Mechanical and Thermal Properties of Polylactic Acid Filled Rice Straw

2015 ◽  
Vol 815 ◽  
pp. 34-38
Author(s):  
Nurul Hani Md Zubir ◽  
S.T. Sam ◽  
H. Kamarudin ◽  
S. Ragunathan ◽  
N.Z. Noriman ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polylactic Acid ◽  
Rice Straw ◽  
Natural Fiber ◽  
Mechanical And Thermal Properties ◽  
Elongation At Break ◽  
Fiber Loading ◽  
Biodegradable Composites ◽  
Roll Mill ◽  
Thermal Stability Of

Natural fiber reinforced polylactic acid based biocomposites are broadly considered by the researchers to compete with non-renewable petroleum based products. In this study, the biodegradable composites which are the polylactic acid, PLA and rice straw, RS were prepared by using heated two roll-mill at 180°C. Mechanical properties showed that the tensile strength and elongation at break, Eb decreased with the increasing of RS while the Young’s modulus had increased. The TGA results confirmed that thermal stability of PLA with RS composites decreased when the RS fiber loading increased.

scholarly journals Enhancement of Mechanical and Thermal Properties of Polylactic Acid/Polycaprolactone Blends by Hydrophilic Nanoclay

2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
Chern Chiet Eng ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Hidayah Ariffin ◽  
Wan Md. Zin Wan Yunus ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Polylactic Acid ◽  
Mechanical Analysis ◽  
Basal Spacing ◽  
Mechanical And Thermal Properties ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
The Matrix ◽  
Thermal Stability Of

The effects of hydrophilic nanoclay, Nanomer PGV, on mechanical properties of Polylactic Acid (PLA)/Polycaprolactone (PCL) blends were investigated and compared with hydrophobic clay, Montmorillonite K10. The PLA/PCL/clay composites were prepared by melt intercalation technique and the composites were characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Dynamic Mechanical Analysis (DMA), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). FTIR spectra indicated that formation of hydrogen bond between hydrophilic clay with the matrix. XRD results show that shifting of basal spacing when clay incorporated into polymer matrix. TEM micrographs reveal the formation of agglomerate in the composites. Based on mechanical properties results, addition of clay Nanomer PGV significantly enhances the flexibility of PLA/PCL blends about 136.26%. TGA showed that the presence of clay improve thermal stability of blends. DMA show the addition of clay increase storage modulus and the presence of clay Nanomer PGV slightly shift two Tg of blends become closer suggest that the presence of clay slightly compatibilizer the PLA/PCL blends. SEM micrographs revealed that presence of Nanomer PGV in blends influence the miscibility of the blends. The PLA/PCL blends become more homogeneous and consist of single phase morphology.

scholarly journals Preparation and Characterization of Durian Husk Fiber Filled Polylactic Acid Biocomposites

2018 ◽  
Vol 152 ◽  
pp. 02007 ◽  
Author(s):  
Man Chee Lee ◽  
Seong Chun Koay ◽  
Ming Yeng Chan ◽  
Ming Meng Pang ◽  
Pui May Chou ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Polylactic Acid ◽  
Natural Fiber ◽  
Fiber Content ◽  
Raw Material ◽  
Elongation At Break ◽  
Renewable Raw Material ◽  
The Cost ◽  
Thermal Stability Of

Polylactic acid (PLA) is biodegradable thermoplastic that made from renewable raw material, but its high cost limited the application. Thus, addition of natural fiber can be effectively reduced the cost of PLA. This research is utilised natural fiber extracted from durian husk to made PLA biocomposites. This paper is focus on the effect of fiber content on tensile and thermal properties of PLA/durian husk fiber (DHF) biocomposites. The results found that the tensile strength and modulus of this biocomposites increased with increase of fiber content, but the strength still lower compared to neat PLA. Then, the elongation at break of biocomposites was expected decreased at higher fiber content. The PLA/DHF biocomposites with 60 phr fiber content exhibited tensile strength of 11 MPa, but it is too brittle yet for any application. The addition of DHF caused an early thermal degradation on PLA biocomposites. Then, the thermal stability of PLA biocomposites was decreased with more fiber content.

Effects of Fiber Surface Treatment on Mechanical and Thermal Properties of Coir-MCC/Polylactic Acid Composites

2012 ◽  
Vol 488-489 ◽  
pp. 638-642 ◽  
Author(s):  
Tanawat Tayommai ◽  
Duangdao Aht-Ong
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Surface Treatment ◽  
Polylactic Acid ◽  
Natural Fiber ◽  
Fiber Surface ◽  
Mechanical And Thermal Properties ◽  
Coir Fibers ◽  
Twin Screw ◽  
Fiber Surface Treatment

Biodegradable plastic reinforced natural fiber composites are finding applications in many fields ranging from construction industry to food industry. The use of natural bio based fillers as reinforcements in composites has several advantages over inorganic fillers including lower density, renewability, and biodegradability. In this research, polylactic acid (PLA)/ microcrystalline cellulose (MCC) composites were investigated as a means to reduce the material cost and enhance the material properties. The coir fibers were used to prepare microcrystalline. Subsequently, the prepared MCC was treated with 3-amiopropyl triethoxysilane (APS) to improve interfacial adhesion between fiber and polymer matrix. Treated and untreated MCC were then mixed at 0-10 wt.% with PLA by twin-screw extruder and fabricated into test specimens by compression molding. The effects of MCC loading and surface treatment on morphology, mechanical properties, and thermal properties of PLA/MCC composites were investigated. The results showed that the PLA with 5 wt.% of MCC exhibited the best mechanical properties compared with all prepared composites. Thermal stability of PLA composites were decreased with increasing MCC content but it can be improved by treated the MCC with APS.

Effects of Multi-Walled Carbon Nanotubes (MWCNTS) on the Mechanical and Thermal Properties of Plasticized Polylactic Acid Nanocomposites

2013 ◽  
Vol 812 ◽  
pp. 181-186 ◽  
Author(s):  
Maizatulnisa Othman ◽  
Kok Hui Tan ◽  
Hashim Mohd Yusof ◽  
Khalid Halisanni ◽  
Ghazali Ruzaidi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Polylactic Acid ◽  
Flexural Properties ◽  
Mechanical And Thermal Properties ◽  
Dynamic Mechanical Analyzer ◽  
Roll Mill ◽  
Multi Walled Carbon Nanotube ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

A multi-walled carbon nanotube (MWCNT)/plasticized polylactic acid (PLA) composite was prepared using a two-roll mill set at 170°C and 50 rev/min. The material was characterized using dynamic mechanical analyzer (DMA). Characterization works include obtaining mechanical properties, such as tensile and flexural properties of the nanocomposites. Polyethylene glycol (PEG) at 6 wt% was used as the plasticizer for blending with the PLA. It was found that the tensile and flexural strengths of the nanocomposites increased up to 43.8 MPa and 81.4 MPa respectively with the addition of 0.15 wt% MWCNTs. The DMA results revealed that the storage modulus and the glass transition temperature (Tg) of the nanocomposites improved with the addition of 0.15 wt% CNTs, which was previously reduced by the incorporation of PEG.

scholarly journals Investigation the effect of Graphene on The Morphology, Mechanical and Thermal properties of PLA/PMMA Blends

2015 ◽  
Vol 37 ◽  
pp. 15 ◽  
Author(s):  
Azin Paydayesh ◽  
Ahmad Aref Azar ◽  
Azam Jalali Arani
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Thermal Analysis ◽  
Thermal Properties ◽  
Poly Lactic Acid ◽  
Mechanical And Thermal Properties ◽  
Elongation At Break ◽  
Blend Morphology ◽  
Pmma Blends ◽  
Thermal Stability Of

In this work, Poly Lactic Acid/Poly methyl Methacrylate (PLA/PMMA) blends in various compositions prepared and morphology and properties of these blends was investigated. Moreover, the effect of adding different amounts of Graphene Nanoplatelets (GNP) on the morphology of the blends (by SEM), the interaction of nanopalates with polymer phases (by FTIR) and its effect on the mechanical properties and thermal stability of the samples were examined. The results of the study showed that in different amounts of graphene, these plates were preferentially located in the polymer phases dissimilarly and thus, caused the change of the blend morphology. In addition, measuring the mechanical properties by tensile test and results of thermal analysis by TGA indicated the improvement of thermal stability, modulus and mechanical strength and reduction of the elongation at break of graphene containing blends with increasing the loading of GNP. The changing behavior of the mechanical and thermal properties was proportional to the Graphene localization in blend phases.

Tensile and Morphology Properties of Polylactic Acid/Treated Typha latifolia Composites

2013 ◽  
Vol 594-595 ◽  
pp. 775-779 ◽  
Author(s):  
Muthmirah Ibrahim ◽  
Jalilah Abd Jalil ◽  
Syarifah Nuraqmar Syed Mahamud ◽  
Daud Yusrina Mat ◽  
Salmah Husseinsyah ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Natural Fiber ◽  
Typha Latifolia ◽  
Tensile Modulus ◽  
Sem Analysis ◽  
Fiber Content ◽  
Elongation At Break ◽  
Roll Mill ◽  
Composite Samples ◽  
Scanning Electron

This paper is focused to investigate the effect of treated natural fiber (typha latifolia) content on tensile and morphology properties of polylactic acid (PLA)/treated typha latifolia (T-TyLa) composites. The composite was compounded using heated two roll mill and the composite samples were prepared through compression molding. Tensile test and scanning electron microscopy (SEM) analysis were carried out to study the properties of PLA/T-TyLa composites. The results showed that the tensile strength of PLA/T-TyLa composites was decreased for about 43% with initial addition of T-TyLa content. The tensile modulus of the composites was increased (23%-91%) with increasing of fiber content. However, increased in fiber content reduced the elongation at break for about 53%-67% of PLA/T-TyLa composites. The optimum increment was obtained at 30 wt% of fiber content. SEM results showed that fiber dispersion was better for PLA/T-TyLa composites at lower fiber content.

Mechanical Properties and Thermal Stability of TiO2 Nanofiller Reinforced Silicone Sealants

2016 ◽  
Vol 864 ◽  
pp. 23-27
Author(s):  
Ananda Manuela S. Mandalihan ◽  
Jaya L. Sitjar ◽  
Eduardo Magdaluyo Jr.
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Construction Materials ◽  
Mechanical And Thermal Properties ◽  
Glass Panel ◽  
Elongation At Break ◽  
Structural Applications ◽  
Modulus Of Resilience ◽  
Thermal Stability Of ◽  
Physical Crosslinking

Structural sealants are one of the most essential construction materials due to a rising demand of buildings having glass panel faćades. Silicones are the most preferred base component due to their excellent properties appropriate for structural applications. The effect of titanium dioxide (TiO2) nanofillers on the mechanical and thermal properties of commercially available silicone-based sealants was investigated. The incorporation of 1 wt% and 2 wt% of TiO2 has caused an increase on the elongation at break SSG4000E and SilPruf SCS2000N sealants while an increase on the modulus of resilience was observed at SilPruf SCS2000N with 1wt% TiO2. The elastic modulus was highest at 5 wt% TiO2 for all sealants. Swelling behavior decreased with increasing nanofiller due to the physical crosslinking effect, thus preventing the diffusion of the solvent into the material. Thermal stability also improved with the incorporation of 2 wt% TiO2 as observed in the increase of the onset temperature of decomposition.

scholarly journals Effect of Organic Modifier Types on the Physical–Mechanical Properties and Overall Migration of Post-Consumer Polypropylene/Clay Nanocomposites for Food Packaging

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1502
Author(s):  
Eliezer Velásquez ◽  
Sebastián Espinoza ◽  
Ximena Valenzuela ◽  
Luan Garrido ◽  
María José Galotto ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Food Packaging ◽  
Clay Nanocomposites ◽  
Organic Modifier ◽  
Thermal And Mechanical Properties ◽  
Chemical Safety ◽  
Elongation At Break ◽  
Fatty Food ◽  
Recycled Plastics ◽  
Thermal Stability Of

The deterioration of the physical–mechanical properties and loss of the chemical safety of plastics after consumption are topics of concern for food packaging applications. Incorporating nanoclays is an alternative to improve the performance of recycled plastics. However, properties and overall migration from polymer/clay nanocomposites to food require to be evaluated case-by-case. This work aimed to investigate the effect of organic modifier types of clays on the structural, thermal and mechanical properties and the overall migration of nanocomposites based on 50/50 virgin and recycled post-consumer polypropylene blend (VPP/RPP) and organoclays for food packaging applications. The clay with the most hydrophobic organic modifier caused higher thermal stability of the nanocomposites and greater intercalation of polypropylene between clay mineral layers but increased the overall migration to a fatty food simulant. This migration value was higher from the 50/50 VPP/RPP film than from VPP. Nonetheless, clays reduced the migration and even more when the clay had greater hydrophilicity because of lower interactions between the nanocomposite and the fatty simulant. Conversely, nanocomposites and VPP/RPP control films exhibited low migration values in the acid and non-acid food simulants. Regarding tensile parameters, elongation at break values of PP film significantly increased with RPP addition, but the incorporation of organoclays reduced its ductility to values closer to the VPP.

scholarly journals Heat Deflection Temperature (HDT) Properties of Polypropylene Composite Reinforced Cellulose Microfibrils of Oil Palm Empty Fruit Bunch and Frond

2020 ◽  
Vol 9 (1) ◽  
pp. 8-14
Author(s):  
Wida Banar Kusumaningrum ◽  
Sasa Sofyan Munawar
Keyword(s):  
Mechanical Properties ◽  
Oil Palm ◽  
Initial Temperature ◽  
Natural Fiber ◽  
Plastic Material ◽  
Synthetic Fiber ◽  
Cellulose Microfibrils ◽  
Normal Loading ◽  
Fiber Loading ◽  
Heat Deflection Temperature

Polypropylene composites reinforcing with natural fiber is potentially applied for automotive particularly on interior part design. Those kind of composites were contributed on renewable material, rapid rate biodegradation, and low cost of production compared to synthetic fiber. Furthermore, the mechanical properties including strenghtness, young modulus, and thermal stability have revealed good performance than glass fiber. Fiber which were fibrillated and have high aspect ratio that coresspond to diameter and lenght ratio of the fiber were noticed as enhancement factor for mechanical properties. Fiber fibrillation processing into microfibrillated cellulose (MFC) attempts for widening surface area of the fiber that improve polymer matrices compatibility. MFC from empty fruit bunches (EFB) and oil palm frond (FB) fibers were performed as pulp by mechanically and chemically treatments. Chemically treatment was conducted with bleach and unbleach procedure. Polypropylene with fiber was mixed using kneader, and injection for molding process. Manufacturing uses needs appropriate size presition, moderate lead time, and low defect. Heat deflection temperature (HDT) provide information for plastic material on indicating temperature condition effect to material deformation during normal loading. Material of origin, additive or filler size, and molding temperature were directly corelated to the HDT performance. Initial temperature of HDT exhibits different value for different kind of fillers and fiber treatments. PP/EFB composite by mechanical treatment gives high value of HDT compared to the fiber processing by chemical treatment both with bleach and unbleach process. Similar result have been performed in PP/FB composites related to initial temperature. PP/ EFB composite with 30% of fiber loading represent HDT in 149.4°C, and for PP/ FB composite with 30% fiber loading gives 150.7°C. By the addition of fiber loading could improve the HDT value of the composites.

scholarly journals Curing and mechanical properties of chlorosulphonated polyethylene rubber blends

2011 ◽  
Vol 17 (3) ◽  
pp. 315-321 ◽  
Author(s):  
Gordana Markovic ◽  
Vojislav Jovanovic ◽  
Suzana Samarzija-Jovanovic ◽  
Milena Marinovic-Cincovic ◽  
Jaroslava Budinski-Simendic
Keyword(s):  
Mechanical Properties ◽  
Crosslink Density ◽  
Hydraulic Press ◽  
Elongation At Break ◽  
Rubber Blends ◽  
Tensile Tester ◽  
Roll Mill ◽  
Cure Time ◽  
Chlorosulphonated Polyethylene ◽  
Scanning Electron

In this paper the curing and mechanical properties of two series of prepared blends, i.e., chlorosulphonated polyethylene (CSM)/isobutylene-co-isoprene (IIR) rubber blends and chlorosulphonated polyethylene (CSM)/chlorinated isobutylene-co-isoprene (CIIR) rubber blends were carried out. Blends were prepared using a two roll-mill at a temperature of 40-50?C. The curing was assessed by using a Monsanto Oscillating Disc Rheometer R-100. The process of vulcanization accelerated sulfur of pure rubbers and their blends was carried out in an electrically heated laboratory hydraulic press under a pressure of about 4 MPa and 160?. The stress-strain experiments were performed using tensile tester machine (Zwick 1425). Results indicate that the scorch time, ts2 and optimum cure time, tc90 increase with increasing CSM content in both blends. The values of modulus at 100% and at 300% elongation and tensile strength increases with increasing CSM content, whereas elongation at break shows a decreasing trend. The enhancement in mechanical properties was supported by data of crosslink density in these samples obtained from swelling measurement and scanning electron microscopy studies of the rubber blends fractured surfaces.

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