Investigation of structure of milled wood and dioxane lignins of Populus nigra and Cupressus sempervirens using the DFRC method

2012 ◽  
Vol 66 (8) ◽  
Author(s):  
Tayyebe Partovi ◽  
Abdol Massoudi ◽  
Seyyed Mirshokraie

AbstractIn this study, derivatisation followed by reductive cleavage (DFRC) were used to investigate milled wood lignin (MWL) and dioxane lignin (DL) structures of Populus nigra and Cupressus sempervirens. After the DFRC reactions, the constituents obtained from these two kinds of lignin were recognised structurally using several chromatographic and spectral methods such as 13C NMR, GC-MS, and GPC. Comparative results showed that the dominant structural components of the two kinds of lignin are obtained from the cleavage of β-O-4 bonds. The main component of DL and MWL of P. nigra is 4-hydroxy-3,5-dimethoxy-1-phenyl-γ-hydroxypropene (syringyl structures). Also, some guaiacyl structures were observed. The dominant component identified in both lignins of C. sempervirens is 4-hydroxy-3-methoxy-1-phenyl-γ-hydroxypropene (guaiacyl structures). The cleavage method has a good performance for both P. nigra and C. sempervirens and the results obtained are in good agreement with previously published data.

1989 ◽  
Vol 172 ◽  
Author(s):  
T. S. Aurora ◽  
D. O. Pederson ◽  
S. M. Day

AbstractLinear thermal expansion and refractive index variation have been measured in lead fluoride with a laser interferometer as a function of temperature. Data has been analyzed using the Lorentz-Lorenz relation. Molecular polarizability, band gap, variation of refractive index with density, and strain-polarizability parameter have been studied as a function of temperature. They exhibit a small variation with temperature except near the superionic phase transition where the variation appears to be more pronounced. The results are in good agreement with the published data near room temperature.


1961 ◽  
Vol 14 (4) ◽  
pp. 598 ◽  
Author(s):  
EJ Williams

Though randomly moving insects released from a central point in a uniform environment are often found to be distributed according to a circular normal distribution, their larvae will not conform to this distribution. When such insects lay at a constant rate and are subject to constant mortality, their larvae are found to be spatially distributed according to a highly peaked frequency function, depending on the modified Bessel function of the second kind. This theoretical conclusion is in good agreement with published data. Some of the properties of the theoretical distribution are discussed.


2020 ◽  
Vol 58 (4) ◽  
Author(s):  
Dongju Won ◽  
Jung Yong Park ◽  
Hyon-Suk Kim ◽  
Younhee Park

ABSTRACT The QuantiFERON-TB Gold plus (QFT-Plus) assay, an interferon gamma (IFN-γ) release assay (IGRA), was recently introduced as the next version of the QuantiFERON-TB Gold In-Tube (QFT-GIT) assay for diagnosing latent tuberculosis (TB). Whereas the QFT-GIT assay uses only one TB tube that induces a cell-mediated immune (CMI) response of CD4+ T cells, the QFT-Plus has an additional TB antigen 2 tube (TB2) for the CMI response of CD8+ T and CD4+ T cells, in addition to a TB antigen 1 (TB1) tube for the CMI response of CD4+ T cells only. We compared the results of the QFT-Plus and QFT-GIT assays as routine clinical tests for diagnosing TB. Samples from 220 patients referred for routine IGRA in various clinical departments were used. Correlations between IFN-γ levels in the QFT-GIT and QFT-Plus assays were strong and showed good agreement (kappa value = 0.69). Seven cases with positive QFT-GIT assay results and negative QFT-Plus assay results showed IFN-γ values near the cutoff value. However, 10 cases with active TB, recent TB, or immune problems showed discordance with the positive results only in the TB2 tube in QFT-Plus, unlike the negative results in TB1 and TB tubes. In these cases, IFN-γ levels in the TB2 tube were significantly higher than those in other tubes. This is the first study to compare these assays as routine IGRAs in the clinical setting. The QFT-Plus assay showed good agreement with the QFT-GIT assay and is presumably advantageous for patients with active TB, recent TB, and specific immune conditions involving CD8+ T-cell responses.


Author(s):  
F Frendo ◽  
W Rosellini

This paper describes an activity aimed at analysing the loads occurring on a two-wheeler during one of the most widespread tests among two-wheeler companies. In this test, the vehicle with additional ballasts, is positioned on two rollers, having synchronized rotational speed, and is subjected to loads coming from obstacles positioned on the rollers' surface. In order to achieve an in-depth understanding of the loads produced by the test, a vehicle was provided with displacement transducers, accelerometers, and strain gauges. At the same time, two multi-body models of the test were set up, in which the motorscooter had a rigid frame or a flexible frame respectively. The dynamics of the tyre was reproduced by the rigid ring model, where the tyre interacts with the wheel rim by means of linear and rotational springs and dampers. The loads from the obstacles are evaluated on the basis of a series of experimental curves (envelope properties of the tyre) directly obtained with the tyres and obstacle employed for the tests. The comparison between experimental and numerical results regarding suspension strokes, wheel vertical accelerations, and vertical and longitudinal loads showed fairly good agreement; it is also shown how the model having the rigid frame overestimates the peaks in the vertical load. The availability of an accurate model for this kind of test in the early phase of the development process of new vehicles, allows the design of structural components to be optimized.


2014 ◽  
Vol 670-671 ◽  
pp. 613-616 ◽  
Author(s):  
Jabrane Belabid ◽  
Abdelkhalek Cheddadi

This work presents a numerical study of the natural convection in a saturated porous medium bounded by two horizontal concentric cylinders. The governing equations (in the stream function and temperature formulation) were solved using the ADI (Alternating Direction Implicit) method and the Samarskii-Andreev scheme. A comparison between the two methods is conducted. In both cases, the results obtained for the heat transfer rate given by the Nusselt number are in a good agreement with the available published data.


2005 ◽  
Vol 297-300 ◽  
pp. 10-15 ◽  
Author(s):  
Kyung Su Kim ◽  
Byung Ok Kim ◽  
Young Kwan Kim ◽  
Chang Hwan Lee ◽  
Sung Won Lee

Recently, most of fatigue cracks in ship structures are reported within a few years after delivery. This type of fatigue characteristics cannot be explained adequately by the S-N curve based on high cycle fatigue. Calculation results under critical loading conditions reveal that stress magnitude higher than three times the yield stress occurs at some critical locations. It shows the fatigue cracks are related to low cycle fatigue. But the existing recommended design procedures in maritime industry do not properly cover low cycle fatigue problems. This work represents the first step in an effort to develop a design code that addresses low cycle fatigue problems. Low cycle fatigue test for uniform round specimen made of base/weld metal and for cruciform welded joint are carried out under constant amplitude alternating load, controlled by strain. Strain-cycle curves for the base metal and weld joints show good agreement with published data as well as some code recommended design curves.


2007 ◽  
Vol 353-358 ◽  
pp. 50-53
Author(s):  
Jian Qui Zhou ◽  
Yuan Ling Li

In order to understand the grain size and porosity dependent mechanical behavior of porous, multi-phase nanocrystalline ceramics, each phase is treated as a mixture of grain interior and grain boundary, and pores are taken as a single phase. In conjunction with the secant-modulus approach and iso-strain assumption, Budiansky’s self-consistent method is extended to build a constitutive model for nanocrystalline ceramics with small plastic deformation. Based on the developed model, the predicted yield strength (σ0.2) values of porous, multi-phase nanocrystalline ceramics with different grain size and porosity are compared with experimental data in the literature, the comparison shows that the predictions are in good agreement with the published data. This suggests that the developed model is capable of describing the grain size and porosity dependent mechanical behaviors of nanocrystalline ceramics with small plastic deformation.


Author(s):  
Waqas Waheed ◽  
Anas Alazzam ◽  
Ashraf N. Al Khateeb ◽  
Eiyad Abu Nada

In this paper, a two-dimensional Dissipative Particle Dynamics (DPD) technique to simulate the poiseuille flow in a microchannel is developed using an in-house code. The calculated Reynolds number is reduced via adjusting the DPD parameters. The obtained velocity profile is compared with the analytical results and a good agreement is found. The drag force and the drag coefficient on a stationary cylinder exerted by the fluid particles are obtained using the developed DPD code. The calculated drag coefficient exhibits a close match with already published data in the literature.


Radiocarbon ◽  
2010 ◽  
Vol 52 (3) ◽  
pp. 1422-1434 ◽  
Author(s):  
P Ding ◽  
C D Shen ◽  
N Wang ◽  
W X Yi ◽  
X F Ding ◽  
...  

This paper examines the carbon isotopes (13C, 14C) of soil organic carbon (SOC) and soil CO2 from an evergreen broadleaf forest in southern China during the rainy season. The distribution of SOC δ13C, and SOC content with depth, exhibits a regular decomposition of SOC compartments with different turnover rates. Labile carbon is the main component in the topsoil (0–12 cm) and has a turnover rate between 0.1 and 0.01 yr–1. In the middle section (12–35 cm), SOC was mainly comprised of mediate carbon with turnover rates ranging between 0.01 and 0.025. Below 35 cm depth (underlayer section), the SOC turnover rate is slower than 0.001 yr–1, indicating that passive carbon is the main component of SOC in this section. The total production of humus-derived CO2 is 123.84 g C m–2 yr–1, from which 88% originated in the topsoil. The middle and underlayer sections contribute only 10% and 2% to the total humus-derived CO2 production, respectively. Soil CO2 δ13C varies from –24.7‰ to –24.0‰, showing a slight isotopic depth gradient. Similar to soil CO2 δ13C, Δ14C values, which range from 100.0‰ to 107.2‰, are obviously higher than that of atmospheric CO2 (60–70‰) and SOC in the middle and underlayer section, suggesting that soil CO2 in the profile most likely originates mainly from SOC decomposition in the topsoil. A model of soil CO2 Δ14C indicates that the humus-derived CO2 from the topsoil contributes about 65–78% to soil CO2 in each soil gas sampling layer. In addition, the humus-derived CO2 contributes ∼81% on average to total soil CO2 in the profile, in good agreement with the field observation. The distribution and origin of soil 14CO2 imply that soil CO2 will be an important source of atmospheric 14CO2 well into the future.


2010 ◽  
Vol 133 (3) ◽  
Author(s):  
J. Michael Owen

Ingress of hot gas through the rim seals of gas turbines can be modeled theoretically using the so-called orifice equations. In Part I of this two-part paper, the orifice equations were derived for compressible and incompressible swirling flows, and the incompressible equations were solved for axisymmetric rotationally induced (RI) ingress. In Part II, the incompressible equations are solved for nonaxisymmetric externally induced (EI) ingress and for combined EI and RI ingress. The solutions show how the nondimensional ingress and egress flow rates vary with Θ0, the ratio of the flow rate of sealing air to the flow rate necessary to prevent ingress. For EI ingress, a “saw-tooth model” is used for the circumferential variation of pressure in the external annulus, and it is shown that ε, the sealing effectiveness, depends principally on Θ0; the theoretical variation of ε with Θ0 is similar to that found in Part I for RI ingress. For combined ingress, the solution of the orifice equations shows the transition from RI to EI ingress as the amplitude of the circumferential variation of pressure increases. The predicted values of ε for EI ingress are in good agreement with the available experimental data, but there are insufficient published data to validate the theory for combined ingress.


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