scholarly journals The Impact Resistance of Highly Densified Metal Alloys Manufactured from Gas-Atomized Pre-Alloyed Powders

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 216
Author(s):  
Ramin Rahmani ◽  
Maksim Antonov ◽  
Konda Gokuldoss Prashanth
Keyword(s):  
Physical Vapor Deposition ◽  
Impact Resistance ◽  
Three Dimensional ◽  
Metal Alloys ◽  
Powder Bed ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
3D Printed ◽  
Printed Materials ◽  
The Impact

With the increasing acceleration of three-dimensional (3D) printing (for example, powder bed fusion (PBF)) of metal alloys as an additive manufacturing process, a comprehensive characterization of 3D-printed materials and structures is inevitable. The purpose of this work was to test highly densified materials produced from gas-atomized pre-alloyed metallic powders, namely 316L, Ti6Al4V, AlSi10Mg, CuNi2SiCr, CoCr28Mo6, and Inconel718, under impact conditions. This was done to demonstrate the best possible performance of such materials. Optimized spark plasma sintering (SPS) parameters (pressure, temperature, heating rate, and holding time) are applied as a novel technique of powder metallurgy. The densification level, impact site (imprint) diameter and volume, and Vickers hardness were studied. The comparison of 316L stainless steel (1) sintered by the SPS process, (2) manufactured by PBF process, and (3) coated by the physical vapor deposition (PVD) process (thin layer of TiAlN) was successfully achieved.

scholarly journals Sintered and 3D-Printed Bulks of MgB2-Based Materials with Antimicrobial Properties

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 6045
Author(s):  
Petre Badica ◽  
Nicolae Dan Batalu ◽  
Mariana Carmen Chifiriuc ◽  
Mihail Burdusel ◽  
Mihai Alexandru Grigoroscuta ◽  
...  
Keyword(s):  
Antimicrobial Properties ◽  
Bacterial Strains ◽  
E Coli ◽  
Plasma Sintering ◽  
Complex Shapes ◽  
Spark Plasma ◽  
Powder Particles ◽  
3D Printed ◽  
Printed Materials

Pristine high-density bulk disks of MgB2 with added hexagonal BN (10 wt.%) were prepared using spark plasma sintering. The BN-added samples are machinable by chipping them into desired geometries. Complex shapes of different sizes can also be obtained by the 3D printing of polylactic acid filaments embedded with MgB2 powder particles (10 wt.%). Our present work aims to assess antimicrobial activity quantified as viable cells (CFU/mL) vs. time of sintered and 3D-printed materials. In vitro antimicrobial tests were performed against the bacterial strains Escherichia coli ATCC 25922, Pseudomonas aeruginosa ATCC 27853, Staphylococcus aureus ATCC 25923, Enterococcus faecium DSM 13590, and Enterococcus faecalis ATCC 29212; and the yeast strain Candida parapsilosis ATCC 22019. The antimicrobial effects were found to depend on the tested samples and microbes, with E. faecium being the most resistant and E. coli the most susceptible.

scholarly journals Vacuum brazing of Al2O3 and 3D printed Ti6Al4V lap-joints using high entropy driven AlZnCuFeSi filler

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ashutosh Sharma ◽  
Byungmin Ahn
Keyword(s):  
Strength Properties ◽  
Lap Joints ◽  
High Entropy Alloy ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
3D Printed ◽  
Face Centered ◽  
Alloy Filler

AbstractIn this work, we studied the brazing characteristics of Al2O3 and 3D printed Ti–6Al–4V alloys using a novel equiatomic AlZnCuFeSi high entropy alloy filler (HEAF). The HEAF was prepared by mechanical alloying of the constituent powder and spark plasma sintering (SPS) approach. The filler microstructure, wettability and melting point were investigated. The mechanical and joint strength properties were also evaluated. The results showed that the developed AlZnCuFeSi HEAF consists of a dual phase (Cu–Zn, face-centered cubic (FCC)) and Al–Fe–Si rich (base centered cubic, BCC) phases. The phase structure of the (Cu–Al + Ti–Fe–Si)/solid solution promises a robust joint between Al2O3 and Ti–6Al–4V. In addition, the joint interfacial reaction was found to be modulated by the brazing temperature and time because of the altered activity of Ti and Zn. The optimum shear strength reached 84 MPa when the joint was brazed at 1050 °C for 60 s. The results can be promising for the integration of completely different materials using the entropy driven fillers developed in this study.

scholarly journals Influence of CFRC Insulating Plates on Spark Plasma Sintering Process

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 393
Author(s):  
Alexander M. Laptev ◽  
Jürgen Hennicke ◽  
Robert Ihl
Keyword(s):  
Temperature Distribution ◽  
Spark Plasma Sintering ◽  
Energy Demand ◽  
Composite Powders ◽  
Fem Method ◽  
Plasma Sintering ◽  
Axial Temperature ◽  
Spark Plasma ◽  
Power And Energy ◽  
The Impact

Spark Plasma Sintering (SPS) is a technology used for fast consolidation of metallic, ceramic, and composite powders. The upscaling of this technology requires a reduction in energy consumption and homogenization of temperature in compacts. The application of Carbon Fiber-Reinforced Carbon (CFRC) insulating plates between the sintering setup and the electrodes is frequently considered as a measure to attain these goals. However, the efficiency of such a practice remains largely unexplored so far. In the present paper, the impact of CFRC plates on required power, total sintering energy, and temperature distribution was investigated by experiments and by Finite Element Modeling (FEM). The study was performed at a temperature of 1000 °C with a graphite dummy mimicking an SPS setup. A rather moderate influence of CFRC plates on power and energy demand was found. Furthermore, the cooling stage becomes considerably longer. However, the application of CFRC plates leads to a significant reduction in the axial temperature gradient. The comparative analysis of experimental and modeling results showed the good capability of the FEM method for prediction of temperature distribution and required electric current. However, a discrepancy between measured and calculated voltage and power was found. This issue must be further investigated, considering the influence of AC harmonics in the DC field.

scholarly journals A Study of the Impact of Graphite on the Kinetics of SPS in Nano- and Submicron WC-10%Co Powder Compositions

Ceramics ◽  
2021 ◽  
Vol 4 (2) ◽  
pp. 331-363
Author(s):  
Eugeniy Lantcev ◽  
Aleksey Nokhrin ◽  
Nataliya Malekhonova ◽  
Maksim Boldin ◽  
Vladimir Chuvil'deev ◽  
...  
Keyword(s):  
Activation Energy ◽  
Solid Phase ◽  
Continuous Heating ◽  
Diffusion Creep ◽  
Hard Alloys ◽  
Fine Grained ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
The Impact ◽  
Kinetics Of

This study investigates the impact of carbon on the kinetics of the spark plasma sintering (SPS) of nano- and submicron powders WC-10wt.%Co. Carbon, in the form of graphite, was introduced into powders by mixing. The activation energy of solid-phase sintering was determined for the conditions of isothermal and continuous heating. It has been demonstrated that increasing the carbon content leads to a decrease in the fraction of η-phase particles and a shift of the shrinkage curve towards lower heating temperatures. It has been established that increasing the graphite content in nano- and submicron powders has no significant effect on the SPS activation energy for “mid-range” heating temperatures, QS(I). The value of QS(I) is close to the activation energy of grain-boundary diffusion in cobalt. It has been demonstrated that increasing the content of graphite leads to a significant decrease in the SPS activation energy, QS(II), for “higher-range” heating temperatures due to lower concentration of tungsten atoms in cobalt-based γ-phase. It has been established that the sintering kinetics of fine-grained WC-Co hard alloys is limited by the intensity of diffusion creep of cobalt (Coble creep).

Effect of Spark Plasma Sintering on the Microstructure Evolution and Properties of M3:2 High-Speed Steel

2014 ◽  
Vol 788 ◽  
pp. 329-333
Author(s):  
Rui Zhou ◽  
Xiao Gang Diao ◽  
Jun Chen ◽  
Xiao Nan Du ◽  
Guo Ding Yuan ◽  
...  
Keyword(s):  
Powder Metallurgy ◽  
Spark Plasma Sintering ◽  
High Speed ◽  
Bending Strength ◽  
Sintering Temperature ◽  
High Speed Steel ◽  
Continuous Heating ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
The Impact

Effects of sintering temperatures on the microstructure and mechanical performance of SPS M3:2 high speed steel prepared by spark plasma sintering was studied. High speed steel sintering curve of continuous heating from ambient temperature to 1200°C was estimated to analyze the sintering processes and sintering temperature range. The sintering temperature within this range was divided into groups to investigate hardness, relative density and microstructure of M3:2 high-speed steel. Strip and quadrate carbides were observed inside the equiaxed grains. SPS sintering temperature at 900°C can lead to nearly full densification with grain size smaller than 20μm. The hardness and bending strength are higher than that of the conventionally powder metallurgy fabricated ones sintered at 1270°C. However, fracture toughness of the high speed steel is lower than that of the conventional powder metallurgy steels. This can be attributed to the shape and distribution of M6C carbides which reduce the impact toughness of high speed steels.

scholarly journals Crystallization Kinetics and Consolidation of Al82La10Fe4Ni4 Glassy Alloy Powder by Spark Plasma Sintering

Metals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 812
Author(s):  
Nguyen Viet ◽  
Nguyen Oanh ◽  
Ji-Soon Kim ◽  
Alberto Jorge
Keyword(s):  
Nucleation Rate ◽  
Glassy Alloy ◽  
Intermetallic Phase ◽  
Three Dimensional ◽  
Sample Surface ◽  
Sintered Sample ◽  
Amorphous Structure ◽  
Mechanically Alloyed ◽  
Plasma Sintering ◽  
Spark Plasma

The mechanically alloyed Al82La10Ni4Fe4 glassy powder displays a two-step devitrification characterized by the precipitation of fcc-Al together with small amounts of the intermetallic Al11La3 phase in the first crystallization. The interface-controlled growth mechanism governed the first crystallization event. Calculations of the activation energy, using the methods of Kissinger, Ozawa, and Augis-Bennett gave values of 432.33, 443.2, and 437.76 kJ/mol, respectively. The calculated Avrami exponent (n) for the first crystallization peak was about 1.41, suggesting an almost zero nucleation rate. On the other hand, the value of n for the second peak related to the residual amorphous phase completely transformed into the intermetallic phase Al11La3 was about 3.61, characterizing diffusion controlled three-dimensional crystal growth with an increasing nucleation rate. Samples sintered at 573 K kept an amorphous structure and exhibited a high compressive strength of 650 MPa with a maximum elongation of 2.34% without any plastic deformation. The failure morphology of the sintered sample surface presented a transparticle fracture mechanism, indicating the efficiency of the sintering processing.

Enhancing Mechanical Properties of Various Sintered Pellets with Nano-Additives

2021 ◽  
Vol 410 ◽  
pp. 62-67
Author(s):  
Tien Hiep Nguyen ◽  
Yury V. Konyukhov ◽  
Van Minh Nguyen
Keyword(s):  
Mechanical Properties ◽  
Spark Plasma Sintering ◽  
Bending Strength ◽  
Size Range ◽  
Pressureless Sintering ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Nano Additives ◽  
Free Spaces ◽  
The Impact

The impact of Fe, Co, Ni nano-additives on the density, microhardness and bending strength was investigated for several sintered pellets. Fe, Co, Ni nanopowders (NP) were prepared in the size range 67-94 nm using chemical metallurgy techniques. These powders (0.5 wt. %) were dispersed into three sets of micron powders: Co (+0.5 wt. % Co NP); Fe (+0.5 wt. % Fe NP); Fe+0.5wt. % C (+0.5 wt. % Co and 0.5 wt. % Ni NP). Mixtures were further mixed and processed using a magnetic mill and a turbulent mixer. Sintering was carried out using spark plasma sintering (SPS) as well as pressureless sintering (PS). The densities of sintered pellets were found to increase by 2.5-3% (SPS) and 3-5% (PS) in the presence of nano-additives; corresponding increases in microhardness and bending strength were determined to be 7.9-11.1% and 17.9-38.7%, respectively. These results are discussed in terms enhanced packing due to interparticle sliding and the filling of free spaces with the nanodisperse phase.

Effect of 3D Manipulatives on Students with Visual Impairments Who Are Learning Chemistry Constructs: A Pilot Study

2020 ◽  
Vol 114 (5) ◽  
pp. 370-381
Author(s):  
Derrick W. Smith ◽  
Sandra A. Lampley ◽  
Bob Dolan ◽  
Greg Williams ◽  
David Schleppenbach ◽  
...  
Keyword(s):  
Stem Education ◽  
3D Model ◽  
Atomic Orbital ◽  
Visual Impairments ◽  
Three Dimensional ◽  
3D Models ◽  
Specific Content ◽  
3D Printed ◽  
Printed Materials ◽  
Tactile Graphics

Introduction: The emerging technology of three-dimensional (3D) printing has the potential to provide unique 3D modeling to support specific content in science, technology, engineering, and mathematics (STEM) education, particularly chemistry. Method: Seventeen ( n = 17) students with visual impairments were provided direct instruction on chemistry atomic orbital content and allowed to use either print or tactile graphics or 3D models in rotating order. Participants were asked specific content questions based upon the atomic orbitals. Results: The students were asked two sets of comprehension questions: general and specific. Overall, students’ responses for general questions increased per iteration regardless of which manipulative was used. For specific questions, the students answered more questions correctly when using the 3D model regardless of order. When asked about their perceptions toward the manipulatives, the students preferred the 3D model over print or tactile graphics. Discussion: The findings show the potential for 3D printed materials in learning complex STEM content. Although the students preferred the 3D models, they all mentioned that a combination of manipulatives helped them better understand the material. Implications for practitioners: Practitioners should consider the use of manipulatives that include 3D printed materials to support STEM education.

Characteristic and Sinterability of Alumina-Zirconia-Yttria Nanoparticles Prepared by Different Chemical Methods

2014 ◽  
Vol 87 ◽  
pp. 30-35
Author(s):  
Janis Grabis ◽  
Dzidra Jankovica ◽  
Ints Steins ◽  
Krisjanis Smits ◽  
Inta Sipola
Keyword(s):  
Phase Transition ◽  
Spark Plasma Sintering ◽  
Molten Salts ◽  
Preparation Method ◽  
Bulk Materials ◽  
Chemical Methods ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
The Impact ◽  
Sintering Method

The characteristics and sinterability of the Al2O3-ZrO2(Y2O3) nanoparticles produced by simple and effective microwave and molten salts methods and processed by using spark plasma sintering were studied and compared. The crystalline powders with the specific surface area in the range of 72–108 m2/g and crystallite size of 5–13 nm were obtained by calcination of samples prepared by both methods at 800 °C. The content of t-ZrO2 phase depends on concentration of Al2O3, Y2O3 and on calcination temperature but the impact of the preparation method is insignificant. The phase transition of tetragonal ZrO2 to monoclinic for the samples without Y2O3 started at 1000 °C though it was incomplete in the case of high content of Al2O3. The bulk materials with relative density of 86.1–98.7% were fabricated by the spark plasma sintering method at 1500–1600 °C depending on the content of Al2O3 and Y2O3.

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