scholarly journals Silver Doping Mechanism in Bioceramics—From Ag+: Doped HAp to Ag°/BCP Nanocomposite

Crystals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 326 ◽  
Author(s):  
Jacobs ◽  
Gaulier ◽  
Duval ◽  
Renaudin
Keyword(s):  
Calcium Phosphates ◽  
Sol Gel ◽  
Biological Behavior ◽  
Metallic Silver ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ag Particles ◽  
Doping Mechanism ◽  
Silver Cations ◽  
Complex Doping

The results presented in this paper, based on the powder X-ray diffraction technique followed by Rietveld analyses, are devoted to the mechanism of silver incorporation in biphasic calcium phosphates. Results were confirmed by SEM observation. Samples were synthesized via the sol-gel route, followed by heat treatments. Two incorporation sites were highlighted: Ca2+ replacement by Ag+ into the calcium phosphates (HAp: hydroxyapatite and β-TCP: tricalcium phosphate), and the other as metallic silver Ag° nanoparticles (formed by autogenous reduction). The samples obtained were thus nanocomposites, written Ag°/BCP, composed of closely-mixed Ag° particles of about 100 nm at 400 °C (which became micrometric upon heating) and calcium phosphates, themselves substituted by Ag+ cations. Between 400 °C and 700 °C the cationic silver part was mainly located in the HAp phase of the composition Ca10-xAgx(PO4)6(OH)2-x (written Ag+: HAp). From 600 °C silver cations migrated to β-TCP to form the definite compound Ca10Ag(PO4)7 (written Ag+: TCP). Due to the melting point of Ag°, the doping element completely left our sample at temperatures above 1000 °C. In order to correctly understand the biological behavior of such material, which is potentially interesting for biomaterial applications, its complex doping mechanism should be taken into consideration for subsequent cytotoxic and bacteriologic studies.

scholarly journals Acetaldehyde Adsorption Characteristics of Ag/ACF Composite Prepared by Liquid Phase Plasma Method

Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2344
Author(s):  
Byung-Joo Kim ◽  
Kay-Hyeok An ◽  
Wang-Geun Shim ◽  
Young-Kwon Park ◽  
Jaegu Park ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Photoelectron Spectroscopy ◽  
Silver Oxide ◽  
Activated Carbon Fiber ◽  
Metallic Silver ◽  
X Ray Diffraction ◽  
Adsorption Experiment ◽  
X Ray ◽  
Ag Particles ◽  
Liquid Phase Plasma

Ag particles were precipitated on an activated carbon fiber (ACF) surface using a liquid phase plasma (LPP) method to prepare a Ag/ACF composite. The efficiency was examined by applying it as an adsorbent in the acetaldehyde adsorption experiment. Field-emission scanning electron microscopy and energy-dispersive X-ray spectrometry confirmed that Ag particles were distributed uniformly on an ACF surface. X-ray diffraction and X-ray photoelectron spectroscopy confirmed that metallic silver (Ag0) and silver oxide (Ag2O) precipitated simultaneously on the ACF surface. Although the precipitated Ag particles blocked the pores of the ACF, the specific surface area of the Ag/ACF composite material decreased, but the adsorption capacity of acetaldehyde was improved. The AA adsorption of ACF and Ag/ACF composites performed in this study was suitable for the Dose–Response model.

Synthesis and Luminescent Properties of Monodisperse Spherical SiO2/Ca10(PO4)6(OH)2: Eu3+ Particles with Core-Shell Structure

2014 ◽  
Vol 1004-1005 ◽  
pp. 344-347
Author(s):  
Huan Wang
Keyword(s):  
Smooth Surface ◽  
Calcium Phosphates ◽  
Sol Gel ◽  
Spherical Shape ◽  
Luminescent Properties ◽  
Core Shell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sol Gel Process ◽  
Shell Particles

The growing necessity of biomaterials has increased the interest in calcium phosphates, particularly hydroxyapatite. In this paper, monodisperse and spherical SiO2particles have been coated with Ca10(PO4)6(OH)2:Eu3+layers via a Pechini sol-gel process, resulting in core-chell ctructured SiO2/Ca10(PO4)6(OH)2:Eu3+samples. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), photoluminescence (PL) spectra were employed to characterize the SiO2/Ca10(PO4)6(OH)2:Eu3+core-shell particles. The resulted core-shell particles have perfect spherical shape with narrow size distribution, smooth surface and non-agglomeration.

Thermoelectric and Mechanical Properties of Ca0.9Yb0.1MnO3 Based Materials

2007 ◽  
Vol 1044 ◽  
Author(s):  
Atsuko Kosuga ◽  
Saori Urata ◽  
Ryoji Funahashi
Keyword(s):  
Mechanical Properties ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
Metallic Silver ◽  
Wet Milling ◽  
X Ray Diffraction ◽  
Thermoelectric Oxide ◽  
X Ray ◽  
Ag Particles ◽  
Two Phases

AbstractThe Ca0.9Yb0.1MnO3/Ag composites(the ratio of Ag to Ca0.9Yb0.1MnO3 was 0, 4.7, 9.4, and 18.8 wt %) were prepared by wet milling various amounts of Ca0.9Yb0.1MnO3 and Ag2O powder mixtures followed by sintering in order to improve the mechanical properties of Ca0.9Yb0.1MnO3 for n-type legs of thermoelectric oxide devices. The obtained composites consisted of two phases such as Ca0.9Yb0.1MnO3 and metallic silver from the X-ray diffraction (XRD) analysis. The scanning electron microscope (SEM) analysis indicated that the Ag particles, the size of which was within 5 μm, were homogeneously dispersed in Ca0.9Yb0.1MnO3 matrix for all the composites. The σf of 18.8 wt% Ag composite became 251 MPa, which was 2 times larger value than that of Ca0.9Yb0.1MnO3. The power factor (S2ρ) was slightly improved by the addition of silver particles. The maximum S2ρ, i.e. 0.26 mWm-1K-2 at 573 K was obtained for 18.8 wt% Ag composite.

scholarly journals Cuttlefish Bone-Derived Biphasic Calcium Phosphate Scaffolds Coated with Sol-Gel Derived Bioactive Glass

2019 ◽  
Author(s):  
Ana S. Neto ◽  
Daniela Brazete ◽  
José M.F. Ferreira
Keyword(s):  
Tissue Engineering ◽  
Bone Tissue Engineering ◽  
Bone Tissue ◽  
Calcium Phosphates ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
Bioactive Glasses ◽  
X Ray ◽  
Hydrothermal Transformation

The combination of calcium phosphates (CaP) with bioactive glasses (BG) has received an increased interest in the field of bone tissue engineering. In the present work, biphasic calcium phosphates (BCP) obtained by hydrothermal transformation (HT) of cuttlefish bone (CB) were coated with a Sr-, Mg- and Zn-doped sol-gel derived BG. The scaffolds were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The initial CB structure was maintained after HT and the scaffold functionalization did not jeopardize the internal structure. The results of in vitro bio-mineralization after immersing the BG coated scaffolds in simulated body fluid (SBF) showed extensive formation of bone-like apatite onto the surface of the scaffolds. Overall, the functionalized CB derived BCP scaffolds revealed promising properties for their use in bone tissue engineering field.

Control of the phase composition of advanced calcium phosphates using an x-ray diffractometer with a curved position-sensitive detector

2020 ◽  
Vol 86 (6) ◽  
pp. 29-35
Author(s):  
V. P. Sirotinkin ◽  
O. V. Baranov ◽  
A. Yu. Fedotov ◽  
S. M. Barinov
Keyword(s):  
Phase Composition ◽  
Calcium Phosphates ◽  
Position Sensitive Detector ◽  
Sensitive Detector ◽  
X Ray Diffraction ◽  
X Ray ◽  
Impurity Phases ◽  
Position Sensitive ◽  
Diffraction Peaks ◽  
Diffraction Patterns

The results of studying the phase composition of advanced calcium phosphates Ca10(PO4)6(OH)2, β-Ca3(PO4)2, α-Ca3(PO4)2, CaHPO4 · 2H2O, Ca8(HPO4)2(PO4)4 · 5H2O using an x-ray diffractometer with a curved position-sensitive detector are presented. Optimal experimental conditions (angular positions of the x-ray tube and detector, size of the slits, exposure time) were determined with allowance for possible formation of the impurity phases during synthesis. The construction features of diffractometers with a position-sensitive detector affecting the profile characteristics of x-ray diffraction peaks are considered. The composition for calibration of the diffractometer (a mixture of sodium acetate and yttrium oxide) was determined. Theoretical x-ray diffraction patterns for corresponding calcium phosphates are constructed on the basis of the literature data. These x-ray diffraction patterns were used to determine the phase composition of the advanced calcium phosphates. The features of advanced calcium phosphates, which should be taken into account during the phase analysis, are indicated. The powder of high-temperature form of tricalcium phosphate strongly adsorbs water from the environment. A strong texture is observed on the x-ray diffraction spectra of dicalcium phosphate dihydrate. A rather specific x-ray diffraction pattern of octacalcium phosphate pentahydrate revealed the only one strong peak at small angles. In all cases, significant deviations are observed for the recorded angular positions and relative intensity of the diffraction peaks. The results of the study of experimentally obtained mixtures of calcium phosphate are presented. It is shown that the graphic comparison of experimental x-ray diffraction spectra and pre-recorded spectra of the reference calcium phosphates and possible impurity phases is the most effective method. In this case, there is no need for calibration. When using this method, the total time for analysis of one sample is no more than 10 min.

PENGGUNAAN TiO2 PARTIKEL NANO HASIL SINTESIS BERBASIS AIR MENGGUNAKAN METODA SOL-GEL PADA BAHAN KAPAS SEBAGAI APLIKASI UNTUK TEKSTIL ANTI UV

Arena Tekstil ◽  
2013 ◽  
Vol 28 (1) ◽  
Author(s):  
Maya Komalasari ◽  
Bambang Sunendar
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Sol Gel ◽  
Crosslinking Agent ◽  
X Ray Diffraction ◽  
Nano Tio2 ◽  
X Ray ◽  
Infra Red ◽  
Scanning Electron

Partikel nano TiO2 berbasis air dengan pH basa telah berhasil disintesis dengan menggunakan metode sol-gel dan diimobilisasi pada kain kapas dengan menggunakan kitosan sebagai zat pengikat silang. Sintesis dilakukan  dengan prekursor TiCl4 pada konsentrasi 0,3 M, 0,5 M dan 1 M, dan menggunakan templat kanji dengan proses kalsinasi pada suhu 500˚C selama 2 jam. Partikel nano TiO2 diaplikasikan ke kain kapas dengan metoda pad-dry-cure dan menggunakan kitosan sebagai crosslinking agent. Berdasarkan hasil Scanning Electron Microscope (SEM),diketahui bahwa morfologi partikel TiO2 berbentuk spherical dengan ukuran nano (kurang dari 100 nm). Karakterisasi X-Ray Diffraction (XRD) menunjukkan adanya tiga tipe struktur kristal utama, yaitu (100), (101) dan (102) dengan fasa kristal yang terbentuk adalah anatase dan rutile. Pada karakterisasi menggunakan SEM terhadap serbuk dari TiO2 yang telah diaplikasikan ke permukaan kain kapas, terlihat adanya imobilisasi partikel nano TiO2 melalui ikatan hidrogen silang dengan kitosan pada kain kapas. Hasil analisa tersebut kemudian dikonfirmasi dengan FTIR (Fourier Transform Infra Red) yang hasilnya memperlihatkan puncak serapan pada bilangan gelombang 3495 cm-1, 2546 cm-1, dan 511 cm-1,  yang masing-masing diasumsikan sebagai adanya vibrasi gugus fungsi O-H, N-H dan Ti-O-Ti. Hasil SEM menunjukkan pula bahwa kristal nano yang terbentuk diantaranya adalah fasa rutile , yang berdasarkan literatur terbukti dapatberfungsi sebagai anti UV.

scholarly journals Y3+ substituted Sr-hexaferrites: sol-gel synthesis, structural, magnetic and electrical characterization

Cerâmica ◽  
2019 ◽  
Vol 65 (374) ◽  
pp. 274-281 ◽  
Author(s):  
S. S. Satpute ◽  
S. R. Wadgane ◽  
S. R. Kadam ◽  
D. R. Mane ◽  
R. H. Kadam
Keyword(s):  
Electron Microscopy ◽  
Sol Gel ◽  
Electrical Characterization ◽  
Combustion Method ◽  
Hexagonal Structure ◽  
Strontium Hexaferrite ◽  
X Ray Diffraction ◽  
X Ray ◽  
Morphological Studies ◽  
Auto Combustion

Abstract Y3+ substituted strontium hexaferrites having chemical composition SrYxFe12-xO19 (x= 0.0, 0.5, 1.0, 1.5) were successfully synthesized by sol-gel auto-combustion method. The structural and morphological studies of prepared samples were investigated by using X-ray diffraction technique, energy dispersive X-ray spectroscopy, field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy. The X-ray diffraction pattern confirmed the single-phase hexagonal structure of yttrium substituted strontium ferrite and the lattice parameters a and c increased with the substitution of Y3+ ions. The crystallite size also varied with x content from 60 to 80 nm. The morphology was studied by FE-SEM, and the grain size of nanoparticles ranged from 44 to 130 nm. The magnetic properties were investigated by using vibrating sample magnetometer. The value of saturation magnetization decreased from 49.60 to 35.40 emu/g. The dielectric constant decreased non-linearly whereas the electrical dc resistivity increased with the yttrium concentration in strontium hexaferrite.

scholarly journals Green synthesis and characterization of hexaferrite strontium-perovskite strontium photocatalyst nanocomposites

2020 ◽  
Vol 43 (1) ◽  
pp. 26-42 ◽  
Author(s):  
Zahra Hajian Karahroudi ◽  
Kambiz Hedayati ◽  
Mojtaba Goodarzi
Keyword(s):  
Magnetic Properties ◽  
Green Synthesis ◽  
Sol Gel ◽  
Synthesis Method ◽  
Combustion Method ◽  
Lemon Juice ◽  
X Ray Diffraction ◽  
X Ray ◽  
Auto Combustion

AbstractThis study presents a preparation of SrFe12O19– SrTiO3 nanocomposite synthesis via the green auto-combustion method. At first, SrFe12O19 nanoparticles were synthesized as a core and then, SrTiO3 nanoparticles were prepared as a shell for it to manufacture SrFe12O19–SrTiO3 nanocomposite. A novel sol-gel auto-combustion green synthesis method has been used with lemon juice as a capping agent. The prepared SrFe12O19–SrTiO3 nanocomposites were characterized by using several techniques to characterize their structural, morphological and magnetic properties. The crystal structures of the nanocomposite were investigated via X-ray diffraction (XRD). The morphology of SrFe12O19– SrTiO3 nanocomposite was studied by using a scanning electron microscope (SEM). The elemental composition of the materials was analyzed by an energy-dispersive X-ray (EDX). Magnetic properties and hysteresis loop of nanopowder were characterized via vibrating sample magnetometer (VSM) in the room temperature. Fourier transform infrared spectroscopy (FTIR) spectra of the samples showed the molecular bands of nanoparticles. Also, the photocatalytic behavior of nanocomposites has been checked by the degradation of azo dyes under irradiation of ultraviolet light.

Effect of Calcinations on Characterizations of Fabricated Nano Manganese Ferrite

2013 ◽  
Vol 634-638 ◽  
pp. 2150-2154 ◽  
Author(s):  
Rita Sundari ◽  
Tang Ing Hua ◽  
M. Rusli Yosfiah
Keyword(s):  
Sol Gel ◽  
Volatile Components ◽  
Manganese Ferrite ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Reflectance Analysis ◽  
Transmission Electron Microscope Analysis ◽  
Electron Microscope Analysis ◽  
Nano Size

A citric acid anionic surfactant has been applied for nano manganese ferrite (MnFeO3) fabrication using sol gel method. The calcinations have been varied for 300, 600 and 800oC. The UVDR (UV-Vis Diffused Reflectance) analysis shows a high absorptive band gap after 400 nm for the 600oC calcinated MnFeO3. The DTA (Differential Thermal Analysis) profiles exhibit remarkably trapped volatile matters (H2O, CO2, and NO2) in the fabricated MnFeO3 under sol gel heat treatment at 100oC and the peaks disappeared as the calcination increased to 600oC. As the temperature elevated from 100 to 300oC, the absorption peaks of volatile components are disappeared as demonstrated clearly by the FTIR (Fourier Transform Infrared) spectra of the fabricated material, which 3393 cm-1 corresponded to OH group, 1624 cm-1 to CO group, and 1384 cm-1 to NO group. The XRD (X-Ray Diffraction) spectra show clearly the alteration process from amorphous to crystalline structure as the calcinations increased from 300 to 600oC. In addition, the TEM (Transmission Electron Microscope) analysis exhibits parts of the fabricated MnFeO3 found in cubic nano size of 15-40 nm under interested calcinations and the result is in agreement with that obtained by XRD investigation.

Nanostructured TiO2-Based Composites for Light Absorption

2014 ◽  
Vol 975 ◽  
pp. 207-212
Author(s):  
Dayse I. dos Santos ◽  
Olayr Modesto Jr. ◽  
Luis Vicente A. Scalvi ◽  
Americo S. Tabata
Keyword(s):  
Metal Oxide ◽  
Light Absorption ◽  
Structural Characteristics ◽  
Sol Gel ◽  
Second Phase ◽  
X Ray Diffraction ◽  
Two Phase ◽  
X Ray ◽  
Oxide Powders

Metal oxide nanocomposites were prepared by two different routes: polyol and sol-gel. Characterization by X ray diffraction showed that the first process produces directly a two-phase material, while the sol-gel powder never showed second phase below 600°C. Light spectroscopy of the treated powders indicated similarities for the processed materials. Although the overall material compositions are about the same, different structural characteristics are found for each processing. With the exception of Ti-Zn materials, all the double metal oxide powders showed higher absorbance than either TiO2 powder.

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