scholarly journals Epoxidation of Palm Olein as Base Oil for Calcium Complex Bio Grease

2021 ◽  
Vol 4 (1) ◽  
pp. 22-30
Author(s):  
Erliza Hambali ◽  
Ni Nyoman Indah Adi Puspita
Keyword(s):  
Fatty Acids ◽  
Corrosion Resistance ◽  
Acetic Acid ◽  
Iodine Number ◽  
Palm Olein ◽  
Calcium Acetate ◽  
Peroxy Acid ◽  
Base Oil ◽  
Dropping Point ◽  
Color Density

The development of palm oil bio grease aimed to substitute grease made from petroleum with a material that is more environmentally friendly. The enhancement of bio grease characteristics can be performed by chemical synthesis. This research aimed to obtain best mole ratio of palm olein and H2O2 in the epoxidation process, and to analyze the physical characteristics of the bio grease products. This process used acetic acid and H2O2 with mole ratio variations of olein and H2O2 of 1: 3, 1: 6, and 1: 9. The mole ratio was selected based on the analysis of iodine and oxiran numbers, which was then processed into bio grease with the addition of calcium stearate and calcium acetate. Epoxidized olein with a mole ratio of olein and H2O2 of 1: 9 was selected because it achieved the highest average oxiran number (0.99), the lowest iodine number (33.09), and it was based on ANOVA and LSD tests. The higher the oxiran number, the more epoxide compounds produced. Low iodine number indicated low unsaturation in fatty acids. The peroxy acid used in the epoxidation process reacted with unsaturated compounds, so that the lower iodine number in the epoxidized olein produced more epoxide compounds. Bio grease had a light cream color, density of 0.96 g/cm3, viscosity of 31,280 mPa.s, unworked penetration of 438 (0.1 mm), worked penetration of 443 (0.1 mm), dropping point < 26°C, corrosion resistance of 2c and NLGI number 00.

scholarly journals Pilot Study of the Effects of Polyphenols from Chestnut Involucre on Methane Production, Volatile Fatty Acids, and Ammonia Concentration during In Vitro Rumen Fermentation

Animals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 108
Author(s):  
Yichong Wang ◽  
Sijiong Yu ◽  
Yang Li ◽  
Shuang Zhang ◽  
Xiaolong Qi ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Acetic Acid ◽  
Propionic Acid ◽  
Acid Content ◽  
Volatile Fatty Acids ◽  
Rumen Fermentation ◽  
Gas Production ◽  
Quadratic Response ◽  
In Vitro Rumen Fermentation

Nutritional strategies can be employed to mitigate greenhouse emissions from ruminants. This article investigates the effects of polyphenols extracted from the involucres of Castanea mollissima Blume (PICB) on in vitro rumen fermentation. Three healthy Angus bulls (350 ± 50 kg), with permanent rumen fistula, were used as the donors of rumen fluids. A basic diet was supplemented with five doses of PICB (0%–0.5% dry matter (DM)), replicated thrice for each dose. Volatile fatty acids (VFAs), ammonia nitrogen concentration (NH3-N), and methane (CH4) yield were measured after 24 h of in vitro fermentation, and gas production was monitored for 96 h. The trial was carried out over three runs. The results showed that the addition of PICB significantly reduced NH3-N (p < 0.05) compared to control. The 0.1%–0.4% PICB significantly decreased acetic acid content (p < 0.05). Addition of 0.2% and 0.3% PICB significantly increased the propionic acid content (p < 0.05) and reduced the acetic acid/propionic acid ratio, CH4 content, and yield (p < 0.05). A highly significant quadratic response was shown, with increasing PICB levels for all the parameters abovementioned (p < 0.01). The increases in PICB concentration resulted in a highly significant linear and quadratic response by 96-h dynamic fermentation parameters (p < 0.01). Our results indicate that 0.2% PICB had the best effect on in-vitro rumen fermentation efficiency and reduced greenhouse gas production.

scholarly journals The Combined Effects of Magnesium Oxide and Inulin on Intestinal Microbiota and Cecal Short-Chain Fatty Acids

Nutrients ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 152
Author(s):  
Kanako Omori ◽  
Hiroki Miyakawa ◽  
Aya Watanabe ◽  
Yuki Nakayama ◽  
Yijin Lyu ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Acetic Acid ◽  
Dietary Fiber ◽  
Magnesium Oxide ◽  
Acid Concentration ◽  
Short Chain Fatty Acids ◽  
Water Soluble ◽  
Short Chain ◽  
Acetic Acid Concentration ◽  
Chain Fatty Acids

Constipation is a common condition that occurs in many people worldwide. While magnesium oxide (MgO) is often used as the first-line drug for chronic constipation in Japan, dietary fiber intake is also recommended. Dietary fiber is fermented by microbiota to produce short-chain fatty acids (SCFAs). SCFAs are involved in regulating systemic physiological functions and circadian rhythm. We examined the effect of combining MgO and the water-soluble dietary fiber, inulin, on cecal SCFA concentration and microbiota in mice. We also examined the MgO administration timing effect on cecal SCFAs. The cecal SCFA concentrations were measured by gas chromatography, and the microbiota was determined using next-generation sequencing. Inulin intake decreased cecal pH and increased cecal SCFA concentrations while combining MgO increased the cecal pH lowered by inulin and decreased the cecal SCFA concentrations elevated by inulin. When inulin and MgO were combined, significant changes in the microbiota composition were observed compared with inulin alone. The MgO effect on the cecal acetic acid concentration was less when administered at ZT12 than at ZT0. In conclusion, this study suggests that MgO affects cecal SCFA and microbiota during inulin feeding, and the effect on acetic acid concentration is time-dependent.

Modifying egg fatty acid content by supplementation of laying hen diets with palm olein oil (POO)

2009 ◽  
Vol 2009 ◽  
pp. 212-212
Author(s):  
S J Hosseini Vashan ◽  
N Afzali ◽  
A Golian ◽  
M Malekaneh ◽  
A Allahressani
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Acid Content ◽  
Palm Olein ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Fatty Acid Content ◽  
Processing Plant ◽  
Optimum Level ◽  
Olein Oil

Palm oil is the most abundant of all oils produced globally. It is very high in saturated fatty acids specifically palmitic acid, but other fatty acids (monounsaturated (MUFA) and polyunsaturated) are presented at low concentrations. In the processing plant some high amount of oleic acid with some other unsaturated fatty acids are extracted and marketed as Palm olein oil, and used to reduce blood or egg cholesterol (Rievelles et al., 1994). The objective of this study was to determine the optimum level of dietary palm olein oil required to enrich the mono-unsaturated fatty acid content of yolk, egg cholesterol and antibody titre.

The voluntary intake of acetate by dairy cows given ammonium salts of short-chain fatty acids in their drinking water

1968 ◽  
Vol 10 (4) ◽  
pp. 473-481 ◽  
Author(s):  
P. Jackson ◽  
J. Hodgson ◽  
J. A. F. Rook
Keyword(s):  
Fatty Acids ◽  
Drinking Water ◽  
Acetic Acid ◽  
Water Intake ◽  
Daily Intake ◽  
Short Chain Fatty Acids ◽  
Sole Source ◽  
Ammonium Salts ◽  
Short Chain ◽  
Chain Fatty Acids

A solution of ammonium salts of a mixture of short-chain fatty acids (mainly acetic acid) was added to the sole source of drinking water of 10 lactating Jersey cows. There was considerable variation in the concentration of salts tolerated without depression in water intake. Some animals refused solution offered at a concentration of 0·5% (w/w) whereas one animal accepted solution at a concentration of 8% (w/w) and had a mean daily intake of salts equivalent to 836 g acetic acid.2. Adjustment of the pH of the drinking solution to 6·5–7·5 increased the tolerance to the salts solution of animals which showed a low tolerance to the unadjusted solution. A mean daily intake equivalent to 480 g acetic acid was achieved without a significant depression of water intake. Replacement of 50 % of the ammonium ions by calcium increased the intake of salts by some cows but two out of eight refused the solution at a concentration of 0·5% (w/w).3. The addition of saccharine, vanilla or aniseed to a solution of the ammonium salts gave little or no improvement in acetate intake but sodium cyclamate, ethyl acetate or molasses reduced the variability between animals in their tolerance to the solution and increased the mean intake of salts. With an addition of molasses, which gave the most marked response, there was a mean daily intake of salts equivalent to 495±26 g acetic acid.

The effect of the microbial flora on the flavour and free fatty acid composition of cheddar cheese

1967 ◽  
Vol 34 (3) ◽  
pp. 257-272 ◽  
Author(s):  
B. Reiter ◽  
T. F. Fryer ◽  
A. Pickering ◽  
Helen R. Chapman ◽  
R. C. Lawrence ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Acetic Acid ◽  
Fatty Acid Composition ◽  
Milk Fat ◽  
Gluconic Acid ◽  
Bacterial Flora ◽  
Single Strain ◽  
Acid Lactone ◽  
Aseptic Conditions ◽  
Higher Fatty Acids

SummaryComparisons were made of the flavour, free fatty acids and bacterial flora of commercial cheese made at different factories and experimental cheese made under aseptic conditions: (i) with δ-gluconic acid lactone instead of starter, (ii) with starter only, (iii) with starter and added floras derived from the curd of the commercial cheeses (reference flora cheeses).Comparison of the bacterial flora of commercial and reference flora cheeses showed that replication of organisms was better with some reference floras than with others. In all the cheeses the lactobacilli increased in numbers during maturation, whilst other groups of organisms died out.The amount of acetic acid present was influenced by the starter and by the lactobacilli. Single-strain starters produced some acetic acid, most of which was lost in the whey; commercial starters produced considerably more, due to the presence in them of Streptococcus diacetilactis. Later in maturation lactobacilli increased the acetic acid content, a greater increase being observed with homo-than with heterofermentative strains.The initial levels of butyric and higher fatty acids in the milk varied with source of the milk and with the season, summer milk having higher levels than winter milk. During cheese-making a slight increase of these acids occurred in every cheese made with starter and a further small increase occurred during ripening. However, there was no increase in the content of these acids in the cheese made with δ-gluconic acid lactone, indicating that lactic acid bacteria were weakly hydrolysing the milk fat.Flavour trials showed that Cheddar flavour was present not only in the reference flora and commercial cheese, but also in the cheese made with starter only. Different starters produced different intensities of flavour; one strain produced an intense fruity off-flavour. Cheeses made with δ-gluconic acid lactone were devoid of cheese flavour.

FLAVOUR REVERSION IN HYDROGENATED LINSEED OIL: I. THE PRODUCTION OF AN ISOMER OF LINOLEIC ACID FROM LINOLENIC ACID

1944 ◽  
Vol 22f (6) ◽  
pp. 191-198 ◽  
Author(s):  
H. W. Lemon
Keyword(s):  
Fatty Acids ◽  
Linoleic Acid ◽  
High Temperature ◽  
Iodine Number ◽  
Spectral Method ◽  
Linolenic Acid ◽  
Linseed Oil ◽  
Naturally Occurring ◽  
Total Fatty Acids ◽  
Isomeric Acid

Linseed oil that has been hydrogenated to a plastic consistency is subject to a type of deterioration termed "flavour reversion" when heated to temperatures used in baking or frying. Investigation of the course of hydrogenation of linseed oil by the spectral method of Mitchell, Kraybill, and Zscheile (11) has indicated that linolenic acid is converted to an isomeric linoleic acid; this acid differs from naturally occurring linoleic acid in that the double bonds are in such positions that diene conjugation is not produced by high-temperature saponification. In a typical hydrogenation, the concentration of the isomeric acid increased to a maximum, at about iodine number 120, of 18% of the total fatty acids, and at iodine number 80, at which point the plasticity was similar to that of a commercial shortening, the concentration of the isomer was 13%. Evidence is presented that the isomeric linoleic acid in partially hydrogenated linseed oil is responsible for the unpleasant flavour that develops when the oil is heated.

DUST-BORNE TRACE GASES AND ODORANTS The analysis of dust-borne trace gases requires their i-solation from the dust particles. Procedures for the isolation and characterization of trace gases and odorants in the dust from pig houses are given by SCHAEFER et al. (29), HAMMOND et al.(30) and TRAVIS and ELLIOTT (31). Alcoholic solvents were found to be effective for the extraction of volatile fatty ac­ ids and phenols from the dust of hen (32) and pig houses (33), (34). Today, gas chromatography is usually used for the sepa­ ration and identification of the trace gases. Table IV gives a literature review of compounds identified in the dust of pig houses. There are only very few reports on investigations on the dust from hen houses (32). Most of the odours coming from livestock production units are associated with the biological degradation of the animal wastes (35), the feed and the body odour of the animals (1). Volatile fatty acids and phenolic compounds were found to con­ tribute mostly to the strong, typical odour of animal houses by the help of sensory evaluations parallel to the chemical analysis (29),(30). Table V gives quantitative values of volatile fatty acids and phenolic/indolic compounds found in the aerosol phase and in settled dust of piggeries, respectively. The results from the aerosol phase coincide, particularly as far as acetic acid is concerned. For the investigations of the settled dust the coefficients of variation (CV) and the relative values (%) characterizing the percentage of the single compounds as part of the total amount are quoted. The values are corrected with the dry matter content of the dust. Main components are acetic acid and p-cresol, respectively. Table VI compares results from air, dust and slurry in­ vestigations on VFA and phenolic/indolic compounds in piggeries. Relative values are used. When comparing the results derived from investigations on dust, air or slurry it is necessary to use relative values because of the different dimensions, for experience shows that in spite of large quantitative differ­ ences between two samples within the group of carboxylic acids and within the group of phenolic/indolic compounds the propor­ tions of the components remain rather stable (36). In the group of VFA acetic acid is the main component in air, dust, and slurry followed by propionic and butyric acid. The other three acids amount to less than 25%. In the group of phenols/ indoles p-cresol is the main component in the four cited in­ vestigations. However, it seems that straw bedding can reduce the p-cresol content; in this case phenol is the main compo­ nent , i nstead (37 ). 4. EMISSION OF DUST-BORNE VFA AND PHENOLS/INDOLES FROM PIGGERIES The investigations of dust from piggeries show that both VFA and phenols/indoles are present in a considerable amount. However, compared to the air-borne emissions calculated on the base of the results of LOGTENBERG and STORK (38) less than the tenth part (1/10) of phenols/indoles and about the hundredth part (1/100) of VFA are emitted by the dust, only. Table VII compares the dust-borne and air-borne emissions of VFA and

1986 ◽  
pp. 337-337
Keyword(s):  
Fatty Acids ◽  
Acetic Acid ◽  
Volatile Fatty Acids ◽  
Trace Gases ◽  
Matter Content ◽  
Biological Degradation ◽  
Indolic Compounds ◽  
Settled Dust ◽  
Main Components ◽  
Main Component

DISTRIBUTION OF ENERGY SOURCE EXPENDITURE IN WARM- AND COLD-EXPOSED SHEEP

1984 ◽  
Vol 64 (5) ◽  
pp. 265-266 ◽  
Author(s):  
TSUNEYUKI TSUDA ◽  
YOSHIO SHOJI ◽  
KAICHI AMBO ◽  
MASANORI FUJITA ◽  
KATSUNORI SUNAGAWA
Keyword(s):  
Energy Source ◽  
Fatty Acids ◽  
Acetic Acid ◽  
Free Fatty Acids ◽  
Key Words ◽  
Heat Production ◽  
Total Heat

The heat production of sheep exposed to 0 °C increased 2.14 times compared with that at 20 °C. At 0 °C, the percentage of heat derived from oxidation of acetic acid decreased but that of free fatty acids increased remarkably. The substances which comprise 50% of total heat production remained unknown. Key words: Sheep, cold, heat production, energy source

IMPROVEMENT OF THE BIOLOGICAL EFFECTIVENESS OF FAT FROM THE LIVER OF THE BLACK SEA SHARK-KATRAN

2021 ◽  
Author(s):  
Е.Е. ИВАНОВА ◽  
Е.А. ДУБИНЕЦ ◽  
А.Л. БОЧАРОВА-ЛЕСКИНА
Keyword(s):  
Fatty Acids ◽  
Iodine Number ◽  
Black Sea ◽  
Liquid Fraction ◽  
Saturated Fatty Acids ◽  
Biologically Active ◽  
The Black Sea ◽  
Omega 3 ◽  
Biological Effectiveness

Для стабилизации показателя биологической эффективности исследована возможность повышения количества полиненасыщенных жирных кислот (ПНЖК) за счет снижения количества насыщенных жирных кислот (НЖК) в жирнокислотном составе жира из печени черноморской акулы-катрана в летний период вылова (с мая по октябрь). С целью повышения содержания омега-3 ПНЖК в продукте применен способ винтеризации. Кристаллизацию жира из печени акулы-катрана проводили в специальном охладителе при температуре от 0 до –5°С. Во время охлаждения жир медленно перемешивали (скорость вращения мешалки 20–25 об/мин) для равномерного охлаждения по всему объему. Полная кристаллизация НЖК при этих условиях проходила за 5–6 ч. Охлажденный жир немедленно направляли на осадительную центрифугу. В качестве параметров оптимизации процесса были выбраны: качество жира – прозрачность при температуре 15°С и степень ненасыщенности – йодное число жира. Установлено, что факторами, существенно влияющими на йодное число и органолептические показатели жира, являются: температура охлажденного жира, продолжительность центрифугирования, число оборотов барабана центрифуги. Для моделирования значений йодного числа и органолептического показателя в области изменения указанных факторов применена схема полного факторного двухуровневого эксперимента, в результате которого определены натуральные значения факторов, отвечающие наилучшему значению показателя качества жира: температура охлаждения жира –4°С, продолжительность центрифугирования 30 мин, частота вращения барабана центрифуги 6000 об/мин. Общая ненасыщенность жидкой фракции возросла с 122,2–138,0 до 131,0–145,0% йодного числа жира. Полученный очищенный жир был прозрачен, имел светло-желтый цвет, низкие значения кислотного и перекисного чисел. Содержание ПНЖК в полученном продукте увеличилось на 10–30%. Содержание неомыляемых веществ в нем, в том числе биологически активных веществ алкилглицеролов, при этом не снизилось. Биологическая эффективность жира увеличилась с 0,6 до 0,9. To stabilize the increased biological effectiveness the possibility of increasing the amount of polyunsaturated fatty acids (PUFA) by reducing the amount of saturated fatty acids (SFA) in the fatty acid composition of fat from the liver of the black sea shark-katran in the summer fishing period (May – October) is investigated. With the aim of increasing the content of omega-3 PUFA in the product method of winterization was applied. Crystallization of fat from the liver of sharks-katran dogfish was conducted in a special chiller with temperature from 0 to –5°C. During cooling, the fat is slowly stirred (speed of rotation of the mixer 20–25 rpm) for uniform cooling throughout. Full crystallization of SFA under these conditions was held for 5–6 h. The cooled fat was immediately sent to precipitating in the centrifuge. Quality of fat – transparency at a temperature of 15°C and unsaturation – iodine number of fat was selected as the optimization parameters of the process. It is established that: the temperature of the refrigerated fat, the duration of centrifugation, the number of drum rotations of the centrifuge are factors that significantly affect the iodine number and the organoleptic indicators of fat. Scheme two-level full factorial experiment was applied for modeling the values of iodine number and organoleptic indicator in changing these factors. Natural values of factors corresponding to the best value of indicator of the quality of the fat: temperature of cooling fat –4°C, duration of centrifugation 30 min, and the speed of rotation of the drum centrifuge 6000 rpm were determined in the experiment. The result of this treatment, the total unsaturation of the liquid fraction increased from 122,2–138,0 up to 131,0–145,0% of iodine number. The purified obtained fat was transparent, had a light yellow color, low acid value and peroxide values. In the obtained product the content of PUFA increased by 10–30%. The content of unsaponifiables in it, including biologically active substances alkylglycerols, was not decreased. The biological effectiveness of fat increased from 0,6 to 0,9.

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