scholarly journals Natural and human-induced factors controlling the phreatic groundwater geochemistry of the Longgang River basin, South China

2020 ◽  
Vol 12 (1) ◽  
pp. 203-219
Author(s):  
Wei Li ◽  
Xiaohong Chen ◽  
Linshen Xie ◽  
Gong Cheng ◽  
Zhao Liu ◽  
...  
Keyword(s):  
Groundwater Quality ◽  
Chemical Evolution ◽  
South China ◽  
Major Ions ◽  
Negative Impact ◽  
Flow Direction ◽  
Anthropogenic Activities ◽  
Ionic Composition ◽  
Primary Source ◽  
Ammonia Concentration

AbstractGroundwater chemical evolution is the key to ensuring the sustainability of local society and economy development. In this study, four river sections and 59 groundwater wells are investigated in the Longgang River (L.R.) basin in South China. Comprehensive hydrochemical analysis methods are adopted to determine the dominant factors controlling the chemical evolution of the local phreatic groundwater and the potential impact of human activities on groundwater quality. The results indicate that the ionic composition of the local phreatic groundwater is dominated by Ca2+ (0.9–144.0 mg/L), HCO3− (4.4–280.0 mg/L), and SO42− (1.0–199.0 mg/L). Ca–Mg–HCO3, Ca–Na–HCO3, and Na–Ca–HCO3 are the major groundwater hydrochemical facies. Water–rock interactions, such as the dissolution of calcite and dolomite, are the primary source of the major ions in the local groundwater. Cation-exchange reaction has its effects on the contents of Ca2+, Mg2+, and Na+. Ammonia concentration of the sampling sections in the L.R. increases from 0.03 to 2.01 mg/L along the flow direction. Groundwater nitrate in the regions of the farmland is attributed to the lowest level of the groundwater quality standards of China, while the same test results are obtained for heavy metals in the industrial park and landfill, suggesting a negative impact of the anthropogenic activities on the local phreatic groundwater quality.

scholarly journals Study on Seasonal Variations and Spatial Distribution of Major Ions with Focus on Paper Industry Effluents - A Case study of Sirpur Paper Mills (SPM) Telangana

2020 ◽  
Vol 15 (3) ◽  
pp. 406-429
Author(s):  
Harish Kumar Agre
Keyword(s):  
Spatial Distribution ◽  
Groundwater Quality ◽  
Seasonal Variations ◽  
Major Ions ◽  
Negative Impact ◽  
Paper Industry ◽  
Paper Mill ◽  
Paper Mills ◽  
Paper Mill Effluent ◽  
Post Monsoon

The present paper examines the seasonal variations in groundwater quality (Pre-monsoon & Post- Monsoon) with an emphasis on paper industry effluents from the Sirpur-Kaghaznagar area. Spatial distribution of samples from 24 sites collected during pre and post-monsoon using surfer software gives an insight of important parameters such as pH, EC, TDS, BOD, COD, DO, Ca+, Mg2+, Na+, F, Cl-, NO3,- SO42- and TH to be significantly elevated beyond the acceptable and permissible levels prescribed by BIS limits. Also, the Physico-chemical analysis of paper mill effluent collected from 12 different sites revealed that parameters such as pH, EC, TDS, BOD, COD, Alkalinity, SO42-, Cu, and Fe were beyond the BIS permissible limits for effluent discharge and designated a profound negative impact on groundwater quality and lead us to conclude that the overall quality is deteriorated due to the influx of paper industry effluents.

Physicochemical processes in the main river of Mexico using geochemical models

2021 ◽  
Author(s):  
Selene Olea-Olea ◽  
Javier Alcocer ◽  
Luis A. Oseguera
Keyword(s):  
Water Quality ◽  
North America ◽  
Ion Exchange ◽  
Major Ions ◽  
Anthropogenic Activities ◽  
Ionic Composition ◽  
Geological Environment ◽  
Physicochemical Processes ◽  
Geochemical Models ◽  
Evaporation Models

<p>The Usumacinta River is the most extensive tropical fluvial system in North America and the principal river in Mexico and the tenth of North America. Diverse and growing anthropogenic activities (land-use change, agriculture, and urban development) modify water quality. However, to separate natural (e.g., geology) from anthropic factors responsible for this system characteristics, we looked to evaluate geological environment’s influence on the river’s water quality.</p><p>Water and sediment samples were collected along the mainstem and principal tributaries in the rainy and the dry seasons (2017-2018). We analyzed the major ionic composition in water and metals in sediments. We applied inverse and evaporation models (PHREEQC code) to reveal the physicochemical reactions taking place in the river.</p><p>The inverse models in the middle basin in both seasons showed the influence of ion-exchange between Ca and K, dissolution of dolomite, and precipitation of kaolinite and calcite, whereas in the lower basin in the rainy season suggested the chemical composition is controlled by ion-exchange among Ca, Na and K, dissolution of dolomite, halite, plagioclase, and feldspar and precipitation of calcite, gypsum, and kaolinite. In addition, the evaporation models in the dry season in the lower basin demonstrate the dominant process taking place is the precipitation of calcite, dolomite, gypsum, halite, and kaolinite.</p><p>We found that Cr and Ni are the most abundant metals in the sediments along the river. The geological environment in the basin suggests that the volcanic rocks with felsic minerals could be the source of Ni, whereas sedimentary rocks such as shales and clays could be the source of Cr.</p><p>The use of geochemical models in river systems is of great relevance to understanding the presence of major ions concentrations in water and their seasonal and spatial variations, as well the physicochemical processes (i.e., ion-exchange, dissolution, precipitation, redox reactions, and so on) that allow associating or discard the presence of metals.</p>

scholarly journals Integration of multivariate statistics and water quality indices to evaluate groundwater quality and its suitability in middle Gangetic floodplain, Bihar

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Ajay Govind Bhatt ◽  
Anand Kumar ◽  
Priya Ranjan Trivedi
Keyword(s):  
Water Quality ◽  
Groundwater Quality ◽  
Major Ions ◽  
Anthropogenic Activities ◽  
Hierarchical Cluster ◽  
Quality Parameters ◽  
Health Concern ◽  
Water Type ◽  
Groundwater Samples ◽  
Group 2

AbstractThis study is conducted along the middle Gangetic floodplain, to investigate the hydrogeochemical characteristics and suitability of groundwater for irrigation and human consumptions. Altogether 65 groundwater samples were collected and analyzed for major ions and water quality parameters. pH of all the samples except 1 is found > 7, which suggests alkaline aquifer condition. Groundwater samples predominately belong to Ca-Mg-HCO3 water type followed by Na-HCO3, Mg-HCO3 and Mg-SO4 water types. Hierarchical cluster analysis (HCA) combines groundwater into two distinct groups, Group 1 is found as less mineralized as the average EC value is found 625.3 μS/cm, while it is found 1375 μS/cm for Group 2. The results of correlation analysis and PCA suggest influence of natural and anthropogenic activities on groundwater. PCA extracts four major PCs which describes 71.7% of total variance. PC1 indicates influence of both lithogenic and anthropogenic activities on groundwater quality. PC2 and PC3 infer natural factors, and PC4 suggests influence of anthropogenic activities on groundwater. Exceeding concentration of F−, Fe and Mn above WHO guidelines are found as major public health concern. WQI of all except 4 groundwater samples suggests excellent to good water quality; however, 23% of the samples are not suitable based on WPI values. Irrigation indices suggest that groundwater is mostly suitable for irrigation; however, 10.7%, 12.3% and 3% samples for RSBC, MAR and KR, respectively, exceed the recommended limits and are unsuitable for irrigation. A proper management strategy and quality assurance is recommended before groundwater consumption and use in the study area.

scholarly journals Water Quality and Hydrogeochemical Characteristics of Some Karst Water Sources in Apuseni Mountains, Romania

Water ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 857
Author(s):  
Maria-Alexandra Hoaghia ◽  
Ana Moldovan ◽  
Eniko Kovacs ◽  
Ionut Cornel Mirea ◽  
Marius Kenesz ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Chemistry ◽  
Major Ions ◽  
Anthropogenic Activities ◽  
Water Sources ◽  
Main Process ◽  
Karst Water ◽  
Rock Interaction ◽  
Apuseni Mountains ◽  
Karst Waters

Human activities and natural factors determine the hydrogeochemical characteristics of karst groundwaters and their use as drinking water. This study assesses the hydrogeochemical characteristics of 14 karst water sources in the Apuseni Mountains (NW Romania) and their potential use as drinking water sources. As shown by the Durov and by the Piper diagrams, the chemical composition of the waters is typical of karst waters as it is dominated by HCO3− and Ca2+, having a circumneutral to alkaline pH and total dissolved solids ranging between 131 and 1092 mg L−1. The relation between the major ions revealed that dissolution is the main process contributing to the water chemistry. Limestone and dolostone are the main Ca and Mg sources, while halite is the main Na and Cl source. The Gibbs diagram confirmed the rock dominance of the water chemistry. The groundwater quality index (GWQI) showed that the waters are of excellent quality, except for two waters that displayed medium and good quality status. The quality of the studied karst waters is influenced by the geological characteristics, mainly by the water–rock interaction and, to a more limited extent, by anthropogenic activities. The investigated karst waters could be exploited as drinking water resources in the study area. The results of the present study highlight the importance of karst waters in the context of good-quality water shortage but also the vulnerability of this resource to anthropogenic influences.

scholarly journals Depth–Sequential Investigation of Major Ions, δ18o, δ2h and δ13C in Fractured Aquifers of the St. Lawrence Lowlands (Quebec, Canada) Using Passive Samplers

Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1806
Author(s):  
Guillaume Meyzonnat ◽  
Florent Barbecot ◽  
José Corcho Alvarado ◽  
Daniele Luigi Pinti ◽  
Jean-Marc Lauzon ◽  
...  
Keyword(s):  
Stable Isotopes ◽  
Major Ions ◽  
Anthropogenic Activities ◽  
Carbon Sources ◽  
Passive Samplers ◽  
Flow Paths ◽  
Aquifer Heterogeneity ◽  
Fractured Aquifers ◽  
Fractured Carbonate ◽  
Observation Wells

General and isotopic geochemistry of groundwater is an essential tool to decipher hydrogeological contexts and flow paths. Different hydrogeochemical patterns may result from the inherent physical aquifer heterogeneity, which may go unnoticed without detailed investigations gathered from multilevel or multiple observation wells. An alternative to overcome the frequent unavailability of multiple wellbores at sites is to perform a detailed investigation on the single wellbore available. In this perspective, the aim of this study is to use passive samplers to sequentially collect groundwater at depths in long–screened wellbores. Such investigation is carried out for major ions and stable isotopes compositions (δ2H, δ18O, δ13C) at ten sites in the context of fractured carbonate aquifers of the St. Lawrence Lowlands (Quebec, Canada). The information gathered from the calco–carbonic system, major ions and stable isotopes report poorly stratified and evolved groundwater bodies. Contribution of water impacted by anthropogenic activities, such as road salts pollution and carbon sources from C4 vegetation, when they occur, are even observed at the greatest depths. Such observations suggest quick flow paths and efficient mixing conditions, which leads to significant contributions of contemporary groundwater bodies in the fractured aquifers investigated down to depths of about 100 m. Although physical aquifer investigation reported few and heterogeneously distributed fractures per wellbore, hydrogeochemical findings point to at overall well interconnected fracture networks in the aquifer and high vulnerability of groundwater, even at significant depths.

scholarly journals Evaluation of Groundwater Quality in the Vicinity of Khurrianwala Industrial Zone, Pakistan

Water ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1321 ◽  
Author(s):  
Muhammad Aleem ◽  
Cao Shun ◽  
Chao Li ◽  
Arslan Aslam ◽  
Wu Yang ◽  
...  
Keyword(s):  
Water Quality ◽  
Groundwater Quality ◽  
Anthropogenic Activities ◽  
World Health ◽  
Total Hardness ◽  
Industrial Zone ◽  
High Concentration ◽  
Physico Chemical ◽  
Health Organization ◽  
National Environmental

The industrial augmentation and unguided anthropogenic activities contaminate water sources in most parts of the world especially in developing countries like Pakistan. High concentration of pollutants in groundwater affects human, soil, and crop health badly. The present study was conducted to investigate groundwater quality for drinking and irrigation purposes in an industrial zone of Pakistan. A GIS tool was used to investigate the spatial distribution of different physico-chemical parameters. In this study, the average results exceeding World Health Organization (WHO) and National Environmental Quality Standards (NEQS) were found for pH 7.84, total dissolved solids (TDS) 1492 mg/L, phosphate 0.51 mg/L, dissolved oxygen (DO) 9.92% saturation, F-coli 6.48 colonies/100 mL, Na+ 366 mg/L, HCO3− 771 mg/L, sulfate 251 mg/L, chlorides 427 mg/L, total hardness (as CaCO3) 292 mg/L, electrical conductivity (EC) 2408 μS/cm, iron (Fe) 0.48 mg/L, chrome (Cr) 0.50 mg/L, arsenic (As) 0.04 mg/L, total phosphorus (TP) 0.17 mg/L, sodium adsorption ratio (SAR) 9.76 (in meq/L), residual sodium carbonate (RSC) 9.28 meq/L, % ion balance 14.4 (in meq/L), percentage sodium ion (% Na+) concentration 58.9 meq/L, and water quality index (WQI) 69.0. The trend of cations and anions were (in meq/L) Na > Mg > Ca > K and HCO3 > Cl > CO3 > SO4 respectively. Although the results of the present study showed poor conditions of the groundwater for drinking as WQI but and irrigation purposes as SAR, it needs to improve some more conditions for the provision of safe drinking water and irrigation water quality.

Electrical Conductivity of Agricultural Drainage Water in Iowa

2017 ◽  
Vol 33 (3) ◽  
pp. 369-378 ◽  
Author(s):  
Brett A Zimmerman ◽  
Amy L Kaleita
Keyword(s):  
Electrical Conductivity ◽  
Environmental Conditions ◽  
Major Ions ◽  
Ionic Composition ◽  
Field Investigation ◽  
Drainage Water ◽  
Specific Electrical Conductivity ◽  
Agricultural Drainage ◽  
Bulk Electrical Conductivity ◽  
Drainage Waters

Abstract. Assessing the effectiveness of management strategies to reduce agricultural nutrient efflux is hampered by the lack of affordable, continuous monitoring systems. Generalized water quality monitoring is possible using electrical conductivity. However environmental conditions can influence the ionic ratios, resulting in misinterpretations of established electrical conductivity and ionic composition relationships. Here we characterize specific electrical conductivity (k25) of agricultural drainage waters to define these environmental conditions and dissolved constituents that contribute to k25. A field investigation revealed that the magnitude of measured k25 varied from 370 to 760 µS cm-1. Statistical analysis indicated that variability in k25 was not correlated with drainage water pH, temperature, nor flow rate. While k25 was not significantly different among drainage waters from growing and post-growing season, significant results were observed for different cropping systems. Soybean plots in rotation with corn had significantly lower conductivities than those of corn plots in rotation with soybeans, continuous corn plots, and prairie plots. In addition to evaluating k25 variability, regression analysis was used to estimate the concentration of major ions in solution from measured k25. Regression results indicated that HCO3-, Ca2+, NO3-, Mg2+, Cl-, Na2+, SO42- were the major drainage constituents contributing to the bulk electrical conductivity. Calculated ionic molal conductivities of these analytes suggests that HCO3-, Ca2+, NO3-, and Mg2+ account for approximately 97% of the bulk electrical conductivity. Keywords: Electrical conductivity, Salinity, Subsurface drainage, Total dissolved solids.

Application of a GIS-based DRASTIC model and groundwater quality index method for evaluation of groundwater vulnerability: a case study, Sefid-Dasht

2015 ◽  
Vol 15 (4) ◽  
pp. 784-792 ◽  
Author(s):  
Nastaran Khodabakhshi ◽  
Gholamreza Asadollahfardi ◽  
Nima Heidarzadeh
Keyword(s):  
Groundwater Quality ◽  
Quality Index ◽  
Major Ions ◽  
Groundwater Vulnerability ◽  
Vulnerability Index ◽  
Aquifer Vulnerability ◽  
Index Method ◽  
Drastic Model ◽  
Groundwater Quality Index ◽  
The North

Pollution control and removal of pollutants from groundwater are a challenging and expensive task. The aims of this paper are to determine the aquifer vulnerability of Sefid-Dasht, in Chaharmahal and Bakhtiari province, Iran, using the DRASTIC model. In addition, the groundwater quality index (GQI) technique was applied to assess the groundwater quality and study the spatial variability of major ion concentrations using a geographic information system (GIS). The vulnerability index ranged from 65 to 132, classified into two classes: low and moderate vulnerability. In the southern part of the aquifer, the vulnerability was moderate. Furthermore, the results indicate that the magnitude of the GQI index varies from 92% to 95%. This means the water has a suitable quality. However, from the north to the south and southwest of the aquifer, the water quality has been deteriorating, and the highest concentration of major ions was found in the southwest of the Sefid-Dasht aquifer. A comparison of the vulnerability maps with the GQI index map indicated a poor relation between them. In the DRASTIC method, movement of groundwater is not considered and may be the reason for such inconsistency. However, the movement of groundwater can transport contaminants.

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