scholarly journals Biodegradable PGA/PBAT Blends for 3D Printing: Material Performance and Periodic Minimal Surface Structures

Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3757
Author(s):  
Zihui Zhang ◽  
Fengtai He ◽  
Bo Wang ◽  
Yiping Zhao ◽  
Zhiyong Wei ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Three Dimensional ◽  
Weight Ratio ◽  
Polyglycolic Acid ◽  
Green Energy ◽  
Surface Structures ◽  
Good Thermal Stability ◽  
Fused Deposition

Biodegradable polymers have been rapidly developed for alleviating excessive consumption of non-degradable plastics. Additive manufacturing is also a green energy-efficiency and environment-protection technique to fabricate complicated structures. Herein, biodegradable polyesters, polyglycolic acid (PGA) and poly (butyleneadipate-co-terephthalate) (PBAT) were blended and developed into feedstock for 3D printing. Under a set of formulations, PGA/PBAT blends exhibited a tailored stiffness-toughness mechanical performance. Then, PGA/PBAT (85/15 in weight ratio) with good thermal stability and mechanical property were extruded into filaments with a uniform wire diameter. Mechanical testing clearly indicated that FDM 3D-printed exhibited comparable tensile, flexural and impact properties with injection-molded samples of PGA/PBAT (85/15). Furthermore, uniform and graded Diamond-Triply Periodic Minimal Surfaces (D-TPMS) structures were designed and successfully manufactured via the fused deposition modeling (FDM) technique. Computer tomography (CT) was employed to confirm the internal three-dimensional structures. The compressive test results showed that PGA/PBAT (85/15) D-surface structures bear better load-carrying capacity than that of neat PGA, giving an advantage of energy absorption. Additionally, typical industrial parts were manufactured with excellent dimension-stability, no-wrapping and fine quality. Collectively, biodegradable PGA/PBAT material with good printability has great potentials in application requiring stiffer structures.

Mechanical performance of honeycomb sandwich structures built by FDM printing technique

2021 ◽  
pp. 089270572199789
Author(s):  
S Gohar ◽  
G Hussain ◽  
A Ali ◽  
H Ahmad
Keyword(s):  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Sandwich Structures ◽  
Weight Ratio ◽  
High Strength ◽  
Core Material ◽  
Interfacial Bond Strength ◽  
Fused Deposition ◽  
Competitive Prices ◽  
Composite Face

Honey Comb Sandwich Structures (HCSS) have numerous applications in aerospace, automobile, and satellite industry because of their properties like high strength to weight ratio, stiffness and impact strength. Fused Deposition Modeling (FDM) is a process which, through its flexibility, simple processing, short manufacturing time, competitive prices and freedom of design, has an ability to enhance the functionality of HCSS. This paper investigates the mechanical behavior (i.e. flexural, edgewise compression and Interfacial bond strength) of FDM-built HCSS. The influence of face/core material was examined by manufacturing four types of specimens namely ABS core with Composite (PLA + 15% carbon fibers) face sheets, ABS core with PLA face sheets, TPU core with composite face sheets and TPU core with PLA face sheets. To measure the effect of face sheets geometry, raster layup was varied at 0°/90° and 45°/−45°. The mechanical characterization revealed that an optimum combination of materials is ABS core with composite face sheets having raster layup of 0°/90°. This study indicates that HCSS with complex lamination schemes and adequate mechanical properties could be manufactured using FDM which may widen the applications of FDM on an industrial scale.

scholarly journals Mesh-Type Three-Dimensional (3D) Printing of Human Organs and Tumors: Fast, Cost-Effective, and Personalized Anatomic Modeling of Patient-Oriented Visual Aids

2021 ◽  
Vol 11 (3) ◽  
pp. 1047
Author(s):  
Jungirl Seok ◽  
Sungmin Yoon ◽  
Chang Hwan Ryu ◽  
Junsun Ryu ◽  
Seok-ki Kim ◽  
...  
Keyword(s):  
3D Printing ◽  
3D Modeling ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Tumor Location ◽  
Visual Aids ◽  
Surgical Specimen ◽  
Personalized Care ◽  
Fused Deposition ◽  
Mesh Work

Although three-dimensional (3D)-printed anatomic models are not new to medicine, the high costs and lengthy production times entailed have limited their application. Our goal was developing a new and less costly 3D modeling method to depict organ-tumor relations at faster printing speeds. We have devised a method of 3D modeling using tomographic images. Coordinates are extracted at a specified interval, connecting them to create mesh-work replicas. Adjacent constructs are depicted by density variations, showing anatomic targets (i.e., tumors) in contrasting colors. An array of organ solid-tumor models was printed via a Fused Deposition Modeling 3D printer at significantly less cost ($0.05/cm3) and time expenditure (1.73 min/cm3; both, p < 0.001). Printed models helped promote visual appreciation of organ-tumor anatomy and adjacent tissues. Our mesh-work 3D thyroidal prototype reproduced glandular size/contour and tumor location, readily approximating the surgical specimen. This newly devised mesh-type 3D printing method may facilitate anatomic modeling for personalized care and improve patient awareness during informed surgical consent.

scholarly journals 3D-Printable PP/SEBS Thermoplastic Elastomeric Blends: Preparation and Properties

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 347 ◽  
Author(s):  
Shib Banerjee ◽  
Stephen Burbine ◽  
Nischay Kodihalli Shivaprakash ◽  
Joey Mead
Keyword(s):  
3D Printing ◽  
Carbon Black ◽  
Computer Aided Design ◽  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Polymeric Materials ◽  
Fused Deposition ◽  
3D Printed ◽  
Injection Molded ◽  
Preferential Location

Currently, material extrusion 3D printing (ME3DP) based on fused deposition modeling (FDM) is considered a highly adaptable and efficient additive manufacturing technique to develop components with complex geometries using computer-aided design. While the 3D printing process for a number of thermoplastic materials using FDM technology has been well demonstrated, there still exists a significant challenge to develop new polymeric materials compatible with ME3DP. The present work reports the development of ME3DP compatible thermoplastic elastomeric (TPE) materials from polypropylene (PP) and styrene-(ethylene-butylene)-styrene (SEBS) block copolymers using a straightforward blending approach, which enables the creation of tailorable materials. Properties of the 3D printed TPEs were compared with traditional injection molded samples. The tensile strength and Young’s modulus of the 3D printed sample were lower than the injection molded samples. However, no significant differences could be found in the melt rheological properties at higher frequency ranges or in the dynamic mechanical behavior. The phase morphologies of the 3D printed and injection molded TPEs were correlated with their respective properties. Reinforcing carbon black was used to increase the mechanical performance of the 3D printed TPE, and the balancing of thermoplastic elastomeric and mechanical properties were achieved at a lower carbon black loading. The preferential location of carbon black in the blend phases was theoretically predicted from wetting parameters. This study was made in order to get an insight to the relationship between morphology and properties of the ME3DP compatible PP/SEBS blends.

scholarly journals Cellulose Nanofibrils Filled Poly(Lactic Acid) Biocomposite Filament for FDM 3D Printing

Molecules ◽  
2020 ◽  
Vol 25 (10) ◽  
pp. 2319 ◽  
Author(s):  
Qianqian Wang ◽  
Chencheng Ji ◽  
Lushan Sun ◽  
Jianzhong Sun ◽  
Jun Liu
Keyword(s):  
Thermal Stability ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Cellulose Nanofibrils ◽  
Poly Lactic Acid ◽  
Fused Deposition ◽  
Wide Range ◽  
The Matrix ◽  
Direct Digital Manufacturing

As direct digital manufacturing, 3D printing (3DP) technology provides new development directions and opportunities for the high-value utilization of a wide range of biological materials. Cellulose nanofibrils (CNF) and polylactic acid (PLA) biocomposite filaments for fused deposition modeling (FDM) 3DP were developed in this study. Firstly, CNF was isolated by enzymatic hydrolysis combined with high-pressure homogenization. CNF/PLA filaments were then prepared by melt-extrusion of PLA as the matrix and CNF as the filler. Thermal stability, mechanical performance, and water absorption property of biocomposite filaments and 3D-printed objects were analyzed. Findings showed that CNF increased the thermal stability of the PLA/PEG600/CNF composite. Compared to unfilled PLA FDM filaments, the CNF filled PLA biocomposite filament showed an increase of 33% in tensile strength and 19% in elongation at break, suggesting better compatibility for desktop FDM 3DP. This study provided a new potential for the high-value utilization of CNF in 3DP in consumer product applications.

scholarly journals Research on the Application of MWCNTs/PLA Composite Material in the Manufacturing of Conductive Composite Products in 3D Printing

Micromachines ◽  
2018 ◽  
Vol 9 (12) ◽  
pp. 635 ◽  
Author(s):  
Jinjie Luo ◽  
Haibao Wang ◽  
Duquan Zuo ◽  
Anping Ji ◽  
Yaowen Liu
Keyword(s):  
Composite Material ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Poly Lactic Acid ◽  
Melt Flow Rate ◽  
Conductive Composites ◽  
Fused Deposition ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

As an advanced manufacturing technology that has been developed in recent years, three-dimensional (3D) printing of macromolecular materials can create complex-shaped components that cannot be realized by traditional processing. However, only a few types of macromolecular materials are suitable for 3D printing: the structure must have a single function, and manufacturing macromolecular functional devices is difficult. In this study, using poly lactic acid (PLA) as a matrix, conductive composites were prepared by adding various contents of multi-walled carbon nanotubes (MWCNTs). The printability and properties of MWCNT/PLA composites with different MWCNT proportions were studied by using the fused deposition modeling (FDM) processing technology of 3D printing. The experimental results showed that high conductivity can be realized in 3D-printed products with a composite material containing 5% MWCNTs; its conductivity was 0.4 ± 0.2 S/cm, its tensile strength was 78.4 ± 12.4 MPa, and its elongation at break was 94.4% ± 14.3%. It had a good melt flow rate and thermal properties, and it enabled smooth printing, thus meeting all the requirements for the 3D printing of consumables.

A Heuristic Scaling Strategy for Multi-Robot Cooperative Three-Dimensional Printing

2020 ◽  
Vol 20 (4) ◽  
Author(s):  
Laxmi Poudel ◽  
Chandler Blair ◽  
Jace McPherson ◽  
Zhenghui Sha ◽  
Wenchao Zhou
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Evaluation Framework ◽  
Geometric Constraints ◽  
Mathematical Representation ◽  
Printing Process ◽  
Fused Deposition ◽  
3D Printers ◽  
Printing Time

Abstract While three-dimensional (3D) printing has been making significant strides over the past decades, it still trails behind mainstream manufacturing due to its lack of scalability in both print size and print speed. Cooperative 3D printing (C3DP) is an emerging technology that holds the promise to mitigate both of these issues by having a swarm of printhead-carrying mobile robots working together to finish a single print job cooperatively. In our previous work, we have developed a chunk-based printing strategy to enable the cooperative 3D printing with two fused deposition modeling (FDM) mobile 3D printers, which allows each of them to print one chunk at a time without interfering with the other and the printed part. In this paper, we present a novel method in discretizing the continuous 3D printing process, where the desired part is discretized into chunks, resulting in multi-stage 3D printing process. In addition, the key contribution of this study is the first working scaling strategy for cooperative 3D printing based on simple heuristics, called scalable parallel arrays of robots for 3DP (SPAR3), which enables many mobile 3D printers to work together to reduce the total printing time for large prints. In order to evaluate the performance of the printing strategy, a framework is developed based on directed dependency tree (DDT), which provides a mathematical and graphical description of dependency relationships and sequence of printing tasks. The graph-based framework can be used to estimate the total print time for a given print strategy. Along with the time evaluation metric, the developed framework provides us with a mathematical representation of geometric constraints that are temporospatially dynamic and need to be satisfied in order to achieve collision-free printing for any C3DP strategy. The DDT-based evaluation framework is then used to evaluate the proposed SPAR3 strategy. The results validate the SPAR3 as a collision-free strategy that can significantly shorten the printing time (about 11 times faster with 16 robots for the demonstrated examples) in comparison with the traditional 3D printing with single printhead.

scholarly journals Polymers for Extrusion-Based 3D Printing of Pharmaceuticals: A Holistic Materials–Process Perspective

Pharmaceutics ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 124 ◽  
Author(s):  
Mohammad A. Azad ◽  
Deborah Olawuni ◽  
Georgia Kimbell ◽  
Abu Zayed Md Badruddoza ◽  
Md. Shahadat Hossain ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Active Pharmaceutical Ingredient ◽  
Dosage Forms ◽  
Polymer Mixtures ◽  
Compression Process ◽  
Fused Deposition ◽  
Process Perspective ◽  
Printing Processes

Three dimensional (3D) printing as an advanced manufacturing technology is progressing to be established in the pharmaceutical industry to overcome the traditional manufacturing regime of 'one size fits for all'. Using 3D printing, it is possible to design and develop complex dosage forms that can be suitable for tuning drug release. Polymers are the key materials that are necessary for 3D printing. Among all 3D printing processes, extrusion-based (both fused deposition modeling (FDM) and pressure-assisted microsyringe (PAM)) 3D printing is well researched for pharmaceutical manufacturing. It is important to understand which polymers are suitable for extrusion-based 3D printing of pharmaceuticals and how their properties, as well as the behavior of polymer–active pharmaceutical ingredient (API) combinations, impact the printing process. Especially, understanding the rheology of the polymer and API–polymer mixtures is necessary for successful 3D printing of dosage forms or printed structures. This review has summarized a holistic materials–process perspective for polymers on extrusion-based 3D printing. The main focus herein will be both FDM and PAM 3D printing processes. It elaborates the discussion on the comparison of 3D printing with the traditional direct compression process, the necessity of rheology, and the characterization techniques required for the printed structure, drug, and excipients. The current technological challenges, regulatory aspects, and the direction toward which the technology is moving, especially for personalized pharmaceuticals and multi-drug printing, are also briefly discussed.

scholarly journals An overview on 3D Printed Medicine

2021 ◽  
Vol 18 (1) ◽  
pp. 07-13
Author(s):  
Neha Thakur ◽  
Hari Murthy
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Low Cost ◽  
Selective Laser Sintering ◽  
Three Dimensional ◽  
Herbal Medicines ◽  
Fused Deposition ◽  
Digitally Controlled ◽  
3D Printed ◽  
Semi Solid

Three-dimensional printing (3DP) is a digitally-controlled additive manufacturing technique used for fast prototyping. This paper reviews various 3D printing techniques like Selective Laser Sintering (SLS), Fused Deposition Modeling, (FDM), Semi-solid extrusion (SSE), Stereolithography (SLA), Thermal Inkjet (TIJ) Printing, and Binder jetting 3D Printing along with their application in the field of medicine. Normal medicines are based on the principle of “one-size-fits-all”. This is not true always, it is possible medicine used for curing one patient is giving some side effects to another. To overcome this drawback “3D Printed medicines” are developed. In this paper, 3D printed medicines forming different Active Pharmaceutical Ingredients (API) are reviewed. Printed medicines are capable of only curing the diseases, not for the diagnosis. Nanomedicines have “theranostic” ability which combines therapeutic and diagnostic. Nanoparticles are used as the drug delivery system (DDS) to damaged cells’ specific locations. By the use of nanomedicine, the fast recovery of the disease is possible. The plant-based nanoparticles are used with herbal medicines which give low-cost and less toxic medication called nanobiomedicine. 4D and 5D printing technology for the medical field are also enlightened in this paper.

Multimaterial printing and characterization for mechanical and surface properties of functionally graded prototype

2019 ◽  
Vol 233 (19-20) ◽  
pp. 6741-6753 ◽  
Author(s):  
Sudhir Kumar ◽  
Rupinder Singh ◽  
TP Singh ◽  
Ajay Batish
Keyword(s):  
Polylactic Acid ◽  
Surface Properties ◽  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Three Dimensional ◽  
Surface Hardness ◽  
Functionally Graded ◽  
Three Dimensional Printing ◽  
Fused Deposition ◽  
Dimensional Printing

In this work, an effort has been made for multimaterial three-dimensional printing of functionally graded prototypes of polylactic acid matrix (tensile specimens as per ASTM D638 type IV) followed by characterization of mechanical and surface properties. The work is an extension of previous reported studies on twin-screw extrusion process for the preparation of multimaterial wires as feedstock filaments in possible three-dimensional printing applications. The results of the study suggest that the highest peak strength (46.28 MPa) and break strength (41.65 MPa) was obtained for multimaterial three-dimensional printed samples at infill density 100%, infill angle 45°, and infill speed of 90 mm/s on commercial open source fused deposition modeling setup. Further surface hardness measurements performed on two extreme surfaces (top surface comprising magnetite (Fe3O4)-reinforced polylactic acid and bottom with polylactic acid without any reinforcement) revealed that the hardness for the bottom layer was more than the hardness for the top layer. From fractured surface analysis (using photomicrographs), it has been observed that the three-dimensional printed samples with low infill density resulted into more void formation due to which the performance while mechanical testing was poor in comparison to samples printed with higher infill density. The results are also supported by rendered images of photomicrographs, which revealed that high roughness value of samples printed with low infill density was also one of the reasons for poor mechanical performance of multimaterial three-dimensional printed functionally graded prototypes.

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