Zr budgets for metamorphic reactions, and the formation of zircon from garnet breakdown

2001 ◽  
Vol 65 (6) ◽  
pp. 749-758 ◽  
Author(s):  
H. Degeling ◽  
S. Eggins ◽  
D. J. Ellis
Keyword(s):  
High Resolution ◽  
Nucleation And Growth ◽  
Metamorphic Rocks ◽  
High Grade ◽  
Metamorphic Zircon ◽  
Temperature Conditions ◽  
Zircon Growth ◽  
Insight Into ◽  
Cordierite Structure ◽  
Zircon Formation

AbstractThe construction of zirconium (Zr) budgets for metamorphic reactions in high-grade rocks provides new insight into zircon growth during metamorphism. In this study we target reactions involving garnet, as they enable zircon growth to be related to known pressure and temperature conditions. Two reactions involving the breakdown of Zr-bearing garnet from Rogaland, SW Norway have been investigated in detail, showing contrasting behaviour of Zr, with zircon formation being subject to the solubility of Zr in product phases. In the decompression reaction garnet + sillimanite + quartz → cordierite, Zr released during garnet breakdown cannot be incorporated into the cordierite structure, resulting in zircon nucleation and growth. In contrast, for the reaction garnet + biotite + sillimanite + quartz → osumilite + orthopyroxene + spinel + magnetite, no new zircon growth takes place, despite the garnet involved containing more than double the Zr concentration of the former reaction. In the latter case, all the Zr released by garnet breakdown can be detected in the product phases osumilite and orthopyroxene, thereby preventing growth of new metamorphic zircon. This study highlights the potential for high resolution geochronology in metamorphic rocks by relating zircon growth to specific metamorphic reactions.

The Pikwitonei Granulite Domain, Manitoba: a giant Neoarchean high-grade terrane in the northwest Superior ProvinceThis article is one of a series of papers published in this Special Issue on the theme of Geochronology in honour of Tom Krogh.N. Machado, T.E. Krogh, and W. Weber are deceased.

2011 ◽  
Vol 48 (2) ◽  
pp. 205-245 ◽  
Author(s):  
L. M. Heaman ◽  
Ch. O. Böhm ◽  
N. Machado ◽  
T. E. Krogh ◽  
W. Weber ◽  
...  
Keyword(s):  
Granulite Facies ◽  
Superior Province ◽  
High Grade ◽  
Metamorphic Zircon ◽  
Special Issue ◽  
Metamorphic History ◽  
Zircon Growth ◽  
The World ◽  
Northwestern Margin ◽  
History Of

The Pikwitonei Granulite Domain located at the northwestern margin of the Superior Province is one of the largest Neoarchean high-grade terranes in the world, with well-preserved granulite metamorphic assemblages preserved in a variety of lithologies, including enderbite, opdalite, charnockite, and mafic granulite. U–Pb geochronology has been attempted to unravel the protolith ages and metamorphic history of numerous lithologies at three main localities; Natawahunan Lake, Sipiwesk Lake, and Cauchon Lake. The U–Pb age results indicate that some of the layered enderbite gneisses are Mesoarchean (3.4–3.0 Ga) and the more massive enderbites are Neoarchean. The high-grade metamorphic history of the Pikwitonei Granulite Domain is complex and multistage with at least four episodes of metamorphic zircon growth identified: (1) 2716.1 ± 3.8 Ma, (2) 2694.6 ± 0.6 Ma, (3) 2679.6 ± 0.9 Ma, and (4) 2642.5 ± 0.9 Ma. Metamorphic zircon growth during episodes 2 and 3 are interpreted to be regional in extent, corresponding to M1 amphibolite- and M2 granulite-facies events, respectively, consistent with previous field observations. The youngest metamorphic episode at 2642.5 Ma is only recognized at southern Cauchon Lake, where it coincides with granite melt production and possible development of a major northeast-trending deformation zone. The timing and multistage metamorphic history recorded in the Pikwitonei Granulite Domain is similar to most Superior Province high-grade terranes and marks a fundamental break in Archean crustal evolution worldwide at the termination of prolific global Neoarchean greenstone belt formation.

Skeletal elements of crinoid echinoderms: High-resolution structural and microanalytical results

1983 ◽  
Vol 41 ◽  
pp. 194-195
Author(s):  
D. F. Blake ◽  
L. F. Allard ◽  
D. R. Peacor
Keyword(s):  
High Resolution ◽  
Marine Invertebrates ◽  
Sea Urchins ◽  
Structural Features ◽  
Sea Stars ◽  
High Resolution Tem ◽  
Relationship Of ◽  
The Relationship ◽  
Insight Into

Echinodermata is a phylum of marine invertebrates which has been extant since Cambrian time (c.a. 500 m.y. before the present). Modern examples of echinoderms include sea urchins, sea stars, and sea lilies (crinoids). The endoskeletons of echinoderms are composed of plates or ossicles (Fig. 1) which are with few exceptions, porous, single crystals of high-magnesian calcite. Despite their single crystal nature, fracture surfaces do not exhibit the near-perfect {10.4} cleavage characteristic of inorganic calcite. This paradoxical mix of biogenic and inorganic features has prompted much recent work on echinoderm skeletal crystallography. Furthermore, fossil echinoderm hard parts comprise a volumetrically significant portion of some marine limestones sequences. The ultrastructural and microchemical characterization of modern skeletal material should lend insight into: 1). The nature of the biogenic processes involved, for example, the relationship of Mg heterogeneity to morphological and structural features in modern echinoderm material, and 2). The nature of the diagenetic changes undergone by their ancient, fossilized counterparts. In this study, high resolution TEM (HRTEM), high voltage TEM (HVTEM), and STEM microanalysis are used to characterize tha ultrastructural and microchemical composition of skeletal elements of the modern crinoid Neocrinus blakei.

Nucleosome dynamics

2006 ◽  
Vol 73 ◽  
pp. 109-119 ◽  
Author(s):  
Chris Stockdale ◽  
Michael Bruno ◽  
Helder Ferreira ◽  
Elisa Garcia-Wilson ◽  
Nicola Wiechens ◽  
...  
Keyword(s):  
High Resolution ◽  
Chromatin Structure ◽  
Current Knowledge ◽  
Dynamic Properties ◽  
Structure And Dynamics ◽  
Nucleosome Dynamics ◽  
Sharp Focus ◽  
Recent Advances ◽  
Insight Into ◽  
Chromatin Structure And Dynamics

In the 30 years since the discovery of the nucleosome, our picture of it has come into sharp focus. The recent high-resolution structures have provided a wealth of insight into the function of the nucleosome, but they are inherently static. Our current knowledge of how nucleosomes can be reconfigured dynamically is at a much earlier stage. Here, recent advances in the understanding of chromatin structure and dynamics are highlighted. The ways in which different modes of nucleosome reconfiguration are likely to influence each other are discussed, and some of the factors likely to regulate the dynamic properties of nucleosomes are considered.

scholarly journals Rapid systemic surge of IL-33 after severe human trauma: a prospective observational study

2021 ◽  
Vol 27 (1) ◽  
Author(s):  
Olav Sundnes ◽  
William Ottestad ◽  
Camilla Schjalm ◽  
Peter Lundbäck ◽  
Lars la Cour Poulsen ◽  
...  
Keyword(s):  
High Resolution ◽  
Prospective Observational Study ◽  
Tissue Injury ◽  
Trauma Patients ◽  
Decoy Receptor ◽  
Interleukin 33 ◽  
Injured Patients ◽  
First Time ◽  
Kinetics Of ◽  
Insight Into

Abstract Background Alarmins are considered proximal mediators of the immune response after tissue injury. Understanding their biology could pave the way for development of new therapeutic targets and biomarkers in human disease, including multiple trauma. In this study we explored high-resolution concentration kinetics of the alarmin interleukin-33 (IL-33) early after human trauma. Methods Plasma samples were serially collected from 136 trauma patients immediately after hospital admission, 2, 4, 6, and 8 h thereafter, and every morning in the ICU. Levels of IL-33 and its decoy receptor sST2 were measured by immunoassays. Results We observed a rapid and transient surge of IL-33 in a subset of critically injured patients. These patients had more widespread tissue injuries and a greater degree of early coagulopathy. IL-33 half-life (t1/2) was 1.4 h (95% CI 1.2–1.6). sST2 displayed a distinctly different pattern with low initial levels but massive increase at later time points. Conclusions We describe for the first time early high-resolution IL-33 concentration kinetics in individual patients after trauma and correlate systemic IL-33 release to clinical data. These findings provide insight into a potentially important axis of danger signaling in humans.

scholarly journals BIMG-04. MAPPING HETEROGENEITY OF HIGH-GRADE GLIOMA METABOLISM USING HIGH RESOLUTION 7T MRSI

2021 ◽  
Vol 3 (Supplement_1) ◽  
pp. i1-i1
Author(s):  
Gilbert Hangel ◽  
Cornelius Cadrien ◽  
Philipp Lazen ◽  
Sukrit Sharma ◽  
Julia Furtner ◽  
...  
Keyword(s):  
High Resolution ◽  
Imaging Techniques ◽  
Basis Set ◽  
Metabolic Imaging ◽  
Tumor Segmentation ◽  
Low Grade ◽  
High Grade ◽  
Isotropic Resolution ◽  
Contrast Enhanced ◽  
Definition Of

Abstract OBJECTIVES Neurosurgical resection in gliomas depends on the precise preoperative definition of the tumor and its margins to realize a safe maximum resection that translates into a better patient outcome. New metabolic imaging techniques could improve this delineation as well as designate targets for biopsies. We validated the performance of our fast high-resolution whole-brain 3D-magnetic resonance spectroscopic imaging (MRSI) method at 7T in high-grade gliomas (HGGs) as first step to this regard. METHODS We measured 23 patients with HGGs at 7T with MRSI covering the whole cerebrum with 3.4mm isotropic resolution in 15 min. Quantification used a basis-set of 17 neurochemical components. They were evaluated for their reliability/quality and compared to neuroradiologically segmented tumor regions-of-interest (necrosis, contrast-enhanced, non-contrast-enhanced+edema, peritumoral) and histopathology (e.g., grade, IDH-status). RESULTS We found 18/23 measurements to be usable and ten neurochemicals quantified with acceptable quality. The most common denominators were increases of glutamine, glycine, and total choline as well as decreases of N-acetyl-aspartate and total creatine over most tumor regions. Other metabolites like taurine and serine showed mixed behavior. We further found that heterogeneity in the metabolic images often continued into the peritumoral region. While 2-hydroxy-glutarate could not be satisfyingly quantified, we found a tendency for a decrease of glutamate in IDH1-mutant HGGs. DISCUSSION Our findings corresponded well to clinical tumor segmentation but were more heterogeneous and often extended into the peritumoral region. Our results corresponded to previous knowledge, but with previously not feasible resolution. Apart from glycine/glutamine and their role in glioma progression, more research on the connection of glutamate and others to specific mutations is necessary. The addition of low-grade gliomas and statistical ROI analysis in a larger cohort will be the next important steps to define the benefits of our 7T MRSI approach for the definition of spatial metabolic tumor profiles.

High-resolution performance tests of nucleation and growth suppression by two kinetic hydrate inhibitors

2021 ◽  
pp. 116776
Author(s):  
Mark T.J. Barwood ◽  
Peter J. Metaxas ◽  
Vincent W.S. Lim ◽  
Michael L. Johns ◽  
Zachary M. Aman ◽  
...  
Keyword(s):  
High Resolution ◽  
Nucleation And Growth ◽  
Growth Suppression ◽  
Performance Tests
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