scholarly journals Mesoporous Silica MCM-48 as Chloramphenicol Adsorbent

2021 ◽  
Vol 8 (3) ◽  
pp. 242-246
Author(s):  
Paulina Taba ◽  
Miftahul Jannah ◽  
Yusafir Hala
Keyword(s):  
Adsorption Isotherm ◽  
Mesoporous Silica ◽  
Contact Time ◽  
Freundlich Isotherm ◽  
Freundlich Adsorption Isotherm ◽  
Potential Use

This study is aimed to determine the potential use of MCM-48 to adsorb chloramphenicol pollution. Chloramphenicol adsorption was conducted at various times contact and concentration. Adsorption isotherm was studied by comparing Langmuir and Freundlich adsorption isotherm. The results showed that chloramphenicol adsorption was suited to Freundlich isotherm with an optimum contact time of 80 minutes 

scholarly journals Adsorption Study for Trifluralin on Iraqi ? –Alumina

2012 ◽  
Vol 9 (1) ◽  
pp. 153-159 ◽  
Author(s):  
Baghdad Science Journal
Keyword(s):  
Adsorption Isotherm ◽  
Aqueous Solutions ◽  
Contact Time ◽  
Adsorption Process ◽  
Kinetic Equations ◽  
Adsorption Study ◽  
Adsorption Capacities ◽  
Experimental Parameters ◽  
Freundlich Adsorption Isotherm ◽  
Equilibrium Adsorption Isotherm

Equilibrium adsorption isotherm for the removal of trifluralin from aqueous solutions using ? –alumina clay has been studied. The result shows that the isotherms were S3 according Giels classification. The effects of various experimental parameters such as contact time, adsorbent dosage, effect of pH and temperature of trifluralin on the adsorption capacities have been investigated. The adsorption isotherms were obtained by obeying freundlich adsorption isotherm with (R2 = 0.91249-0.8149). The thermodynamic parameters have been calculated by using the adsorption process at five different temperature, the values of ?H, ?G and ?S were (_1.0625) kj. mol-1, (7.628 - 7.831) kj.mol-1 and (_2.7966 - _2.9162) kg. k-1. mol-1 respectively. The kinetic study of adsorption process has been studied depending on three kinetic equations: 1- Allergen equation 2- Morris –weber eguation 3- Reichenberg eguation. In general, the result shows the isotherm were on ?- alumina according to Giels classification.? –alumina and thermodynamic

On the fractality of the Freundlich adsorption isotherm in equilibrium and non-equilibrium cases

2016 ◽  
Vol 18 (30) ◽  
pp. 20784-20789 ◽  
Author(s):  
Przemysław Borys ◽  
Zbigniew J. Grzywna
Keyword(s):  
Adsorption Isotherm ◽  
Freundlich Isotherm ◽  
Fractal Properties ◽  
Freundlich Adsorption Isotherm ◽  
Isotherm Of Adsorption ◽  
Non Equilibrium

This work relates the fractal properties of the adsorbent to the exponent of the Freundlich Isotherm of adsorption.

scholarly journals ISOTERM ADSORPSI FENOL OLEH LEMPUNG ALAM

2019 ◽  
Vol 7 (1) ◽  
pp. 029
Author(s):  
Nelly Wahyuni ◽  
Imelda H. Silalahi ◽  
Dina Angelina
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Contact Time ◽  
Freundlich Isotherm ◽  
Langmuir Adsorption Isotherm ◽  
Batch Experiments ◽  
Natural Clay ◽  
Langmuir Adsorption ◽  
Equilibrium Data ◽  
Initial Phenol Concentration

Abstrak Fenol merupakan polutan yang sangat berbahaya di lingkungan karena bersifat racun dan sulit terdegradasi oleh organisme pengurai. Lempung alam yang berasal dari Kecamatan Capkala, Kabupaten Bengkayang  akan dikaji penggunaannya sebagai adsorben fenol. Adsorpsi dilakukan dengan metoda batch pada variasi waktu kontal dan konsentrasi awal fenol. Data kesetimbangan adsorpsi diuji dengan isoterm Langmuir dan Freundlich. Hasil penelitian menunjukkan waktu kontak optimum adsorpsi adalah 4 jam. Proses adsorpsi fenol  oleh lempung alam  mengikuti model isoterm adsorpsi Langmuir dengan kapasitas adsorpsi sebesar 0,65mg/g. Kata Kunci: fenol, Freundlich, isoterm adsorpsi, Langmuir, lempung alamAbstract Phenol is a pollutant that is very dangerous in the environment because it is toxic and difficult to degrade by decomposing organisms. Natural clay from Capkala District, Bengkayang Regency will be studied as phenol adsorbent. Batch experiments were carried out by varying the parameters like contact time of adsorption and initial phenol concentration. The equilibrium data were tested with Langmuir and Freundlich isotherm. The results showed that the optimum contact time for adsorption was 4 hours. The process of adsorption of phenol by natural clay follows the Langmuir adsorption isotherm model with an adsorption capacity of 0.65mg/g.  Keywords: adsorption isotherm, Freundlich, natural clay, phenol, Langmuir.

scholarly journals Utilization of Banana (Musa sapientum) Peel for Removal of Pb2+ from Aqueous Solution

2021 ◽  
Vol 1 (2) ◽  
pp. 117-128
Author(s):  
Afrida Nurain ◽  
Protima Sarker ◽  
Md. Shiblur Rahaman ◽  
Md. Mostafizur Rahman ◽  
Md. Khabir Uddin
Keyword(s):  
Aqueous Solution ◽  
Heavy Metal ◽  
Adsorption Isotherm ◽  
Contact Time ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Agitation Speed ◽  
Banana Peel ◽  
Management Problem ◽  
Freundlich Adsorption Isotherm

Biosorption is a convenient process for heavy metal remediation. In this study, banana peel was experimented to eliminate lead (Pb2+) from an aqueous solution following batch experiments. The functional groups of banana peel were identified by Fourier-transform infrared spectroscopy (FTIR). The adsorption mechanism was studied by the Langmuir and Freundlich adsorption isotherm model and determined the separation factor from the Langmuir adsorption isotherm. The adsorption of Pb2+ on dried banana peel had been studied at different adsorbent doses, pH, initial concentration of Pb, contact time, temperature, and agitation speed. After adsorption, Pb2+ was measured using atomic absorption spectroscopy (AAS). Maximum adsorption had taken place at pH 5 for adsorbent dose 45 g L-1. The optimum contact time and agitation speed was 30 minutes and 150 rpm, respectively for the initial Pb concentration of 100 ppm at 25°C. Both, Langmuir and Freundlich adsorption isotherm models shows the best fitting (r2 = 0.9978 and 0.9595) for Pb2+ adsorption. The maximum Pb2+ adsorption capacity was 2.1 mg g-1. The findings indicate that the banana peel waste could be a potential adsorbent for heavy metal removal. Moreover, the waste management problem could be solved in an eco-friendly manner by utilizing it for the eradication of Pb2+ from wastewater.

scholarly journals Aplikasi Zeolit Alam Aktif Wonosari Sebagai Adsorben Zat Warna Remazol Yellow Fg

2021 ◽  
Vol 1 ◽  
pp. 80-87
Author(s):  
Neni Damajanti ◽  
Anwar Ma’ruf ◽  
Hanafi Khafid Nugraha
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Textile Industry ◽  
Contact Time ◽  
Langmuir Adsorption Isotherm ◽  
Isotherm Model ◽  
Isotherm Models ◽  
Activation Process ◽  
Langmuir Adsorption ◽  
Freundlich Adsorption Isotherm

Zeolite as an adsorbent has been widely used. Zeolite activation was carried out to increase the absorption. This study aimed to determine the characteristics of the active zeolite and apply it as an adsorbent. The activation process was carried out by adding acid and calcining at 4500C for 6 hours. Remazol Yellow FG is a dye that is widely used in the textile industry. In this study, the adsorption process was carried out on the Remazol Yellow FG solution, then analyzed the effect of changes in pH (5, 6, 7, 8, 9), contact time (30, 60, 90, 120, 150 minutes) and the concentration of Remazol Yellow FG solution ( 50, 100, 150, 200, 250 ppm) on the adsorption of Remazol Yellow FG dye. From the analysis of the sample solution of Remazol Yellow, the values of Ce and qe can be calculated. These values were then used to calculate KL and KF in the Langmuir adsorption isotherm and Freundlich adsorption isotherm models. From the experimental results, it could be seen that as the contact time increased, the adsorption capacity would be greater. However, when the zeolite was already in the saturated phase, the adsorption capacity would tend to decrease. In the Langmuir adsorption isotherm, the KL value was 0.0274 L/mg and in the Freundlich adsorption isotherm model, the KF value was 29.25 L/mg. Remazol Yellow FG adsorption tended to follow the Langmuir adsorption isotherm model with an R2 value of 0.998.

Simultaneous Adsorption of Trichloroethylene and Cadmium on Attapulgite in the Groundwater

2012 ◽  
Vol 610-613 ◽  
pp. 3202-3205
Author(s):  
Hai Ying Gao ◽  
Xiao Qian Li ◽  
Hui Jie Yan ◽  
Xiao Wei Wang
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Adsorption Rate ◽  
Adsorption Time ◽  
Freundlich Adsorption Isotherm ◽  
Effects Of Ph ◽  
Combined Contamination

The adsorption of trichloroethylene (TCE) and Cd2+ combined contamination in the groundwater by attapulgite were studied, and the effects of pH, dosage of attapulgite and adsorption time on adsorption were investigated, equilibrium of the adsorptions processes were further conducted. Results showed that the adsorption rate of TCE affected little by the pH; TCE adsorption equilibrium reached after 3d, the removal rate was 71.34%; when attapulgite dosage was 0.03g, the adsorption rate was up to more than 51.08%. Freundlich isotherm was best fitted the adsorption process of TCE. Compound contamination of TCE and Cd2+ decreased the removal rate of TCE; but was in line with Freundlich adsorption isotherm.

scholarly journals Nonlinear Kinetic and Equilibrium Adsorption Isotherm Study of Cadmium (II) Sorption by Dacryodes edulis Biomass

2021 ◽  
Vol 28 (2) ◽  
pp. 10-19
Author(s):  
L.C. Overah
Keyword(s):  
Adsorption Isotherm ◽  
Active Sites ◽  
Freundlich Isotherm ◽  
Equilibrium Adsorption ◽  
Isotherm Study ◽  
Freundlich Adsorption Isotherm ◽  
Seed Biomass ◽  
Good Potential ◽  
Equilibrium Adsorption Isotherm ◽  
Dacryodes Edulis

The kinetics and equilibrium adsorption isotherm of cadmium (II) adsorption onto Dacryodes edulis (native peer seed) biomass was studied using a nonlinear approach, which is unpopular but proven in some literature to be more reliable and easier. In optimizing the process, about 98% removal of the cadmium ion was achieved within five minutes at pH 7 by contacting just 30 mg of the Dacryodes edulis seed biomass with the adsorbate solution of a concentration of 100 mg/L. Non-linear investigation of the kinetics and adsorption isotherms of the process was done using the R console statistical and computing software. The results indicated that the Elovich mechanism and the Freundlich adsorption isotherm most suitably described the kinetics and adsorption isotherm, respectively, of the process as provided by their least values of the sum of squared residuals (SSR). This outcome implied a chemical adsorption  (chemisorption) mechanism and a multi-layer coverage by the cadmium ions on heterogeneous active sites of the biomass surface with a Freundlich constant or capacity factor, Kf of 27.83 mg g-1, heterogeneity factor, 1/n of 0.2614 and Elovich constants, α and β of 7.0 mg g−1 s−1 and 1.0 g mg-1, respectively. These findings indicate that Dacryodes edulis seed biomass has a good potential for cadmium (II) adsorption. Keywords: Dacryodes edulis, Elovich kinetic model, Freundlich isotherm, Langmuir isotherm, Nonlinear 

Removal of Total Phosphorus from Domestic Wastewater with Clay-Zeolite Medium

2013 ◽  
Vol 647 ◽  
pp. 753-757 ◽  
Author(s):  
Grace K. Luk
Keyword(s):  
Adsorption Isotherm ◽  
Removal Efficiency ◽  
Total Phosphorus ◽  
Contact Time ◽  
Domestic Wastewater ◽  
Scale Model ◽  
Isotherm Model ◽  
Chemical Adsorption ◽  
Solvent Concentration ◽  
Freundlich Adsorption Isotherm

Chemical adsorption of a clay-zeolite pellet medium is being investigated for the removal of total phosphorus from domestic wastewater. The effect of pellet composition, influent concentration, and contact time on the overall removal efficiency is being studied in a five-layer bench-scale model. Results showed that an equilibrium removal of 72% is achieved after a 3 hour contact time, supporting the Freundlich adsorption isotherm model based on the linearization of solute adsorption to equilibrium solvent concentration.

scholarly journals KARAKTERISASI ISOTERM ADSORPSI DARI ION LOGAM BESI (Fe) PADA TANAH DI KOTA BENGKULU

Alotrop ◽  
2018 ◽  
Vol 2 (1) ◽  
Author(s):  
Hesti Apriyanti ◽  
I Nyoman Candra ◽  
Elvinawati Elvinawati
Keyword(s):  
Adsorption Isotherm ◽  
Moisture Content ◽  
Soil Ph ◽  
Soil Type ◽  
Contact Time ◽  
Agricultural Land ◽  
Ph Value ◽  
Freundlich Isotherm ◽  
Maximum Adsorption Capacity ◽  
Dominant Form

[CHARACTERIZATION OF THE  ADSORPTION FROM IRON METAL IONS ISOTHERM ON THE SOIL IN BENGKULU CITY] Level of micronutrient elements Fe takes part in determining the fertility rate of agricultural land. Continuous oxidation of Fe the soil will cause soil poisoning, due to the soil saturated in absorb of Fe. This research aims to determine the characteristics of the soil, adsorption and its ability in absorption isotherm on  Fe metal. Soil samples were taken from the farm in the city of Bengkulu. The characteristics of the soil tested, i.e., water content, pH, and soil type. Adsorption isotherm type is a determination as Langmuir or  Freundlich isotherm. Soil sample after it is dried and cleaned and then milled and sieved at 100 mesh sieve. Moisture content is measured by dried in an oven for 24 hours and the measurement of the difference between the initial and the final weight of the soil. Determination of soil pH is measured by the pH meter on the CaCl2, and soil type is determined by calculating the percentage of sand, silt, and clay from the soil. Maximum adsorption capacity is determined from Fe adsorption isotherm after getting the pH, the weight of adsorbent and optimum contact time. Adsorption Isotherm was determined by adsorption of aqueous Fe variation at the concentration of  2.5; 5; 10; 15; 20; and 25 ppm on optimum pH and weight, and stirred at an optimum contact time, then filtered and measured its absorbance with UV-Vis spectrophotometer. Results of research results in the form of moisture content average 23.5%, soil pH value at 5 and soil type, i.e., dusty clay with the dominant form of Isotherm adsorption is a Freundlich isotherm, and the capacity of soil in adsorbing of iron on this research obtained is amounting to 45.6.

Synthesis and Characterization of Chitosan templated Mesoporous Silica: Efficient use of Mesoporous Silica in the removal of Cu(II) from Aqueous Solutions

2016 ◽  
Vol 4 (2) ◽  
pp. 105-112
Author(s):  
Lalchhing puii ◽  
◽  
Seung-Mok Lee ◽  
Diwakar Tiwari ◽  
◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Aqueous Solutions ◽  
Background Electrolyte ◽  
Second Order ◽  
Order Kinetic ◽  
Sorption Data ◽  
Column Reactor ◽  
Wide Ph Range ◽  
Freundlich Adsorption Isotherm ◽  
Pseudo Second Order

A mesoporous silica was synthesized by annealing (3-Aminopropyl) triethoxysilane grafted chitosan at 800˚C. The mesoporous silica was characterized by the XRD (X-ray diffraction) analysis. The BET specific surface area and pore size of silica was found to be 178.42 m2/g and 4.13 nm. The mesoporous silica was then employed for the efficient remediation of aqueous solutions contaminated with Cu(II) under batch and column reactor operations. The mesoporous silica showed extremely high per cent removal of Cu(II) at wide pH range i.e., pH ~2.0 to 7.0. Relatively a fast uptake of Cu(II) was occurred and high percentage removal was obtained at initial concentrations studied from 1.0 to 15.0 mg/L. The equilibrium state sorption data were utilized for the Langmuir and Freundlich adsorption isotherm studies. Moreover, the effect of an increase in background electrolyte concentrations from 0.0001 to 0.1 mol/L NaNO3 was assessed for the uptake of Cu(II) by mesoporous silica. The equilibrium sorption was achieved within 240 min of contact and the kinetic data is best fitted to the pseudo-second-order and fractal like pseudo-second-order kinetic models. In addition, the mesoporous silica was used for dynamic studies under column reactor operations. The breakthrough curve was then used for the non-linear fitting of the Thomas equation and the loading capacity of the column for Cu(II) was estimated.

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