scholarly journals Enhancement of Viscoelastic and Electrical Properties of Magnetorheological Elastomers with Nanosized Ni-Mg Cobalt-Ferrites as Fillers

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3531 ◽  
Author(s):  
Siti Aishah Abdul Aziz ◽  
Saiful Amri Mazlan ◽  
U Ubaidillah ◽  
Muhammad Kashfi Shabdin ◽  
Nurul Azhani Yunus ◽  
...  

Carbon-based particles, such as graphite and graphene, have been widely used as a filler in magnetorheological elastomer (MRE) fabrication in order to obtain electrical properties of the material. However, these kinds of fillers normally require a very high concentration of particles to enhance the conductivity property. Therefore, in this study, the nanosized Ni-Mg cobalt ferrite is introduced as a filler to soften MRE and, at the same time, improve magnetic, rheological, and conductivity properties. Three types of MRE samples without and with different compositions of Mg, namely Co0.5Ni0.2Mg0.3Fe2O4 (A1) and Co0.5Ni0.1Mg0.4Fe2O4 (A2), are fabricated. The characterization related to the micrograph, magnetic, and rheological properties of the MRE samples are analyzed using scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and the rheometer. Meanwhile, the effect of the nanosized Ni-Mg cobalt ferrites on the electrical resistance property is investigated and compared with the different Mg compositions. It is shown that the storage modulus of the MRE sample with the nanosized Ni-Mg cobalt ferrites is 43% higher than that of the MRE sample without the nanomaterials. In addition, it is demonstrated that MREs with the nanosized Ni-Mg cobalt ferrites exhibit relatively low electrical resistance at the on-state as compared to the off-state condition, because MRE with a higher Mg composition shows lower electrical resistance when higher current flow occurs through the materials. This salient property of the proposed MRE can be effectively and potentially used as an actuator to control the viscoelastic property of the magnetic field or sensors to measure the strain of the flexible structures by the electrical resistance signal.

2017 ◽  
Vol 424 ◽  
pp. 282-289 ◽  
Author(s):  
M. Bunoiu ◽  
J. Neamțu ◽  
L. Chirigiu ◽  
M. Bălășoiu ◽  
G. Pascu ◽  
...  

2020 ◽  
Vol 10 (4) ◽  
pp. 147-164
Author(s):  
Mohammed Al-Bahrani ◽  
Mohammed Ridh H. Alhakeem ◽  
Alistair Cree

In this work, we present a new criterion, unlike other attempts, to evaluate and quantify the degree of damage of composite material when it subjected to a sudden impact load. Our criterion exploits the high intrinsic electrical conductivity property of the Multi-walled carbon nanotubes (MWCNTs) after dispersing different concentrations of them (0, 0.5, 1.0, 1.5 and 2.0 %) in the epoxy matrix of a glass fibre composite. Following this goal, the low-velocity impact and flexural after impact (FAI) tests on the MWCNTs-glass epoxy (i.e. MWCNTs-GF) nanocomposite were evaluated. At the same time, the changes in its electrical resistance were measured. The results showed that the properties of the self-sensing composites were significantly affected by impact energy. The damage after impact causes an increase in the electrical resistance of the MWCNTs-GF nanocomposite and increases with increased impact energy. In addition, the samples containing a high concentration of MWCNTs showed lower damage sensitivity under all impact energies levels as compared with the samples contain a lower MWCNTs concentration. Therefore, the results presented in this work have shown that it is possible to associate the change in electrical resistance of the MWCNTs-GF nanocomposite with the degree of damages caused by impact load.


2014 ◽  
Vol 979 ◽  
pp. 297-301 ◽  
Author(s):  
Arpapong Changjan ◽  
Pongkaew Udomsamuthirun

Superconductivity is a phenomenon of exactly zero electrical resistance and expulsion of magnetic fields occurring in certain materials when cooled below a characteristic critical temperature. Fe-based superconductors are superconductors whose containing iron compounds and having a very high critical magnetic field. London penetration depth can assist in the study of the behavior of the critical magnetic field. The London penetration depth is the distance to which a magnetic field penetrates into a superconductor and becomes equal to 0.367879 times that of the magnetic field at the surface of the superconductor. In this paper, the London penetration depth of Fe-based superconductors is studied by Ginzburg-Landau scenery. Free energy of Fe-based superconductors is assumed by modified the free energy of two-band magnetic superconductors model and theof Fe-based superconductors is derived analytically. Finally, the temperature dependence of is investigated and applied to Single-Crystal superconductors.


2019 ◽  
Author(s):  
Chem Int

The assessment of groundwater is essential for the estimation of suitability of water for safe use. An attempt has been made to study the groundwater of selected areas of Punjab (Sheikhupura & Sahiwal) and Sindh (Sindh, Jawar Dharki and Dharki), Pakistan. The results indicate that pH, color and odor were all within limits of WHO that is pH ranges 6.5–8.5, colorless and odorless, respectively. The high values of suspended solids were observed in the Sindh-1 and Dharki samples. Microbiologically only Sahiwal and Jawar Dharki were found fit for drinking purpose. Trace metals analysis of Sheikhupura-1 and Sindh-1 showed that values do not fall within limits of WHO for Iron. The ionic concentration analysis showed that high bicarbonate (HCO3-), ions are present in the samples of Sahiwal and Dharki; Sindh-1 and Jawar Dharki samples showed very high concentration for chloride ions, all samples were satisfactory level for sulphate (SO42-), sodium, magnesium and phosphate ions except samples of Sindh-1 and Jawar Dharki. High concentration of calcium and potassium ions was observed in samples of Sindh-1, while all other samples were found fit for drinking purposes in respect of nitrate, nitrite and ammonium ions. The high concentration of Fluoride was found only in Sheikhupura-2 samples.


Author(s):  
Way-Jam Chen ◽  
Lily Shiau ◽  
Ming-Ching Huang ◽  
Chia-Hsing Chao

Abstract In this study we have investigated the magnetic field associated with a current flowing in a circuit using Magnetic Force Microscopy (MFM). The technique is able to identify the magnetic field associated with a current flow and has potential for failure analysis.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 507
Author(s):  
Luca Seravalli ◽  
Claudio Ferrari ◽  
Matteo Bosi

In this paper, we model the electrical properties of germanium nanowires with a particular focus on physical mechanisms of electrical molecular sensing. We use the Tibercad software to solve the drift-diffusion equations in 3D and we validate the model against experimental data, considering a p-doped nanowire with surface traps. We simulate three different types of interactions: (1) Passivation of surface traps; (2) Additional surface charges; (3) Charge transfer from molecules to nanowires. By analyzing simulated I–V characteristics, we observe that: (i) the largest change in current occurs with negative charges on the surfaces; (ii) charge transfer provides relevant current changes only for very high values of additional doping; (iii) for certain values of additional n-doping ambipolar currents could be obtained. The results of these simulations highlight the complexity of the molecular sensing mechanism in nanowires, that depends not only on the NW parameters but also on the properties of the molecules. We expect that these findings will be valuable to extend the knowledge of molecular sensing by germanium nanowires, a fundamental step to develop novel sensors based on these nanostructures.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingfeng Yang ◽  
Hanze Ying ◽  
Zhixia Li ◽  
Jiang Wang ◽  
Yingying Chen ◽  
...  

AbstractMacrocycles are unique molecular structures extensively used in the design of catalysts, therapeutics and supramolecular assemblies. Among all reactions reported to date, systems that can produce macrocycles in high yield under high reaction concentrations are rare. Here we report the use of dynamic hindered urea bond (HUB) for the construction of urea macrocycles with very high efficiency. Mixing of equal molar diisocyanate and hindered diamine leads to formation of macrocycles with discrete structures in nearly quantitative yields under high concentration of reactants. The bulky N-tert-butyl plays key roles to facilitate the formation of macrocycles, providing not only the kinetic control due to the formation of the cyclization-promoting cis C = O/tert-butyl conformation, but also possibly the thermodynamic stabilization of macrocycles with weak association interactions. The bulky N-tert-butyl can be readily removed by acid to eliminate the dynamicity of HUB and stabilize the macrocycle structures.


Author(s):  
Yasuyoshi Fukuda ◽  
Misako Higashiya ◽  
Takahiro Obata ◽  
Keita Basaki ◽  
Megumi Yano ◽  
...  

Abstract To cryopreserve cells, it is essential to avoid intracellular ice formation during cooling and warming. One way to achieve this is to convert the water inside the cells into a non-crystalline glass. It is currently believed that to accomplish this vitrification, the cells must be suspended in a very high concentration (20–40%) of a glass-inducing solute, and subsequently cooled very rapidly. Herein, we report that this belief is erroneous with respect to the vitrification of one-cell rat embryos. In the present study, one-cell rat embryos were vitrified with 5 μL of EFS10 (a mixture of 10% ethylene glycol, 27% Ficoll, and 0.45 M sucrose) in cryotubes at a moderate cooling rate, and warmed at various rates. Survival was assessed according to the ability of the cells to develop into blastocysts and to develop to term. When embryos were vitrified at a 2,613 °C/min cooling rate and thawed by adding 1 mL of sucrose solution (0.3 M, 50 °C) at a warming rate of 18,467 °C/min, 58.1 ± 3.5% of the EFS10-vitrified embryos developed into blastocysts, and 50.0 ± 4.7% developed to term. These rates were similar to those of non-treated intact embryos. Using a conventional cryotube, we achieved developmental capabilities in one-cell rat embryos by rapid warming that were comparable to those of intact embryos, even using low concentrations (10%) of cell-permeating cryoprotectant and at low cooling rates.


1964 ◽  
Vol 41 (2) ◽  
pp. 229-256 ◽  
Author(s):  
TORKEL WEIS-FOGH

1. The tracheal system of insect wing muscle is so dense that between 10-1 and 10-3 of any cut area is occupied by air tubes. In most cases, air tube diffusion of O2 and CO2 through the muscle is therefore several thousand times quicker than diffusion in the liquid phase. 2. In large insects the primary tracheal supply must be strongly ventilated while diffusion is sufficient in the remaining part of the air tubes, even at the highest metabolic rates encountered in any insect. 3. The tracheoles represent the main site of exchange between the gaseous and the liquid phase while the tracheae are of little significance in this respect. The fibres cannot exceed about 20 µ in diameter unless the tracheoles indent the surface and become ‘internal’. 4. Muscular pumping of air and blood due to shortening is of little importance for the exchange of gases but of major importance for the supply with fuel for combustion. However, the large fibre diameters and the tidal nature of the pumping necessitates a very high concentration of fuel in the haemolymph. The high concentration of trehalose in insect blood is considered to be an essential adaptation to flapping flight. 5. The transport by diffusion of O2 and CO2 was followed in detail in a number of concrete examples in the gaseous as well as in the liquid phase. Within a safety factor of 2-3, the rate of transport was always found to be adequate. There is no reason to suggest other mechanisms than a simple, normal diffusion.


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