scholarly journals Impact of Aggressive Media on the Properties of Polymeric Coatings with Solidification Products as Fillers

Coatings ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 793 ◽  
Author(s):  
Jakub Hodul ◽  
Lenka Mészárosová ◽  
Tomáš Žlebek ◽  
Rostislav Drochytka ◽  
Zdeněk Dufek

Dealing with waste materials, particularly hazardous waste, is a serious problem. Disposal areas keep growing, and the costs incurred are high. Disposing of such waste reduces negative environmental impacts and offers considerable financial savings. This paper focuses on the possibilities of incorporating pollutants found in hazardous wastes as fillers in coatings based on polymers (epoxide and polyurethane). These coatings are intended mainly for concrete and metal bases and offer secondary protection against adverse weather conditions. Important physical and mechanical properties of the newly developed materials were determined; they include surface hardness, impact resistance, tensile properties, and chemical resistance. These properties were also compared to those of the reference filler. At the same time, the influence of aggressive media on the properties of these materials was observed, in particular on flexural characteristics. The microstructures of the developed coatings were tested using a high-resolution optical microscope, before and after exposure to the chemicals. The positive effect of using progressive fillers, such as solidified hazardous waste (a solidification product (SF)), was witnessed by their constructive contribution to the materials’ physical and mechanical properties. The use of solidification products is unambiguously advantageous from technical, ecological, and economical stand points (utilization of hazardous waste as a progressive filler instead of landfilling, improvement of tensile properties, reduction in the price of coating system, and incorporation of the pollutants into the polymer matrix).

2015 ◽  
Vol 63 (4) ◽  
pp. 397-404
Author(s):  
Graziella Morfim Schramm ALIGNANI ◽  
Juliana Maria Costa Nuñez PANTOJA ◽  
Jessica Mie Ferreira Koyama TAKAHASHI ◽  
Andréa Araújo de VASCONCELLOS ◽  
Marcelo Ferraz MESQUITA ◽  
...  

Objective: To evaluate the effect of aging in a hard denture reline (New Truliner) and an acrylic resin (Classic) after chemical and mechanical polishing. Methods: Eighty specimens were made, divided randomly between 8 groups: G1.Acrylic Resin Classic (RAC)/Mechanical Polishing (PM); G2.RAC/PM + thermocycling (TR); G3) RAC/Chemical Polishing (PQ); G4.RAC/PQ + TR; G5.New Truliner (NT)/PM; G6.NT/PM + TR; G7. NT/PQ; G8.NT/PQ + TR. The surface hardness was measured before and after polishing, and after TR. The impact resistance tests were measured after all applied treatments. The data were submitted to ANOVA and Tukey test (a=5%). Results: Regardless of the polishing, it was noted that RAC presented significantly higher surface hardness than NT; PM had higher hardness in both materials compared with PQ; on both polishing, the impact resistance of the RAC was higher than NT. Independently of TR test, the impact resistance of the materials that received PQ was higher than received PM. The PQ caused greater changes in properties than the PM. Conclusion: Aging and chemical and mechanical polishing influenced the physical and mechanical properties of hard denture reline and acrylic resin.


Alloy Digest ◽  
2008 ◽  
Vol 57 (3) ◽  

Abstract Ansonia alloy C14500 has unique fabrication properties while maintaining both physical and mechanical properties close to pure copper. The addition of Tellurium makes the alloy free machining. This datasheet provides information on composition, physical properties, hardness, tensile properties, and shear strength. It also includes information on forming, heat treating, machining, and joining. Filing Code: CU-752. Producer or source: Ansonia Copper & Brass Inc.


2021 ◽  
Vol 29 (1) ◽  
pp. 21-34
Author(s):  
Vera G. Matveeva ◽  
Mariam Yu. Khanova ◽  
Tatyana V. Glushkova ◽  
Larisa V. Antonova

Aim. To evaluate the potential utility of fibrin matrices containing 10, 20, and 25 mg/ml of fibrinogen (fibrin-10, fibrin-20, and fibrin-30, respectively) in vascular tissue engineering (VTE). Materials and Methods. Fibrinogen was isolated using the method of ethanol cryoprecipitation and polymerized using a solution of thrombin and CaCl2. The fibrin structure was studied in a scanning electron microscope, and the physical and mechanical properties of the material were tested on a Zwick/Roell test machine. The metabolic activity of endothelial cells (EC) on the fibrin surface was evaluated by the MTT assay, and the viability of fibroblasts in the thickness of fibrin and possibility for migration by in fluorescent and light microscopy. Percent of fibrin shrinkage was determined from the difference in the sample volumes before and after removal of moisture. Results. The fiber diameter did not differ among all fibrin samples, but the pore diameter in fibrin-30 was smaller than those in fibrin-10 and fibrin-20. A possibility for migration of fibroblasts into the depth of the fibrin matrix and preservation of 97-100% viability of cells at a depth 5 mm was confirmed. The metabolic activity of EC on the surface of fibrin-20 and fibrin-30 exceeded that on collagen, fibronectin, and fibrin-10. All fibrin samples shrank in volume to 95.5-99.5%, and the highest shrinkage was seen in fibrin-10. The physical and mechanical properties of fibrin were inferior to those of human A. mammaria by a factor of 10. Conclusion. Fibrin with fibrinogen concentrations of 20 and 30 mg/ml maintains a high metabolic and proliferative activity of EC on the surface and also a high viability of fibroblasts in the matrix. Its availability, ease of preparation, and a number of other favorable properties make fibrin a promising material for VTE. However, the problem of insufficient strength requires further investigations.


2007 ◽  
Vol 546-549 ◽  
pp. 257-260 ◽  
Author(s):  
Zhen Yan Zhang ◽  
Li Ming Peng ◽  
Xiao Qin Zeng ◽  
Lin Du ◽  
Lan Ma ◽  
...  

Effects of extrusion on mechanical properties and damping capacity of Mg-1.8wt.%Cu -0.5wt.%Mn (MCM1805) alloy have been investigated. Tensile tests and dynamic mechanical analyzer were respectively used to measure tensile properties and damping capacity at room temperature of as-cast and as-extruded MCM1805 alloy. The microstructure was studied using optical microscope, X-ray diffraction and scanning electron microscope with an energy dispersive X-ray spectrometer. Granato-Lücke model was used to explain the influences of extrusion on damping capacity of MCM1805 alloy. The results showed that extrusion dramatically decreases the grain size but has little influence on phase composition and solute atoms concentration of MCM1805 alloy, and the grain refinement was the dominant reason for the obvious increase of tensile properties and decrease of internal friction of MCM1805 alloy.


2017 ◽  
Vol 863 ◽  
pp. 323-327 ◽  
Author(s):  
Yustiasih Purwaningrum ◽  
Panji Lukman Tirta Kusuma ◽  
Dwi Darmawan

The aimed of this research is to investigate the effect of T-Joint’s root gap on physical and mechanical properties of weld metal. Low carbon steel were joined in T-joint types using MIG (Metal Inert Gas) with variation of root gap. The root gap used were 0 mm, 3 mm and 6 mm. The physical properties examined with chemical composition, microstructure and corrosion using optical microscope. The mechanical properties were measured with respect to the strength and hardness using Universal testing machine and Vickers Microhardness. The results show that the highest value found in welds with a gap of 3 mm with a value of 163.57 MPa. Hardness value is directly proportional to the tensile strength of the material. The highest value found in welds with root gap of 3 mm, followed by root gap of 6 mm, and 0 mm Hardness values in the welding area is higher than the parent metal and HAZ because the number of Si, Mn and Cu elements in the welding metals are bigger than base metal. Weld with all variation of root gap have a good corrosion resistance because the corrosion rate in welds with various root gap have a value below 0.02 mmpy. Microstructure of weld metals were Accicular ferrite, Widmanstatten ferrite, and grain boundary ferrite, while microstructure of base metal and HAZ were ferrite and perlite.


Holzforschung ◽  
2007 ◽  
Vol 61 (2) ◽  
pp. 148-154 ◽  
Author(s):  
Xiaolin Cai ◽  
Bernard Riedl ◽  
S.Y. Zhang ◽  
Hui Wan

Abstract Wood polymer nanocomposites were prepared from solid aspen wood, water-soluble melamine-urea-formaldehyde (MUF) resin, and silicate nanoclays. The nanofillers were ground with a ball-mill before being mixed with the MUF resin and impregnated into the wood. The water-soluble prepolymer was mixed with the nanoclays at a mixing speed of 3050 rpm for 20 min to form impregnation solutions. Wood was impregnated with resin, which polymerized in situ under certain conditions. The physical and mechanical properties of the composite and the effect of ball-milling treatment of nanofillers on these properties were investigated. Significant improvements in physical and mechanical properties, such as density, surface hardness, and modulus of elasticity, were obtained for specimens impregnated with MUF resin and nanoclay-MUF resin mixtures. Ball-mill treatment favors dispersion of the nanofillers into the wood, but also appears to interfere with particle-resin adhesion.


2012 ◽  
Vol 476-478 ◽  
pp. 1930-1933 ◽  
Author(s):  
Jie Gao ◽  
Ge Wang ◽  
Hai Tao Cheng ◽  
Sheldon Q. Shi

The objectives of the current study involve in situ depositing treatments of calcium carbonate particles onto bamboo fibers through the ionic reaction of sodium carbonate and calcium chloride aqueous solution at varied bath temperatures, and their impacts on surface features, wettability and tensile properties of single bamboo fibers. Field emission scanning electron microscopy was employed to characterize surface morphology of fibers. The wettability of bamboo fibers was evaluated by optical contact angle measurement instrument. The results show that nanoparticles and submicron particles grew into the wrinkles and micropores of fibers, the size, morphology and adsorbance of which were distinctively varied at different bath temperatures. The highest calcium carbonate adsorbance (2.34%) was obtained at 25°C. Besides, the mean values of contact angles increased and the variations within group were reduced as the loading percentage of particles rose, which might be due to reduced hydrophilic groups after coatings of calcium carbonate particles. The treatments were approved to enhance tensile properties of single bamboo fibers, comparing to the average tensile strengh and modulus of elasticity of the untreated, those of the treated bamboo fibers with the biggest calcium carbonate loading were higher by 30.50% and 32.71% respectively. It’s proved that the precipitating treatment is a useful method to densify and hydrophobize bamboo fibers and smooth out cell wall defects. What’s more, it provide explanations for improvements of physical and mechanical properties of paper and fiber reinforced plastic composites filled with inorganic nanoparticles.


2012 ◽  
Vol 192-193 ◽  
pp. 136-141
Author(s):  
S.G. Shabestari ◽  
P. Ghaemmaghami ◽  
H. Saghafian ◽  
A. Osanlo

Attractive physical and mechanical properties of aluminum alloys make them very interesting for the automotive industry. The commercial way for manufacturing LM28 alloy is die-casting, but this process encounters several problems such as shrinkage and gas porosities. Their good mechanical properties and high resistance to wear are because of the presence of hard primary silicon particles distributed in the matrix. Therefore, the size and morphology of primary silicon and also the structure of α-Al particles in hypereutectic Al–Si alloys influence the mechanical properties of the alloys. In this research, a new process of manufacturing of this alloy has been developed using LM28 feedstock produced through cooling slope casting. The feedstocks produced via cooling slope casting had a partial globular structure that contained globules, rosettes and dendrites of α-Al. These feedstocks were thixoformed under three different pressures. The primary dendrites and rosettes changed to globular structure. The microstructure of thixoformed parts contained α-Al globules, small primary Si particles dispersed between these globules, and Al-Si eutectic phase. The mechanism of the formation of α-Al globules by this process was explained. Microstructures of as cast specimens, feedstocks produced via cooling slope, specimens that were heat treated in the semi-solid temperature and thixoformed specimens were studied with optical microscope and image analysis. The morphological changes during these processes were interpreted.


2015 ◽  
Vol 816 ◽  
pp. 750-754 ◽  
Author(s):  
Zhi Ping Hu ◽  
Yun Bo Xu ◽  
Xiao Dong Tan ◽  
Xiao Long Yang ◽  
Yong Mei Yu

In this paper, a quenching and tempering process was applied to the cold-rolled medium Mn steel with the delta ferrite (Fe-0.18C-6.4Mn-2.8Al). Microstructure characterization was carried out by means of optical microscope, scanning electron microscope (SEM) equipped with electron backscattered diffraction (EBSD) and transmission electron microscope (TEM). Mechanical properties tests were carried out by uniaxial tension tests. The microstructure characterization results revealed that the steel possessed a complex microstructure composed of three phases (austenite, martensite and delta ferrite). The volume fractions of austenite before and after a deformation were determined by X-ray diffraction (XRD). The XRD results indicated that the amount of austenite reached up to 20 vol.% and the TRIP effect occurred quite apparently. The mechanical property results showed that the steel possessed adequate ultimate tensile strength of 800MPa and excellent elongation of 25%. The outstanding combination of strength and ductility with the product of strength and elongation (PSE) reaching up to over 20GPa% indicates that the steel has a bright application prospect.


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