scholarly journals Solubility and Activation of Hydrogen in the Non-Catalytic Upgrading of Venezuela Orinoco, China Liaohe, and China Fengcheng Atmospheric Residues

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2274
Author(s):  
Shunfeng Ji ◽  
Anran Zeng
Keyword(s):  
Gas Phase ◽  
Hydrogen Solubility ◽  
Reaction Conditions ◽  
Hydrogen Activation ◽  
Catalytic Upgrading ◽  
Positive Effects ◽  
Structure Changes ◽  
Composition And Structure ◽  
Reaction Proceeds ◽  
Positive Effect

The solubility of hydrogen in the Venezuela Orinoco, China Liaohe, and China Fengcheng atmospheric residues under reaction conditions of 400 °C, 4 MPa for 20 min was analyzed by determining the composition and structure changes of the products. Activation of hydrogen during the upgrading process was also determined and discussed by the probe method. The results show that lighter components produced in the reaction can increase the hydrogen solubility as the reaction proceeds, and the lighter components present at the liquid level have positive effects on the transfer of hydrogen from the gas phase to the liquid phase. Naphthenic aromatic structures, sulphur and metals have a positive effect on hydrogen activation in the trend of naphthenic aromatic structures > sulphur > metals. Moreover, when sulphur is present, nickel tetraphenylporphyrin has a better effect on hydrogen activation than Vanadium tetraphenylporphyrin. During upgrading, the Venezuela Orinoco atmospheric residue with more sulphur, metals and naphthenic aromatic structures can activate more hydrogen. Both the hydrogen solubility and residue composition have significant effect on the upgrading process.

scholarly journals Selective Nitration of Chlorobenzene by NO2 in the Alkali Zeolite NaZSM-5

2013 ◽  
Vol 2013 ◽  
pp. 1-5
Author(s):  
Scott J. Kirkby
Keyword(s):  
Gas Phase ◽  
Room Temperature ◽  
Temperature Dependent ◽  
Reaction Conditions ◽  
Cation Site ◽  
Zeolite Lattice ◽  
Reaction Proceeds ◽  
Ft Ir ◽  
Electron Donation

Chlorobenzene was reacted with NO2, in the initially acid-free zeolite NaZSM-5, to yield para-chloronitrobenzene exclusively. The precursors were loaded sequentially into self-supporting pellets of the zeolite, contained within a stainless steel cell, from the gas phase. The reaction proceeds spontaneously at room temperature. It is, however, very temperature dependent and effectively ceases at zero degrees Celsius. The reaction was monitored in situ using FT-IR. The active nitrating agent is formed from the partial electron donation by the NO2 to the Na+ cations present in the zeolite lattice. Under the reaction conditions, chlorobenzene is not readily mobile through the pore system; thus, only the molecules adsorbed near a cation site react to form para-chloronitrobenzene.

Impact of Digitalization on Service Work in Knowledge-Intensive Business Services: An Empirical Study in Tax Consultancies

2019 ◽  
Vol 3 (4) ◽  
pp. 209-222
Author(s):  
Philipp K. Görs ◽  
Henning Hummert ◽  
Anne Traum ◽  
Friedemann W. Nerdinger
Keyword(s):  
Work Engagement ◽  
Service Work ◽  
Psychological Consequences ◽  
Business Services ◽  
Knowledge Intensive Business Services ◽  
Positive Effects ◽  
Knowledge Intensive ◽  
The Impact ◽  
Positive Effect ◽  
Special Case

Digitalization is a megatrend, but there is relatively little knowledge about its consequences for service work in general and specifically in knowledge-intensive business services (KIBS). We studied the impact of digitalization on psychological consequences for employees in tax consultancies as a special case of KIBS. We compare two tax consulting jobs with very different job demands, those of tax consultants (TCs) and assistant tax consultants (ATCs). The results show that the extent of digitalization at the workplace level for ATCs correlates significantly positively with their job satisfaction. For TCs, the same variable correlates positively with their work engagement. These positive effects of digitalization are mediated in the case of ATCs by the impact on important job characteristics. In the case of TCs, which already have very good working conditions, the impact is mediated by the positive effect on self-efficacy. Theoretical and practical consequences of these results are discussed.

scholarly journals The Structural Relationship among Perceived Service Quality, Perceived Value, and Customer Satisfaction-Focused on Starbucks Reserve Coffee Shops in Shanghai, China

2021 ◽  
Vol 13 (15) ◽  
pp. 8633
Author(s):  
Yuhan Ge ◽  
Qing Yuan ◽  
Yaxi Wang ◽  
Keunsoo Park
Keyword(s):  
Customer Satisfaction ◽  
Service Quality ◽  
Behavioral Intention ◽  
Perceived Value ◽  
Significant Positive Effect ◽  
Coffee Shop ◽  
Perceived Service Quality ◽  
Positive Effects ◽  
Coffee Shops ◽  
Positive Effect

In today’s increasingly competitive coffee industry, the point of running a good coffee shop is no longer to run a coffee and beverage shop simply, but to focus on the quality of service and the value that customers feel as a result. Previous studies have mainly discussed the customer satisfaction and behavioral intention of restaurants, while few studies have explored the influencing factors of customer satisfaction and behavioral intention of chain coffee shops. Given that the perceived service quality theory and DINESERV model can effectively predict customer satisfaction and behavioral intention, this study took 385 consumers in the first Starbucks Reserve flagship store in China as survey objects. SmartPLS 3.0 software was used to explore the relationship among respondents’ perceived service quality, customer perceived value, satisfaction, and behavioral intention. The results show that service quality has a partially significant positive effect on perceived value. Perceived service quality and customers’ perceived value both have significant positive effects on satisfaction. Customers’ satisfaction has a significant positive effect on their behavioral intention. These results indicate that enterprises should strengthen the emotional bond between consumers and enterprises and improve the reliability, assurance, and empathy of perceived service quality to create a better emotional resonance between consumers and the Starbucks brand to improve customer satisfaction. At the same time, it should also promote the symbolic perceived value of Chinese consumers to Starbucks to realize the sustainable development of coffee-shop operation and consumer repurchase. This study expands the research on the service quality, perceived value, and behavioral intention of coffee chain enterprises in the context of non-habitual coffee-drinking countries. Moreover, it provides case support for the operation and research of regional cultural consumption habits of international catering chain enterprises.

scholarly journals The Influence of Dynamic and Adaptive Marketing Capabilities on the Performance of Portuguese SMEs in the B2B International Market

2021 ◽  
Vol 13 (2) ◽  
pp. 579
Author(s):  
Caroline Reimann ◽  
Fernando Carvalho ◽  
Marcelo Duarte
Keyword(s):  
Positive Impact ◽  
International Marketing ◽  
International Market ◽  
Marketing Capabilities ◽  
Moderating Effects ◽  
Competitive Intensity ◽  
Positive Effects ◽  
Marketing Performance ◽  
Market Learning ◽  
Positive Effect

The present investigation aims study the sustainability of the business model of the Portuguese SMEs operating in the B2B International market analyzing the influence of dynamic marketing capabilities and adaptive marketing capabilities in their international marketing performance. It will also analyze the moderating effects of Competitive Intensity within this international scenario. A quantitative study was developed, using a questionnaire as a research method. In total, 335 valid responses were collected from Portuguese SMEs in June 2020. To test the hypotheses, multiple hierarchical regressions were performed. As for the analyzes involving Competitive Intensity environments, namely low and high intensity, dummies were developed to evaluate the different effects produced by the capacities in the International Marketing Performance. This study shows the positive impact of the dynamic marketing capabilities and adaptive marketing capabilities on the international marketing performance of the surveyed companies, essentially from the product development management, supply chain management, vigilant market learning and open marketing. when in a low competitive intensity environment only dynamic marketing capabilities had a positive effect on performance, but in a high, competitive, intensity environment both dynamic marketing capabilities and adaptive marketing capabilities showed positive effects in relation to performance. This study innovates by bringing international marketing, through two marketing capacities, from the perspective of SMEs that perform B2B activities.

scholarly journals Weaning Holstein Calves at 17 Weeks of Age Enables Smooth Transition from Liquid to Solid Feed

Animals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1132
Author(s):  
Sarah Schwarzkopf ◽  
Asako Kinoshita ◽  
Jeannette Kluess ◽  
Susanne Kersten ◽  
Ulrich Meyer ◽  
...  
Keyword(s):  
Metabolic Stress ◽  
Live Weight ◽  
The Other ◽  
Smooth Transition ◽  
Blood Metabolites ◽  
Positive Effects ◽  
Weaning Age ◽  
Holstein Calves ◽  
Positive Effect ◽  
Over Time

Development of calves depends on prenatal and postnatal conditions. Primiparous cows were still maturing during pregnancy, which can lead to negative intrauterine conditions and affect the calf’s metabolism. It is hypothesized that weaning calves at higher maturity has positive effects due to reduced metabolic stress. We aimed to evaluate effects of mothers’ parity and calves’ weaning age on growth performance and blood metabolites. Fifty-nine female Holstein calves (38.8 ± 5.3 kg birth weight, about 8 days old) were used in a 2 × 2 factorial experiment with factors weaning age (7 vs. 17 weeks) and parity of mother (primiparous vs. multiparous cows). Calves were randomly assigned one of these four groups. Live weight, live weight gain and morphometry increased over time and were greater in calves weaned later. Metabolic indicators except total protein were interactively affected by time and weaning age. Leptin remained low in early-weaned calves born to primiparous cows, while it increased in the other groups. The results suggest that weaning more mature calves has a positive effect on body growth, and calves born to primiparous cows particularly benefit from this weaning regimen. It also enables a smooth transition from liquid to solid feed, which might reduce the associated stress of weaning.

Brokerage and SME Innovation

2012 ◽  
Vol 26 (5) ◽  
pp. 381-391 ◽  
Author(s):  
Paolo Cattapan ◽  
Mariacarmela Passarelli ◽  
Michele Petrone
Keyword(s):  
Best Practice ◽  
Job Creation ◽  
Science Park ◽  
Revenue Growth ◽  
Positive Effects ◽  
Industry Collaboration ◽  
Product And Process Innovation ◽  
Product And Process ◽  
Positive Effect ◽  
Micro Enterprises

This paper contributes to the literature on innovation brokerage by analysing the effects of brokerage activities on the innovation and growth of small and medium-sized enterprises (SMEs). The authors provide a detailed description of the Technology Transfer Service (TTS), credited as a European best-practice innovation broker, at Area Science Park in Italy. They then carry out an exploratory econometric analysis, the results of which show that the support provided by the TTS enables research–industry collaboration and has positive effects on product and process innovation in SMEs, but it appears not to affect the generation of new patents in SMEs. The results also suggest that the growth in innovation enabled by the support of TTS has a positive effect on the SMEs' revenue growth and job creation. However the innovation broker is more effective in relation to larger firms than it is for micro-enterprises.

Gas phase oxidation of furfural to maleic anhydride on V 2 O 5 /γ-Al 2 O 3 catalysts: Reaction conditions to slow down the deactivation

2017 ◽  
Vol 348 ◽  
pp. 265-275 ◽  
Author(s):  
N. Alonso-Fagúndez ◽  
M. Ojeda ◽  
R. Mariscal ◽  
J.L.G. Fierro ◽  
M. López Granados
Keyword(s):  
Maleic Anhydride ◽  
Gas Phase ◽  
Reaction Conditions ◽  
Phase Oxidation ◽  
Gas Phase Oxidation

Modern aspects of the use of drugs of microbial origin

2021 ◽  
Author(s):  
I. O. Pasichna ◽  
V. I. Vdovychenko
Keyword(s):  
Intestinal Microflora ◽  
Antibacterial Properties ◽  
Low Molecular Weight ◽  
Positive Effects ◽  
Microbial Origin ◽  
Transient Nature ◽  
Immunological Effects ◽  
Positive Effect ◽  
Intestinal Microbiocenosis

The recent scientific researches provide evidence of the important role of microbiota for human health. The microbiome is a very complex system, that exists in an equilibrium state and performs multiple functions. The intestinal microflora is disturbed under the influence of iatrogenic factors, and products of microbial origin are used to correct this. The first group of such drugs include probiotics. Their positive effect is associated with immunological and non‑immunological effects. The results of many studies proved the positive effects of probiotics in clinical practice, however publications of recent years outline their low effectiveness and transient nature of the effect, even with prolonged use. Another group of preparations refers to prebiotics, which selectively stimulate the growth of colon microflora. A combination of probiotics and prebiotics, called synbiotics, also in use. Currently, much attention is paid to metabiotics. This group includes various low molecular weight molecules with various chemical manifestations. The components of metabiotics are cellular elements, metabolites and signaling molecules of probiotic cultures. Metabiotics provide the optimal conditions of homeostasis in the contact zone, which are necessary for the normal interaction of the epithelium and microflora, as well as directly affect the physiological functions and biochemical reactions of the macroorganism. The antibacterial properties of metabiotics allow to fight pathogenic and opportunistic flora, without affecting the beneficial microorganisms of the intestine. Creation of targeted metabiotics is a novel promising direction in this area. The possibility of creating a programmed metabiotic drug is considered, depending on the type of disorders of the intestinal microbiocenosis and the peculiarities of the life of specific pathogenic or opportunistic strains.

scholarly journals Preparation of Glucosamine Hydrochloride from Indigenous Shrimp Processing Waste

1970 ◽  
Vol 46 (3) ◽  
pp. 375-378 ◽  
Author(s):  
MM Islam ◽  
SM Masum ◽  
MM Rahman ◽  
AA Shaikh
Keyword(s):  
Maximum Yield ◽  
Therapeutic Activity ◽  
Processing Waste ◽  
Reaction Conditions ◽  
Glucosamine Hydrochloride ◽  
Glycoside Linkage ◽  
Shrimp Shell ◽  
Reaction Proceeds ◽  
Ft Ir ◽  
Hydrolysis Of

The present investigation described the effective preparation of glucosamine hydrochloride (GluHCl) from chitin which was extracted from indigenous shrimp shell. GluHCl has attracted much attention owing to its therapeutic activity in osteoarthritis and widely used dietary supplement. The key step involved was extraction of chitin from shrimp skeleton and then hydrolysis of chitin by concentrated hydrochloric acid. The reaction proceeds via break down of glycoside linkage. Structural analysis was carried out by melting point, TLC, FT-IR, elemental analysis and all the data were compared with that of standard GluHCl. The elemental (C, 32.75; H, 6.51; N, 6.20) analysis is good concord with the calculated value (C, 33.42; H, 6.54; N, 6.50). Absence of v max at 1726 cm-1 indicates that GluHCl is a deacetylated product of chitin. The yields of the product mainly depend on reaction conditions. Maximum yield (63.5%) was obtained when chitin was hydrolyzed with concentrated HCl for 1.30 h. Key words: Shrimp shell; Chitin, Acid hydrolysis; Glucosamine hydrochloride Osteoarthritis. DOI: http://dx.doi.org/10.3329/bjsir.v46i3.9046 BJSIR 2011; 46(3): 375-378

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