scholarly journals A Review of Sintering-Bonding Technology Using Ag Nanoparticles for Electronic Packaging

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 927
Author(s):  
Jianfeng Yan

Metal nanoparticles (NPs) have attracted growing attention in recent years for electronic packaging applications. Ag NPs have emerged as a promising low-temperature bonding material owing to their unique characteristics. In this study, we mainly review our research progress on the interconnection of using polyol-based Ag NPs for electronic packaging. The synthesis, sintering-bonding process, bonding mechanism, and high-temperature joint properties of Ag NP pastes are investigated. The paste containing a high concentration of Ag NPs was prepared based on the polyol method and concentration. A nanoscale layer of organic components coated on the NPs prevents the coalescence of Ag NPs. The effects of organic components on the bondability of the Ag NP paste were studied. Compared to the aqueous-based Ag NP paste, the polyol-based Ag NP with the reduction of organic component can improve the bondability, and the coffee ring effect was successfully depressed due to the increased Marangoni flow. The sintering behaviors of Ag NPs during the bonding process were investigated using the classical sphere-to-sphere approach. The mechanical property of joints using this Ag paste was better than that using Pb95Sn5 solders after storage at high temperatures. The sintering–bonding technology using polyol-based Ag NPs was helpful to the low-temperature interconnection for electronic packaging applications.

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 335
Author(s):  
Gyuwon Jeong ◽  
Dong-Yurl Yu ◽  
Seongju Baek ◽  
Junghwan Bang ◽  
Tae-Ik Lee ◽  
...  

The effects of Ag nanoparticle (Ag NP) addition on interfacial reaction and mechanical properties of Sn–58Bi solder joints using ultra-fast laser soldering were investigated. Laser-assisted low-temperature bonding was used to solder Sn–58Bi based pastes, with different Ag NP contents, onto organic surface preservative-finished Cu pads of printed circuit boards. The solder joints after laser bonding were examined to determine the effects of Ag NPs on interfacial reactions and intermetallic compounds (IMCs) and high-temperature storage tests performed to investigate its effects on the long-term reliabilities of solder joints. Their mechanical properties were also assessed using shear tests. Although the bonding time of the laser process was shorter than that of a conventional reflow process, Cu–Sn IMCs, such as Cu6Sn5 and Cu3Sn, were well formed at the interface of the solder joint. The addition of Ag NPs also improved the mechanical properties of the solder joints by reducing brittle fracture and suppressing IMC growth. However, excessive addition of Ag NPs degraded the mechanical properties due to coarsened Ag3Sn IMCs. Thus, this research predicts that the laser bonding process can be applied to low-temperature bonding to reduce thermal damage and improve the mechanical properties of Sn–58Bi solders, whose microstructure and related mechanical properties can be improved by adding optimal amounts of Ag NPs.


2015 ◽  
Vol 2015 (DPC) ◽  
pp. 001847-001884
Author(s):  
Peter Ramm ◽  
Armin Klumpp ◽  
Alan Mathewson ◽  
Kafil M. Razeeb ◽  
Reinhard Pufall

The European 3D heterogeneous integration platform has been established by the consortium of the Integrated Project e-BRAINS [1], where technologies of the following relevant main categories of 3D integration are provided to enable future applications of smart sensor systems:3D System-on-Chip Integration - 3D-SOC: TSV technology for stacking of thinned devices or large IC blocks (global level),3D Wafer-Level-Packaging - 3D-WLP: embedding technology with through-polymer vias (TPV) for stacking of thinned ICs on wafer-level (no TSV), and3D System-in-Package - 3D-SIP: 3D stacking of packaged devices or substrates *definitions according to [2] Regarding TSV performance, the applications do not need ultra-high vertical interconnect densities as for 3D stacked Integrated Circuits – 3D-SIC*. Nevertheless, the lateral sizes of the TSVs are preferably minimized to allow for place and route for small “open” IC areas. Smaller TSVs are also preferred in order to reduce thermo-mechanical stress. e-BRAINS' focus is on how heterogeneous integration and sensor device technologies can be combined to bring new performance levels to targeted applications with high market potentials. The consortium, under coordination of Infineon and technical management by Fraunhofer EMFT, is composed of major European system manufacturers (Infineon, Siemens, SensoNor, 3D PLUS, Vermon and IQE), SMEs (DMCE, Magna Diagnostics, SORIN and eesy-ID), the large research institutions CEA Grenoble, Fraunhofer (EMFT Munich & IIS-EAS Dresden), imec, SINTEF, Tyndall and ITE Warsaw, and universities (EPFL Lausanne, TU Chemnitz and TU Graz). Target applications include automotive, ambient living and medical devices, with a specific focus on wireless sensor systems. Concerning the enabling 3D Heterogeneous Integration Platform, the e-BRAINS partners are working close together, where Infineon, Fraunhofer EMFT, imec and SINTEF are focusing mainly on 3D-SOC and 3D-WLP, and the French system manufacturer 3D PLUS and Tyndall on 3D-WLP and 3D-SIP technologies. The focus of this paper is on low-temperature bonding processes for highly reliable 3D integrated sensor systems. One of the key issues for heterogeneous systems production is the impact of 3D processes to the reliability of the product, i.e. the high built-in stresses caused by e.g. the CTE mismatch of complex layer structures (thin Si, ILDs, metals etc.) in combination with elevated bonding temperatures. As consequence, extensive project work was dedicated in the developments of reliable low-temperature bonding processes. Mainly intermetallic compound (IMC) bonding with Cu/Sn metal systems supported by ultrasonic agitation (Fraunhofer EMFT) was successfully introduced in 3D integration technology (see Fig. 2). A copper/tin solid-liquid interdiffusion (SLID) system was investigated using ultrasonic agitation to reduce the assembly temperature below the melting point of tin. Cleaning procedures are important shortly before joining the samples; dry cleaning has best results due to removal of thin oxide layers. Figure 2 shows a cross section of US supported Cu/Sn bonding at 150C. The intermetallic compounds Cu3Sn and Cu6Sn5 as well as pure tin easily can be identified. Due to low temperature assembly the most stable intermetallic compound (IMC) Cu3Sn has a minor share of the metal system. Most importantly there is no gap between top and bottom part of the joint despite the macroscopic assembly temperature is far away from the melting point of tin. But maybe the ultrasonic agitation brings enough energy to the interfaces, so locally melting can occur. In this way robust IMC bonding technology at 150C could be demonstrated with shear forces of 17 MPa and an alignment accuracy of 3 μm, well-suited for 3D integration. Figure 2: Low-temperature IMC bonding technology using ultrasonic agitation (Fraunhofer EMFT) Reliability for SLID contacts is certainly a very challenging objective especially looking for robust solutions in automotive applications. Thermally induced mechanical stress is the main reason for early fails during temperature cycling. Cross sectioned samples were investigated and methods like nanoindentation, Raman spectroscopy, fibDAC, and high local resolution x-ray scattering were applied to measure the intrinsic stresses. It can be shown that low temperature bonding is the right approach to avoid excessive stress cracking the interface or even fracturing the silicon. Also fatigue of metals can be reduced in a range that plastic deformation is no lifetime limiting factor.


2010 ◽  
Vol 2010 (DPC) ◽  
pp. 001221-001252 ◽  
Author(s):  
Kei Murayama ◽  
Mitsuhiro Aizawa ◽  
Mitsutoshi Higashi

The bonding technique for High density Flip Chip(F.C.) packages requires a low temperature and a low stress process to have high reliability of the micro joining ,especially that for sensor MEMS packages requires hermetic sealing so as to ensure their performance. The Transient Liquid Phase (TLP) bonding, that is a kind of diffusion bonding is a technique that connects the low melting point material such as Indium to the higher melting point metal such as Gold by the isothermal solidification and high-melting-point intermetallic compounds are formed. Therefore, it is a unique joining technique that can achieve not only the low temperature bonding and also the high temperature reliability. The Gold-Indium TLP bonding technique can join parts at 180 degree C and after bonding the melting point of the junction is shifted to more than 495 degree C, therefore itfs possible to apply the low temperature bonding lower than the general use as a lead free material such as a SAC and raise the melting point more than AuSn solder which is used for the high temperature reliability usage. Therefore, the heat stress caused by bonding process can be expected to be lowered. We examined wafer bonding and F.C bonding plus annealing technique by using electroplated Indium and Gold as a joint material. We confirmed that the shear strength obtained at the F.C. bonding plus anneal technique was equal with that of the wafer bonding process. Moreover, it was confirmed to ensure sufficient hermetic sealing in silicon cavity packages that had been bonded at 180 degree C. And the difference of the thermal stress that affect to the device by the bonding process was confirmed. In this paper, we report on various possible application of the TLP bonding.


2010 ◽  
Vol 13 (7) ◽  
pp. 536-542
Author(s):  
Masami Nakamoto ◽  
Toru Nagaoka ◽  
Yoshiaki Morisada ◽  
Masao Fukusumi ◽  
Yukiyasu Kashiwagi ◽  
...  

2009 ◽  
Vol 1156 ◽  
Author(s):  
Rahul Agarwal ◽  
Wouter Ruythooren

AbstractHigh yielding and high strength Cu-Cu thermo-compression bonds have been obtained at temperatures as low as 175°C. Plated Cu bumps are used for bonding, without any surface planarization step or plasma treatment, and bonding is performed at atmospheric condition. In this work the 25μm diameter bumps are used at a bump pitch of 100μm and 40μm. Low temperature bonding is achieved by using immersion bonding in citric acid. Citric acid provides in-situ cleaning of the Cu surface during the bonding process. The daisy chain electrical bonding yield ranges from 84%-100% depending on the bonding temperature and pressure.


2012 ◽  
Vol 706-709 ◽  
pp. 2962-2967 ◽  
Author(s):  
Akio Hirose ◽  
Naoya Takeda ◽  
Yosuke Konaka ◽  
Hiroaki Tatsumi ◽  
Yusuke Akada ◽  
...  

A novel bonding process using Ag2O paste composed of Ag2O particles and a reducing agent has been proposed as a Pb-free alternative of high melting point solders in electronics packaging. Ag2O paste formed Ag nanoparticles through the redox reaction in the bonding process and in-situ formed Ag nanoparticles sintered immediately. While the bonding process using Ag metallo-organic nanoparticles, which have been proposed, was unfavorable to the bonding at 250 degree Celsius or lower in terms of requiring removal of stable organic shells, the bonding process using Ag2O paste demonstrated the possibility of further low-temperature bonding.


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