scholarly journals An Experimental and Theoretical Study of the Gasification of Miscanthus Briquettes in a Double-Stage Downdraft Gasifier: Syngas, Tar, and Biochar Characterization

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3225 ◽  
Author(s):  
Tejasvi Sharma ◽  
Diego Yepes Maya ◽  
Francisco M. Nascimento ◽  
Yunye Shi ◽  
Albert Ratner ◽  
...  
Keyword(s):  
Surface Area ◽  
Reaction Model ◽  
Heating Value ◽  
Downdraft Gasifier ◽  
Gasification Process ◽  
Bed Temperature ◽  
Bet Analysis ◽  
Logarithmic Relationship ◽  
Porosity Analysis ◽  
The Impact

The goal of this work is to understand the gasification process for Miscanthus briquettes in a double-stage downdraft gasifier, and the impact of different Equivalence Ratios (ER) on syngas, biochar, and tar characteristics. The optimal ER was found to be 0.35, which yielded a syngas maximum heating value of 5.5 MJ/Nm3 with a syngas composition of 20.29% CO, 18.68% H2, and 0.86% CH4. To better understand the observed behavior, an equilibrium reaction model was created and validated using the experimental data. The model showed that the heating value decreased with increasing ER, and that hydrogen production peaked at ER = 0.37, while methane (CH4) became negligible above ER = 0.42. Tar and particle content in the gas produced at a certain temperature can now be predicted. To assess the biochar characteristics, surface structure image analysis and a surface area porosity analysis were carried out. Employing images from a scanning electron microscope (SEM), the biochar cell bonds and pore structures were examined and analyzed. By using the Brunauer-Emmett-Teller (BET) analysis of the surface porosity, the surface area to be 186.06 m2/g and the micro pore volume was calculated to be 0.07 m3/g. The final aspect of the analysis involved an evaluation of tar production. Combining current and prior data showed a logarithmic relationship between the amount of tar produced and the gasifier bed temperature, where the amount of tar produced decreased with increasing bed temperature. This results in very low tar levels, which is one of the known advantages for a double-stage downdraft gasifier over a single-stage system.

scholarly journals Performance analysis of power generation by wood and woody biomass gasification in a downdraft gasifier

2021 ◽  
Vol 10 (1) ◽  
pp. 80
Author(s):  
Sahar Safarian ◽  
Runar Unnthorsson ◽  
Christiaan Richter
Keyword(s):  
Performance Analysis ◽  
Simulation Model ◽  
Woody Biomass ◽  
Power Production ◽  
Operating Parameters ◽  
Production Plant ◽  
Downdraft Gasifier ◽  
Gasification Process ◽  
The Impact ◽  
Gasification Temperature

An equilibrium simulation model was developed by applying Aspen Plus to evaluate the performance of 28 wood and woody biomass (W&WB) gasification in a downdraft gasifier integrated with power production unit. The developed simulation model does not focus the gasification process as a closed box, it considers important processes in gasification like drying, pyrolysis, combustion, gasification and integrated with power production plant (combustion chamber plus gas turbine). The results for the 28 W&WB alternatives show that the net power produced from 1-ton feedstock entering to the gasification system is between the interval [0-400 kW/ton] and among them, gasification system derived from Tamarack bark biomass significantly outranks all other systems by producing 363 kW/ton, owing to the favorable results obtained in the performance analysis. Moreover, effect of various operating parameters such as gasification temperature and air to fuel ratio (AFR) on the system performance was carried out. Finally, the developed model is applied as an effective tool to assess the impact of so many biomasses and operating parameters on output power.

Evaluation of Nanotechniques and Conventional Techniques for the Removal of Dioxins

2018 ◽  
Vol 9 (1) ◽  
pp. 79-84
Author(s):  
Vaishali V. Shahare ◽  
Rajni Grover ◽  
Suman Meena
Keyword(s):  
Soil Sample ◽  
Human Health ◽  
Surface Area ◽  
Contaminated Soil ◽  
Conventional Treatment ◽  
Volume Ratio ◽  
Soil Samples ◽  
Dioxins And Furans ◽  
Palladized Iron ◽  
The Impact

Background: The persistent dioxins/furans has caused a worldwide concern as they influence the human health. Recent research indicates that nonmaterial may prove effective in the degradation of Dioxins/furans. The nanomaterials are very reactive owing to their large surface area to volume ratio and large number of reactive sites. However, nanotechnology applications face both the challenges and the opportunities to influence the area of environmental protection. Objective: i) To study the impact of oil mediated UV-irradiations on the removal of 2,3,7,8-TCDD, 2,3,7,8-TCDF, OCDD and OCDF in simulated soil samples. ii) To compare the conventional treatment methods with the modern available nanotechniques for the removal of selected Dioxins/furans from soil samples. Methods: The present work has investigated an opportunity of the degradation of tetra and octachlorinated dioxins and furans by using oil mediated UV radiations with subsequent extraction of respective dioxins/furans from soils. The results have been compared with the available nanotechniques. Results: The dioxin congeners in the simulated soil sample showed decrease in concentration with the increase in the exposure time and intensity of UV radiations. The dechlorination of PCDD/Fs using palladized iron has been found to be effective. Conclusion: Both the conventional methods and nanotechnology have a dramatic impact on the removal of Dioxins/furans in contaminated soil. However, the nanotechniques are comparatively costlier and despite the relatively high rates of PCDDs dechlorination by Pd/nFe, small fraction of the dioxins are recalcitrant to degradation over considerable exposure times.

scholarly journals Suitability of Bronchoscopic Biopsy Tissue Samples for Next-Generation Sequencing

Diagnostics ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 391
Author(s):  
Shuji Murakami ◽  
Tomoyuki Yokose ◽  
Daiji Nemoto ◽  
Masaki Suzuki ◽  
Ryou Usui ◽  
...  
Keyword(s):  
Next Generation Sequencing ◽  
Success Rate ◽  
Rna Sequencing ◽  
Surface Area ◽  
Endobronchial Ultrasound ◽  
Next Generation ◽  
Endobronchial Ultrasonography ◽  
Tissue Surface ◽  
The Impact ◽  
Generation Sequencing

A sufficiently large tissue sample is required to perform next-generation sequencing (NGS) with a high success rate, but the majority of patients with advanced non-small-cell lung cancer (NSCLC) are diagnosed with small biopsy specimens. Biopsy samples were collected from 184 patients with bronchoscopically diagnosed NSCLC. The tissue surface area, tumor cell count, and tumor content rate of each biopsy sample were evaluated. The impact of the cut-off criteria for the tissue surface area (≥1 mm2) and tumor content rate (≥30%) on the success rate of the Oncomine Dx Target Test (ODxTT) was evaluated. The mean tissue surface area of the transbronchial biopsies was 1.23 ± 0.85 mm2 when small endobronchial ultrasonography with a guide sheath (EBUS-GS) was used, 2.16 ± 1.49 mm2 with large EBUS-GS, and 1.81 ± 0.75 mm2 with endobronchial biopsy (EBB). The proportion of samples with a tissue surface area of ≥1 mm2 was 48.8% for small EBUS-GS, 79.2% for large EBUS-GS, and 78.6% for EBB. Sixty-nine patients underwent ODxTT. The success rate of DNA sequencing was 84.1% and that of RNA sequencing was 92.7% over all patients. The success rate of DNA (RNA) sequencing was 57.1% (71.4%) for small EBUS-GS (n = 14), 93.4% (96.9%) for large EBUS-GS (n = 32), 62.5% (100%) for EBB (n = 8), and 100% (100%) for endobronchial ultrasound-guided transbronchial needle aspiration (EBUS-TBNA) (n = 15). Regardless of the device used, a tissue surface area of ≥ 1 mm2 is adequate for samples to be tested with NGS.

scholarly journals Simulation of a Downdraft Gasifier for Production of Syngas from Different Biomass Feedstocks

2021 ◽  
Vol 5 (2) ◽  
pp. 20
Author(s):  
Mateus Paiva ◽  
Admilson Vieira ◽  
Helder T. Gomes ◽  
Paulo Brito
Keyword(s):  
Modeling And Simulation ◽  
Pilot Scale ◽  
Operating Conditions ◽  
Fuel Gas ◽  
Heating Value ◽  
Downdraft Gasifier ◽  
Process Operation ◽  
Independent Parameters ◽  
Gasification Temperature ◽  
Main Operating

In the evaluation of gasification processes, estimating the composition of the fuel gas for different conditions is fundamental to identify the best operating conditions. In this way, modeling and simulation of gasification provide an analysis of the process performance, allowing for resource and time savings in pilot-scale process operation, as it predicts the behavior and analyzes the effects of different variables on the process. Thus, the focus of this work was the modeling and simulation of biomass gasification processes using the UniSim Design chemical process software, in order to satisfactorily reproduce the operation behavior of a downdraft gasifier. The study was performed for two residual biomasses (forest and agricultural) in order to predict the produced syngas composition. The reactors simulated gasification by minimizing the free energy of Gibbs. The main operating parameters considered were the equivalence ratio (ER), steam to biomass ratio (SBR), and gasification temperature (independent variables). In the simulations, a sensitivity analysis was carried out, where the effects of these parameters on the composition of syngas, flow of syngas, and heating value (dependent variables) were studied, in order to maximize these three variables in the process with the choice of the best parameters of operation. The model is able to predict the performance of the gasifier and it is qualified to analyze the behavior of the independent parameters in the gasification results. With a temperature between 850 and 950 °C, SBR up to 0.2, and ER between 0.3 and 0.5, the best operating conditions are obtained for maximizing the composition of the syngas in CO and H2.

Performance Prediction of Gas Turbine Under Different Strategies Using Low Heating Value Fuel

2013 ◽  
Author(s):  
Edson Batista da Silva ◽  
Marcelo Assato ◽  
Rosiane Cristina de Lima
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Equivalence Ratio ◽  
Safe Operation ◽  
Engine Operation ◽  
Heating Value ◽  
Gasification Process ◽  
Surge Margin ◽  
And Performance ◽  
Industrial Gas Turbine

Usually, the turbogenerators are designed to fire a specific fuel, depending on the project of these engines may be allowed the operation with other kinds of fuel compositions. However, it is necessary a careful evaluation of the operational behavior and performance of them due to conversion, for example, from natural gas to different low heating value fuels. Thus, this work describes strategies used to simulate the performance of a single shaft industrial gas turbine designed to operate with natural gas when firing low heating value fuel, such as biomass fuel from gasification process or blast furnace gas (BFG). Air bled from the compressor and variable compressor geometry have been used as key strategies by this paper. Off-design performance simulations at a variety of ambient temperature conditions are described. It was observed the necessity for recovering the surge margin; both techniques showed good solutions to achieve the same level of safe operation in relation to the original engine. Finally, a flammability limit analysis in terms of the equivalence ratio was done. This analysis has the objective of verifying if the combustor will operate using the low heating value fuel. For the most engine operation cases investigated, the values were inside from minimum and maximum equivalence ratio range.

Comparison Between Two-Shaft Simple and Single-Shaft Recuperated Brayton Cycles Using Different Types of Gaseous Fuels

2010 ◽  
Author(s):  
A. K. Malkogianni ◽  
A. Tourlidakis ◽  
A. L. Polyzakis
Keyword(s):  
Natural Gas ◽  
Gas Turbines ◽  
Alternative Fuels ◽  
High Efficiency ◽  
Heating Value ◽  
Gaseous Fuels ◽  
Oil And Natural Gas ◽  
Parametric Studies ◽  
The Impact ◽  
Lower Heating

Geopolitical issues give rise to problems in the smooth and continuous flow of oil and natural gas from the production countries to the consumers’ development countries. In addition, severe environmental issues such as greenhouse gas emissions, eventually guide the consumers to fuels more suitable to the present situation. Alternative fuels such as biogas and coal gas have recently become more attractive because of their benefits, especially for electricity generation. On the other hand, the use of relatively low heating value fuels has a significant effect to the performance parameters of gas turbines. In this paper, the impact of using four fuels with different heating value in the gas turbine performance is simulated. Based on the high efficiency and commercialization criteria, two types of engines are chosen to be simulated: two-shaft simple and single-shaft recuperated cycle gas turbines. The heating values of the four gases investigated, correspond to natural gas and to a series of three gases with gradually lower heating values than that of natural gas. The main conclusions drawn from this design point (DP) and off-design (OD) analysis is that, for a given TET, efficiency increases for both engines when gases with low heating value are used. On the contrary, when power output is kept constant, the use of gases with low heating value will result in a decrease of thermal efficiency. A number of parametric studies are carried out and the effect of operating parameters on performance is assessed. The analysis is performed with customized software, which has been developed for this purpose.

Preparation and Application of Titanate Nanotubes on Methylene Blue Degradation from Aqueous Media

2011 ◽  
Vol 117-119 ◽  
pp. 786-789 ◽  
Author(s):  
Wen Churng Lin ◽  
Wein Duo Yang ◽  
Zen Ja Chung ◽  
Hui Ju Chueng
Keyword(s):  
Methylene Blue ◽  
Surface Area ◽  
Uv Irradiation ◽  
Aqueous Media ◽  
Hydrothermal Process ◽  
Reaction Times ◽  
Titanate Nanotubes ◽  
Methylene Blue Degradation ◽  
Bet Analysis

Titanate nanotubes were synthesized at various hydrothermal temperatures and reaction times by the hydrothermal process and used as photocatalyst. BET analysis was conducted in order to find out the surface area of these as-prepared samples and it was found that the surface area increases with rise in temperature till 130 oC. Synthesized as-prepared titanate nanotubes were applied on methylene blue degradation from aqueous media by UV irradiation. It was observed that dye removes ~99% from the aqueous media at a titanate nanotubes dose of 2 g/L.

scholarly journals Effect of Secondary Carbon Nanofillers on the Electrical, Thermal, and Mechanical Properties of Conductive Hybrid Composites Based on Epoxy Resin and Graphite

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4169
Author(s):  
Marcel Zambrzycki ◽  
Krystian Sokolowski ◽  
Maciej Gubernat ◽  
Aneta Fraczek-Szczypta
Keyword(s):  
Mechanical Properties ◽  
Specific Surface ◽  
Epoxy Resin ◽  
Surface Area ◽  
Specific Surface Area ◽  
Hybrid Composites ◽  
Department Of Energy ◽  
Carbon Nanofillers ◽  
The Impact ◽  
Secondary Carbon

In this work, we present a comparative study of the impact of secondary carbon nanofillers on the electrical and thermal conductivity, thermal stability, and mechanical properties of hybrid conductive polymer composites (CPC) based on high loadings of synthetic graphite and epoxy resin. Two different carbon nanofillers were chosen for the investigation—low-cost multi-layered graphene nanoplatelets (GN) and carbon black (CB), which were aimed at improving the overall performance of composites. The samples were obtained by a simple, inexpensive, and effective compression molding technique, and were investigated by the means of, i.a., scanning electron microscopy, Raman spectroscopy, electrical conductivity measurements, laser flash analysis, and thermogravimetry. The tests performed revealed that, due to the exceptional electronic transport properties of GN, its relatively low specific surface area, good aspect ratio, and nanometric sizes of particles, a notable improvement in the overall characteristics of the composites (best results for 4 wt % of GN; σ = 266.7 S cm−1; λ = 40.6 W mK−1; fl. strength = 40.1 MPa). In turn, the addition of CB resulted in a limited improvement in mechanical properties, and a deterioration in electrical and thermal properties, mainly due to the too high specific surface area of this nanofiller. The results obtained were compared with US Department of Energy recommendations regarding properties of materials for bipolar plates in fuel cells. As shown, the materials developed significantly exceed the recommended values of the majority of the most important parameters, indicating high potential application of the composites obtained.

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