly material was described with the pseudo-second-order model, which indicated the chemisorption mechanism.

scholarly journals K2CO3-Activated Pomelo Peels as a High-Performance Adsorbent for Removal of Cu(II): Preparation, Characterization, and Adsorption Studies

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Zheng Liu ◽  
Yuling Wei
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Capacity ◽  
Activated Carbons ◽  
High Surface ◽  
Second Order ◽  
Order Model ◽  
Activation Temperature ◽  
Batch Mode ◽  
Pseudo Second Order ◽  
Second Order Model

Activated carbons (ACs) were prepared from pomelo peels by K2CO3 activation and used as an adsorbent (PAC) for the removal of Cu(II) from aqueous solutions. BET, SEM, and FT-IR were employed for the characterization of the obtained ACs. The optimum ACs were reported at activation temperature of 850°C, activation time of 60 min, and impregnation ratio of 3, which had a high surface area (1213 m2/g) and total pore volume (0.57 cm3/g). The resulting ACs were used for the adsorption of Cu(II) from aqueous solutions in the batch mode and yielded a superior adsorption capacity of 139.08 mg/g. The pH of optimum adsorption was determined as 5. Pseudo first-order model, pseudo second-order model, and intraparticle diffusion model were applied to describe the adsorption processes. The adsorption kinetic data were found to follow the pseudo second-order model. The adsorption isotherms data were analyzed using Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich models. The Langmuir model was found to provide the best fit, and the calculated adsorption capacity was 151.35 mg/g.

Adsorption Kinetics of Pb2+ Ions Using Chitosan Nanoparticles

2013 ◽  
Vol 367 ◽  
pp. 45-49
Author(s):  
Ying Hong ◽  
Ze Hui Zhong ◽  
You Shi Liu
Keyword(s):  
Adsorption Kinetics ◽  
Chitosan Nanoparticles ◽  
Second Order ◽  
Isotherm Model ◽  
Order Model ◽  
Adsorption Characteristics ◽  
Pseudo Second Order ◽  
Kinetics Of ◽  
Second Order Model

Chitosan nanoparticles were prepared by crosslinkingusing TPP. SEM showed that chitosan nanoparticles were successfully obtained.The adsorption characteristics of chitosan nanoparticles were evaluated. Theresults demonstrated that chitosan nanoparticles were suitable for adsorbent toremoval Pb2+. The parameters for the adsorption of Pb2+by chitosan nanoparticles were also determined. It was shown that chitosannanoparticles were fit for Langmuir’s isotherm model and that the adsorptionkinetics of Pb2+ described by the pseudo-second-order model could bebest.

Polyaniline/ZnO nanocomposites for the removal of methyl orange dye from waste water

2018 ◽  
Vol 32 (19) ◽  
pp. 1840085 ◽  
Author(s):  
Neha V. Nerkar ◽  
Subhash B. Kondawar ◽  
Snehal Kargirwar Brahme ◽  
Yun Hae Kim
Keyword(s):  
Waste Water ◽  
Methyl Orange ◽  
Adsorption Mechanism ◽  
Second Order ◽  
Pure Pani ◽  
Time Interval ◽  
Order Model ◽  
Vis Spectroscopy ◽  
Pseudo Second Order ◽  
Second Order Model

In this paper, we report the safe removal of methyl orange (MO) dye from aqueous solution using chemical interaction of dye molecule with polyaniline/zinc oxide (PANI/ZnO) nanocomposite. PANI/ZnO nanocomposite has been prepared by in situ polymerization. PANI/ZnO nanocomposite was found to be the best promising candidate for adsorption of dyes due to more porosities compared to that of pure PANI. In the present investigation, PANI/ZnO nanocomposite was mixed in a solution of MO dye and used for adsorption process. Color removal was studied using UV-Vis spectroscopy and the spectra were recorded for specific time interval and validation of kinetic model has been applied. Absorbance of PANI/ZnO nanocomposite was found to be increased as compared to that of pure ZnO nanoparticles and pure PANI due to synergistic effect. Comparatively, the removal of dye was also found to be more by using PANI/ZnO nanocomposites. In order to evaluate kinetic mechanism the pseudo-first-order model, pseudo-second-order model and intraparticle diffusion models were verified by the linear equation analysis. Adsorption mechanism of pseudo-second-order model was systematically explained for removal of dye using PANI/ZnO nanocomposite. The results clearly demonstrated that the adsorption mechanism gives very novel and green method of removal of hazardous dyes from waste water.

The Adsorption of Copper Ions Using Cyclodextrin Cross-Linked Magnetic Chitosan Microsphere

2012 ◽  
Vol 209-211 ◽  
pp. 1929-1934
Author(s):  
Jin Song Wang ◽  
Hui Yan Mo ◽  
Qing Wei Guo ◽  
Zhen Cheng Xu
Keyword(s):  
Copper Ions ◽  
Influence Factors ◽  
Second Order ◽  
Kinetic Properties ◽  
Order Model ◽  
Magnetic Chitosan ◽  
Pseudo Second Order ◽  
Percentage Removal ◽  
C 50 ◽  
Second Order Model

In this experiment, cyclodextrin cross-linked magnetic chitosan（CCMC ）microsphere was prepared, glutaraldehyde was chosen as crosslinker, Cyclodextrin and chitosan was synthezied. To observe the influence factors of adsorption and obtain the optimum condition, the adsorption of copper ions by CCMC was explored under the different pH, initial concentration, temperature, reaction time and so on. The results indicated that CCMC had a high percentage removal of Cu2+, optimum adsorption was observed at pH 5.0. The adsorption rate of Cu2+ on CCMC was quick and the percentage removal reached beyond 90% after 30min, indicating that the adsorption equilibrium could be established within 30 min. The kinetic and thermodynamic properties of CCMC was also explored, under the concentration of Cu2+ of 50mg/L, 100mg/L, 150mg/L, 200mg/L, 300mg/L, 500mg/L on the temperature of 25°C, 35°C, 45°C, 50°C. Freunlich isothermal to Langmuir isothermal was used to fit the data of adsorption capacity of Cu2+, which showed that the adsorption process of Cu2+ was better described by Freunlich isothermal than Langmuir isothermal. As to the kinetic properties, the experimental data of Cu2+ adsorption onto CCMC fitted to the pseudo-first order model and pseudo-second order model, but the adsorption of Cu2+ onto CCMC conformed to pseudo-second order model, the R2 reached above 0.999.

Removal of Pb (II) from Aqueous Solution by Blast-Furnace Slags

2013 ◽  
Vol 726-731 ◽  
pp. 2736-2741
Author(s):  
Ming Da Liu ◽  
Ge Tian ◽  
Liang Jie Zhao ◽  
Yao Sheng Wang ◽  
Lei Guo ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Blast Furnace ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Sorption Process ◽  
Second Order ◽  
Order Model ◽  
Pseudo Second Order ◽  
Solution Kinetic ◽  
Second Order Model

Five blast-furnace slags were used as adsorbents to remove Pb (II) from aqueous solution. Kinetic studies showed that the sorption process was best described by pseudo-second-order model. Among Langmuir, Freundlich and Temkin isotherms, the Freundlich isotherm had a better fit with the simulation of the adsorption of Pb (II).

Removal of hazardous pharmaceutical dyes by adsorption onto papaya seeds

2014 ◽  
Vol 70 (1) ◽  
pp. 102-107 ◽  
Author(s):  
Caroline Trevisan Weber ◽  
Gabriela Carvalho Collazzo ◽  
Marcio Antonio Mazutti ◽  
Edson Luiz Foletto ◽  
Guilherme Luiz Dotto
Keyword(s):  
Aqueous Solutions ◽  
Second Order ◽  
Isotherm Models ◽  
Order Model ◽  
Application Range ◽  
First Order ◽  
Adsorption Capacities ◽  
Effects Of Ph ◽  
Pseudo Second Order ◽  
Papaya Seeds

Papaya (Carica papaya L.) seeds were used as adsorbent to remove toxic pharmaceutical dyes (tartrazine and amaranth) from aqueous solutions, in order to extend application range. The effects of pH, initial dye concentration, contact time and temperature were investigated. The kinetic data were evaluated by the pseudo first-order, pseudo second-order and Elovich models. The equilibrium was evaluated by the Langmuir, Freundlich and Temkin isotherm models. It was found that adsorption favored a pH of 2.5, temperature of 298 K and equilibrium was attained at 180–200 min. The adsorption kinetics followed the pseudo second-order model, and the equilibrium was well represented by the Langmuir model. The maximum adsorption capacities were 51.0 and 37.4 mg g−1 for tartrazine and amaranth, respectively. These results revealed that papaya seeds can be used as an alternative adsorbent to remove pharmaceutical dyes from aqueous solutions.

scholarly journals Simultaneous Removal of Lead and Nickel Ions from Aqueous Synthetic Solutions by Chitosan Coated Cobalt Ferrite

2017 ◽  
Vol 68 (1) ◽  
pp. 1-5
Author(s):  
Rodica Elena Patescu ◽  
Claudia Maria Simonescu ◽  
Cristian Onose ◽  
Teodor Laurentiu Busuioc ◽  
Daiana Elena Pasarica ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solutions ◽  
Sorption Capacity ◽  
Cobalt Ferrite ◽  
Second Order ◽  
Simultaneous Removal ◽  
Order Model ◽  
Diffusion Kinetic ◽  
Nickel Ions ◽  
Pseudo Second Order

This research study deals with lead and nickel simultaneous removal from aqueous solutions by the use of chitosan coated cobalt ferrite as adsorbent. Batch removal tests were performed in order to establish the main parameters that influence the sorption capacity, removal efficiency and the selectivity of this adsorbent. The values of sorption capacity for lead and nickel experimentally determined are: 56.23 mg/g and respectively 45.11 mg/g. Langmuir and Freundlich adsorption isotherms were used to interpret the sorption experimental data. The kinetic data were explored by pseudo-first order, pseudo-second order and intraparticle diffusion kinetic models. The experimental data were well fitted with the pseudo-second order model for both heavy metals. The main conclusion that can be drawn from this research is that this material can be successfully used for the removal of lead and nickel from binary aqueous solutions and wastewater.

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