Ammonia nitrogen removal from acetylene purification wastewater from a PVC plant by struvite precipitation

2016 ◽  
Vol 74 (2) ◽  
pp. 508-515 ◽  
Author(s):  
Lei Zhu ◽  
DeMing Dong ◽  
XiuYi Hua ◽  
ZhiYong Guo ◽  
DaPeng Liang
Keyword(s):  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Precipitation Method ◽  
Minor Effect ◽  
N Removal ◽  
Electron Microscopy Analysis ◽  
Typical Morphology ◽  
Coarse Surface ◽  
Struvite Precipitation ◽  
High Concentrations

Acetylene purification wastewater (APW) usually contains high concentrations of ammonia nitrogen (NH4-N), which is generated during the production of acetylene in a polyvinylchloride manufacturing plant. In this study, a struvite precipitation method was selected to remove NH4-N from the APW. Laboratory-scale batch experiments were performed to investigate the effects of the initial APW pH, phosphate (PO43−) concentration, magnesium (Mg2+) concentration, and sources of PO43− and Mg2+ on NH4-N removal. The results indicated that the initial APW pH had a significant effect on the removal of NH4-N, while the other factors had relatively minor effect. The NH4-N could be effectively removed at an optimum initial APW pH of 9.5, when Na2HPO4·12H2O and MgSO4·7H2O were both applied to NH4-N at a ratio of 1.2. Under these conditions, the efficiency of removal of NH4-N, total nitrogen and chemical oxygen demand were 85%, 84% and 18%, respectively. The X-ray diffraction analysis indicated that the precipitates were dominated by struvite. The scanning electron microscopy analysis of the precipitates showed a typical morphology of stick-like and prismatic crystals with coarse surface. The energy dispersive spectroscopy analysis indicated that the precipitates contained P, O, Mg and Ca.

scholarly journals Digestate Liquid Fraction Treatment with Filters Filled with Recovery Materials

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 21
Author(s):  
Ilaria Piccoli ◽  
Giuseppe Virga ◽  
Carmelo Maucieri ◽  
Maurizio Borin
Keyword(s):  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Liquid Fraction ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Green Technology ◽  
Filling Material ◽  
Community Interactions ◽  
Material Particle ◽  
N Removal

Constructed wetlands (CWs) represent a green technology for digestate liquid fraction (DLF) treatment. However, previous research has warned about their performance when treating wastewater with high suspended solid and organic loads. In addition, the high NH4-N concentration typical of this wastewater can compromise vegetation establishment and activity. In view of this, a digestate pretreatment is needed. This study aimed to test the performance of filters filled with recovery materials, such as brick and refractory material, for DLF pretreatment. The effect on DLF physical (electrical conductivity, pH, dissolved oxygen, and temperature) and chemical (total nitrogen, ammonia–nitrogen, nitrate–nitrogen, total phosphorus, soluble phosphorus, and chemical oxygen demand) characteristics was monitored during eight weekly cycles. The effect of filtration on total nitrogen and ammonia–nitrogen removal began after about one month of loading, suggesting that an activation period is necessary for bacteria. For effective N removal, the presence of multiple digestate recirculations per day through the filters appears mandatory to guarantee the alternation of nitrification and denitrification conditions. For P removal, filling material particle size appeared to be more important than its composition. Unclear performances were observed considering chemical oxygen demand. Further studies on filling media and microbial community interactions, and the long-term efficiency of filters, are desirable.

Simultaneous heterotrophic nitrification and aerobic denitrification at high concentrations of NaCl and ammonia nitrogen by Halomonas bacteria

2017 ◽  
Vol 76 (2) ◽  
pp. 386-395 ◽  
Author(s):  
Te Wang ◽  
Jian Li ◽  
Ling Hua Zhang ◽  
Ying Yu ◽  
Yi Min Zhu
Keyword(s):  
Removal Rate ◽  
Sodium Succinate ◽  
Bacterial Genome ◽  
Ammonia Nitrogen ◽  
Compatible Solute ◽  
Heterotrophic Nitrification ◽  
Aerobic Denitrification ◽  
Sequencing Analysis ◽  
N Removal ◽  
High Concentrations

To improve the efficiency of simultaneous heterotrophic nitrification and aerobic denitrification (SND) at high concentrations of NaCl and ammonia nitrogen (NH4+—N), we investigated the SND characteristics of Halomonas bacteria with the ability to synthesize the compatible solute ectoine. Halomonas sp. strain B01, which was isolated, screened and identified in this study, could simultaneously remove nitrogen (N) by SND and synthesize ectoine under high NaCl conditions. Gene cloning and sequencing analysis indicated that this bacterial genome contains ammonia monooxygenase (amoA) and nitrate reductase (narH) genes. Optimal conditions for N removal in a solution containing 600 mg/L NH4+–N were as follows: sodium succinate supplied as organic carbon (C) source at a C/N ratio of 5, pH 8 and shaking culture at 90 rpm. The N removal rate was 96.0% under these conditions. The SND by Halomonas sp. strain B01 was performed in N removal medium containing 60 g/L NaCl and 4,000 mg/L NH4+–N; after 180 h the residual total inorganic N concentration was 21.7 mg/L and the N removal rate was 99.2%. Halomonas sp. strain B01, with the ability to synthesize the compatible solute ectoine, could simultaneously tolerate high concentrations of NaCl and NH4+–N and efficiently perform N removal by SND.

Tech-IA floating system introduced in urban wastewater treatment plants in the Veneto region – Italy

2013 ◽  
Vol 68 (5) ◽  
pp. 1144-1150 ◽  
Author(s):  
Anna Mietto ◽  
Maurizio Borin ◽  
Michela Salvato ◽  
Paolo Ronco ◽  
Nicola Tadiello
Keyword(s):  
Wastewater Treatment Plants ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Alnus Glutinosa ◽  
Primary Treatment ◽  
Ammonia Nitrogen ◽  
Surface Flow ◽  
Treatment Wetland ◽  
N Removal ◽  
Floating System

The performance of three integrated wetland treatment plants (horizontal sub-surface flow (h-SSF) and floating treatment wetland (FTW) with differentiated primary treatments) designed for treating domestic wastewater was investigated, monitoring total (TN), nitrate (NO3-N), nitrite (NO2-N) and ammonia nitrogen (NH4-N), total (TP) and phosphate phosphorus (PO4-P), chemical (COD) and biological oxygen demand (BOD5), and dissolved oxygen (DO) at the inlet and outlet of each wetland section from February 2011 to June 2012. Sediments settled in the FTW were collected and analyzed. The growth of plants in each system was also monitored, observing their general conditions. The chemical–physical characteristics of the pretreated domestic wastewater depended on the primary treatment installed. During the monitoring period we observed different reduction performance of the wetland sector in the three sites. In general, the wetland systems demonstrated the capacity to reduce TN, COD, BOD5 and Escherichia coli, whereas NO3-N and NH4-N removal was strictly influenced by the chemical conditions, in particular DO concentration, in the h-SSF and FTW. Vegetation (Phragmites australis, Alnus glutinosa and Salix eleagnos) was well established in the h-SSF as well as in the floating elements (Iris pseudacorus), although there were some signs of predation. FTW is a relatively novel wetland system, so the results obtained from this study can pave the way for the application of this technology.

scholarly journals Performance of wild-Serbian Ganoderma lucidum mycelium in treating synthetic sewage loading using batch bioreactor

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Zarimah Mohd Hanafiah ◽  
Wan Hanna Melini Wan Mohtar ◽  
Hassimi Abu Hasan ◽  
Henriette Stokbro Jensen ◽  
Anita Klaus ◽  
...  
Keyword(s):  
Ganoderma Lucidum ◽  
Treatment Time ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Ammonia Nitrogen ◽  
Organic Content ◽  
N Removal

Abstract The fluctuation of domestic wastewater characteristic inhibits the current conventional microbial-based treatment. The bioremediation fungi has received attention and reported to be an effective alternative to treat industrial wastewater. Similar efficient performance is envisaged for domestic wastewater whereby assessed performance of fungi for varying carbon-to-nitrogen ratios in domestic wastewater is crucial. Thus, the performance of pre-grown wild-Serbian Ganoderma lucidum mycelial pellets (GLMPs) was evaluated on four different synthetic domestic wastewaters under different conditions of initial pH (pH 4, 5, and 7) and chemical oxygen demand (COD) to nitrogen (COD/N) ratio of 3.6:1, 7.1:1, 14.2:1, and 17.8:1 (C3.6N1, C7.1N1, C14.2N1, and C17.8N1). The COD/N ratios with a constant concentration of ammonia–nitrogen (NH3–N) were chosen on the basis of the urban domestic wastewater characteristics sampled at the inlet basin of a sewage treatment plant (STP). The parameters of pH, COD, and NH3–N were measured periodically during the experiment. The wild-Serbian GLMPs efficiently removed the pollutants from the synthetic sewage. The COD/N ratio of C17.8N1 wastewater had the best COD and NH3–N removal, as compared to the lower COD/N ratio, and the shortest treatment time was obtained in an acidic environment at pH 4. The highest percentage for COD and NH3–N removal achieved was 96.0% and 93.2%, respectively. The results proved that the mycelium of GLMP has high potential in treating domestic wastewater, particularly at high organic content as a naturally sustainable bioremediation system.

The Treatment of Concentrated Landfill Leachate from Membrane-Based Processes by Supercritical Water Oxidation

2014 ◽  
Vol 522-524 ◽  
pp. 560-564 ◽  
Author(s):  
Yan Meng Gong ◽  
Shu Zhong Wang ◽  
Yan Hui Li
Keyword(s):  
Residence Time ◽  
Supercritical Water ◽  
Landfill Leachate ◽  
Water Oxidation ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Supercritical Water Oxidation ◽  
N Removal ◽  
Varied Temperature

Supercritical water oxidation (SCWO) of concentrated landfill leachate has been carried out in a batch reactor in fluidized bed sand bath, operated under varied temperature (450-600 °C), pressure (23-29 MPa), residence time (5-20 min) and oxidation coefficient (1.5-3.0). The experimental results indicated that temperature and oxidation coefficient had significant influences on the oxidation reaction, whereas the pressure and residence time were not crucial factors. The chemical oxygen demand (COD) and ammonia nitrogen (NH4-N) removal efficiencies could reach up to 99.23% and 98.64% at 600 °C, 25 MPa and 5 min with a oxidation coefficient of 2, respectively, and the effluents could be discharged harmlessly.

The Characteristics and Application of Water Quenched Slag Particles (WQSP) as Filter Media

2010 ◽  
Vol 156-157 ◽  
pp. 1247-1250
Author(s):  
Yan Feng ◽  
Yan Zhen Yu ◽  
Jian Wei Zhang ◽  
Tan Juan
Keyword(s):  
Municipal Wastewater ◽  
Oxygen Demand ◽  
Total Porosity ◽  
Total Surface Area ◽  
Ammonia Nitrogen ◽  
Mass Ratio ◽  
Filter Media ◽  
N Removal ◽  
The Media ◽  
Heavy Metal Elements

Novel filter media-water quenched slag particles (WQSP) were prepared using waste material- Water quenched slag, clay and pore-forming material with a mass ratio of 3:2:1. Compared with haydite, WQSP had higher total porosity, larger total surface area and lower bulk and apparent density. Tests of heavy metal elements in lixivium proved that SGSP were safe for wastewater treatment. In order to ascertain the application of WQSP ，WQSP and haydite were applied as the media of biological aerated filters (BAF) to treat municipal wastewater in two lab scale upflow BAFs. The results showed that WQSP reactor brought a relative superiority to haydite reactor in terms of chemical oxygen demand (CODcr) and ammonia nitrogen (NH3-N) removal at the conditions of water temperature ranging from 200C to 260C and DO ≥4.00 mg·L-1. Therefore, WQSP application, as a novel process of treating wastes with wastes, provided a promising way in water quenched slag utilization.

scholarly journals Experimental Study on a Closed-Cycle Humidification and Dehumidification System for Treating Wastewater Containing High Concentrations of Inorganic Salts and Organic Matter

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 671
Author(s):  
Jun Liu ◽  
Yong Sun ◽  
Sanjiang Yv ◽  
Jiaquan Wang ◽  
Kaixuan Hu
Keyword(s):  
Organic Matter ◽  
Industrial Wastewater ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Filter Press ◽  
Inorganic Salts ◽  
Closed Cycle ◽  
Treatment Performance ◽  
High Concentrations

Industrial wastewater contains high concentrations of inorganic salts and organic matter. This experiment studied a system for treating wastewater containing high concentrations of inorganic salts and organic matter. The setup consists of a closed-cycle humidification and dehumidification system and a filter press. Chemical wastewater was used as the treatment solution, and the treatment performance of the system was tested and analyzed. The system effectively reduced the chemical oxygen demand (COD), electric conductivity (EC), total nitrogen (TN), and ammonia nitrogen (NH4-N) in the wastewater and, at the same time, dehydrated sludge was obtained through a filter press. The system maintains a stable removal rate of each index (COD, EC, TN, and NH4-N) in wastewater and can remove inorganic salts and organic matter from wastewater. The system can successfully treat industrial wastewater containing high concentrations of inorganic salts and organic matter.

COD and NH4-N Removal in Two-Stage Batch-Flow Constructed Wetland

2013 ◽  
Vol 448-453 ◽  
pp. 604-607 ◽  
Author(s):  
Hong Jie Sun ◽  
Xin Nan Deng ◽  
Rui Chen
Keyword(s):  
Constructed Wetland ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Two Stage ◽  
Removal Rates ◽  
N Removal ◽  
Domestic Wastewater Treatment

Research was conducted on pilot-scale, two-stage batch-flow constructed wetland systems for domestic wastewater treatment. Synthetic domestic wastewater was treated in a pre-acidification reactor with a hydraulic retention time (HRT) of 3 hours and the average removal rate of chemical oxygen demand (COD) and ammonia-nitrogen (NH4-N) reached 30% and 13.6%, respectively. The first-stage constructed wetland operated with up-flow and batch feed and drain. One cycle was 12h, including 6h feed and 6h drain. With HRT of 3 days, the effluent COD concentrations fluctuated from 32.5 mg/L to 103.4 mg/L, removal rates varied from 60% to 88%; effluent NH4-N concentrations were in the range of 4.8 mg/L to 10.8 mg/L, removal rates varied from 50% to 70%. The second-stage constructed wetland operated with down-flow, which one cycle was 24h, including 12h feed and 12h drain. With HRT of 1 day, effluent COD concentrations varied from 15.7 mg/L to 48.7 mg/L, removal averaged 53.2%; effluent NH4-N concentrations ranged from 0 mg/L to 0.4 mg/L, average removal exceeded 99%. The spatial variation of COD and NH4-N in the first-stage constructed wetland demonstrated that entrainment of air during draining of constructed wetland could strengthen the removal of COD and NH4-N. Temperature had no significant effect on COD degradation while obviously affected the removal of NH4-N.

A novel PSB-EDI system for high ammonia wastewater treatment, biomass production and nitrogen resource recovery: PSB system

2016 ◽  
Vol 74 (3) ◽  
pp. 616-624 ◽  
Author(s):  
Hangyao Wang ◽  
Qin Zhou ◽  
Guangming Zhang ◽  
Guokai Yan ◽  
Haifeng Lu ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Inoculum Size ◽  
Cod Removal ◽  
Treated Wastewater ◽  
Second Stage ◽  
N Concentration ◽  
N Removal ◽  
High Ammonia

A novel process coupling photosynthetic bacteria (PSB) with electrodeionization (EDI) treatment was proposed to treat high ammonia wastewater and recover bio-resources and nitrogen. The first stage (PSB treatment) was used to degrade organic pollutants and accumulate biomass, while the second stage (EDI) was for nitrogen removal and recovery. The first stage was the focus in this study. The results showed that using PSB to transform organic pollutants in wastewater into biomass was practical. PSB could acclimatize to wastewater with a chemical oxygen demand (COD) of 2,300 mg/L and an ammonia nitrogen (NH4+-N) concentration of 288–4,600 mg/L. The suitable pH was 6.0–9.0, the average COD removal reached 80%, and the biomass increased by an average of 9.16 times. The wastewater COD removal was independent of the NH4+-N concentration. Moreover, the PSB functioned effectively when the inoculum size was only 10 mg/L. The PSB-treated wastewater was then further handled in an EDI system. More than 90% of the NH4+-N was removed from the wastewater and condensed in the concentrate, which could be used to produce nitrogen fertilizer. In the whole system, the average NH4+-N removal was 94%, and the average NH4+-N condensing ratio was 10.0.

Performance of constructed wetland treating wastewater from seafood industry

2004 ◽  
Vol 49 (5-6) ◽  
pp. 289-294 ◽  
Author(s):  
C. Yirong ◽  
U. Puetpaiboon
Keyword(s):  
Constructed Wetland ◽  
Nutrient Recycling ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Suspended Solid ◽  
Tertiary Treatment ◽  
Seafood Industry ◽  
High Concentrations ◽  
Solids Removal ◽  
Seafood Processing

Wastewater from seafood industry contains high concentrations of organic matter, nitrogen compounds, and solid matter. Constructed wetland can be used as tertiary treatment and for nutrient recycling. This research studied the performance of nitrogen and suspended solids removal efficiency of a constructed wetland treating wastewater from a seafood-processing factory located at Songkhla, southern Thailand. The existing constructed wetland has dimensions of 85 m, 352 m and 1.5 m in width, length and depth respectively, with an area of about 29,920 m2. The water depth of 0.30 m is maintained in operation with plantation of cattails (Typha augustifolia). Flow rate of influent ranged between 500-4,660 m3/d. Average hydraulic retention time in the constructed wetland was about 4.8 days. Influent and effluent from the constructed wetland were collected once a week and analyzed for pH, temperature, dissolved oxygen (DO), biochemical oxygen demand (BOD5), Suspended solid (SS), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), organic nitrogen (Org-N), nitrate (NO3-N), and nitrite (NO2-N). The average removal efficiencies of BOD5, SS, TKN, NH3-N, and Org-N were 84%, 94%, 49%, 52% and 82%, respectively. It was found that the constructed wetland acting as a tertiary treatment process provided additional removal of BOD5, SS and TKN from wastewater from the seafood industry.

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