scholarly journals Glazing effect for producing environmentally friendly ceramics for cladding applications

2021 ◽  
Vol 75 (3) ◽  
pp. 167-173
Author(s):  
Elizaveta Pavlycheva ◽  
Evgeniy Pikalov ◽  
Oleg Selivanov
Keyword(s):  
Heavy Metals ◽  
High Performance ◽  
Ceramic Materials ◽  
Environmental Safety ◽  
Raw Material ◽  
Charge Composition ◽  
Material Base ◽  
Pressing Pressure ◽  
Electroplating Sludge ◽  
Environmentally Safe

This paper presents results of comparative studies of environmental safety of ceramic materials, based on a low-plasticity clay with the introduction of galvanic sludge, boric acid and titanium dioxide in 3 different combinations. The experimental samples were manufactured under 15 MPa pressing pressure and at the maximum firing temperature of 1050 oC. Prior to the toxicological experiments, diurnal extracts of the materials into the model neutral and acidic media were obtained. The toxicological safety was determined by using the Daphnia mortality method, and by comparing the maximum permissible concentrations of heavy metals for drinking and household water with the heavy metals? concentrations in diurnal extracts. The presented data show that the combined introduction of all the investigated additives results in the glazing effect of ceramic particles surfaces so that an environmentally safe material can be produced that exhibits sufficiently high-performance properties. The use of low-plastic clay and electroplating sludge expands the raw material base for producing ceramics and allows the disposal of environmentally hazardous compounds of heavy metals contained in electroplating sludge. Ceramic materials based on the developed charge composition can be used for producing items for external cladding for buildings and structures.

The Use of Carbonate Sludge in the Production of Porous Aggregate

2020 ◽  
Vol 24 (6) ◽  
pp. 15-19
Author(s):  
A.V. Kolpakov ◽  
E.S. Abdrakhimova
Keyword(s):  
Industrial Waste ◽  
Liquid Glass ◽  
Glass Composition ◽  
Physical And Mechanical Properties ◽  
Ceramic Materials ◽  
Environmental Safety ◽  
Raw Material ◽  
Material Base ◽  
Carbonate Sludge ◽  
The Russian Federation

The possibilities of obtaining porous fillers based on carbonate sludge and liquid-glass composition are considered. One of the issues of industrial waste disposal is the creation of waste-free technologies. The use of nanotechnology-based carbonate sludge in the production of porous aggregates increases environmental safety. A porous aggregate with high physical and mechanical properties was obtained. The use of carbonate sludge in the production of porous aggregate contributes to: a) recycling of industrial waste; b) environmental protection; C) expanding the raw material base for obtaining ceramic materials for construction. A patent of the Russian Federation was obtained for the obtained method of producing a porous aggregate using a liquid-glass composition.

scholarly journals Development of environmentally safe acid-resistant ceramics using heavy metals containing waste

2018 ◽  
Vol 193 ◽  
pp. 03035 ◽  
Author(s):  
Irina Vitkalova ◽  
Anastasiya Torlova ◽  
Evgeniy Pikalov ◽  
Oleg Selivanov
Keyword(s):  
Boric Acid ◽  
Lanthanum Oxide ◽  
Acid Resistance ◽  
Environmental Safety ◽  
Charge Composition ◽  
Functional Additives ◽  
Vladimir Region ◽  
Electroplating Sludge ◽  
Environmentally Safe ◽  
Heavy Metal Oxides

The paper presents research results concerning charge composition development to produce environmentally safe acid-resistant ceramics on the basis of low-plastic clay of the Vladimir region possessing self-glazing effect. 5 wt. % boric acid, 5 wt. % lanthanum oxide and up to 5 wt. % electroplating sludge have been introduced into the charge composition as functional additives. Boric acid serves as a flux and a source acid-resistant and heat-resistant vitreous phase based on borosilicates, but compositions contained in the electroplating sludge are decomposed in the process of ceramics firing causing the formation of calcium oxide and heavy metal oxides, which additionally increase material acid-resistance and heat-resistance like lanthanum oxide. To receive the developed material, semidry pressing technology has been applied under the charge forming moisture of 8 wt. %, specific pressure of 15 МPа and one-stage firing at max temperature of 1050 °C. The research presents the testing results of ceramics principal operating properties and environmental safety. The developed material can be used in clinker and acid-resistant bricks and tiles production for masonry and tiling in aggressive environment like buildings foundations and bases, premises with high moisture, as well as in sewerage systems, chimneys and ventilation ducts.

scholarly journals Study of environmental safety of construction ceramics produced using anthropogenic waste

2021 ◽  
Vol 284 ◽  
pp. 05010
Author(s):  
Elizaveta Pavlycheva ◽  
Evgeniy Pikalov ◽  
Oleg Selivanov
Keyword(s):  
Heavy Metals ◽  
Ceramic Material ◽  
Experimental Studies ◽  
Environmental Safety ◽  
Raw Material ◽  
Toxic Waste ◽  
Material Base ◽  
Acidic Media ◽  
Static Mode ◽  
Research Results

The study presents the research results confirming environmental safety of the ceramic material used for construction purposes, produced basing on low-plasticity clay from the Vladimir region with the introduction of 2.5 wt. % boric acid, 5 wt. % of electroplating sludge and 30 wt. % of cullet. The material environmental safety has been previously confirmed by Daphnia mortality method in diurnal water extracts from the chipped ceramic material samples, including possible mechanical damage and deterioration during the operation. The experimental studies embraced the determination of heavy metal ions concentration in diurnal extracts from the chipped ceramic material samples in neutral and acidic media. Additional studies dealing with the heavy metals migration into the extracts were carried out in static mode during 20 days. The research results confirm the environmental safety of ceramic material in neutral and acidic media during the heavy metals immobilization, caused by ceramics self-glazing and vitrification. The research results proved that the production of the developed material will expand the regional raw material base, will contribute to the utilization of large-capacity and toxic waste with simultaneous manufacturing of high-quality and environmentally friendly construction products for new buildings construction or existing buildings and structures reconstruction.

scholarly journals Improving the efficiency of leaching of metals from ore raw materials

2018 ◽  
pp. 45-57
Author(s):  
V.I. Lyashenko ◽  
F.F. Topolnyi ◽  
G.D. Kovalenko
Keyword(s):  
Underground Mining ◽  
Raw Materials ◽  
Residential Buildings ◽  
Practical Experience ◽  
Environmental Safety ◽  
Theory And Practice ◽  
Raw Material ◽  
Material Base ◽  
Seismic Safety ◽  
Industrial Buildings

Purpose. Improving the efficiency of leaching of metals from ore raw materials by justifying the parameters of underground mining and the introduction of integrated technology in combination with geotechnology, ensuring the rational use, protection of the subsurface and the environment during the development of reserves by combined geotechnological methods. Metology. The methods of generalization, analysis and evaluation of practical experience and scientific achievements in the field of geotechnology, theory and practice of explosive destruction of solid media, continuum mechanics, mathematical statistics, as well as research techniques of wave processes according to standard and new techniques of the leading experts of the world's advanced mining countries are described. Findings. The factors determining the leaching efficiency of metal ores, environmental and seismic safety are established and the parameters of the explosion are justified taking into account the size of an average linear piece of exploded ore mass, the area of an emanating surface and the seismic safety of protected objects (industrial buildings, residential buildings, the Ingul river underflow, Kropivnitsky, etc.). Originality. Recommended empirical dependence for the prediction of the oscillation speed on the reduced mass of charge per deceleration step in the explosive preparation of ore for underground leaching of metals for the field conditions of the form y = a ∙ b also the value of the permissible displacement rate of the soil at the base of the protected objects = 0.4 cm / s. Practical value. When non-conforming ores of deposits are involved in the production, their raw material base at operating mines can be increased 1.4–1.6 times. Keywords: mining technology, underground mining, metal leaching, environmental safety, efficiency.

scholarly journals The selection of technological basis of deep processing of coal.

2021 ◽  
Vol 4 ◽  
pp. 15-21
Author(s):  
M.O. Gordienko
Keyword(s):  
Melting Point ◽  
Environmental Safety ◽  
Coke Production ◽  
Raw Material ◽  
State Enterprise ◽  
Material Base ◽  
Deep Processing ◽  
Technological Basis ◽  
Thermochemical Processing ◽  
Selection Of

THE SELECTION OF TECHNOLOGICAL BASIS OF DEEP PROCESSING OF COAL © M.O. Gordienko (State Enterprise "Ukrainian State Research Coal Chemical Institute (UHIN)", 61023, Kharkov, Vesnina st., 7, Ukraine) The article is devoted to the analysis of the possibility of expanding the raw material base of thermal energy, as well as meeting the demand for motor fuels and chemical products through the thermochemical processing of coal, the reserves of which are large enough and available for extraction and transportation. Moreover, in contrast to technologies such as methanization and liquefaction, the most promising type of deep processing of coal seems to be its gasification. This process is carried out in sealed devices of high power according to the technologies that have a long history of improvement on an industrial scale by the world's leading companies. It was emphasized that Ukraine has significant reserves of low-calorie coal (constantly expanding due to waste of coal preparation), the thermochemical processing of which can significantly expand the domestic energy base. The basic principles of classification and technological foundations of existing industrial and industrial research installations for gasification of coal and similar materials are given. The basic diagrams and main parameters of the existing installations, which carry out the gasification process at temperatures below the melting point of the mineral (ash-forming) components of the raw material, are described - Sasol Lurgi and SES Gasification Technology (SGT). Based on the data on the world experience in the operation of thermochemical coal processing units, it is shown that low-temperature (carried out at a temperature below the melting point of the mineral ashforming components) gasification of various types of non-coking coal with certain technological solutions can be no less effective than more complex and expensive high-temperature technologies. There are grounds for believing that the efficiency of gasification with ash removal in a solid state can be further increased by using some of the technological capabilities available in coke production. Keywords: brown coal, non-coking coals, thermochemical processing, gasification, efficiency, degree of carbon conversion, energy carriers, synthesis gas, environmental safety. Corresponding author M.O. Gordienko, е-mail: [email protected]

Ceramic Composition Material with Mullite Crystals Obtained from the Clayy Raw Material of Yakutia

2020 ◽  
Vol 992 ◽  
pp. 253-258
Author(s):  
M.P. Lebedev ◽  
V.N. Tagrov ◽  
E.S. Lukin
Keyword(s):  
Building Materials ◽  
Raw Materials ◽  
Practical Interest ◽  
Physical And Mechanical Properties ◽  
Ceramic Materials ◽  
Strength Properties ◽  
Raw Material ◽  
Composition Material ◽  
Material Base ◽  
Wide Range

The article deals with the manufacture of modern structural ceramic materials from clay and loam deposits of the Republic of Sakha (Yakutia). The importance and relevance of the development of the production of building materials from local raw materials is emphasized, since this will certainly affect the effectiveness of the construction complex as a whole. The successful development of the construction complex is capable of not only stimulating growth in all sectors of the economy, but also contributes to solving the most pressing social problems. Today, Yakutia has huge reserves of mineral raw materials for the production of a wide range of building materials and products. Of practical interest are wall materials made from clay soils. Given the features of the region’s raw material base, this work focuses on additional processing of traditional material. Controlling the complex physicochemical and structural-mechanical transformations that occur during heat treatment, a methodology has been developed for creating a composite material that will allow competitive innovative materials with enhanced strength properties to be produced with a reinforcing element with a glassy phase matrix of mullite crystals. The fabricated samples have a wide range of physical and mechanical properties and allow using it as a high-quality structural building ceramics, as well as industrial floor technical tile.

scholarly journals Legal regulation of subsoil use when placing and constructing facilities for development of subsoil sites

2019 ◽  
Vol 135 ◽  
pp. 04020
Author(s):  
Elena Voskresenskaya ◽  
Nikolay Zhilskiy ◽  
Nicolay Golovanov
Keyword(s):  
Environmental Safety ◽  
Legal Regulation ◽  
Academic Community ◽  
Raw Material ◽  
Energy Industry ◽  
Material Base ◽  
Huge Amount ◽  
Governmental Regulation ◽  
The Russian Federation ◽  
The Government

Energy Strategy of Russia for the period until 2035 contains a note that Russian Energy Industry is one of the main sources of environmental pollution. More than 50 per cent of polluted matter emissions into the atmosphere, more than 20 per cent of dirty discharge into surface water reservoirs and more than 70 per cent of total emissions of greenhouse gases account for this industry. Issues of environmental safety of the subsoil use are always under consideration in the academic community. However, huge amount of problems concerning this area still remain unresolved. For instance, bankrupt subsoil users often do not satisfy requirements set by the government on mothballing or removing facilities aimed at development or reclamation of used land parcels when the land leasehold is over. This indicates the need to enshrine additional measures in the Russian legislation on ensuring compliance with certain requirements. The authors mention that providing the regeneration of raw material base and its reasonable using for the benefit of current and next generations of nations inhabiting the Russian Federation are among the primary tasks of governmental regulation of relations on the subsoil use. The government should ensure the most efficient and consistent usage of resources obtained from already provided land parcels, complete development of mineral deposits and compliance with appropriate terms of subsoil use.

New Technology of White Portland Cement Production in the Ural Federal District

2018 ◽  
Vol 284 ◽  
pp. 1047-1051
Author(s):  
V.S. Rudnov ◽  
V.A. Belyakov ◽  
R.T. Galiakhmetov
Keyword(s):  
Portland Cement ◽  
High Performance ◽  
New Technology ◽  
Federal District ◽  
Raw Material ◽  
Material Base ◽  
Resource Saving ◽  
Cement Production ◽  
High Temperature Synthesis ◽  
White Portland Cement

In this article the results of research to develop energy - and resource-saving technologies of production on local raw material base of the Ural Federal district of the white portland cement with high performance are represented. An x-ray phase analysis of the obtained building material is performed. The possibility of obtaining white portland cement-based pyrophillite mining waste,the composition of the raw mix for high-temperature synthesis of clinker white portland cement at low temperatures was studied. This reduces the costs for grinding of the mixture, and firing the clinker. The result of this work was the experimental batch of cement and studied all of its construction and technical characteristics.

Building Ecomaterials Based on Secondary Raw Material

2018 ◽  
Vol 284 ◽  
pp. 916-921
Author(s):  
Mihail Gerasimovich Bruyako ◽  
L. Grigoryeva
Keyword(s):  
Building Materials ◽  
Raw Materials ◽  
Raw Material ◽  
Household Waste ◽  
Environmental Damage ◽  
Moisture Resistance ◽  
Pressing Pressure ◽  
Resource Saving ◽  
Urgent Task ◽  
Environmentally Safe

Mineral raw natural resources are not unlimited. Preservation of such non-renewable resources is the most urgent task of mankind. The development of non-waste technologies, the integrated use of secondary raw materials, which simultaneously reduces environmental damage - one of the ways to solve environmental problems. Utilization of wastes makes it possible to solve issues of environmental protection as well as resource saving. In the light of environmental requirements, building materials based on recycled materials, including cellulose-containing solid waste, have significant advantages over other traditional materials. Development of technology for obtaining new effective environmentally safe composite highly filled materials based on cellulose-containing solid household waste for the production of construction products is a rational link in solving the general problem of improving the environmental situation. In the article there are three main ways of combining gypsum binder with cellulose-containing solid household waste. Investigations were carried out on the effect of changing the ratio of cardboard / gypsum binder, specific pressing pressure, sequence of combination of components on the properties of the final product. The strength of the material was determined from the values of the flexural strength, the compression to complete destruction of the sample, and at 10% deformation. Studies have been carried out to increase moisture resistance. The results showed that the most optimal way of combining is the 2 way. The increase in moisture resistance is significantly enhanced by the action of organosilicon hydrophobisers.

scholarly journals SELECTION AND ANALYSIS OF RAW MATERIALS FOR A PROTECTIVE AND DECORATIVE LAYER OF COMPOSITE MATERIAL

2021 ◽  
Vol 6 (12) ◽  
pp. 27-33
Author(s):  
D. Bondarenko
Keyword(s):  
Composite Material ◽  
High Performance ◽  
Raw Materials ◽  
Heating Temperature ◽  
Protective Layer ◽  
Raw Material ◽  
High Alumina ◽  
High Temperature Treatment ◽  
Material Base ◽  
Functional Coatings

With modern housing construction, the cost of finishing work has increased significantly. The development of protective and decorative coatings is necessary, with architectural and artistic advantages and high performance properties with a slight increase in cost. It is necessary to develop a high-quality multilayer monolithic composite with a high degree of adhesion of functional layers to each other. Glass industry waste of various fractions and coloring salts of metals are proposed to be used for a decorative layer, which allows to obtain an almost unlimited color gamut of the coating during plasma chemical modification. The choice of application of high-alumina refractory and alumina cement in the protective layer is justified due to their high thermal resistance to sudden temperature changes. Compositions of a protective layer based on binders and a decorative layer using crushed colored container glass and coloring metal salts moistened with a 5% aqueous solution of liquid glass have been proposed, which makes it possible to significantly expand the raw material base for obtaining functional coatings on concrete. The melt heating temperature and the kinetics of its cooling are determined in order to identify rational rates and duration of high-temperature treatment for further coating creation. Rational rates of plasma processing of composite material for the formation of coatings of various textures are revealed

Sign in / Sign up

Export Citation Format

Share Document