scholarly journals Insights into the Simultaneous Sorption of Ciprofloxacin and Heavy Metals Using Functionalized Biochar

Water ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 2768
Author(s):  
Agnieszka Cuprys ◽  
Zakhar Maletskyi ◽  
Tarek Rouissi ◽  
Harsha Ratnaweera ◽  
Satinder Kaur Brar ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Adsorption Capacity ◽  
Water Purification ◽  
Cost Effective ◽  
Pig Manure ◽  
Simultaneous Removal ◽  
Adsorption Ability ◽  
Free Ions ◽  
Co Precipitation ◽  
Simultaneous Sorption

Biochar and chitosan are considered as green and cost-effective adsorbents for water purification; the combination of these two materials may lead to an improved adsorption capacity of the generated adsorbents. Most sorption studies have been focused on the ability to adsorb one contaminant or the same type of contaminants. Thus, this study aimed to produce chitosan-biochar beads (CH-BB) and test their efficiency in the simultaneous removal of a metal-complexing antibiotic, ciprofloxacin (CIP), and three metal(loid)s (As, Cd and Pb). Modification of raw pig manure biochar resulted in an increase in its adsorption capacity, except for Pb. The highest increment was observed for As (almost 6-fold) and the lowest was observed for CIP (1.1-fold). The adsorbent was able to simultaneously remove all targeted contaminants, individually and in the mixture. The adsorption capacity of CH-BB followed the order: Pb > Cd > >As > CIP. When Pb and As were present in the same mixture, their removal efficiency increased from 0.13 ± 0.01 to 0.26 ± 0.05 mg/g for As and from 0.75 ± 0.08 to 0.85 ± 0.02 mg/g for Pb due to their co-precipitation. The CIP–metal complexation probably resulted in a reduced adsorption ability for inorganics due to the decreased concentration of free ions. The presence of metals and metalloids led to alterations in CIP’s mobility.

Synthesis and application of a ternary composite of clay, saw-dust and peanut husks in heavy metal adsorption

2017 ◽  
Vol 75 (10) ◽  
pp. 2443-2453 ◽  
Author(s):  
Henry H. Mungondori ◽  
Sandile Mtetwa ◽  
Lilian Tichagwa ◽  
David M. Katwire ◽  
Pardon Nyamukamba
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Adsorption Capacity ◽  
Cost Effective ◽  
Order Kinetic ◽  
Ternary Composite ◽  
Adsorption Mechanisms ◽  
Saw Dust ◽  
Order Kinetic Model ◽  
Enhanced Adsorption

The adsorption of a multi-component system of ferrous, chromium, copper, nickel and lead on single, binary and ternary composites was studied. The aim of the study was to investigate whether a ternary composite of clay, peanut husks (PH) and saw-dust (SD) exhibited a higher adsorption capacity than that of a binary system of clay and SD as well as a single component adsorbent of PH alone. The materials were used in their raw state without any chemical modifications. This was done to retain the cost effective aspect of the naturally occurring adsorbents. The adsorption capacities of the ternary composite for the heavy metals Fe2+, Cr3+, Cu2+, Ni2+ and Pb2+ were 41.7 mg/g, 40.0 mg/g, 25.5 mg/g, 41.5 mg/g and 39.0 mg/g, respectively. It was found that the ternary composite exhibited excellent and enhanced adsorption capacity compared with both a binary and single adsorbent for the heavy metals Fe2+, Ni2+ and Cr3+. Characterization of the ternary composites was done using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Kinetic models and adsorption isotherms were also studied. The pseudo second order kinetic model and the Langmuir adsorption isotherm best described the adsorption mechanisms for the ternary composite towards each of the heavy metal ions.

scholarly journals Pemanfaatan Kitosan untuk Menurunkan Kadar Logam Pb dalam Perairan yang Tercemar Minyak Bumi

2021 ◽  
Vol 10 (1) ◽  
pp. 61-66
Author(s):  
Rima Rosema ◽  
Endang Supriyantini ◽  
Sri Sedjati
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Adsorption Capacity ◽  
Research Method ◽  
Human Life ◽  
Factorial Experimental Design ◽  
Adsorption Ability ◽  
Chitosan Concentration ◽  
Experimental Laboratory ◽  
Heavy Metal Adsorbent

Kitosan telah banyak dimanfaatkan dalam berbagai bidang kehidupan manusia, salah satunya dijadikan sebagai adsorben logam berat. Logam berat timbal (Pb) merupakan polutan yang mencemari perairan dan bersifat toksik. Penelitian ini bertujuan untuk menguji kapasitas dan daya adsorpsi larutan kitosan komersial dan non komersial (produk sendiri) dalam konsentrasi berbeda terhadap logam Pb. Metode penelitian yang digunakan yaitu eksperimental laboratoris dengan rancangan percobaan Faktorial 2 Aras dengan menggunakan 1 kontrol (0 %) dan 4 perlakuan yaitu konsentrasi 0,5% (A), 1% (B), 1,5% (C) dan 2% (D). Hasil penelitian menunjukkan bahwa terdapat interaksi antara sumber kitosan dengan konsentrasi kitosan untuk menurunkan kandungan Pb. Dosis terbaik yang mampu menurunkan logam Pb untuk kitosan komersial yaitu pada konsentrasi 1% dengan kapasitas penyerapan sebesar 0,228 mg/g dan kemampuan penyerapan sebesar 87,870 %. Sedangkan kitosan non komersial mampu menurunkan logam Pb pada konsentrasi 1,5% dengan kapasitas penyerapan sebesar 0,143 mg/g dan kemampuan penyerapan sebesar 82,660 %.  Chitosan has been widely used in various fields of human life, one of which is used as a heavy metal adsorbent. Lead heavy metals (Pb) is a pollutants that pollutes the waters and is toxic. This study aims to examine the capacity and adsorption capacity of commercial and non-commercial chitosan  solutions  (own products) in  different concentrations of Pb metal. The research method used is an experimental laboratories with chitosan from the isolation itself and commercial chitosan. The research method used is an experimental laboratory with 2 Aras factorial experimental design using 1 control  (0%) and 4 treatments namely a concentrations of 0.5% (A), 1% (B), 1.5% (C) and 2% (D). The results showed that there was an interaction between chitosan sources and chitosan concentration to reduce Pb content. The best dose that can reduce Pb metal for commercial chitosan is at a concentration of 1% with an adsorption capacity of 0.228 mg/g, and an adsorption ability of 87.870 %. while non-commercial chitosan can reduce Pb metal at a concentration of 1.5 % with an adsorption capacity of 0.143 mg/g and an adsorption ability of 82.660 %.  

scholarly journals Sustainable Application of ZIF-8 for Heavy-Metal Removal in Aqueous Solutions

2021 ◽  
Vol 13 (2) ◽  
pp. 984
Author(s):  
Ke Li ◽  
Nicholas Miwornunyuie ◽  
Lei Chen ◽  
Huang Jingyu ◽  
Paulette Serwaa Amaniampong ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Aqueous Solutions ◽  
Adsorption Capacity ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Cost Effective ◽  
Future Application ◽  
Zeolitic Imidazolate Framework ◽  
Synthesis Approach

Water is life, and clean-water demand is increasing daily as a result of rapid population growth and industrial evolution. Nevertheless, due to the inadequate supply and availability of new water sources, there is a need for effective, sustainable removal of contaminants for wastewater reuse. Several treatment approaches that include chemical, physical, and biological methods have been thoroughly tested, with biological treatment being regarded as the most cost-effective and environmentally friendly method. However, the presence of heavy metals and complicated chemicals that are nonbiodegradable limits the use of this cost-effective approach. In this paper, we review the sustainable application of a cheap, water-stable metal-organic framework, the zeolitic imidazolate framework (ZIF-8), with an easier synthesis approach for heavy-metal removal in aqueous solutions. In this review, we discuss the removal efficiency in terms of adsorption capacity, describe the underlying mechanism behind the adsorption capacity of ZIF-8, present a sustainable synthesis approach, and make vital suggestions to aid in the future application of ZIF-8 for the removal of heavy metals.

Urban pollution control strategy: SBR technology to treat agricultural waste from pig farm in Indonesia

2019 ◽  
Vol 2 (2) ◽  
pp. 21
Author(s):  
Lindawati Lindawati
Keyword(s):  
Cost Estimation ◽  
Batch Reactor ◽  
Agricultural Waste ◽  
Cost Effective ◽  
Land Application ◽  
Pig Manure ◽  
Small Scale ◽  
Piggery Wastewater ◽  
Pig Farm ◽  
Number Of Customers

Reduction of food rations and shortages is one of the impacts of the increasing human population. Food sector industries then try to cope with the fast growing number of customers. Agribusiness sector gains its popularity in these recent years, including pig farm. The increase trend of animal farming industry is likely to bring increasing pollution problem unless effective treatment methods are used. The main problems related to the pig farm include odor nuisance and pig manure disposal. The existing land application of piggery wastewater is the traditional way to discharge the wastewater. This may yield in land and water contamination, due to the accumulation of unused nutrients by crop plant. A case study of a large commercial pig farm from Australia is proposed to apply in smaller scale in Indonesia. Operational strategies for the small-scale SBR (Sequencing Batch Reactor) treating piggery effluent were developed based on lab-scale experiments. Due to SBR characteristics, which are money-saving and space-saving, it is very suitable to be applied in urban area. An economic evaluation was made of various process options. The cost estimation showed that SBR is a cost effective process, allowing operational batches to be adjusted to reduce unnecessary aeration cost. A reduction in the aeration cost was achieved by shortening the batch time from 24-h to 8-h. A comparison of three different SBR options showed that smaller size reactors could be more flexible and cost effective when compared with the larger ones.

Mercury Removal from Wastewater by Steamed Hoof Powder

1999 ◽  
Vol 40 (7) ◽  
pp. 109-116 ◽  
Author(s):  
M. H. Ansari ◽  
A. M. Deshkar ◽  
P. S. Kelkar ◽  
D. M. Dharmadhikari ◽  
M. Z. Hasan ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Adsorption Capacity ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Light Metal ◽  
Mercury Removal ◽  
High Adsorption ◽  
Surface Sites ◽  
Ph Values ◽  
High Adsorption Capacity

Steamed Hoof Powder (SHP), size < 53μ, was observed to have high adsorption capacity for Hg(II) with >95% removal from a solution containing 100 mg/L of Hg(II) with only 0.1% (W/V) concentration of SHP. The SHP has good settling properties and gives clear and odour free effluent. Studies indicate that pH values between 2 and 10 have no effect on the adsorption of Hg(II) on SHP. Light metal ions like Na+, K+, Ca2+ and Mg2+ up to concentrations of 500 mg/L and heavy metals like Cu2+, Zn2+, Cd2+, Co2+, Pb2+, Ni2+, Mn2+, Cr3+, Cr6+, Fe2+ and Fe3+ up to concentrations of 100 mg/L do not interfere with the adsorption process. Anions like sulphate, acetate and phosphate up to concentrations of 200 mg/L do not interfere. Chloride interferes in the adsorption process when Hg(II) concentration is above 9.7 mg/L. The adsorption equilibrium was established within two hours. Studies indicate that adsorption occurs on the surface sites of the adsorbent.

Development and Characterization of Amine-Clay Hybrid Adsorbents for CO2 Capture

2016 ◽  
Vol 1133 ◽  
pp. 547-551 ◽  
Author(s):  
Ali E.I. Elkhalifah ◽  
Mohammad Azmi Bustam ◽  
Azmi Mohd Shariff ◽  
Sami Ullah ◽  
Nadia Riaz ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Surface Area ◽  
Surface Properties ◽  
Molar Mass ◽  
Adsorption Ability ◽  
Stepwise Increase ◽  
Inverse Effect ◽  
Bet Method ◽  
Sodium Form

The present work aims at a better understanding of the influences of the intercalated mono-, di- and triethanolamines on the characteristics and CO2 adsorption ability of sodium form of bentonite (Na-bentonite). The results revealed that the molar mass of intercalated amines significantly influenced the structural and surface properties as well as the CO2 adsorption capacity of Na-bentonite. In this respect, a stepwise increase in the d-spacing of Na-bentonite with the molar mass of amine was recorded by XRD technique. However, an inverse effect of the molar mass of amine on the surface area was confirmed by BET method. CO2 adsorption experiments on amine-bentonite hybrid adsorbents showed that the CO2 adsorption capacity inversly related to the molar mass of amine at 25 ͦC and 101 kPa. Accordingly, Na-bentonite modified by monoethanolammonium cations adsorbed as high as 0.475 mmol CO2/g compared to 0.148 and 0.087 mmol CO2/g for that one treated with di- and triethanolammonium cations, respectively.

scholarly journals Stormwater Runoff Treatment Using Pervious Concrete Modified with Various Nanomaterials: A Comprehensive Review

2021 ◽  
Vol 13 (15) ◽  
pp. 8552
Author(s):  
Vahid Alimohammadi ◽  
Mehdi Maghfouri ◽  
Delaram Nourmohammadi ◽  
Pejman Azarsa ◽  
Rishi Gupta ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Compressive Strength ◽  
Adsorption Capacity ◽  
Removal Rate ◽  
Stormwater Runoff ◽  
Infiltration Rate ◽  
Stormwater Treatment ◽  
Adsorption Mechanisms ◽  
Wide Range ◽  
Adsorption Processes

Clean water is a vital need for all living creatures during their lifespan. However, contaminated stormwater is a major issue around the globe. A wide range of contaminants, including heavy metals, organic and inorganic impurities, has been discovered in stormwater. Some commonly utilized methods, such as biological, physical and chemical procedures, have been considered to overcome these issues. However, these current approaches result in moderate to low contaminant removal efficiencies for certain classes of contaminants. Of late, filtration and adsorption processes have become more featured in permeable concretes (PCs) for the treatment of stormwater. As nanoparticles have vast potential and unique characterizations, such as a higher surface area to cure polluted stormwater, employing them to improve permeable concretes’ capabilities in stormwater treatment systems is an effective way to increase filtration and adsorption mechanisms. The present study reviews the removal rate of different stormwater contaminants such as heavy metals, organic and other pollutants using nanoparticle-improved PC. The application of different kinds of nanomaterials in PC as porous media to investigate their influences on the properties of PC, including the permeability rate, compressive strength, adsorption capacity and mix design of such concrete, was also studied. The findings of this review show that different types of nanomaterials improve the removal efficiency, compressive strength and adsorption capacity and decrease the infiltration rate of PC during the stormwater treatment process. With regard to the lack of comprehensive investigation concerning the use of nanomaterials in PC to treat polluted stormwater runoff, this study reviews 242 published articles on the removal rate of different stormwater contaminants by using PC improved with nanoparticles.

scholarly journals Application of modified green algae Nannochloropsis sp. as adsorbent in the simultaneous adsorption of Methylene Blue and Cu(II) cations in solution

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Buhani ◽  
Tri Agus Wijayanti ◽  
Suharso ◽  
Sumadi ◽  
Muslim Ansori
Keyword(s):  
Heavy Metals ◽  
Methylene Blue ◽  
Green Algae ◽  
Contact Time ◽  
Organic Dyes ◽  
Silica Matrix ◽  
Particle Coating ◽  
Adsorption Data ◽  
Magnetite Particles ◽  
Simultaneous Sorption

AbstractBiomass of algae is a very potent adsorbent for absorbing aqueous waste containing heavy metals and organic dyes. This study purposes to confirm the ability of adsorbents from green algae Nannochloropsis sp. modified with silica (ASN) and followed by coating magnetite particles (ASN-MPs) to absorb simultaneously the mixture of Methylene Blue (ME) and Cu(II) cations in aqueous solution. Simultaneous sorption of ME and Cu(II) cations to ASN and ASN-MPs was carried out by the batch method with the interaction pH condition 7, contact time 90 min, and initial concentrations of ME and Cu(II) cations (0.1–1.0 mM). Based on adsorption data, Cu(II) cations have a greater adsorption rate and capacity (qm) compared to ME at the same contact time and initial concentration. The adsorption capacity (qm) values of the bi-component ME and Cu(II) cation mixture in ASN and ASN-MPs were 1.39 × 10− 1 and 5.32 × 10− 1 mmol g− 1, respectively, with the binary Langmuir adsorption isotherm constant for Cu(II) cations greater than ME. Modified adsorbent from algae Nannochloropsis sp. with silica matrix and magnetite particle coating is an adsorbent that has a high effectiveness in the collective sorption of ME and Cu(II) cations. Therefore, these adsorbents can be used for the adsorption of cation mixtures of heavy metals and organic dyes that are cationic in solution.

scholarly journals Fluorescing Layered Double Hydroxides as Tracer Materials for Particle Injection during Subsurface Water Remediation

2020 ◽  
Vol 4 (3) ◽  
pp. 53
Author(s):  
Karen Maria Dietmann ◽  
Tobias Linke ◽  
Markus Reischer ◽  
Vicente Rives
Keyword(s):  
Layered Double Hydroxides ◽  
Chlorinated Solvents ◽  
Cost Effective ◽  
Water Remediation ◽  
Subsurface Water ◽  
Particle Injection ◽  
Global Issue ◽  
Cost Effective Method ◽  
Co Precipitation ◽  
Double Hydroxides

Nowadays, the contamination of groundwater and soils by highly hazardous and toxic chlorinated solvents is a global issue. Over the past years, different remediation strategies have been developed, involving injection of reactive solutions and/or particles. However, a major difficulty is the monitoring of injected particles during the injection and after secondary mobilisation by groundwater flow. This study is focussed on the development of directly traceable particles by combining fluorescein with Layered Double Hydroxides (LDHs). We present here the facile and easily tuneable synthesis of fluorescing LDHs (Fluo-LDH) via co-precipitation under supersaturation conditions. Their ability to mimic particle sizes of previously studied reactive LDHs, which proved to be able to adsorb or degrade chlorinated organic solvents from aqueous solutions, was investigated as well. Tests using a novel Optical Image Profiler (OIP) confirmed that the fluorescent LDHs can be easily detected with this tool. Even LDHs with the lowest amount of fluorescent dye were detectable. Together with the use of an OIP, which is capable of exciting the fluorescent material and collecting real-time pictures, this can provide a new, efficient, and cost-effective method for in situ tracing of injected particles in the subsurface.

Sign in / Sign up

Export Citation Format

Share Document