scholarly journals Statistical Copolymers of n-Butyl Vinyl Ether and 2-Chloroethyl Vinyl Ether via Metallocene-Mediated Cationic Polymerization. A Scaffold for the Synthesis of Graft Copolymers

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1510 ◽  
Author(s):  
Zouganelis ◽  
Choinopoulos ◽  
Goulas ◽  
Pitsikalis
Keyword(s):  
Vinyl Ether ◽  
Graft Copolymers ◽  
Structural Parameters ◽  
Theoretical Models ◽  
Size Exclusion ◽  
Sequence Length ◽  
Reactivity Ratios ◽  
Scanning Calorimetry ◽  
Initiation System ◽  
Grafting From

The cationic statistical copolymerization of n-butyl (be) and 2-chloroethyl vinyl ether (CEVE), is efficiently conducted using bis(η5-cyclopentadienyl)dimethyl zirconium (Cp2ZrMe2) in combination with tetrakis(pentafluorophenyl)borate dimethylanilinum salt [B(C6F5)4]–[Me2NHPh]+, as an initiation system. The reactivity ratios are calculated using both linear graphical and non-linear methods. Structural parameters of the copolymers are obtained by calculating the dyad sequence fractions and the mean sequence length, which are derived using the monomer reactivity ratios. The glass transition temperatures (Tg) of the copolymers are measured by Differential Scanning Calorimetry (DSC), and the results are compared with predictions based on several theoretical models. The statistical copolymers are further employed as scaffolds for the synthesis of graft copolymers having poly(vinyl ether)s as a backbone and either poly(ε-caprolactone) (PCL) or poly(l-lactide) (PLLA) as side chains. Both the grafting “onto” and the grafting “from” methodologies are employed. The reaction sequence is monitored by Size Exclusion Chromatography (SEC), NMR and IR spectroscopies. The advantages and limitations of each approach are thoroughly examined.

scholarly journals Statistical Copolymers of N-Vinylpyrrolidone and Isobornyl Methacrylate via Free Radical and RAFT Polymerization: Monomer Reactivity Ratios, Thermal Properties, and Kinetics of Thermal Decomposition

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 778
Author(s):  
Olga Kokkorogianni ◽  
Philippos Kontoes-Georgoudakis ◽  
Maria Athanasopoulou ◽  
Nikolaos Polizos ◽  
Marinos Pitsikalis
Keyword(s):  
Thermal Properties ◽  
Free Radical ◽  
Raft Polymerization ◽  
Structural Parameters ◽  
Reactivity Ratio ◽  
Sequence Length ◽  
Reactivity Ratios ◽  
Scanning Calorimetry ◽  
Reversible Addition ◽  
Kinetics Of

The synthesis of statistical copolymers of N-vinylpyrrolidone (NVP) with isobornyl methacrylate (IBMA) was conducted by free radical and reversible addition-fragmentation chain transfer (RAFT) polymerization. The reactivity ratios were estimated using the Finemann-Ross, inverted Fineman-Ross, Kelen-Tüdos, extended Kelen-Tüdos and Barson-Fenn graphical methods, along with the computer program COPOINT, modified to both the terminal and the penultimate models. According to COPOINT the reactivity ratios were found to be equal to 0.292 for NVP and 2.673 for IBMA for conventional radical polymerization, whereas for RAFT polymerization and for the penultimate model the following reactivity ratios were obtained: r11 = 4.466, r22 = 0, r21 = 14.830, and r12 = 0 (1 stands for NVP and 2 for IBMA). In all cases, the NVP reactivity ratio was significantly lower than that of IBMA. Structural parameters of the copolymers were obtained by calculating the dyad sequence fractions and the mean sequence length. The thermal properties of the copolymers were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and differential thermogravimetry (DTG). The results were compared with those of the respective homopolymers.

The analysis on the influence of mixed sliding-rolling motion mode to precision degradation of ball screw

2021 ◽  
pp. 095440622098201
Author(s):  
Qiang Cheng ◽  
Baobao Qi ◽  
Hongyan Chu ◽  
Ziling Zhang ◽  
Zhifeng Liu ◽  
...  
Keyword(s):  
Structural Parameters ◽  
Experimental Tests ◽  
Theoretical Models ◽  
Operating Conditions ◽  
Ball Screw ◽  
Rolling Motion ◽  
Degradation Model ◽  
Sliding Motion ◽  
Factors Analysis ◽  
Motion Mode

The combination of sliding/rolling motion can influence the degree of precision degradation of ball screw. Precision degradation modeling and factors analysis can reveal the evolution law of ball screw precision. This paper presents a precision degradation model for factors analysis influencing precision due to mixed sliding-rolling motion. The precision loss model was verified through the comparison of theoretical models and experimental tests. The precision degradation due to rolling motion between the ball and raceway accounted for 29.09% of the screw precision loss due to sliding motion. Additionally, the total precision degradation due to rolling motion accounted for 21.03% of the total sliding precision loss of the screw and nut, and 17.38% of the overall ball screw precision loss under mixed sliding-rolling motion. In addition, the effects of operating conditions and structural parameters on precision loss were analyzed. The sensitivity coefficients of factors influencing were used to quantitatively describe impact degree on precision degradation.

scholarly journals Redox initiation in semicontinuous polymerization to search for specific mechanical properties of copolymers

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 613-623
Author(s):  
José Manuel Sandoval-Díaz ◽  
Francisco Javier Rivera-Gálvez ◽  
Marta Fernández-García ◽  
Carlos Federico Jasso-Gastinel
Keyword(s):  
Low Cost ◽  
Mechanical Analysis ◽  
Industrial Applications ◽  
Size Exclusion ◽  
Proton Nuclear Magnetic Resonance ◽  
Polymerization Reaction ◽  
Redox Initiation ◽  
Initiation System ◽  
Feeding Profile ◽  
Chain Composition

AbstractIn this work, for a semicontinuous emulsion polymerization reaction, it is shown that using a redox initiation system at 40°C, substantial modifications in copolymer chain composition with conversion can be easily obtained. To test controllable trajectories for comonomer feeding, linear and parabolic profiles were chosen to get different types of chain composition variations for the 50/50 w/w styrene/n-butyl acrylate system. For the “forced composition copolymers,” the molecular weight averages and distribution were obtained by size exclusion chromatography. The composition along conversion was followed by proton nuclear magnetic resonance to determine the weight composition distribution (WCD) of the copolymer chains. Mechanodynamic (dynamic-mechanical analysis), tensile, and hardness tests exhibited consistent results depending on the WCD that outcomes from the respective feeding profile. The results confirm that this methodology is of great potential for industrial applications when looking for synergy in copolymer properties, and low-cost processes.

scholarly journals Effect of DMPA and Molecular Weight of Polyethylene Glycol on Water-Soluble Polyurethane

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1915 ◽  
Author(s):  
Eyob Wondu ◽  
Hyun Woo Oh ◽  
Jooheon Kim
Keyword(s):  
Molecular Weight ◽  
Contact Angle ◽  
Polyethylene Glycol ◽  
Photoelectron Spectroscopy ◽  
Water Solubility ◽  
Soft Segment ◽  
Water Soluble ◽  
Size Exclusion ◽  
Resonance Spectroscopy ◽  
Scanning Calorimetry

In this study water-soluble polyurethane (WSPU) was synthesized from isophorone diisocyanate (IPDI), and polyethylene glycol (PEG), 2-bis(hydroxymethyl) propionic acid or dimethylolpropionic acid (DMPA), butane-1,4-diol (BD), and triethylamine (TEA) using an acetone process. The water solubility was investigated by solubilizing the polymer in water and measuring the contact angle and the results indicated that water solubility and contact angle tendency were increased as the molecular weight of the soft segment decreased, the amount of emulsifier was increased, and soft segment to hard segment ratio was lower. The contact angle of samples without emulsifier was greater than 87°, while that of with emulsifier was less than 67°, indicating a shift from highly hydrophobic to hydrophilic. The WSPU was also analyzed using Fourier transform infrared spectroscopy (FT-IR) to identify the absorption of functional groups and further checked by X-ray photoelectron spectroscopy (XPS). The molecular weight of WSPU was measured using size-exclusion chromatography (SEC). The structure of the WSPU was confirmed by nuclear magnetic resonance spectroscopy (NMR). The thermal properties of WSPU were analyzed using thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC).

Understanding nucleophiles effects in fast living cationic polymerisation of isobutyl vinyl ether in a microflow system from stability and activity of propagating chains

2021 ◽  
Author(s):  
Dan Xie ◽  
Yangcheng Lu
Keyword(s):  
Vinyl Ether ◽  
Initiation System ◽  
Cationic Polymerisation

Previous studies into fast living cationic polymerisation have rarely focused on the effects of nucleophiles, which are crucial in determining a suitable initiation system. In this work, taking the polymerisation...

A study on the kinetics and thermal properties of polystyrene/diatomite nanocomposites prepared via in situ ATRP

2018 ◽  
Vol 33 (2) ◽  
pp. 180-197 ◽  
Author(s):  
Khezrollah Khezri ◽  
Yousef Fazli
Keyword(s):  
Molecular Weight ◽  
In Situ Polymerization ◽  
Structural Characteristics ◽  
Nitrogen Adsorption ◽  
Linear Increase ◽  
Size Exclusion ◽  
Scanning Calorimetry ◽  
Morphological Studies ◽  
Exclusion Chromatography

Pristine mesoporous diatomite was employed to prepare polystyrene/diatomite composites. Diatomite platelets were used for in situ polymerization of styrene by atom transfer radical polymerization to synthesize tailor-made polystyrene nanocomposites. X-Ray fluorescence spectrometer analysis and thermogravimetric analysis (TGA) were employed for evaluating some inherent properties of pristine diatomite platelets. Nitrogen adsorption/desorption isotherm is applied to examine surface area and structural characteristics of the diatomite platelets. Evaluation of pore size distribution and morphological studies were also performed by scanning and transmission electron microscopy. Conversion and molecular weight determinations were carried out using gas and size exclusion chromatography, respectively. Linear increase of ln ( M0/M) with time for all the samples shows that polymerization proceeds in a living manner. Addition of 3 wt% pristine mesoporous diatomite leads to an increase of conversion from 72% to 89%. Molecular weight of polystyrene chains increases from 11,326 g mol−1 to 14134 g mol−1 with the addition of 3 wt% pristine mesoporous diatomite; however, polydispersity index values increases from 1.13 to 1.38. Increasing thermal stability of the nanocomposites is demonstrated by TGA. Differential scanning calorimetry shows an increase in glass transition temperature from 81.9°C to 87.1°C by adding 3 wt% of mesoporous diatomite platelets.

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland-Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

2018 ◽  
Vol 25 (9) ◽  
pp. 2179-2183 ◽  
Author(s):  
Dániel Fegyverneki ◽  
Natália Kolozsvári ◽  
Dániel Molnár ◽  
Orsolya Egyed ◽  
Tamás Holczbauer ◽  
...  
Keyword(s):  
Structural Parameters ◽  
Size Exclusion ◽  
Claisen Rearrangements

Radical copolymerization of acrylic acid and OEGMA475: Monomer reactivity ratios and structural parameters of the copolymer

2014 ◽  
Vol 22 (12) ◽  
pp. 1330-1336 ◽  
Author(s):  
Hossein Abdollahi ◽  
Vahid Najafi ◽  
Farshid Ziaee ◽  
Kourosh Kabiri ◽  
Farhad Narimani
Keyword(s):  
Acrylic Acid ◽  
Structural Parameters ◽  
Radical Copolymerization ◽  
Reactivity Ratios ◽  
Monomer Reactivity Ratios

scholarly journals Preparation and Characterization of Gradient Compressed Porous Metal for High-Efficiency and Thin-Thickness Acoustic Absorber

Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1413 ◽  
Author(s):  
Xiaocui Yang ◽  
Xinmin Shen ◽  
Panfeng Bai ◽  
Xiaohui He ◽  
Xiaonan Zhang ◽  
...  
Keyword(s):  
Sound Absorption ◽  
High Efficiency ◽  
Structural Parameters ◽  
Porous Metal ◽  
Theoretical Models ◽  
Absorption Efficiency ◽  
Total Thickness ◽  
Porous Metals ◽  
Absorption Coefficients ◽  
Optimal Average

Increasing absorption efficiency and decreasing total thickness of the acoustic absorber is favorable to promote its practical application. Four compressed porous metals with compression ratios of 0%, 30%, 60%, and 90% were prepared to assemble the four-layer gradient compressed porous metals, which aimed to develop the acoustic absorber with high-efficiency and thin thickness. Through deriving structural parameters of thickness, porosity, and static flow resistivity for the compressed porous metals, theoretical models of sound absorption coefficients of the gradient compressed porous metals were constructed through transfer matrix method according to the Johnson–Champoux–Allard model. Sound absorption coefficients of four-layer gradient compressed porous metals with the different permutations were theoretically analyzed and experimentally measured, and the optimal average sound absorption coefficient of 60.33% in 100–6000 Hz was obtained with the total thickness of 11 mm. Sound absorption coefficients of the optimal gradient compressed porous metal were further compared with those of the simple superposed compressed porous metal, which proved that the former could obtain higher absorption efficiency with thinner thickness and fewer materials. These phenomena were explored by morphology characterizations. The developed high-efficiency and thin-thickness acoustic absorber of gradient compressed porous metal can be applied in acoustic environmental detection and industrial noise reduction.

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