scholarly journals Legacy and Emerging Pollutants in an Urban River Stretch and Effects on the Bacterioplankton Community

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3402
Author(s):  
Andrea Visca ◽  
Anna Barra Caracciolo ◽  
Paola Grenni ◽  
Ludovica Rolando ◽  
Livia Mariani ◽  
...  
Keyword(s):  
Treatment Plant ◽  
Principal Component ◽  
Contaminated Site ◽  
Antibiotic Resistant ◽  
Bacterioplankton Community ◽  
River Contamination ◽  
River Stretch ◽  
Emerging Compounds ◽  
Polycyclic Aromatic ◽  
The City

River contamination is due to a chemical mixture of point and diffuse pollution, which can compromise water quality. Polycyclic Aromatic Hydrocarbons (PAHs) and emerging compounds such as pharmaceuticals and antibiotics are frequently found in rivers flowing through big cities. This work evaluated the presence of fifteen priority PAHs, eight pharmaceuticals including the antibiotics ciprofloxacin (CIP) and sulfamethoxazole (SMX), together with their main antibiotic resistant genes (ARGs) and the structure of the natural bacterioplankton community, in an urbanized stretch of the river Danube. SMX and diclofenac were the most abundant chemicals found (up to 20 ng/L). ARGs were also found to be detected as ubiquitous contaminants. A principal component analysis of the overall microbiological and chemical data revealed which contaminants were correlated with the presence of certain bacterial groups. The highest concentrations of naphthalene were associated with Deltaproteobacteria and intI1 gene. Overall, the most contaminated site was inside the city and located immediately downstream of a wastewater treatment plant. However, both the sampling points before the river reached the city and in its southern suburban area were still affected by emerging and legacy contamination. The diffuse presence of antibiotics and ARGs causes particular concern because the river water is used for drinking purposes.

Characterization of Polycyclic Aromatic Hydrocarbon Profiles by Multivariate Statistical Analysis

2013 ◽  
pp. 102-116
Author(s):  
D. J. Marino ◽  
E. A. Castro ◽  
L. Massolo ◽  
A. Mueller ◽  
O. Herbarth ◽  
...  
Keyword(s):  
Statistical Analysis ◽  
Principal Component ◽  
Emission Sources ◽  
Multivariate Statistical ◽  
Data Set ◽  
Polycyclic Aromatic ◽  
The City ◽  
Sampling Times ◽  
Sample Identity

In the present study, statistical methods based on multivariate analyses such as the Descriptive Discriminant Analysis (DDA) and Principal Component Analysis (PCA) were applied to determine relationships between particle sizes and the composition of the associated semi-volatile compounds, in addition to evaluating these observations in relation to the emission sources, study areas, sampling campaigns and season. Results from the DDA showed that the PAHs distributions give the best discrimination capacity within the data set, whereas the PAH distribution in intermediate particle fractions incorporates noise in the statistical analysis. The PCA was useful in identifying the main emission sources in each study area. It showed that in the city of La Plata the most important pollution sources are traffic emissions and the industrial activity associated with oil and petrochemical plants. In Leipzig, the main sources are those associated with traffic and also a power plant. The combined PCA and DDA methods applied to PAH distributions is a valuable tool in characterizing types of emissions burdens and also in obtaining a differentiation of sample identity according to study areas and sampling times.

scholarly journals Identification of emission sources of particle-bound polycyclic aromatic hydrocarbons in the vicinity of the industrial zone of the city of Novi Sad

2013 ◽  
Vol 67 (2) ◽  
pp. 337-348 ◽  
Author(s):  
Natasa Jovcic ◽  
Jelena Radonic ◽  
Maja Turk-Sekulic ◽  
Mirjana Vojinovic-Miloradov ◽  
Srdjan Popov
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Heavy Traffic ◽  
Principal Component ◽  
Ambient Air ◽  
Emission Sources ◽  
Industrial Zone ◽  
Polycyclic Aromatic ◽  
Novi Sad ◽  
The City

Data on polycyclic aromatic hydrocarbons (PAHs) in ambient air accessed at selected locations in the vicinity of the industrial zone of the city of Novi Sad, Serbia, have been presented and analyzed in order to determine seasonal and spatial variations and to identify emission sources of particle-bound PAHs. Previous studies have demonstrated that the major contributors of PAHs in urban areas are the emissions from vehicle exhaust, and emissions releases from industrial processes like aluminium production, creosote and wood preservation, waste incineration, cement manufacture, petrochemical and related industries, commercial heat/power production etc. The sampling campaigns have been conducted at three sampling sites, during the two 14-day periods. The first site was situated near industrial area, with a refinery, power plant and heavy-traffic road in the vicinity. The second site was located nearby the heavy traffic area, especially busy during the rush hour. The third site was residential district. Summer sampling period lasted from June 26th to July 10th 2008, while sampling of ambient air during the winter was undertaken from January 22nd to February 5th 2009. Eighty-four (84) air samples were collected using a high volume air sampler TCR Tecora H0649010/ECHO. 16 US EPA polycyclic aromatic hydrocarbons were determined in all samples using a gas chromatographer with a mass spectrometer as a detector (Shimatzu MDGC/GCMS-2010). The total average concentrations of PAHs ranged from 1.21 to 1.77 ng/m3 during the summer period and from 6.31 to 7.25 ng/m3 in the winter. Various techniques, including diagnostic ratio (DR) and principal component analysis (PCA), have been used to define and evaluate potential emission sources of PAHs. Diagnostic ratio analysis indicated that vehicles, diesel or/and gasoline, industrial and combustion emissions were sources of PAHs in the vicinity of the industrial zone. Additionally, principal component analysis was used to constrain the potential sources. The results showed that vehicles are the predominant source of particle-bound PAHs during the whole year, and stationary sources (thermal power and heating plant, oil refinery, individual furnaces) during the winter period.

Characterization of Polycyclic Aromatic Hydrocarbon Profiles by Multivariate Statistical Analysis

2011 ◽  
Vol 1 (2) ◽  
pp. 1-14
Author(s):  
D. J. Marino ◽  
E. A. Castro ◽  
L. Massolo ◽  
A. Mueller ◽  
O. Herbarth ◽  
...  
Keyword(s):  
Statistical Analysis ◽  
Principal Component ◽  
Emission Sources ◽  
Multivariate Statistical ◽  
Data Set ◽  
Polycyclic Aromatic ◽  
The City ◽  
Sampling Times ◽  
Sample Identity

In the present study, statistical methods based on multivariate analyses such as the Descriptive Discriminant Analysis (DDA) and Principal Component Analysis (PCA) were applied to determine relationships between particle sizes and the composition of the associated semi-volatile compounds, in addition to evaluating these observations in relation to the emission sources, study areas, sampling campaigns and season. Results from the DDA showed that the PAHs distributions give the best discrimination capacity within the data set, whereas the PAH distribution in intermediate particle fractions incorporates noise in the statistical analysis. The PCA was useful in identifying the main emission sources in each study area. It showed that in the city of La Plata the most important pollution sources are traffic emissions and the industrial activity associated with oil and petrochemical plants. In Leipzig, the main sources are those associated with traffic and also a power plant. The combined PCA and DDA methods applied to PAH distributions is a valuable tool in characterizing types of emissions burdens and also in obtaining a differentiation of sample identity according to study areas and sampling times.

scholarly journals Evaluation of Sources and Ecological Risk of PAHs in Different Layers of Soil and Groundwater

2020 ◽  
Author(s):  
Predrag Ilić ◽  
Dragana Nešković Markić ◽  
Ljiljana Stojanović Bjelić
Keyword(s):  
Ecological Risk ◽  
Soil Depth ◽  
Principal Component ◽  
Mean Value ◽  
Industrial Complex ◽  
Research Subjects ◽  
Mean Values ◽  
Polycyclic Aromatic ◽  
Banja Luka ◽  
The City

Research subjects of this study are four representative locations in the industrial complex, in the city of Banja Luka, Republic of Srpska, Bosnia and Herzegovina. 16 polycyclic aromatic hydrocarbons (PAHs) (∑16PAHs), humus and pH were determined. The main objective of the paper is to determine the concentration levels, to assess the probable sources of PAHs contamination in soil and groundwater and to determine the ecological risk. The ∑16PAHs in soil (at depths of 30 cm, 100 cm, 200 cm, 300 cm and 400 cm) ranged from 0.99 to 2.24 mg/kg, from 0.34 to 0.46, from 0.24 to 0.32, from 0.13 to 0.27 and from 0.13 to 0.47, with mean values of 1.70 mg/kg, 0.40 mg/kg, 0.28 mg/kg, 0.20 mg/kg and 0.26 mg/kg, respectively. The ∑16PAHs in groundwater ranged from 0.23 to 4.50 mg/m3, with a mean value of 1.42 mg/m3. Surface soil and groundwater are heavily contaminated. All values of ∑PAHs in soil layers were lower in the depths of the soil. Factor analysis indicates three sources of contamination, i.e. principal component (PC) PC1 (pyrogenic), PC2 (petrogenic) and PC3 (biomass), with 52.39%, 26.14% and 8.46% of the total variance, respectively. ∑PAH and PAHs indicate high ecological risk for most PAHs, which decreases with soil depth.

Leading the City of Baltimore into the 21st Century: Flexible Treatment Solutions and Integrated Raw Water Management

2010 ◽  
Vol 5 (4) ◽  
Author(s):  
J. L. Manuszak ◽  
M. MacPhee ◽  
S. Liskovich ◽  
L. Feldsher
Keyword(s):  
Water Management ◽  
Water Quality ◽  
Water Supply ◽  
Conceptual Design ◽  
Membrane Filtration ◽  
Treatment Plant ◽  
Low Pressure ◽  
Management Tool ◽  
Raw Water ◽  
The City

The City of Baltimore, Maryland is one of many US cities faced with challenges related to increasing potable water demands, diminishing fresh water supplies, and aging infrastructure. To address these challenges, the City recently undertook a $7M study to evaluate water supply and treatment alternatives and develop the conceptual design for a new 120 million gallon per day (MGD) water treatment plant. As part of this study, an innovative raw water management tool was constructed to help model source water availability and predicted water quality based on integration of a new and more challenging surface water supply. A rigorous decision-making approach was then used to screen and select appropriate treatment processes. Short-listed treatment strategies were demonstrated through a year-long pilot study, and process design criteria were collected in order to assess capital and operational costs for the full-scale plant. Ultimately the City chose a treatment scheme that includes low-pressure membrane filtration and post-filter GAC adsorption, allowing for consistent finished water quality irrespective of which raw water supply is being used. The conceptual design includes several progressive concepts, which will: 1) alleviate treatment limitations at the City's existing plants by providing additional pre-clarification facilities at the new plant; and 2) take advantage of site conditions to design and operate the submerged membrane system by gravity-induced siphon, saving the City significant capital and operations and maintenance (O&M) costs. Once completed, the new Fullerton Water Filtration Plant (WFP) will be the largest low-pressure membrane plant in North America, and the largest gravity-siphon design in the world.

The Implementation of Biological Phosphorus and Nitrogen Removal with the Bio-Denipho Process on a 265,000 PE Treatment Plant

1992 ◽  
Vol 25 (4-5) ◽  
pp. 161-168 ◽  
Author(s):  
J. Einfeldt
Keyword(s):  
Nitrogen Removal ◽  
Treatment Plant ◽  
First Year ◽  
In Series ◽  
Design Loads ◽  
Last Stage ◽  
Two Stages ◽  
The City ◽  
Biological Phosphorus

A process, called Bio-Denipho, for combined biological phosphorus and nitrogen removal in a combination of an anaerobic tank and two oxidation ditches is described. In this process the anaerobic tank consisting of three sections working in series is followed by two oxidation ditches. These too are working in series, but with both inlet to and outlet from the tanks changing in a cycle. The Bio-Denipho process is described specifically for the process itself and as a case study for the implementation of the process on a 265,000 pe wastewater treatment plant for the city of Aalborg in Denmark. The plant was designed and erected in two stages and the last stage was inaugurated October 31,1989. Lay-out and functions for the plant is described and design loads, plan lay-out and tank volumes are given in this paper together with performance data for the first year in operation.

Two-stage chemical-biological treatment at Thessaloniki greater area WWTP - experiences and potentials

1995 ◽  
Vol 32 (9-10) ◽  
pp. 75-84 ◽  
Author(s):  
A. D. Andreadakis ◽  
G. H. Kristensen ◽  
A. Papadopoulos ◽  
C. Oikonomopoulos
Keyword(s):  
Biological Treatment ◽  
Treatment Plant ◽  
Cost Effective ◽  
Primary Treatment ◽  
Effective Control ◽  
Two Stage ◽  
Effluent Quality ◽  
Filamentous Microorganisms ◽  
Sludge Settling ◽  
The City

The wastewater from the city of Thessaloniki is discharged without treatment to the nearby inner part of the Thessaloniki Gulf. The existing, since 1989, treatment plant offers only primary treatment and did not operate since the expected effluent quality is not suitable for safe disposal to the available recipients. Upgrading of the plant for advanced biological treatment, including seasonal nitrogen removal, is due from 1995. In the mean time, after minor modifications completed in February 1992, the existing plant was put into operation as a two-stage chemical-biological treatment plant for 40 000 m3 d−1, which corresponds to about 35% of the total sewage flow. The operational results obtained during the two years operation period are presented and evaluated. All sewage and sludge treatment units of the plant perform better than expected, with the exception of the poor sludge settling characteristics, due to severe and persistent bulking caused by excessive growth of filamentous microorganisms, particularly M. Parvicella. Effective control of the bulking problem could lead to more cost-effective operation and increased influent flows.

scholarly journals Grill Workers Exposure to Polycyclic Aromatic Hydrocarbons: Levels and Excretion Profiles of the Urinary Biomarkers

2020 ◽  
Vol 18 (1) ◽  
pp. 230
Author(s):  
Marta Oliveira ◽  
Sílvia Capelas ◽  
Cristina Delerue-Matos ◽  
Simone Morais
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
High Performance ◽  
Principal Component ◽  
Fold Increase ◽  
Urinary Biomarkers ◽  
Analysis Model ◽  
Exposed Workers ◽  
Polycyclic Aromatic ◽  
The Impact

Grilling activities release large amounts of hazardous pollutants, but information on restaurant grill workers’ exposure to polycyclic aromatic hydrocarbons (PAHs) is almost inexistent. This study assessed the impact of grilling emissions on total workers’ exposure to PAHs by evaluating the concentrations of six urinary biomarkers of exposure (OHPAHs): naphthalene, acenaphthene, fluorene, phenanthrene, pyrene, and benzo(a)pyrene. Individual levels and excretion profiles of urinary OHPAHs were determined during working and nonworking periods. Urinary OHPAHs were quantified by high-performance liquid-chromatography with fluorescence detection. Levels of total OHPAHs (∑OHPAHs) were significantly increased (about nine times; p ≤ 0.001) during working comparatively with nonworking days. Urinary 1-hydroxynaphthalene + 1-hydroxyacenapthene and 2-hydroxyfluorene presented the highest increments (ca. 23- and 6-fold increase, respectively), followed by 1-hydroxyphenanthrene (ca. 2.3 times) and 1-hydroxypyrene (ca. 1.8 times). Additionally, 1-hydroxypyrene levels were higher than the benchmark, 0.5 µmol/mol creatinine, in 5% of exposed workers. Moreover, 3-hydroxybenzo(a)pyrene, biomarker of exposure to carcinogenic PAHs, was detected in 13% of exposed workers. Individual excretion profiles showed a cumulative increase in ∑OHPAHs during consecutive working days. A principal component analysis model partially discriminated workers’ exposure during working and nonworking periods showing the impact of grilling activities. Urinary OHPAHs were increased in grill workers during working days.

scholarly journals Antibiotic-Resistant Bacteria in Clams—A Study on Mussels in the River Rhine

Antibiotics ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 571
Author(s):  
Nicole Zacharias ◽  
Iris Löckener ◽  
Sarah M. Essert ◽  
Esther Sib ◽  
Gabriele Bierbaum ◽  
...  
Keyword(s):  
Bacterial Infections ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Multidrug Resistant ◽  
Resistant Bacteria ◽  
River Rhine ◽  
Antibiotic Resistant Bacteria ◽  
Surrounding Water ◽  
Antibiotic Resistant

Bacterial infections have been treated effectively by antibiotics since the discovery of penicillin in 1928. A worldwide increase in the use of antibiotics led to the emergence of antibiotic resistant strains in almost all bacterial pathogens, which complicates the treatment of infectious diseases. Antibiotic-resistant bacteria play an important role in increasing the risk associated with the usage of surface waters (e.g., irrigation, recreation) and the spread of the resistance genes. Many studies show that important pathogenic antibiotic-resistant bacteria can enter the environment by the discharge of sewage treatment plants and combined sewage overflow events. Mussels have successfully been used as bio-indicators of heavy metals, chemicals and parasites; they may also be efficient bio-indicators for viruses and bacteria. In this study an influence of the discharge of a sewage treatment plant could be shown in regard to the presence of E. coli in higher concentrations in the mussels downstream the treatment plant. Antibiotic-resistant bacteria, resistant against one or two classes of antibiotics and relevance for human health could be detected in the mussels at different sampling sites of the river Rhine. No multidrug-resistant bacteria could be isolated from the mussels, although they were found in samples of the surrounding water body.

scholarly journals Persulfate mediated solar photo-Fenton aiming at wastewater treatment plant effluent improvement at neutral PH: emerging contaminant removal, disinfection, and elimination of antibiotic-resistant bacteria

2021 ◽  
Author(s):  
Maria Clara V. M. Starling ◽  
Elizângela P. Costa ◽  
Felipe A. Souza ◽  
Elayne C. Machado ◽  
Juliana Calábria de Araujo ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Wastewater Treatment Plant ◽  
Treatment Plant ◽  
Resistant Bacteria ◽  
Antibiotic Resistant Bacteria ◽  
Antibiotic Resistant ◽  
E Coli ◽  
Effluent Quality ◽  
Neutral Ph ◽  
Wastewater Treatment Plant Effluent

AbstractThis work investigated an innovative alternative to improve municipal wastewater treatment plant effluent (MWWTP effluent) quality aiming at the removal of contaminants of emerging concern (caffeine, carbendazim, and losartan potassium), and antibiotic-resistant bacteria (ARB), as well as disinfection (E. coli). Persulfate was used as an alternative oxidant in the solar photo-Fenton process (solar/Fe/S2O82−) due to its greater stability in the presence of matrix components. The efficiency of solar/Fe/S2O82− at neutral pH using intermittent iron additions is unprecedented in the literature. At first, solar/Fe/S2O82− was performed in a solar simulator (30 W m−2) leading to more than 60% removal of CECs, and the intermittent iron addition strategy was proved effective. Then, solar/Fe/S2O82− and solar/Fe/H2O2 were compared in semi-pilot scale in a raceway pond reactor (RPR) and a cost analysis was performed. Solar/Fe/S2O82− showed higher efficiencies of removal of target CECs (55%), E. coli (3 log units), and ARB (3 to 4 log units) within 1.9 kJ L−1 of accumulated irradiation compared to solar/Fe/H2O2 (CECs, 49%; E. coli, 2 log units; ARB, 1 to 3 log units in 2.5 kJ L−1). None of the treatments generated acute toxicity upon Allivibrio fischeri. Lower total cost was obtained using S2O82− (0.6 € m−3) compared to H2O2 (1.2 € m−3). Therefore, the iron intermittent addition aligned to the use of persulfate is suitable for MWWTP effluent quality improvement at neutral pH.

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