Technologies for the Recycling of Polymer Waste at Coking Plants

2021 ◽  
Vol 25 (1) ◽  
pp. 9-13
Author(s):  
R.R. Gimaletdinov ◽  
M.R. Usmanov ◽  
S.F. Valeev ◽  
F.R. Zainullov ◽  
A.V. Sulimov
Keyword(s):  
Thermal Destruction ◽  
Polymeric Materials ◽  
Raw Material ◽  
Household Waste ◽  
Quantitative Composition ◽  
Polymer Waste ◽  
Polymeric Waste ◽  
Inorganic Components ◽  
Comprehensive Study

The results of a comprehensive study of the process of thermal destruction of household waste and industrial polymeric materials in a mixture with petroleum feedstock at a pilot coking unit are presented. A mixture containing polyethylene, polypropylene, polystyrene and polyethylene terephthalate was used as household polymeric waste. Industrial waste was represented by a mixture of polyethylene and polypropylene. The qualitative and quantitative composition of the resulting products was investigated. It is shown that the involvement of polymer waste in an amount of up to 8% by weight in the raw material of the coking plant will make it possible to efficiently process polymer waste without changing the technological regime and quality of the products obtained. It has been established that the impurities of inorganic components present in the polymer raw material do not affect the coking process.

scholarly journals Use and disposal of disposable plastic packaging by retail chains and catering companies

2020 ◽  
Vol 5 (4) ◽  
pp. 356-363
Author(s):  
Elena Yu. Panasenkova ◽  
◽  
Olga E. Gruzdeva ◽  
Maria G. Kuznetsova ◽  
◽  
...  
Keyword(s):  
Waste Recycling ◽  
Plastic Waste ◽  
Raw Material ◽  
Polymer Waste ◽  
Plastic Packaging ◽  
Legal Documents ◽  
Effective System ◽  
Retail Chains ◽  
Polymeric Waste ◽  
Disposable Plastic

The increased use of disposable plastic consumer packaging, especially in the sanitary and epidemiological conditions of COVID-19, makes it necessary to dispose of the resulting waste. The problem is aggravated by the weak processing of waste, which is stored and not destroyed in nature. In this regard, the purpose of the article is to analyze the problems caused by the consumption and disposal of plastic disposable plastic packaging by retail chains and public catering companies. A brief comparative analysis of the composition and quantities of the plastic waste was carried out. The legal documents governing the waste management in Russia and abroad were studied. The Russian waste recycling market was compared with the foreign ones. Data on polymeric waste(composition, quantity, share in the total mass of waste, cost, and possibility of using as a secondary raw material) were studied. The lack of an effective system for collecting polymer waste and its utilization in Russia was emphasized and compared with Asian, European and American countries. In these countries, there are regulatory documents governing the collection and recycling of plastic products; the production itself is economically attractive. Recommendations aimed to encourage manufacturers to recycle waste were given; options for solving the problem of recycling plastic waste on a legislative, economic and managerial basis were offered.

scholarly journals Study of performance properties of an asphalt modified with polyethylen

2018 ◽  
pp. 24-30
Author(s):  
Safura Satayeva ◽  
Aibarsha Аbdrakhmanova ◽  
Anar Kurmangaliyeva
Keyword(s):  
Mechanical Properties ◽  
Physical And Mechanical Properties ◽  
Polymeric Materials ◽  
Softening Temperature ◽  
Oil Refining ◽  
Rational Approach ◽  
Road Asphalt ◽  
Polymer Waste ◽  
Needle Penetration

The quality of road bitumen is one of the most important factors determining the service life and quality of road asphalt concrete pavements. Current trends in oil refining and, in particular, increasingly deeper processing of crude oil, require consideration of the characteristics of its chemical composition and structure for the production of road bitumen, and, accordingly, the physical and mechanical properties of the bitumen produced. In this study the BOR 70/100 oil asphalt from the Aktau Bitumen Factory LLP “CaspiBitum” was considered. An asphalt was modified with polymer waste to upgrade operating properties. The I-40 industrial oil was used as a softener. Indicators like penetration, extensibility (ductility), brittleness temperature and softening temperature of bitumen were explored in this study. It was shown, that physical-mechanical properties of bitumen increased after modification: needle penetration depth decreased, extensibility decreased, softening temperature increased. Also, the influence of polymers on the structure of bitumen and the effect of their action in the composition were examined. Structure of polymer waste in Republic of Kazakhstan was analyzed. It was proved, that the usage of the recycled polyethylene as a modifier is a rational approach, and it lets to recycle stocks of secondary polymeric materials. Also problems of improving the properties of polymer-bitumen binder and ecology solved.

Criteria for the Selection of Synthetic Polymeric Waste as a Raw Material for Producing Carbon Sorbents with Predetermined Properties

2020 ◽  
Vol 24 (10) ◽  
pp. 13-19
Author(s):  
Ya.I. Vaisman ◽  
I.S. Glushankova ◽  
L.V. Rudakova ◽  
A.A. Surkov ◽  
A.S. Atanova
Keyword(s):  
Raw Materials ◽  
Synthetic Polymer ◽  
Raw Material ◽  
Technological Parameters ◽  
Polymer Waste ◽  
Factors Affecting ◽  
Carbon Sorbents ◽  
Degree Of Aromaticity ◽  
Polymeric Waste ◽  
Selection Of

The results of studies on the thermal processing of synthetic multi-tonnage polymeric waste (polypropylene, polycarbonate, textolite, PET, organoplastics and tire rubber) with the production of carbon sorbents for technological and environmental purposes are presented. The influence of the nature of the activating agent and the conditions of the process with the production of sorbents with predetermined properties was studied. Analysis of the research results allowed us to establish that the main factors affecting the yield of carbonizate and the formation of a porous structure of carbon sorbents from synthetic polymer waste are the degree of aromaticity and the location of benzene rings in the polymer structure, the proportion of oxygen in the precursor. The criteria for selecting synthetic polymer wastes as raw materials for obtaining carbon sorbents with predetermined properties are established. The results of the research can be used in the development of technologies for obtaining carbon sorbents with predetermined properties from waste synthetic polymers and the selection of technological parameters for processes.

scholarly journals Circulatory Management of Polymer Waste: Recycling into Fine Fibers and Their Applications

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4694
Author(s):  
Alena Opálková Šišková ◽  
Petra Peer ◽  
Anita Eckstein Andicsová ◽  
Igor Jordanov ◽  
Piotr Rychter
Keyword(s):  
Circular Economy ◽  
Polymeric Materials ◽  
Environmental Issues ◽  
Modern Society ◽  
Waste Recycling ◽  
The European Union ◽  
Polymer Waste ◽  
Alternative Technologies ◽  
Centrifugal Spinning ◽  
Polymeric Waste

In modern society, it is impossible to imagine life without polymeric materials. However, managing the waste composed of these materials is one of the most significant environmental issues confronting us in the present day. Recycling polymeric waste is the most important action currently available to reduce environmental impacts worldwide and is one of the most dynamic areas in industry today. Utilizing this waste could not only benefit the environment but also promote sustainable development and circular economy management. In its program statement, the European Union has committed to support the use of sorted polymeric waste. This study reviews recent attempts to recycle this waste and convert it by alternative technologies into fine, nano-, and microscale fibers using electrospinning, blowing, melt, or centrifugal spinning. This review provides information regarding applying reprocessed fine fibers in various areas and a concrete approach to mitigate the threat of pollution caused by polymeric materials.

scholarly journals Thermal destruction of polymers: analysis of the process physicochemical parameters

2021 ◽  
Vol 4 (10(112)) ◽  
pp. 31-37
Author(s):  
Oleksii Sezonenko ◽  
Oleksii Vasechko ◽  
Viktor Aleksyeyenko
Keyword(s):  
Experimental Study ◽  
Low Temperature ◽  
Synthesis Gas ◽  
Thermal Destruction ◽  
Caloric Content ◽  
Industrial Installation ◽  
Polymer Waste ◽  
Gaseous Products ◽  
Low Temperature Pyrolysis ◽  
Polymeric Waste

This experimental study has confirmed that during thermal decomposition of polymeric waste samples at a temperature of 850 °C, without oxygen access, there is a 90 % drop in the mass of this waste with the release of a large volume of gaseous products. This feature should be taken into consideration in the engineering calculations of reaction chambers, reactors, and connecting gas pipelines. The analytical study was carried out by a method of thermodynamic analysis using the universal estimation system Astra (TERRA). It has been shown that with an increase in reaction temperature there is a change in the composition of the products of thermal destruction of polymeric waste by reducing the mole fraction of СН4 and increasing the proportion of Н2. The calorific value was calculated according to Mendeleev’s empirical formula. The experimental study (a pyrolysis-gas chromatography method) has confirmed the calculation results regarding an increase in the proportion of hydrogen in the gaseous products of destruction with an increase in process temperature. As a result, due to the lower volumetric heat of hydrogen combustion, the total caloric content of the synthesis gas obtained is significantly reduced. For the experiments, a laboratory installation of low-temperature pyrolysis of polymers with external supply of thermal energy was built, and synthesis gas was used as an energy carrier. At the experimental-industrial installation, by a low-temperature pyrolysis method, the synthesis gas of a stable composition with a lower heat of combustion of 24.8 kJ/m3 was obtained. The reliability of the results of the proposed estimation method to the results of instrumental measurements has been shown. Promising areas of further studies have been determined, including the optimization of processes of thermal destruction of chlorine-containing polymer waste; the effective use of hydrogen from the composition of the synthesis gas obtained.

The Influence Of The Led Luminaires Electrical Parameters On Their Correlated Colour Temperature During Operation Mode

2020 ◽  
pp. 89-96
Author(s):  
Sergei S. Kapitonov ◽  
Alexei S. Vinokurov ◽  
Sergei V. Prytkov ◽  
Sergei Yu. Grigorovich ◽  
Anastasia V. Kapitonova ◽  
...  
Keyword(s):  
Operation Mode ◽  
Light Sources ◽  
Electrical Parameters ◽  
Colour Temperature ◽  
Radiation Spectra ◽  
Service Period ◽  
Close Proximity ◽  
Definition Of ◽  
Comprehensive Study

The article describes the results of comprehensive study aiming at increase of quality of LED luminaires and definition of the nature of changes in their correlated colour temperature (CCT) in the course of operation. Dependences of CCT of LED luminaires with remote and close location of phosphor for 10 thousand hours of operation in different electric modes were obtained; the results of comparison between the initial and final radiation spectra of the luminaires are presented; using mathematical statistics methods, variation of luminaire CCT over the service period claimed by the manufacturer is forecast; the least favourable electric operation modes with the highest CCT variation observed are defined. The obtained results have confirmed availability of the problem of variation of CCT of LED luminaires during their operation. Possible way of its resolution is application of more qualitative and therefore expensive LEDs with close proximity of phosphor or LEDs with remote phosphor. The article may be interesting both for manufacturers and consumers of LED light sources and lighting devices using them.

TECHNOLOGICAL ASPECTS OF HIGH QUALITY RAW MATERIAL OBTAINING FOR PECTIN PRODUCTION

1970 ◽  
pp. 47-50
Author(s):  
I. A. Ilina ◽  
I. A. Machneva ◽  
E. S. Bakun
Keyword(s):  
Raw Materials ◽  
Thermal Characteristics ◽  
Environmental Safety ◽  
Raw Material ◽  
High Quality ◽  
Temperature Conductivity ◽  
Drying Temperature ◽  
Plant Raw Materials ◽  
Gel Forming Ability

  The article is devoted to the study of the chemical composition, physical and thermal-pfysical characteristics of damp apple pomaces and the identifying patterns of influence of drying temperature the functional composition and gel-forming ability of pectin. The research is aimed at obtaining initial data for the subsequent calculation of the main technological, hydro-mechanical, thermal, structural and economic characteristics of devices for drying the plant raw materials, ensuring the environmental safety and high quality of pectin-containing raw materials, the reducing heat and energy costs. As a result of the study of the thermal characteristics of apple pomaces, the critical points (temperature conductivity – 16.5 x 10-8 m2/s, thermal conductivity – 0.28 W/m K, heat capacity – 1627 j/(kg K)) at a humidity of 56 % are determined, which characterizing the transition from the extraction of weakly bound moisture to the extraction of moisture with strong bonds (colloidal, adsorption). It was found that the pomaces obtained from apples of late ripening have a higher content of solids (21-23 %), soluble pectin and protopectin (2.5-4.5 %). Dried pomaces obtained from apple varieties of late ripening contain up to 25 % pectin, which allow us to recommend them as a source of raw materials for the production of pectin. The optimum modes of preliminary washing of raw materials are offered, allowing to the remove the ballast substances as much as possible. It is established that when the drying temperature increases, the destructive processes are catalyzed: the strength of the pectin jelly and the uronide component and the degree of pectin esterification are reduced. The optimum drying temperature of damp apple pomaces is 80 0C, at which the quality of pectin extracted from the dried raw materials is maintained as much as possible. It is shown that the most effective for the pectin production is a fraction with a particle size of 3-5 mm, which allow us to extract up to 71 % of pectin from raw materials.

Physico-Chemical Aspects of the Influence of Raw Material Components on the Quality of Ceramic Brick

2019 ◽  
Vol 777 (12) ◽  
pp. 37-42
Author(s):  
G.Yu. SHAGIGALIN ◽  
◽  
P.A. FEDOROV ◽  
L.N. LOMAKINA ◽  
◽  
...  
Keyword(s):  
Raw Material ◽  
Ceramic Brick ◽  
Physico Chemical

scholarly journals A Methodology Based on FT-IR Data Combined with Random Forest Model to Generate Spectralprints for the Characterization of High-Quality Vinegars

Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1411
Author(s):  
José Luis P. Calle ◽  
Marta Ferreiro-González ◽  
Ana Ruiz-Rodríguez ◽  
Gerardo F. Barbero ◽  
José Á. Álvarez ◽  
...  
Keyword(s):  
Random Forest ◽  
Raw Materials ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Raw Material ◽  
Support Vector ◽  
Protected Designation Of Origin ◽  
Ft Ir

Sherry wine vinegar is a Spanish gourmet product under Protected Designation of Origin (PDO). Before a vinegar can be labeled as Sherry vinegar, the product must meet certain requirements as established by its PDO, which, in this case, means that it has been produced following the traditional solera and criadera ageing system. The quality of the vinegar is determined by many factors such as the raw material, the acetification process or the aging system. For this reason, mainly producers, but also consumers, would benefit from the employment of effective analytical tools that allow precisely determining the origin and quality of vinegar. In the present study, a total of 48 Sherry vinegar samples manufactured from three different starting wines (Palomino Fino, Moscatel, and Pedro Ximénez wine) were analyzed by Fourier-transform infrared (FT-IR) spectroscopy. The spectroscopic data were combined with unsupervised exploratory techniques such as hierarchical cluster analysis (HCA) and principal component analysis (PCA), as well as other nonparametric supervised techniques, namely, support vector machine (SVM) and random forest (RF), for the characterization of the samples. The HCA and PCA results present a clear grouping trend of the vinegar samples according to their raw materials. SVM in combination with leave-one-out cross-validation (LOOCV) successfully classified 100% of the samples, according to the type of wine used for their production. The RF method allowed selecting the most important variables to develop the characteristic fingerprint (“spectralprint”) of the vinegar samples according to their starting wine. Furthermore, the RF model reached 100% accuracy for both LOOCV and out-of-bag (OOB) sets.

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