scholarly journals Photocatalysis and flocculation processes for recycling aquaculture effluent into nutrient-rich irrigation water

Author(s):  
Maad F. Al Juboury ◽  
Muhammad Abdulredha ◽  
Basim K. Nile

Abstract This research aimed to create a novel technique for recovering fertilizers from aquaculture effluent to overcome potential non-renewable fertilizers shortages. There are two steps: Photocatalyst technique for nutrient mobilization, succeeded by solids precipitating with two natural and one synthetic flocculant. The photocatalytic degradation of organonitrogen compounds in batch experiments started under the irradiation of sunlight. Following that, photocatalytic breakdown of organonitrogen compounds produces inorganic nitrogen constituents like NH4+, NO2−, and NO3−, which could be used as manure. It was found that, after 12 h of circulating, the concentration of inorganic nitrogen become as NH4+ = 17.2 g/L, NO2− = 18.1 mg/L, and NO3− = 15.9 mg/L. The jar test was adopted to assess the capacity of two natural compounds (tamarind kernel polysaccharide (TKP) and tannin-based product (TBS)) and synthetic water-soluble polymer cationic polyacrylamide (SWP) to reduce turbidity, total suspended solids (TSS), COD and colour. The findings reveal that with a dose of 20 mg/L of TBS, 20 mg/L of TKP, and 50 mg/L of SWP, the maximum turbidity reductions were 95, 93, and 94%, respectively. The TBS was slightly better than TKP and highly better than SWP in terms of coagulation activities with TSS, COD and colour maximum removal efficiencies.

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 514 ◽  
Author(s):  
Atanu Biswas ◽  
H. N. Cheng ◽  
Sanghoon Kim ◽  
Carlucio R. Alves ◽  
Roselayne F. Furtado

Cashew gum (CG) shows promise of being useful as an agro-based raw material for the production of eco-friendly and biodegradable polymers. In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than 88%. Samples with degrees of substitution (DS) between 0.02 and 0.20 were made. The resulting polymers were characterized using 1H NMR, 13C NMR, FTIR, TGA, and GPC. The addition of the hydrophobe decreased the affinity of cashew gum for water absorption. Hydrophobically modified polysaccharides are often used as polymeric emulsifiers, thickeners, and compatibilizers; we anticipate that these new hydrophobically modified CGs may be used for the same applications.


2011 ◽  
Vol 8 (2) ◽  
pp. 33
Author(s):  
Norfaezah Mazalan ◽  
Mazatulikhma Mat Zain ◽  
Nor Saliyana Jumali ◽  
Norhanim Mohalid ◽  
Zurina Shaameri ◽  
...  

Recently, research and development in the field of drug delivery systems (DDS) facilitating site-specific therapy has reached significant progression. DDS based on polymer micelles, coated micro- and nanoparticles, and various prodrug systems including water-soluble polymer have been prepared and extensively studied as novel drugs designed for cancer chemotherapy and brain delivery. Since polymers are going to be used in human, this study has the interest of testing two types of polymer, polyimides (PI) and polyphenylenevinylene (PPV) on neuronal cells. The objective of this study was to determine the possible neurotoxicity and potential neuroprotective effects of PI and PPV towards SH-SY5Y neuronal cells challenged by hydrogen peroxide (H2O2) as an oxidant. Cells were pretreated with either PI or PPV for 1 hour followed by incubation for 24 hour with 100 µM of H2O2. MTS assay was used to assess cell viability. Results show that PI and PPV are not harmful within the concentration up to 10 µM and 100 µM, respectively. However, PI and PPV do not protect neuronal cells against toxicity induced by H2O2 or further up the cell death.


2021 ◽  
Author(s):  
Aranee Pleng Teepakakorn ◽  
Makoto Ogawa

Water-induced self-healing materials were prepared by the hybridization of a water-soluble polymer, poly(vinyl alcohol), with a smectite clay by mixing in an aqueous media and subsequent casting. Without using chemical...


2013 ◽  
Vol 675 ◽  
pp. 317-321
Author(s):  
Meng Ying Fang ◽  
Li Chun Liu ◽  
Fang Yin ◽  
Wu Di Zhang ◽  
Shi Qing Liu ◽  
...  

Using petroleum ether to extract the fermentative fluid (bio-slurry), then to get the inhibition mechanism of it, and infer which is the main component in inhibition mechanism of biogas. The conclusion found by the experiment is that fat soluble substance is better than water soluble substance in inhibition mechanism, and fat soluble substance is close to 75% biogas fermentation fluid, while water soluble substance is worst. That is to say, the main subject in inhibition mechanism is hided in the fat soluble substance.


SPE Journal ◽  
2010 ◽  
Vol 16 (01) ◽  
pp. 43-54 ◽  
Author(s):  
Guillaume Dupuis ◽  
David Rousseau ◽  
René Tabary ◽  
Bruno Grassl

Summary The specific molecular structure of hydrophobically modified water-soluble polymers (HMWSPs), also called hydrophobically associative polymers, gives them interesting thickening and surface-adsorption abilities compared with classical water-soluble polymers (WSPs), which could be useful in polymer-flooding and well-treatment operations. However, their strong adsorption obviously can impair their injectivity, and, conversely, the shear sensitivity of their gels can be detrimental to well treatments. Determining for which improved-oil-recovery (IOR) application HMWSPs are best suited, therefore, remains difficult. The aim of this work is to bring new insight regarding the interaction mechanisms between HMWSPs and rock matrix and the consequences concerning their propagation in reservoirs. A consistent set of HMWSPs with sulfonated polyacrylamide backbones and alkyl hydrophobic side chains together with an equivalent WSP was synthesized and fully characterized. HMWSP and WSP solutions were then injected in model granular packs. As expected, with HMWSPs, high resistance factors (or mobility reductions, Rm) were observed. Yet, within the limit of the injected volumes, the effluent showed the same viscosity and polymer concentration as the injected solutions. A first significant outcome concerns the specificities of the Rm curves during HMWSP injections. Rm increases took place in two steps. The first corresponded to the propagation of the viscous front, as observed with WSP, whereas the second was markedly delayed, occurring several pore volumes (PV) after the breakthrough. This result is not compatible with the classical picture of multilayer adsorption of HMWSPs but suggests that injectivity is controlled solely by the adsorption of minor polymeric species. This hypothesis was confirmed by reinjecting the collected effluents into fresh cores; no second-step Rm increases were observed. Brine injections in HMWSP-treated cores revealed high residual resistance factors (or irreversible permeability reductions, Rk), which can be attributed to the presence of thick polymer-adsorbed layers on the pore surface. Nevertheless, Rk values strongly decreased when increasing the brine-flow rate. This second significant outcome shows that the adsorbed-layer thickness is shear-controlled. These new results should lead to proposing new adapted filtration and injection procedures for HMWSPs, aimed, in particular, at improving their injectivity.


2018 ◽  
Vol 176 ◽  
pp. 08012
Author(s):  
Rei Kudo ◽  
Tomoaki Nishizawa ◽  
Akiko Higurashi ◽  
Eiji Oikawa

For the monitoring of the global 3-D distribution of aerosol components, we developed the method to retrieve the vertical profiles of water-soluble, light absorbing carbonaceous, dust, and sea salt particles by the synergy of CALIOP and MODIS data. The aerosol product from the synergistic method is expected to be better than the individual products of CALIOP and MODIS. We applied the method to the biomass-burning event in Africa and the dust event in West Asia. The reasonable results were obtained; the much amount of the water-soluble and light absorbing carbonaceous particles were estimated in the biomass-burning event, and the dust particles were estimated in the dust event.


1965 ◽  
Vol 45 (3) ◽  
pp. 229-237 ◽  
Author(s):  
M. R. Kilcher ◽  
S. Smoliak ◽  
W. A. Hubbard ◽  
A. Johnston ◽  
A. T. H. Gross ◽  
...  

N, P, and N + P at 60, 26, and 60 + 26 lb per acre were applied on native grass sites during three successive years at seven, locations in Western Canada. Single applications of the N fertilizer resulted in 3- or 4-year total yield increases of 300 to 600 lb per acre at six locations. At Summerland the 3-year increase was nearly 1400 lb. Phosphorus fertilizer by itself provided very little yield increase. N + P gave yield increases that were only slightly better than those from N alone.Residual responses to fertilizer were important, especially in the 12- to 16-in. rainfall locations. Only about one-third of the total yield increase occurred in the first year, with the remainder coming in the subsequent seasons.Weeds, where present, showed a marked response to fertilizer N in the first season; in subsequent years the response largely disappeared.


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