scholarly journals 5-(2,6-Diacetamidopyridin-4-yl)-kryptoBODIPY

Molbank ◽  
10.3390/m1271 ◽  
2021 ◽  
Vol 2021 (3) ◽  
pp. M1271
Author(s):  
Massimiliano Cordaro ◽  
Mariachiara Trapani
Keyword(s):  
Scientific Community ◽  
Functional Materials ◽  
Primary Interest ◽  
One Pot ◽  
Potential Applications ◽  
Meso Position ◽  
Synthesis Procedure

The development of new dyes for various fields of application is of primary interest for the scientific community, among these BODIPY are widely studied for their versatility. This communication describes the synthesis of a BODIPY dye on which a diacetoamidopyridine moiety is connected in meso position. The synthesis procedure requires a one-pot step and the dye is obtained with a yield of 20%. The diacetoamido portion contains chemical functionalities able to favor the interaction of BODIPY with complementary molecules, such as uracil or thymine, offering potential applications for the design of new functional materials or sensors.

scholarly journals Hydrothermal Synthesis and Optical Properties of Magneto-Optical Na3FeF6:Tb3+ Octahedral Particles

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 320
Author(s):  
Zhiguo Zhao ◽  
Xue Li
Keyword(s):  
Light Emission ◽  
Red Light ◽  
Hydrothermal Process ◽  
Functional Materials ◽  
Rare Earth Ions ◽  
Monoclinic Crystal ◽  
One Pot ◽  
Monoclinic Crystal Structure ◽  
Micro Particles ◽  
Potential Applications

Sodium iron hexafluoride (Na3FeF6), as a colorless iron fluoride, is expected to be an ideal host for rare earth ions to realize magneto-optical bi-functionality. Herein, monodispersed terbium ions (Tb3+) doped Na3FeF6 particles are successfully synthesized by a facile one-pot hydrothermal process. X-ray diffraction (XRD) and Field emission scanning electron microscopy (FESEM) reveal that the Tb3+ doped Na3FeF6 micro-particles with regular octahedral shape can be assigned to a monoclinic crystal structure (space group P21/c). Under ultraviolet light excitation, the Na3FeF6:Tb3+ octahedral particles given orange-red light emission originated from the 5D4→7FJ transitions of the Tb3+ ions. In addition, the magnetism measurement indicates that Na3FeF6:Tb3+ octahedral particles are paramagnetic with high magnetization at room temperature. Therefore, the Na3FeF6:Tb3+ powders may find potential applications in the biomedical field as magnetic-optical bi-functional materials.

scholarly journals Formation of Bifunctional Octasilsesquioxanes via Silylative Coupling and Cross-Metathesis Reaction

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 3966
Author(s):  
Małgorzata Bołt ◽  
Patrycja Żak ◽  
Beata Dudziec ◽  
Anna Schulmann ◽  
Bogdan Marciniec
Keyword(s):  
Functional Materials ◽  
Metathesis Reaction ◽  
One Pot ◽  
Intermediate Products ◽  
Design And Synthesis ◽  
Cross Metathesis ◽  
Synthetic Procedure ◽  
Wide Range ◽  
Potential Applications ◽  
New Compounds

Bifunctional silsesquioxanes create an attractive group of compounds with a wide range of potential applications, and recently they have gained much interest. They are known to be obtained mainly via hydrosilylation, but we disclose novel synthetic protocols based on different but complementary reactions, i.e., cross-metathesis (CM) and silylative coupling (SC). A series of cubic T8 type silsesquioxane derivatives with a broad scope of styryl substituents were synthesized in a one-pot procedure and characterized by spectroscopic and spectrometric methods. All of the new compounds can be obtained in a one-pot manner, which has an attractive impact on the synthetic procedure, as it is economic in terms of the isolation of intermediate products. Additionally, the methodology disclosed here enables the (E)-stereoselective introduction of styrenes derivative to the cubic T8 type core. The presented compounds can be interesting precursors for a further functionalization that may significantly increase the possibility of their application in the design and synthesis of new functional materials.

Recent advances in the potential applications of hollow kapok fiber-based functional materials

Cellulose ◽  
2021 ◽  
Author(s):  
Yian Zheng ◽  
Jintao Wang ◽  
Aiqin Wang
Keyword(s):  
Functional Materials ◽  
Kapok Fiber ◽  
Recent Advances ◽  
Potential Applications

Self-assembly mode and supramolecular framework of cyclopentanocucurbit[6]uril and aromatic amines

2021 ◽  
Vol 25 ◽  
Author(s):  
Jun Zheng ◽  
Yan Mei Jin ◽  
Xi Nan Yang ◽  
Lin Zhang ◽  
Dao Fa Jiang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Functional Materials ◽  
Supramolecular Interactions ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
Characterization Methods ◽  
Potential Applications ◽  
Non Covalent Interactions ◽  
Multi Level ◽  
Covalent Interactions

: Single-crystal X-ray diffraction analysis, nuclear magnetic resonance (NMR), and other characterization methods are used to characterize the complexes formed by cyclopentano-cucurbit[6]uril (abbreviated as CyP6Q[6]) as a host interacting with p-aminobenzenesulfonamide (G1), 4,4'-diaminobiphenyl (G2), and (E)-4,4'-diamino-1,2-diphenylethene (G3) as guests, respectively. The experimental results show that these three aromatic amine molecules have the same interaction mode with CyP6Q[6], interacting with its negatively electric potential portals. The supramolecular interactions include non-covalent interactions of hydrogen bonding and ion-dipole between host and guest molecules. CdCl2 acts as a structureinducing agent to form self-assemblies of multi-dimensional and multi-level supramolecular frameworks that may have potential applications in various functional materials.

scholarly journals Biosynthesis and Potential Applications of Silver and Gold Nanoparticles and Their Chitosan-Based Nanocomposites in Nanomedicine

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Haliza Katas ◽  
Noor Zianah Moden ◽  
Chei Sin Lim ◽  
Terence Celesistinus ◽  
Jie Yee Chan ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Metallic Nanoparticles ◽  
Cost Effective ◽  
One Pot ◽  
Silver And Gold Nanoparticles ◽  
Stabilizing Agents ◽  
Cost Effective Method ◽  
Multistep Process ◽  
Potential Applications ◽  
Biological Sources

Biosynthesized or biogenic metallic nanoparticles, particularly silver and gold nanoparticles (AgNPs and AuNPs, respectively), have been increasingly used because of their advantages, including high stability and loading capacity; moreover, these nanoparticles are synthesized using a green and cost-effective method. Previous studies have investigated reducing and/or stabilizing agents from various biological sources, including plants, microorganisms, and marine-derived products, using either a one-pot or a multistep process at different conditions. In addition, extensive studies have been performed to determine the biological or pharmacological effects of these nanoparticles, such as antimicrobial, antitumor, anti-inflammatory, and antioxidant effects. In the recent years, chitosan, a natural cationic polysaccharide, has been increasingly investigated as a reducing and/or stabilizing agent in the synthesis of biogenic metallic nanoparticles with potential applications in nanomedicine. Here, we have reviewed the mechanism of biosynthesis and potential applications of AgNPs and AuNPs and their chitosan-mediated nanocomposites in nanomedicine.

A new twofold interpenetrated two-dimensional cadmium(II) coordination polymer constructed from 2,2′-(benzene-1,4-dicarboxamido)dipropionate

2018 ◽  
Vol 74 (11) ◽  
pp. 1434-1439
Author(s):  
Hong-Tao Zhang ◽  
Xiao-Long Wang
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Fluorescence Emission ◽  
Functional Materials ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Groups ◽  
Potential Applications

In recent years, much initial interest and enthusiasm has focused on the self-assembly of coordination polymers due to the aesthetics of their crystalline architectures and their potential applications as new functional materials. As part of an exploration of chiral coordination polymers, a new twofold interpenetrated two-dimensional (2D) coordination polymer, namely, poly[[tetraaquabis[μ3-(2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionato-κ5 O,O′:O′′,O′′′:O′′]dicadmium(II)] trihydrate], {[Cd2(C14H14N2O6)2(H2O)4]·3H2O} n , has been synthesized by the reaction of Cd(CH3COO)2·2H2O with the designed ligand (2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionic acid (H2 L). The compound has been structurally characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analysis. In the crystal structure, each CdII cation binds to three carboxylate groups from two crystallographically independent L 2− dianions. Four carboxylate groups link two crystallographically independent cadmium cations into a 4,4-connected secondary building unit (SBU). The resulting SBUs are extended into a two-dimensional folding sheet via the terephthalamide moiety of the ligand as a spacer, which can be simplified as a (4,4)-connected 4,4L15 net with the point symbol (3.53.62)(32.52.62). In the lattice, two independent folding sheets interpenetrate each other to yield a double-sheet layer. The resulting 2D layers pack in parallel arrays through intermolecular hydrogen bonds and interlayer π–π interactions. The thermal stability and photoluminescence properties of the title compound have been investigated and it exhibits an enhanced fluorescence emission and a longer lifetime compared with free H2 L.

scholarly journals Synthesis of Micro/nano Urchin-like VO2 Particles and Its Decolorization of Methylene Blue

2019 ◽  
Vol 35 (3) ◽  
Author(s):  
Nguyen The Manh ◽  
Duong Hong Quan ◽  
Vu Thi Ngoc Minh ◽  
Vuong Pham Hung
Keyword(s):  
Methylene Blue ◽  
Sodium Dodecyl ◽  
Adsorption Properties ◽  
Contaminated Water ◽  
Potential Applications ◽  
Synthesis Procedure ◽  
Water Treatments ◽  
Sds Surfactant ◽  
Mb Adsorption

Micro/nano urchin-like VO2 particles were synthesized successfully by hydrothermal method. Vanadium pentoxide (V2O5), oxalic acid (C2H2O4) and sodium dodecyl sulfate (SDS) surfactant were used as reagents for the synthesis of VO2. In this article, we have reported the synthesis procedure of VO2 nanorods and micro/nano urchin-like VO2 structure and evaluating the methylene blue (MB) adsorption properties. Morphology and particle size of VO2 were observed by FE-SEM. The phase formation of VO2 was studied by XRD. Raman spectroscopy was also used for characterization of VO2. Micro/nano urchin-like VO2 structure was showed good MB adsorption properties that have potential applications in dye-contaminated water treatments.

Functionalization of Cellulose Paper by Coating Nano Metal-Organic Frameworks for Use as Photochromic Material

2021 ◽  
Vol 43 (1) ◽  
pp. 67-67
Author(s):  
Qiang Yang Qiang Yang ◽  
Wei Gong Wei Gong ◽  
Xiaowei Cui Xiaowei Cui ◽  
Chunsheng Zhou Chunsheng Zhou
Keyword(s):  
Functional Materials ◽  
Photochromic Properties ◽  
Coated Paper ◽  
Cellulose Paper ◽  
Chemical Structures ◽  
Coating Method ◽  
Potential Applications ◽  
Metal Organic ◽  
Light Green ◽  
Photochromic Reaction

The cellulose paper-based functional materials modified by Zn-NDI and Cu-NDI were prepared by the coating method. The chemical structures were characterized by FTIR, XRD, UV-vis and SEM, and the photochromic properties of the composite functional materials were studied. The results showed that Zn-NDI and Cu-NDI were successfully prepared and retained on the surface of copy paper, the wavelength of photochromic reaction is between 300-400 nm of MOFs materials. Optical analysis confirmed that the NDI/paper, Zn-NDI/paper and Cu-NDI/paper changed from tan to wheat, light green to olive, and dark tan to brown after 60 seconds of exposure to hernia light irradiations, the MOFs coated paper returned to its original color when it was placed in the dark for 4 hours. The above results indicated that the prepared Zn-NDI and Cu-NDI coated paper composites exhibited excellent photochromic ability and had potential applications in the field of anti-counterfeiting packaging materials.

scholarly journals Synthesis of Carbon Quantum Dot Nanoparticles Derived from Byproducts in Bio-Refinery Process for Cell Imaging and In Vivo Bioimaging

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 387 ◽  
Author(s):  
Caoxing Huang ◽  
Huiling Dong ◽  
Yan Su ◽  
Yan Wu ◽  
Robert Narron ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Cell Imaging ◽  
Degradation Products ◽  
Green Fluorescence ◽  
One Pot ◽  
Carbon Nanoparticle ◽  
Carbon Quantum Dot ◽  
Potential Applications ◽  
Main Components

The carbon quantum dot (CQD), a fluorescent carbon nanoparticle, has attracted considerable interest due to its photoluminescent property and promising applications in cell imaging and bioimaging. In this work, biocompatible, photostable, and sustainably sourced CQDs were synthesized from byproducts derived from a biorefinery process using one-pot hydrothermal treatment. The main components of byproducts were the degradation products (autohydrolyzate) of biomass pretreated by autohydrolysis. The as-synthesized CQDs had a size distribution from 2.0–6.0 nm and had high percentage of sp2 and sp3 carbon groups. The CQDs showed blue-green fluorescence with a quantum yield of ~13%, and the fluorescence behaviors were found to be stable with strong resistance to photobleaching and temperature change. In addition, it is found that the as-synthesized CQDs could be used for imaging of cells and tumors, which show potential applications in bioimaging and related fields such as phototherapy and imaging.

scholarly journals Recent Advances in One-Pot Modular Synthesis of 2-Quinolones

Molecules ◽  
2020 ◽  
Vol 25 (22) ◽  
pp. 5450
Author(s):  
Wan Pyo Hong ◽  
Inji Shin ◽  
Hee Nam Lim
Keyword(s):  
Reaction Mechanism ◽  
Small Molecules ◽  
Functional Materials ◽  
Synthetic Methods ◽  
Microwave Irradiation Method ◽  
One Pot ◽  
Bond Forming ◽  
Chemical Structures ◽  
The Core ◽  
Modular Synthesis

It is known that 2-quinolones are broadly applicable chemical structures in medicinal and agrochemical research as well as various functional materials. A number of current publications about their synthesis and their applications emphasize the importance of these small molecules. The early synthetic chemistry originated from the same principle of the classical Friedländer and Knorr procedures for the preparation of quinolines. The analogous processes were developed by applying new synthetic tools such as novel catalysts, the microwave irradiation method, etc., whereas recent innovations in new bond forming reactions have allowed for novel strategies to construct the core structures of 2-quinolones beyond the bond disconnections based on two classical reactions. Over the last few decades, some reviews on structure-based, catalyst-based, and bioactivity-based studies have been released. In this focused review, we extensively surveyed recent examples of one-pot reactions, particularly in view of modular approaches. Thus, the contents are categorized as three major sections (two-, three-, and four-component reactions) according to the number of reagents that ultimately compose atoms of the core structures of 2-quinolones. The collected synthetic methods are discussed from the perspectives of strategy, efficiency, selectivity, and reaction mechanism.

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