scholarly journals Contact Melting of Metals Explained via the Theory of Quasi-Liquid Layer

2020 ◽  
Vol 11 (1) ◽  
pp. 51
Author(s):  
Alexey V. Melkikh

It has been shown that the contact melting rate for metals is determined by the fact that at least one of them has a quasi-liquid layer on the surface. As a result, the diffusion of metal atoms occurs in the liquid phase, and not in the solid phase, which determines the characteristic contact melting time (seconds and minutes).

2021 ◽  
Vol 11 (8) ◽  
pp. 3443
Author(s):  
Chan Ho Jeong ◽  
Kwangu Kang ◽  
Ui-Joon Park ◽  
Hyung Ju Lee ◽  
Hong Seok Kim ◽  
...  

This study investigates the transient behavior of an electro-thermal drilling probe (ETDP) during a close-contact melting process within a glacier. In particular, the present work analyzes the effect of the tip temperature on the formation of molten thin liquid films and the subsequent rate of penetration (ROP) through numerical simulation. We used the commercial code of ANSYS Fluent (v.17.2) to solve the Reynolds-averaged Navier–Stokes equation, together with an energy equation considering the solidification and melting model. The ROP of the drilling probe is determined based on the energy balance between the heating power and melting rate of ice. As the results, the ETDP penetrates the ice through a close-contact melting process. The molten liquid layer with less than 1 mm of thickness forms near the heated probe tip. In addition, the ROP increases with the heated temperature of the probe tip.


Author(s):  
A. Rozenfeld ◽  
Y. Kozak ◽  
T. Rozenfeld ◽  
G. Ziskind

This research is an experimental investigation of a double-pipe heat storage unit. The inner pipe of the unit, through which a heat-transfer fluid (HTF) is supplied, is made of aluminum and has an outer helix-like fin. The annular space between the pipes is filled with a phase change material (PCM). Actually, this research presents a novel design of the heat storage unit, which, unlike traditional designs with e.g. radial (circumferential) or longitudinal fins, has a single fin which does not divide the shell volume into separated cells. Moreover, this research focuses on close-contact melting (CCM), a process which is characterized by detachment of the solid bulk from the unit envelope and its sinking towards the hot fin surface. In previous investigations, performed in our laboratory, this effect has been achieved in units with above-mentioned traditional fin configurations. It was demonstrated that CCM reduces the overall melting time, i.e. the rate of unit charging, significantly as compared with commonly encountered melting in which the fins serve just to enlarge the heat transfer area. The experimental system employed in this study includes a vertically-oriented double-pipe heat storage unit and thermostatic baths capable of providing hot or cold HTF. The unit has a transparent Perspex shell which makes visualization possible. The entire unit may be placed in a heated water tank with transparent walls. In the latter case, close-contact melting is achieved by detaching the solid phase from the envelope and thus allowing its gravity-induced motion. Regular melting is compared to CCM and advantages of the latter are demonstrated. Also demonstrated are the advantages of the novel fin, including in solidification. Possible mathematical and numerical modeling of the melting processes is discussed.


Author(s):  
C.D. Humphrey ◽  
T.L. Cromeans ◽  
E.H. Cook ◽  
D.W. Bradley

There is a variety of methods available for the rapid detection and identification of viruses by electron microscopy as described in several reviews. The predominant techniques are classified as direct electron microscopy (DEM), immune electron microscopy (IEM), liquid phase immune electron microscopy (LPIEM) and solid phase immune electron microscopy (SPIEM). Each technique has inherent strengths and weaknesses. However, in recent years, the most progress for identifying viruses has been realized by the utilization of SPIEM.


Author(s):  
N. A. Bulychev

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.


Biomolecules ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1014
Author(s):  
Macy L. Sprunger ◽  
Meredith E. Jackrel

Aberrant protein folding underpins many neurodegenerative diseases as well as certain myopathies and cancers. Protein misfolding can be driven by the presence of distinctive prion and prion-like regions within certain proteins. These prion and prion-like regions have also been found to drive liquid-liquid phase separation. Liquid-liquid phase separation is thought to be an important physiological process, but one that is prone to malfunction. Thus, aberrant liquid-to-solid phase transitions may drive protein aggregation and fibrillization, which could give rise to pathological inclusions. Here, we review prions and prion-like proteins, their roles in phase separation and disease, as well as potential therapeutic approaches to counter aberrant phase transitions.


2000 ◽  
Vol 2000 ◽  
pp. 144-144
Author(s):  
A.J. Ayala-Burgos ◽  
F.D.DeB. Hovell ◽  
R.M. Godoy ◽  
Hamana S. Saidén ◽  
R. López ◽  
...  

Cattle in the tropics mostly depend on pastures. During dry periods the forage available is usually mature, constraining both intake and digestion. These constraints need to be understood, for intake and digestibility define productivity. Intake depends on the rumen space made available by fermentation and outflow. Markers such as PEG (liquid phase), and chromium mordanted fibre (solid phase) can be used to measure rumen volume and outflow, but have limitations. The objective of this experiment was to measure intake, digestibility, and rumen kinetics of cattle fed ad libitum forages with very different degradation characteristics, and also to compare rumen volumes measured with markers with those obtained by manual emptying.


1998 ◽  
Vol 22 ◽  
pp. 306-308
Author(s):  
M. D. Carro ◽  
E. L. Miller

The estimation of rumen microbial protein synthesis is one of the main points in the nitrogen (N)-rationing systems for ruminants, as microbial protein provides proportionately 0.4 to 0.9 of amino acids entering the small intestine in ruminants receiving conventional diets (Russell et al., 1992). Methods of estimating microbial protein synthesis rely on marker techniques in which a particular microbial constituent is related to the microbial N content. Marker : N values have generally been established in mixed bacteria isolated from the liquid fraction of rumen digesta and it has been assumed that the same relationship holds in the total population leaving the rumen (Merry and McAllan, 1983). However, several studies have demonstrated differences in composition between solid-associated (SAB) and fluid-associated bacteria in vivo (Legay-Carmier and Bauchart, 1989) and in vitro (Molina Alcaide et al, 1996), as well in marker : N values (Pérez et al., 1996). This problem could be more pronounced in the in vitro semi-continuous culture system RUSITEC, in which there are three well defined components (a free liquid phase, a liquid phase associated with the solid phase and a solid phase), each one having associated microbial populations.The objective of this experiment was to investigate the effect of using different bacterial isolates (BI) on the estimation of microbial production of four different diets in RUSITEC (Czerkawski and Breckenridge, 1977), using (15NH4)2 SO4 as microbial marker, and to assess what effects any differences would have on the comparison of microbial protein synthesis between diets.This study was conducted in conjunction with an in vitro experiment described by Carro and Miller (1997). Two 14-day incubation trials were carried out with the rumen simulation technique RUSITEC (Czerkawski and Breckenridge, 1977). The general incubation procedure was the one described by Czerkawski and Breckenridge (1977) and more details about the procedures of this experiment are given elsewhere (Carro and Miller, 1997).


2008 ◽  
Vol 8 (23) ◽  
pp. 7087-7099 ◽  
Author(s):  
W. Liao ◽  
D. Tan

Abstract. A 1-D air-snowpack model of HONO has been developed and constrained by observed chemistry and meteorology data. The 1-D model includes molecular diffusion and mechanical dispersion, windpumping in snow, gas phase to quasi-liquid layer phase HONO transfer and quasi-liquid layer nitrate and interstitial air HONO photolysis. Photolysis of nitrate is important as a dominant HONO source inside the snowpack, however, the observed HONO emission from the snowpack was triggered mainly by the equilibrium between quasi liquid layer nitrite and firn air HONO deep down the snow surface (i.e. 30 cm below snow surface). The high concentration of HONO in the firn air is subsequently transported above the snowpack by diffusion and windpumping. The model uncertainties come mainly from lack of measurements and the interpretation of the QLL properties based on the bulk snow measurements. One critical factor is the ionic strength of QLL nitrite, which is estimated here by the bulk snow pH, nitrite concentration, and QLL to bulk snow volume ratio.


2008 ◽  
Vol 8 (16) ◽  
pp. 4855-4864 ◽  
Author(s):  
C. S. Boxe ◽  
A. Saiz-Lopez

Abstract. We utilize a multiphase model, CON-AIR (Condensed Phase to Air Transfer Model), to show that the photochemistry of nitrate (NO3−) in and on ice and snow surfaces, specifically the quasi-liquid layer (QLL), can account for NOx volume fluxes, concentrations, and [NO]/[NO2] (γ=[NO]/[NO2]) measured just above the Arctic and coastal Antarctic snowpack. Maximum gas phase NOx volume fluxes, concentrations and γ simulated for spring and summer range from 5.0×104 to 6.4×105 molecules cm−3 s−1, 5.7×108 to 4.8×109 molecules cm−3, and ~0.8 to 2.2, respectively, which are comparable to gas phase NOx volume fluxes, concentrations and γ measured in the field. The model incorporates the appropriate actinic solar spectrum, thereby properly weighting the different rates of photolysis of NO3− and NO2−. This is important since the immediate precursor for NO, for example, NO2−, absorbs at wavelengths longer than nitrate itself. Finally, one-dimensional model simulations indicate that both gas phase boundary layer NO and NO2 exhibit a negative concentration gradient as a function of height although [NO]/[NO2] are approximately constant. This gradient is primarily attributed to gas phase reactions of NOx with halogens oxides (i.e. as BrO and IO), HOx, and hydrocarbons, such as CH3O2.


Sign in / Sign up

Export Citation Format

Share Document