Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases
Keyword(s):
The efficient synthesis of hydrosilanes by catalytic ydrogenolysis of chlorosilanes is described, using an Iridum (III) pincer catalyst. A careful selection of a nitrogen base (incl. sterically hindered guanidines and phosphazenes) can unlock the preparation of Me<sub>3</sub>SiH, Et<sub>3</sub>SiH and Me<sub>2</sub>SiHCl in high yield (up to 98%), directly from their corresponding chlorosilanes.
2020 ◽
pp. 680-683
Keyword(s):
Keyword(s):
Keyword(s):
2019 ◽
Vol 21
(1)
◽
pp. 165
◽
Keyword(s):
2012 ◽
Vol 90
(11)
◽
pp. 965-974
◽
Keyword(s):
Keyword(s):