scholarly journals Thermodynamic Estimation of the Parameters for the C–H–O–N–Me-Systems as Operating Fluid Simulants for New Processes of Powder Thermal Spraying and Spheroidizing

2021 ◽  
Vol 20 (5) ◽  
pp. 390-398
Author(s):  
A. V. Gorbunov ◽  
O. G. Devoino ◽  
V. A. Gorbunova ◽  
O. K. Yatskevitch ◽  
V. A. Koval
Keyword(s):  
High Temperature ◽  
Solid Fuel ◽  
Ambient Pressure ◽  
Specific Energy Consumption ◽  
Arc Spraying ◽  
Heating Process ◽  
Powder Materials ◽  
Appreciable Effect ◽  
Functional Coatings ◽  
Oxide Powders

Over the past few years, a group of new processes was developed for high-temperature, including plasma electric arc spraying (at ambient pressure) and spheroidizing of some ceramic and metal powder materials with the use of gaseous hydrocarbons in the heat carriers as well as with feeding of organic additions into a high-temperature jet, in particular, polymeric ones, to control porosity of sprayed metallic functional coatings. The paper considers the possibility to modify such technological processes by introducing solid fuel additions of a polymer type into the operating fluid of an apparatus for gasthermal (plasma or other) treatment, which provides melting of metal or oxide powders. For this, with the help of thermodynamic analysis, the processes have been evaluated at temperatures (300–3000) K for the set of such reacting five component systems as C–H–O–N–Me (at ambient pressure 0.101 MPa) with five variants of Ме – aluminum, titanium, chrome, copper, nickel. This makes it possible to consider these systems as simulants for potential technologies for the treatment of oxide powders (Al2O3, TiO2, Cr2O3) as well as metallic ones (Cu, Ni and their alloys). In order to obtain high exothermic contribution to the heating of powders, the combination “air + polymeric addition (polyethylene) of LDPE grade” was chosen as mixed heat carrier (operating fluid) for the basic version of simulated process. During the analysis of equilibria for the considered multicomponent systems (17 variants), a set of following parameters has been used to characterize the energy intensity of the target powder heating process: the equivalence ratio for reacting mixture and its adiabatic temperature; the energy efficiency of material heating with and without taking into account the effect of fuel addition; specific energy consumption for the powder melting; autothermicity degree of the process during the combined heating (electrothermal heating by the arc of plasma torch and heat flux from the “air + solid fuel additions” mixture) of refractory powders. As a result of the assessment, the preferred (from thermodynamic standpoint) regimes of the considered processes have been found and the possibility to realize an energy-efficient heating of these oxide and metal materials (without oxidation of the latter to CuOx, NiO) with a reduced part of the electric channel of energy transfer, resulted from the carrying out of appreciable effect of the fuel-initiated mechanism of heating in the analyzed C–H–O–N–Mesystems, has been shown in the paper.

Ultra-High Temperature Ceramics (UHTCs) via Reactive Sintering

2007 ◽  
Vol 336-338 ◽  
pp. 1159-1163 ◽  
Author(s):  
Guo Jun Zhang ◽  
Wen Wen Wu ◽  
Yan Mei Kan ◽  
Pei Ling Wang
Keyword(s):  
Phase Composition ◽  
High Temperature ◽  
Oxidation Resistance ◽  
High Performance ◽  
Thermal Protection ◽  
Ambient Pressure ◽  
Stable Phase ◽  
Reactive Sintering ◽  
Dissociation Temperature ◽  
Monolithic Ceramics

Current high temperature ceramics, such as ZrO2, Si3N4 and SiC, cannot be used at temperatures over 1600°C due to their low melting temperature or dissociation temperature. For ultrahigh temperature applications over 1800°C, materials with high melting points, high phase composition stability, high thermal conductivity, good thermal shock and oxidation resistance are needed. The transition metal diborides, mainly include ZrB2 and HfB2, have melting temperatures of above 3000°C, and can basically meet the above demands. However, the oxidation resistance of diboride monolithic ceramics at ultra-high temperatures need to be improved for the applications in thermal protection systems for future aerospace vehicles and jet engines. On the other hand, processing science for making high performance UHTCs is another hot topic in the UHTC field. Densification of UHTCs at mild temperatures through reactive sintering is an attracting way due to the chemically stable phase composition and microstructure as well as clean grain boundaries in the obtained materials. Moreover, the stability studies of the materials in phase composition and microstructures at ultra high application temperatures is also critical for materials manufactured at relatively low temperature. Furthermore, the oxidation resistance in simulated reentry environments instead of in static or flowing air of ambient pressure should be evaluated. Here we will report the concept, advantages and some recent progress on the reactive sintering of diboride–based composites at mild temperatures.

scholarly journals Current Research Status on Cold Sprayed Amorphous Alloy Coatings: A Review

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 206
Author(s):  
Qiang Wang ◽  
Peng Han ◽  
Shuo Yin ◽  
Wen-Juan Niu ◽  
Le Zhai ◽  
...  
Keyword(s):  
High Temperature ◽  
Amorphous Alloy ◽  
Amorphous Alloys ◽  
Composite Coatings ◽  
Thermal Spraying ◽  
Functional Coatings ◽  
Research Status ◽  
Key Issues ◽  
Wear And Corrosion Resistance ◽  
Amorphous Coatings

Compared with traditional crystalline materials, amorphous alloys have excellent corrosion and wear resistance and high elastic modulus, due to their unique short-range ordered and long-range disordered atomic arrangement as well as absence of defects, such as grain boundaries and dislocations. Owing to the limitation of the bulk size of amorphous alloys as structural materials, the application as functional coatings can widely extend their use in various engineering fields. This review first briefly introduces the problems involved during high temperature preparation processes of amorphous coatings, including laser cladding and thermal spraying. Cold spray (CS) is characterized by a low-temperature solid-state deposition, and thus the oxidation and crystallization related with a high temperature environment can be avoided during the formation of coatings. Therefore, CS has unique advantages in the preparation of fully amorphous alloy coatings. The research status of Fe-, Al-, Ni-, and Zr-based amorphous alloy coatings and amorphous composite coatings are reviewed. The influence of CS process parameters, and powders and substrate conditions on the microstructure, hardness, as well as wear and corrosion resistance of amorphous coatings is analyzed. Meanwhile, the deposition mechanism of amorphous alloy coatings is discussed by simulation and experiment. Finally, the key issues involved in the preparation of amorphous alloy coatings via CS technology are summarized, and the future development is also being prospected.

scholarly journals Mechanical Properties of Concrete with Various Water-Cement Ratio After High Temperature Exposure

2019 ◽  
Vol 2 (2) ◽  
pp. 126-136
Author(s):  
M.I Retno Susilorini ◽  
Budi Eko Afrianto ◽  
Ary Suryo Wibowo
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
High Temperature ◽  
Modulus Of Elasticity ◽  
Building Materials ◽  
Heating Process ◽  
High Temperature Exposure ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Temperature Exposure

Concrete building safety of fire is better than other building materials such as wood, plastic, and steel,because it is incombustible and emitting no toxic fumes during high temperature exposure. However,the deterioration of concrete because of high temperature exposure will reduce the concrete strength.Mechanical properties such as compressive strength and modulus of elasticity are absolutely corruptedduring and after the heating process. This paper aims to investigate mechanical properties of concrete(especially compressive strength and modulus of elasticity) with various water-cement ratio afterconcrete suffered by high temperature exposure of 500oC.This research conducted experimental method and analytical method. The experimental methodproduced concrete specimens with specifications: (1) specimen’s dimension is 150 mm x 300 mmconcrete cylinder; (2) compressive strength design, f’c = 22.5 MPa; (3) water-cement ratio variation =0.4, 0.5, and 0.6. All specimens are cured in water for 28 days. Some specimens were heated for 1hour with high temperature of 500oC in huge furnace, and the others that become specimen-controlwere unheated. All specimens, heated and unheated, were evaluated by compressive test.Experimental data was analyzed to get compressive strength and modulus of elasticity values. Theanalytical method aims to calculate modulus of elasticity of concrete from some codes and to verifythe experimental results. The modulus elasticity of concrete is calculated by 3 expressions: (1) SNI03-2847-1992 (which is the same as ACI 318-99 section 8.5.1), (2) ACI 318-95 section 8.5.1, and (3)CEB-FIP Model Code 1990 Section 2.1.4.2.The experimental and analytical results found that: (1) The unheated specimens with water-cementratio of 0.4 have the greatest value of compressive strength, while the unheated specimens with watercementratio of 0.5 gets the greatest value of modulus of elasticity. The greatest value of compressivestrength of heated specimens provided by specimens with water-cement ratio of 0.5, while the heatedspecimens with water-cement ratio of 0.4 gets the greatest value of modulus of elasticity, (2) Allheated specimens lose their strength at high temperature of 500oC, (3) The analytical result shows thatmodulus of elasticity calculated by expression III has greater values compares to expression I and II,but there is only little difference value among those expressions, and (4)The variation of water-cementratio of 0.5 becomes the optimum value.

scholarly journals Tuning, Impedance Matching, and Temperature Regulation during High-Temperature Microwave Sintering of Ceramics

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Sylvain Marinel ◽  
Nicolas Renaut ◽  
Etienne Savary ◽  
Rodolphe Macaigne ◽  
Guillaume Riquet ◽  
...  
Keyword(s):  
Material Processing ◽  
High Temperature ◽  
Microwave Sintering ◽  
Impedance Matching ◽  
Single Mode ◽  
Electrical Circuit ◽  
Ease Of Use ◽  
Heating Process ◽  
Process Technology ◽  
Volumetric Heating

Over the years, microwave radiation has emerged as an efficient source of energy for material processing. This technology provides a rapid and a volumetric heating of material. However, the main issues that prevent microwave technology from being widespread in material processing are temperature control regulation and heating distribution within the sample. Most of the experimental works are usually manually monitored, and their reproducibility is rarely evaluated and discussed. In this work, an originally designed 915 MHz microwave single-mode applicator for high-temperature processing is presented. The overall microwave system is described in terms of an equivalent electrical circuit. This circuit has allowed to point out the different parameters which need to be adjusted to get a fully controlled heating process. The basic principle of regulation is then depicted in terms of a block function diagram. From it, the process has been developed and tested to sinter zirconia- and spinel-based ceramics. It is clearly shown that the process can be successfully used to program multistep temperature cycles up to ∼1550°C, improving significantly the reproducibility and the ease of use of this emerging high-temperature process technology.

High-Pressure Synthesis, Crystal Structure, and Properties of the New Orthorhombic Rare-Earth meta-Oxoborates RE(BO2)3 (RE = Dy – Lu)

2004 ◽  
Vol 59 (2) ◽  
pp. 202-215 ◽  
Author(s):  
Holger Emme ◽  
Tanja Nikelski ◽  
Thomas Schleid ◽  
Rainer Pöttgen ◽  
Manfred Heinrich Möller ◽  
...  
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Ambient Pressure ◽  
Structure And Properties ◽  
Crystal Data ◽  
Temperature Conditions ◽  
Pressure Synthesis ◽  
Ir Spectroscopic ◽  
Pressure Phase

The new orthorhombic meta-oxoborates RE(BO2)3 (≡REB3O6) (RE = Dy-Lu) have been synthesized under high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C. They are isotypic to the known ambient pressure phase Tb(BO2)3, space group Pnma. In contrast to Dy(BO2)3, which was also obtained in small amounts under high-temperature conditions, the preparation of the higher orthorhombic homologues RE(BO2)3 (RE = Ho-Lu) was only possible using high-pressure. The meta-oxoborates RE(BO2)3 (RE = Dy-Er) were synthesized as pure products, whereas the orthorhombic phases with RE = Tm-Lu were only obtained as byproducts. With the exception of Yb(BO2)3 it was possible to establish single crystal data for all compounds. The results of temperature-resolved in-situ powder-diffraction measurements, DTA, IR-spectroscopic investigations, and magnetic properties are also presented.

High N2 uptake by MgFeOx-C nano-hybrid for under high temperature and ambient pressure

2021 ◽  
pp. e00361
Author(s):  
Jiayi Zhu ◽  
Tingjiao Liu ◽  
Wenjie Huang ◽  
Fei Ge ◽  
Runliang Zhu ◽  
...  
Keyword(s):  
High Temperature ◽  
Ambient Pressure

Feasibility Studies on Selective Laser Melting of Copper Powders for the Development of High-temperature Circuit Carriers

2016 ◽  
Vol 2016 (1) ◽  
pp. 000517-000522
Author(s):  
Aarief Syed-Khaja ◽  
Christopher Kaestle ◽  
Joerg Franke
Keyword(s):  
High Temperature ◽  
Selective Laser Melting ◽  
Pure Copper ◽  
Feasibility Studies ◽  
Influential Factors ◽  
Powder Materials ◽  
Laser Melting ◽  
Bronze Alloy ◽  
Ceramic Surfaces ◽  
Copper Powders

Abstract Additive manufacturing (AM) has the potential to lead significant changes in the present state-of-the-art production processes. This provides tool-free and direct manufacturing of complex geometries simultaneously integrating various functions into components. Though AM techniques are widely used in various sectors, the application into electronics production has been not yet explored. In electronics production, substrate development has high relevance due to their multi-functionality in giving the mechanical support and electrically connecting electronic components. This contribution introduces an innovative approach in the development of high-temperature substrates through additive layered manufacturing. The technique used in the investigations was selective laser melting (SLM) of copper based powder materials mainly bronze alloy and pure copper, for the generation of conductive patterns on ceramic surfaces. The process parameters for the SLM technique and the influential factors in the generation of conductive structures are discussed in detail.

scholarly journals Thermal Analysis, Compressibility, and Decomposition of Synthetic Bastnäsite-(La) to Lanthanum Oxyfluoride

Minerals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 212
Author(s):  
Richard L. Rowland ◽  
Barbara Lavina ◽  
Kathleen E. Vander Kaaden ◽  
Lisa R. Danielson ◽  
Pamela C. Burnley
Keyword(s):  
High Temperature ◽  
Equation Of State ◽  
Ambient Temperature ◽  
Evolved Gas Analysis ◽  
Ambient Pressure ◽  
Basic Material ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Thermal Equation ◽  
X Ray

Understanding basic material properties of rare earth element (REE) bearing minerals such as their phase stability and equations of state can assist in understanding how economically viable deposits might form. Bastnäsite is the most commonly mined REE bearing mineral. We synthesized the lanthanum-fluoride end member, bastnäsite-(La) (LaCO3F), and investigated its thermal behavior and decomposition products from 298 K to 1173 K under ambient pressure conditions through thermogravimetric analysis, differential scanning calorimetry, evolved gas analysis, and high temperature powder X-ray diffraction. We also investigated the compressibility of bastnäsite-(La) via single crystal X-ray diffraction in diamond anvil cells at an ambient temperature up to 11.3 GPa and from 4.9 GPa to 7.7 GPa up to 673 K. At ambient pressure, bastnäsite-(La) was stable up to 598 K in air, where it decomposed into CO2 and tetragonal γ-LaOF. Above 948 K, cubic α-LaOF is stable. High temperature X-ray diffraction data were used to fit the Fei thermal equation of state and the thermal expansion coefficient α298 for all three materials. Bastnäsite-(La) was fit from 298 K to 723 K with V0 = 439.82 Å3, α298 = 4.32 × 10−5 K−1, a0 = −1.68 × 10−5 K−1, a1 = 8.34 × 10−8 K−1, and a2 = 3.126 K−1. Tetragonal γ-LaOF was fit from 723 K to 948 K with V0 = 96.51 Å3, α298 = 2.95×10−4 K−1, a0 = −2.41×10−5 K−1, a1 = 2.42×10−7 K−1, and a2 = 41.147 K−1. Cubic α-LaOF was fit from 973 K to 1123 K with V0 = 190.71 Å3, α298 = −1.12×10−5 K−1, a0 = 2.36×10−4 K−1, a1 = −1.73 × 10−7 K−1, and a2 = −17.362 K−1. An ambient temperature third order Birch–Murnaghan equation of state was fit with V0 = 439.82 Å3, K0 = 105 GPa, and K’ = 5.58.

scholarly journals Solar-driven high-temperature steam generation at ambient pressure

2019 ◽  
Vol 29 (1) ◽  
pp. 10-15 ◽  
Author(s):  
Xinyu Wang ◽  
Yanming Liu ◽  
Rui Feng ◽  
Yao Zhang ◽  
Chao Chang ◽  
...  
Keyword(s):  
High Temperature ◽  
Ambient Pressure ◽  
Steam Generation ◽  
High Temperature Steam

scholarly journals Molecular-scale investigation of the oxidation behavior of chromia-forming alloys in high-temperature CO2

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Richard P. Oleksak ◽  
Rafik Addou ◽  
Bharat Gwalani ◽  
John P. Baltrus ◽  
Tao Liu ◽  
...  
Keyword(s):  
High Temperature ◽  
Power Systems ◽  
High Purity ◽  
Photoelectron Spectroscopy ◽  
Ambient Pressure ◽  
Critical Role ◽  
Atomic Scale ◽  
Atomic Diffusion ◽  
Carbon Transport

AbstractCurrent and future power systems require chromia-forming alloys compatible with high-temperature CO2. Important questions concerning the mechanisms of oxidation and carburization remain unanswered. Herein we shed light onto these processes by studying the very initial stages of oxidation of Fe22Cr and Fe22Ni22Cr model alloys. Ambient-pressure X-ray photoelectron spectroscopy enabled in situ analysis of the oxidizing surface under 1 mbar of flowing CO2 at temperatures up to 530 °C, while postexposure analyses revealed the structure and composition of the oxidized surface at the near-atomic scale. We found that gas purity played a critical role in the kinetics of the reaction, where high purity CO2 promoted the deposition of carbon and the selective oxidation of Cr. In contrast, no carbon deposition occurred in low purity CO2 and Fe oxidation ensued, thus highlighting the critical role of impurities in defining the early oxidation pathway of the alloy. The Cr-rich oxide formed on Fe22Cr in high purity CO2 was both thicker and more permeable to carbon compared to that formed on Fe22Ni22Cr, where carbon transport appeared to occur by atomic diffusion through the oxide. Alternatively, the Fe-rich oxide formed in low purity CO2 suggested carbon transport by molecular CO2.

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