scholarly journals Influence of the reaction time on the quality (physical-chemical properties) of biofuels obtained through catalytic cracking of crude palm oil

2021 ◽  
Vol 17 (6) ◽  
Author(s):  
Silvio Alex Pereira Mota ◽  
Andréia Andrade Mancio ◽  
Jhuliana Silva Santanna ◽  
Valtiane de Jesus Pantoja Gama ◽  
Nélio Teixeira Machado
Keyword(s):  
Reaction Time ◽  
Specific Gravity ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Kinematic Viscosity ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Crude Palm Oil ◽  
Physical Chemical

The present paper investigated the influence of the reaction time on the quality (physical-chemical properties) of biofuels obtained by catalytic cracking of crude palm oil (CPO). The influence of the reaction time (10, 20, 30, 40, 50, and 60 min) on the quality of crude biofuels denominated organic liquid products (OLP) was investigated through experiments carried out in a cracking pilot plant with capacity of 143 L in the following operating conditions: 20 wt% sodium carbonate (Na2CO3) as catalyst, 450 °C, 1 atm and batch mode operation. The quality of the biofuels produced was certified through physical-chemical analyzes (acid value, saponification value, specific gravity, refractive index, kinematic viscosity, corrosiveness to copper, and flash point). The results show that the physical-chemical properties of OLP decrease as the reaction time increases, in such a way that, catalytic cracking process occurs efficiently in the interval of 10 to 20 min after its start, which can be finalized when it reaches 30 minutes of reaction. In addition, Na2CO3 was essential as a catalyst in the cracking reaction to reduce the physical-chemical properties of OLPs obtained at different times, allowing the specific gravity, kinematic viscosity and corrosivity to copper to be within or very close to the limits established for Diesel S10.

Thermal catalytic cracking of crude palm oil at pilot scale: Effect of the percentage of Na2CO3 on the quality of biofuels

2016 ◽  
Vol 91 ◽  
pp. 32-43 ◽  
Author(s):  
A.A. Mancio ◽  
K.M.B. da Costa ◽  
C.C. Ferreira ◽  
M.C. Santos ◽  
D.E.L. Lhamas ◽  
...  
Keyword(s):  
Scale Effect ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Pilot Scale ◽  
Crude Palm Oil

scholarly journals BIOFUEL PRODUCTION FROM PALM OLEIN BY CATALYTIC CRACKING PROCESS USING ZSM-5 CATALYST

2017 ◽  
Vol 6 (1) ◽  
pp. 50-55 ◽  
Author(s):  
Rondang Tambun ◽  
Oktris Novali Gusti ◽  
Muhammad Anshori Nasution ◽  
Rangga Pramana Saptawaldi
Keyword(s):  
Reaction Time ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Palm Olein ◽  
Liquid Product ◽  
Operating Conditions ◽  
Biofuel Production ◽  
Energy Reserves ◽  
Fossil Energy ◽  
Cracking Process

The depletion of fossil energy reserves raises the potential in the development of renewable fuels from vegetable oils. Indonesia is the largest palm oil producer in the world, where palm oil can be converted into biofuels such as biogasoline, kerosene and biodiesel. These biofuels are environmentally friendly and free of the content of nitrogen and sulfur through catalytic cracking process. In this research, palm olein is used as feedstock using catalytic cracking process. ZSM-5 is used as a catalyst, which has a surface area of 425 m2/g and Si/Al ratio of 50. Variables varied are the operating temperature of 375 oC - 450 C and reaction time of 60 minutes - 150 minutes. The result shows that the highest yield of liquid product is 84.82%. This yield is obtained at a temperature of 400 C and reaction time of 120 minutes. The yield of the liquid product in the operating conditions consisting of C6-C12 amounted to 19.47 %, C14-C16 amounted to 16.56 % and the C18-C28 amounted to 48.80 %.

DAYA SAING EKSPOR PRODUK CPO INDONESIA DAN POTENSI HILIRISASI DIOLAH MENJADI BIODIESEL

2020 ◽  
Vol 4 (2) ◽  
Author(s):  
Danar Agus Susanto
Keyword(s):  
Palm Oil ◽  
Comparative Advantage ◽  
Global Market ◽  
National Standard ◽  
Revealed Comparative Advantage ◽  
Crude Palm Oil ◽  
A Value ◽  
World Demand ◽  
Domestic Use

ABSTRACTIndonesia is the world's largest producer of crude palm oil (CPO). Even so, the trend of international trade in Indonesian CPO products has decreased in the last 10 years with a value of -10.19%. The decline in world demand for CPO can be dealt with by utilizing CPO as a biofuel for domestic use, like biodiesel. The purpose of this study is to determine the competitiveness of Indonesian CPO in global trade and determine the parameters of the quality requirements of CPO and biodiesel. The competitiveness analysis method uses the Revealed Comparative Advantage (RCA) method, while the analysis of the potential quality of CPO as a biofuel is carried out by analyzing the Indonesian National Standard (SNI). CPO trade in the global market is controlled by Indonesia with a market share of 50% and Malaysia 25.6%, with the declining trade trend in the last 10 years relatively (2010-2019) of -6.91%. The level of competitiveness of Indonesian CPO products in 2019 is very strong, but on average in the last 10 years, the level of competitiveness of Indonesian CPO is no better than that of Malaysia. Indonesia has SNI 01-2901-2006 and SNI 7182: 2015 as a determinant of the quality of CPO and biodiesel products developed in Indonesia so that the CPO and biodiesel produced fullfil sacurity and safety aspects when used by consumers.Keywords: crude palm oil (CPO), competitivenessv, quality, Indonesian National Standard (SNI) ABSTRAKIndonesia merupakan negara produsen minyak kelapa sawit mentah/ Crude Palm Oil (CPO) terbesar di dunia. Meskipun demikian, tren perdagangan internasional produk CPO Indonesia mengalami penurunan dalam sepuluh tahun terakhir dengan nilai -10,19%. Penurunan permintaan dunia terhadap CPO, dapat disiasati dengan memanfaatkan CPO sebagai bahan bakar nabati untuk keperluan dalam negeri sebagai biodiesel. Tujuan penelitian ini adalah mengetahui daya saing CPO Indonesia dalam perdagangan global dan mengetahui parameter persyaratan mutu CPO dan biodiesel. Metode analisis daya saing menggunakan metode Revealed Comparative Advantage (RCA), sedangkan analisis potensi kualitas CPO sebagai biofuel dilakukan dengan menganalisis Standar Nasional Indoensia (SNI). Perdagangan CPO dalam pasar global dikuasai oleh Indonesia dengan pangsa pasar 50% dan Malaysia 25,6%, dengan tren perdagangan relatif menurun dalam 10 tahun terakhir (2010-2019) sebesar -6,91%. Tingkat daya saing produk CPO Indonesia pada tahun 2019 sangat kuat, namun secara rata-rata dalam 10 tahun terakhir, tingkat daya saing CPO Indonesia tidak lebih baik dari Malaysia. Indonesia memiliki SNI 01-2901-2006 dan SNI 7182:2015 sebagai penentu kualitas produk CPO dan biodiesel yang dikembangkan di Indonesia, sehingga CPO dan biodiesel yang dihasilkan memenuhi aspek keamanan dan keselamatan ketika digunakan oleh konsumen.Kata kunci: crude palm oil (CPO), daya saing, kualitas, Standar Nasional Indonesia (SNI)

scholarly journals Production and Characterization of Green gasoline Obtained by Thermal Catalytic Cracking of Crude Palm Oil (Elaeis guineensis, Jacq.) in a Pilot Plant

2017 ◽  
Vol 13 (01) ◽  
Author(s):  
Silvio Alex Pereira Mota ◽  
Andréia De Andrade Mancio ◽  
Luiz Eduardo Pizarro Borges ◽  
Nélio Teixeira Machado
Keyword(s):  
Palm Oil ◽  
Catalytic Cracking ◽  
Pilot Plant ◽  
Elaeis Guineensis ◽  
Crude Palm Oil ◽  
Elaeis Guineensis Jacq

scholarly journals Engineering Process Of Deodorization To Improve Product Quality Of Red Palm Oil With Rich Of Carotene

2018 ◽  
Vol 1 (1) ◽  
pp. 20-26
Author(s):  
Mursalin Mursalin
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Palm Oil ◽  
Chemical Properties ◽  
Absolute Temperature ◽  
Odor Intensity ◽  
Process Duration ◽  
Red Palm Oil ◽  
Physico Chemical

Efforts to develop the production technology of high quality red palm-oil (RPO) in order to provide source of food ingredient that naturally rich of nutrients, become urgents regarding the need of such products drastically increased recently. Application of deodorization technology by temperature, time, and deodorizer pressure combinations (engineering of deodorization process) are studied and evaluated to obtain good quality of RPO. Crude palm oil (CPO) used in this research were supplied by PT. Salim Ivomas (Bimoli) Jakarta. The equipments used were degumming and neutralization unit, deodorization unit and other equipment units to analize the oil physico-chemical properties. The research consisted of 5 stages as the following: characterising CPO physico-chemical properties, conducting chemically degumming and deacidification, process enginering of deodorization, characterizing of physico-chemical properties and organoleptic of RPO resulted, and analyzing data for product resulted from process engineering applied. Deodorization with the range of temperature and process duration of 135–145 oC (408–418 K) and 1–4 hours have led to carotene retention decreasing (%) following the equation “Carotene Retention (%) = -764 x ln(absolute temperature) + 4693” and process duration with the equation “Carotene Retention (%) = -7.81 x ln(process duration) + 91.02”; and also resulted odor intensity with the equation “Odor Intensity = 0.08 x (squared absolute temperature) – 66.88 x (absolute temperature) + 13823” and duration process with the equation “Odor Intensity = 0.315 x (squared process duration) – 1.52 x (process duration) + 5.268”. Effective deodorization to produce RPO with the content of free fatty acid and peroxide value that met the requirements of Indonesian National Standard (SNI) quality of carotene content above 400 ppm and odor scale below 3.3, were the combination of temperature (T) of 141.34 oC, heat process duration (t) of 2.35 hours and vacuum pressure of (P) of 20 mmHg. The resulted RPO contained free fatty acid and peroxide value of 0.11% dan 0.12 meq/kg oil respectively, total carotene of 444.09 ppm and odor value of 3.21  

scholarly journals The Effect of Coating as Antifungi of Harumanis Mango's Post Harvest Losses

2020 ◽  
Vol 1 (2) ◽  
pp. 7-16
Author(s):  
Winda Amilia ◽  
Andrew Setiawan Rusdianto ◽  
Arma Dwi Novemi
Keyword(s):  
Corn Starch ◽  
Chemical Properties ◽  
Inhibition Zone ◽  
Post Harvest ◽  
Physical Chemical ◽  
Chemical Content ◽  
Total Dissolved Solid ◽  
Tobacco Extract ◽  
Physical And Chemical

The amount of mango production in Indonesia is quite high, but the quality of postharvest mangoes is still quite low. The quality of the fruit will decline due to contamination; one of the contaminants is fungi. The way to reduce the damage of postharvest products is by coating applications. The purpose of this study was to study the physical, chemical and antifungal activities of harumanis mangoes’s quality which had been given coating during storage that could cause postharvest losses of harumanis mangoes. There are 3 treatments, each of them are respectively the provision of corn based coating  6% tobacco extract, 8% tobacco extract and 10% tobacco extract. The physical and chemical properties of the antifungal coating of tobacco extract made from corn coating for post-harvest damage on harumanis mangoes were obtained by weight loss, texture, colour, respiration rate, vitamin C and total dissolved solid. Preventing coating can prevent damage after harvest and protect the harumanis mango; therefore the quality of the mangoes can be maintained. The best results from the priority with the largest diameter inhibition zone were given corn starch 10% tobacco extract. Then the higher the concentration of extract used, the greater the diameter of the inhibition zone obtained. Based on all the tests performed (physical, chemical, and antifungal) the best treatment from the treatment was obtained that consisted of mangoes with antifungal layers of corn starch 10% tobacco extract. Because the P3 obtained the best results in maintaining physical, chemical content and fungi for 15 days.

scholarly journals The Effect of the Operating Conditions on the Apparent Viscosity of Crude Palm Oil During Oil Clarification

1970 ◽  
Vol 5 (1) ◽  
Author(s):  
Sulaiman Al-Zuhair, Mirghani I. Ahmed and Yousif A. Abakr
Keyword(s):  
Shear Rate ◽  
Boundary Conditions ◽  
Palm Oil ◽  
Apparent Viscosity ◽  
Operating Conditions ◽  
Effect Of Temperature ◽  
Optimum Operating ◽  
Crude Palm Oil ◽  
Different Boundary Conditions ◽  
Rotary Viscometer

This paper discusses the apparent viscosity of crude palm oil, using rotary viscometer, under different boundary conditions. It was experimentally shown that the apparent viscosity of palm oil drops with increasing of the shear rate and the temperature.  However, the effect of temperature on the viscosity tends to fade at temperatures beyond 80 oC.  A correlation between the apparent viscosity of crude palm oil and the operating conditions was developed. This correlation can be used in design of crude palm oil settlers and in determining the optimum operating conditions.Key Words:  Crude palm oil, apparent viscosity, shear rate, modelling, separation 

scholarly journals Esterification of Crude Palm Oil Using H2SO4 and Transesterification Using CaO Catalyst Derived from Anadara granosa

2017 ◽  
Vol 17 (2) ◽  
pp. 309 ◽  
Author(s):  
Nurhayati Nurhayati ◽  
Sofia Anita ◽  
Tengku Ariful Amri ◽  
Amilia Linggawati
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Palm Oil ◽  
Reaction Times ◽  
Crude Palm Oil ◽  
Process Step ◽  
Molar Ratios ◽  
One Step ◽  
Esterification Reactions ◽  
Anadara Granosa

In this study biodiesel was produced from crude palm oil through two-step processes, namely esterification reactions using homogeneous H2SO4 catalyst and transesterification using the heterogeneous base CaO catalyst derived from Anadara granosa shell. Several parameters affecting to the yields of biodiesel were investigated including the amount of the catalysts, the molar ratios of oil to methanol, reaction times and reaction temperatures. The CaO catalyst was prepared by calcining the A. granosa shells at the temperatures of 800 and 900 °C for 10 h. The as-synthesized biodiesel was analyzed using GC and its characteristics were determined and the results were compared to Standard National for Biodiesel (SNI 04-7183-2006). The optimum condition for the esterification process (step 1) was as follows: reaction temperature of 65 °C, reaction time of 3 h and mol ratio of oil to methanol 1:24. For the transesterification (step 2) the optimum conditions were attained using the catalyst weight 3%, reaction temperature of 60 °C, reaction time of 3 h, mole ratio of oil/methanol 1:6 and the catalyst calcination time of 10 h with the conversion of 87.17%. This biodiesel yield by the two-step processes was higher (2.7%) than that using only one-step process (transesterification).

scholarly journals Process Analysis of PMMA Dental Resins Scraps Depolimerization: Optimization of Reaction Time and Temperature

2021 ◽  
Author(s):  
Paulo Bisi dos Santos Jr. ◽  
Haroldo Jorge da Silva Ribeiro ◽  
Armando Costa Ferreira ◽  
Caio Campos Ferreira ◽  
Lucas Pinto Bernar ◽  
...  
Keyword(s):  
Refractive Index ◽  
Reaction Time ◽  
Liquid Phase ◽  
Kinematic Viscosity ◽  
Process Analysis ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Dental Resins ◽  
Liquid Products ◽  
The Cross

In this work, the cross-linked PMMA-based dental resins scraps were submitted to pyrolysis to recover MMA (Methylmethacrylate). The thermal degradation of cross-linked PMMA-based dental resins scraps was analyzed by TG/DTG to guide the operating conditions in pilot scale. The pyrolysis experiments carried out in a reactor of 143L, at 345, 405, and 420°C, 1.0 atmosphere. The reaction liquid products obtained at 345°C, physicochemical characterized for density, kinematic viscosity, and refractive index. The chemical composition of liquid products obtained at 345°C, 30, 40, 50, 60, 70, 80, and 110 minutes, at 405°C, 50, 70, and 130 minutes, and at 420°C, 40, 50, 80, 100, 110, and 130 minutes determined by GC-MS. The experiments show that liquid phase yields were 55.50%, 48.73%, and 48.20% (wt.), at 345, 405, and 420°C, respectively, showing a smooth sigmoid behavior, decreasing with increasing temperature, while that of gas phase were 31.69%, 36.60%, and 40.13% (wt.), respectively, increasing with temperature. The liquid products density, kinematic viscosity, and refractive index obtained at 30, 40, 50, 60, 70, 80, and 110 minutes, varied between 0.9227 and 0.9380 g/mL, 0.566 and 0.588 mm2/s, and 1.401 and 1.414, respectively, showing percentage deviations between 0.74 and 2.36%, 7.40 and 10.86%, and 0.00 and 0.92%, respectively, compared to standard values for density, kinematic viscosity, and refractive index of pure MMA at 20 °C. The GC-MS identified in the reaction liquid products at 345, 405, and 420°C, 1.0 atm, esters of carboxylic acids, alcohols, ketones, and aromatics, showing concentrations of MMA between 83.454 and 98.975% (area.). For all the depolymerization experiments, the concentrations of MMA in the liquid phase, between 30 and 80 minutes, reach purities above 98% (area.), decreasing drastically with increasing reaction time after 100 minutes, thus making it possible to depolymerize the cross-linked PMMA-based dental resins scraps by pyrolysis to recover MMA. The optimum operating conditions to achieve high MMA concentrations, as well as elevated yields of liquid reaction products were 345 °C and 80 minutes.

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