Adsorption and removal of arsenic from water by iron ore mining waste

2009 ◽  
Vol 60 (9) ◽  
pp. 2301-2308 ◽  
Author(s):  
Tien Vinh Nguyen ◽  
Thi Van Trang Nguyen ◽  
Tuan Linh Pham ◽  
Saravanamuth Vigneswaran ◽  
Huu Hao Ngo ◽  
...  

There is a global need to develop low-cost technologies to remove arsenic from water for individual household water supply. In this study, a purified and enriched waste material (treated magnetite waste, TMW) from the Trai Cau's iron ore mine in the Thai Nguyen Province in Vietnam was examined for its capacity to remove arsenic. The treatment system was packed with TMW that consisted of 75% of ferrous-ferric oxide (Fe3O4) and had a large surface area of 89.7 m2/g. The experiments were conducted at a filtration rate of 0.05 m/h to treat groundwater with an arsenic concentration of 380 μg/L and iron, manganese and phosphate concentrations of 2.07 mg/L, 0.093 mg/L and 1.6 mg/L respectively. The batch experimental results show that this new material was able to absorb up to 0.74 mg arsenic/g. The results also indicated that the treatment system removed more than 90% arsenic giving an effluent with an arsenic concentration of less than 30 μg/L while achieving a removal efficiency of about 80% for Mn2 +  and PO43−. This could be a promising and cost-effective new material for capturing arsenic as well as other metals from groundwater.

2020 ◽  
Vol 32 (3) ◽  
pp. 550-554 ◽  
Author(s):  
Suresh Kumar Patel ◽  
Dhananjay Singh ◽  
Rahul Dev

Arsenic is a ubiquitous and short-term poisoning element, which affects living things. In this study, the removal of arsenic from Gomti river water, Lucknow, Uttar Pradesh integrated modified double slope solar still with activated adsorption bed has been applied. Arsenic contamination in Gomti river at five places were found in the river water in the range of 55.70 ppb to 681.60 ppb, which exceed the maximum permissible limit of 10 ppb as recommended by WHO. Maximum concentration of arsenic in water was found in Mohan Maekins (681.60 ppb). However, mean arsenic concentration in water followed the order: Gaughat (115.37 ppb) < Hanuman setu (297.80 ppb) < Barrage (302.62 ppb) <Kukrail (336.27 ppb) < Mohan Maekins (481.89 ppb). The amount of adsorbed arsenic was increased with increasing initial concentration of arsenic. The aim of this study is to develop a low-cost process for the removal of arsenic effectively including the production of potable water. After results, data were analyzed with ICP-MS method and also verified with Langmuir and Freundlich adsorption isotherm models.


2008 ◽  
Vol 58 (10) ◽  
pp. 2009-2015 ◽  
Author(s):  
U. Rott ◽  
H. Kauffmann

Arsenic in groundwater is a huge problem in numerous regions of the world. Many people are exposed to high arsenic concentrations and consequently risk getting ill or even die as a result of arsenic poisoning. There are several efficient technologies for the removal of arsenic but often these methods have disadvantages, e.g. high costs for installation and/or operation, the need for chemicals or the production of arsenic contaminated filter sludge. These disadvantages can make the application difficult, especially in poor regions. Under suitable ancillary conditions the subterranean (in-situ) treatment, which is often used for iron and manganese removal from groundwater, can also be applied for the removal of arsenic and can be a cost-effective treatment technology. A field trial was carried out with a low-cost in-situ treatment plant in West Bengal/India which is described in this paper, in order to investigate whether this treatment technology is also applicable under the boundary conditions there. As for the in-situ treatment technology besides oxygen no additives are required and no arsenic contaminated filter sludge is produced this technology could be a suitable method for arsenic removal especially in poor regions.


2020 ◽  
Vol 8 (5) ◽  
pp. 4488-4493 ◽  

In the present day context of urban areas in Indian climate, looking at the statistics of the operating efficiency of existing mechanically operated water treatment plants run by local governing bodies and even when huge costs are incurred in their maintenance, it is necessitated that an efficient wastewater treatment system suitable in Indian climatic conditions and that too efficient, self-operating with minimum interference and at a low-cost construction, operating and maintenance cost. Decentralized onsite and naturally operating treatment methods are much efficient, cost-effective and feasible for Indian context. In current research, Effective positioning and modeling of the non-mechanised, gravity-based wastewater treatment system is carried out at refuge floor which is coined to be proposed as “environmental floor” for G+32 storeyed residential building. Comparative analytical study for structural and seismic response of both the structures (with and without environmental floors) is performed to check feasibility of the treatment system and quantify the benefits arising from it. It is observed form obtained results that the system can be adopted as an ultimate sustainable solution for wastewater treatment in cities where otherwise a lot of unhygienic conditions prevail if centralized treatment plants are not efficiently working.


1997 ◽  
Vol 36 (12) ◽  
pp. 189-197 ◽  
Author(s):  
Izarul Machdar ◽  
Hideki Harada ◽  
Akiyoshi Ohashi ◽  
Yuji Sekiguchi ◽  
Hiroyuki Okui ◽  
...  

A novel sewage treatment system was proposed, which consists of a UASB anaerobic pre-treatment unit and the following DHS (downflow hanging sponge-cubes) aerobic post-treatment unit, as a low-cost and easy-maintenance process for developing countries. Over six months experiment by feeding sewage our proposed system achieved 94% of total-COD removal, 81% of soluble-COD removal, and nearly perfect SS removal and total-BOD removal at the overall HRT of 8.3 hr (7 hr in UASB and 1.3 hr in DHS unit). Moreover, the DHS reactor was capable of performing high (73–78%) nitrification. Our whole system requires neither external aeration input nor withdrawal of excess sludge.


2011 ◽  
Vol 356-360 ◽  
pp. 1427-1432
Author(s):  
Zhi Yan Lu ◽  
Qing Hai Guo

The leachate from the Zixiaguan landfill of Wuhan City contains a lot of undesirable or toxic chemicals, among which arsenic may have the most serious threat to environment and human health. Lowering the arsenic concentration in the leachate is therefore of extreme importance. In this study, natural sediments obtained from Wuhan City, including clay, silty soil and silty sand, were used as low-cost sorbents to remove arsenic from solution. The results of the batch sorption experiments indicate that the sorption processes of clay and silty sand match well with linear isothermal sorption model, while that of silty soil is in good accordance with Langmuir isothermal sorption model. Among the three sorbents, clay has the best ability for arsenic removal from solution. Further experiments were carried out to determine the optimum sorption conditions for clay sorbent, the results showing that as the ratio of sorbent dosage to solution volume is 25.0 g/L, the reaction time is 120 min, and the pH of solution equals 7.0, the removal rate of arsenic from the leachate by clay sorbent reaches the highest value of 99.3 %.


Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2876 ◽  
Author(s):  
Saif Ullah Khan ◽  
Izharul Haq Farooqi ◽  
Muhammad Usman ◽  
Farrukh Basheer

Threats due to insufficient, inadequate and costlier methods of treating contaminants such as arsenic have emphasized the significance of optimizing and managing the processes adopted. This study was aimed at the complete elimination of arsenic from an aqueous medium with minimum energy consumption using the electrocoagulation process. Arsenic removal around 95% was rapidly attained for optimized conditions having a pH of 7, 0.46 A current intensity, 10 mg/L initial concentration and only 2 min of applied time duration using the energy of 3.1 watt-hour per gram of arsenic removed. Low values of applied current for longer durations resulted in the complete removal of arsenic with low energy consumption. Various hydroxide complexes including ferrous hydroxide and ferric hydroxide assisted in the removal of arsenic by adsorption along with co-precipitation. Surface models obtained were checked and found with a reasonably good fit having high values of coefficient of determination of 0.933 and 0.980 for removal efficiency and energy consumption, respectively. Adsorption was found to follow pseudo-first-order kinetics. Multivariate optimization proved it as a low-cost effective technology having an operational cost of 0.0974 Indian rupees (equivalent to USD 0.0013) per gram removal of arsenic. Overall, the process was well optimized using CCD based on response surface methodology.


2021 ◽  
Vol 11 (7) ◽  
pp. 3021
Author(s):  
Linda Ansone-Bertina ◽  
Karina Upska ◽  
Linda Dobkevica ◽  
Jorens Kviesis ◽  
Raimonds Meija ◽  
...  

Environmental pollution with contaminants of emerging concern (CECs) is a worldwide problem that is receiving increasing attention. Although these substances have been released in the aquatic environment for a long time, wastewater treatment plants are still incapable of removing emerging contaminants completely. Consequently, trace metals, metalloids and pharmaceuticals, as well as surfactant leftovers, are often found in environmental samples. Environmentally friendly and cost-effective sorbents such as humic substances can be used for purification if their sorption properties are increased by immobilization. To our knowledge, immobilized humic substances have not been widely studied as sorbents up to now. In this study, humic substances were immobilized to obtain low-cost sorbents. The chosen methods for characterization of the obtained sorbents showed successful immobilization. Traditional pollutants, such as Cr(III) (a metal), As(V) (a metalloid) and chlorpromazine (a pharmaceutical), were used as representative contaminants. Sorption experiments were conducted using the batch system, and sorption was also studied based on the sorbent dosage, initial concentration of the studied element or substance, solution pH and sorption time. The results show that all the obtained immobilized humic substances in this study can be used as sorbents to remove contaminants from water. At the same time, from these humic substances, only those immobilized using iron compounds are suitable for the removal of arsenic.


2019 ◽  
pp. 35-42
Author(s):  
Tashfia Aktar ◽  
Hossain Barsha ◽  
Fardeen Arafat ◽  
Nadim Reza Khandaker ◽  
Barsha Hossain

Over seventy million people in Bangladesh are drinking arsenic contaminated water. There is a lack of available sustainable arsenic removal technologies in the rural Bangladesh. This paper reports on a successful retrofit that allows for readily available, cost effective and dependable membrane system application for arsenic removal in rural Bangladesh. The retrofit is very simple, overcoming the limitation of a hydraulic pressure by a low cost pump placement in line to the membrane system. The system was field tested in a well with high arsenic concentration 0.1 mg/L (Government of Bangladesh Limit is 0.05 mg/L), along with high iron and hardness. In the field trial, the retrofitted technology was successful and produced water that does not contain any arsenic (0.0 mg/L), low in iron, and low in hardness. The system cost, along with the retrofitting, is only a hundred and seventy US dollars, a sum within the reach of many in Bangladesh. It is also important to note that we are using an existing technology available off the shelf and retrofitting it using locally available materials. The work reported in the paper will create a significant impact relief to the people in the arsenic affected regions of Bangladesh.


Author(s):  
Abdul Qudoos ◽  
Sikandar ALMANI ◽  
Kashif Hussain Mangi ◽  
Memoona Hafeez ◽  
Syed Farman Ali Shah

Arsenic (As) being a carcinogenic element present in drinking water in the less developed areas in the deprived countries contributes to many infectious diseases. The removal of arsenic traces from water needs to have an easy and efficient way for poor countries. Concerning this, a low-cost bio-adsorbent from Rice husk is prepared to remove arsenic from groundwater. Preparation of the absorbent is performed by crushing, sieving, washing and drying the rice husk. The Arsenic present in groundwater samples before and after treatment were tested by Arsenic kit. Batch experiments were carried out with ten contaminated samples of groundwater from Indus river origin area (Nasarpur) to investigate the influence of operating parameters such as adsorbent bed height (ABH) and initial arsenic concentration and residence time(TR) on As removal efficiency using locally fabricated adsorption column. Environmental parameters such as pH, temperature, TDS, and EC were also determined. It was observed that the highest optimized removal efficiency of 90% was achieved at ABH 30 cm: residence time, 60 minutes for feed arsenic concentration of 80 ppb samples. These results suggest that this bio-adsorbent can provide an easy, efficient, and economical method for removing As ions from effluents and water resources.


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